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By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By Thomas M. Barczak

This U.S. Bureau of Mines report describes methods to enhance the capacity, stiffness, and timber utilization of wood crib supports. Since stiffer supports minimize strata deflections that contribute to roof instability, efforts to maximize crib stiffness while maintaining stability through a wide displacement range should be a design priority. The stiffness and capacity of conventional crib designs, employing alternating layers of wood timbers that are loaded perpendicular to the grain, can be increased by increasing the interlayer contact area or by using higher strength wood. Contact area can be increased by using wider timbers or employing more timbers per layer. Concepts that provide parallel-to-the-grain timber loading will provide substantial increases in crib stiffness and capacity. Two concepts that utilize this principle are examined: (1) an original South African design that constructs wood cribs from preformed layers (mats) of timber where short blocks are oriented vertically between horizontal slabs; and (2) a design that employs full lengths of timber placed vertically in the interior of a conventional crib structure. These designs also provide more efficient timber utilization by providing greater support capacity per volume of wood used in the crib construction.

Jan 1, 2010

By L. B. Pankratzt

The heat capacity of dimo1ybdenum carbide (Mo2C) was measured from 51° to 298° K, and the entropy at 298.15° K was evaluated. Heat content measurements above 298.15° It were conducted for dimolybdenum carbide (M0caY) and monotantalum carbide (TaC). The results were combined with known heats of formation and the 298.15° K entropy for TaC to obtain values of the heat and free energy of formation from 298.15° K to 1,400° K for MoaC and from 298.15°K to 1,800° K for TaC.

Jan 1, 1966

By W. A. Stickney

As part of a Bureau of Mines program to investigate recovery of manganese (Mn) from low-grade materials, laboratory studies were made of four samples of mill rejects: Three from Montana and one from Peru. These studies demonstrated that certain mill-waste products can be a potential source of manganese. Both manganese oxide and carbonate minerals were recovered by flotation in an acid circuit with a fuel oil-tall oil emulsion as collector. Sintering) required to prepare a physically acceptable product, also was used as a method of beneficiation. In addition to being low-grade, some of the samples presented problems of intimate mineral association and complex textures.

Jan 1, 1960

By Heinz W. Sternberg

The literature on electrochemical treatment of coal is reviewed, and possible avenues of further research in this field are discussed in this report. Electrolytic reduction of finely distributed coal resulted in the addition of as many as 9 atoms of hydrogen to 100 atoms of carbon. Reduction of coal extracts at controlled potentials indicated the presence of condensed aromatic hydrocarbons and reducible quinones in coal. As much as 65 percent of low-rank coal can be made alkali soluble by electrochemical treatment. Higher rank coals gave smaller yields of alkali-soluble products. However, the nature of this reaction is not clear. The difficulty of reducing coal electrolytically is probably due to the insolubility of coal and not to any structural peculiarity. Reduction of coal by electrolytically generated radical anions appears to be a promising approach for further research.

Jan 1, 1962

By A. C. Rice

Investigation of a variety of mines to determine efficiency for rare- earth extraction has resulted in a solvent extraction technique wherein Primene 81-R,4 N-benzylheptadeeylamine (BHDA), and Primene JM-T give favorable extraction from sulfate solutions. Extraction from chloride, nitrate, and perchlorate solutions is negligible. Distribution coefficients for 10 rare-earth elements with Primene 81-R establish an extraction sequence beginning with lanthanum and proceeding through lutetium according to atomic number. Yttrium and ytterbium are exceptions in the extract ion sequence.

Jan 1, 1962

By R. V. Lundquist, H. Leitch

Two hydrated calcium aluminates , formed by side reactions in the leaching step and desilication step of the lime- soda sinter process , were investigated to better define their influence on alumina recovery . The two calcium aluminates , Caз [ Al ( OH) 6 ]₂ and зCa0.Al½ 03 · ( 8-12 ) H₂ ) , were prepared and identified by chemical and X- ray analysis . The relative proportions of each of these compounds formed in typical leach solutions at several temperatures were determined . The influence of free lime as a promoter of calcium aluminate formation was also investigated . The formation and precipitation from leach liquors of calcium aluminates contributes to the low alumina recoveries in the process . The presence of carbonate ion in the leach solution suppresses calcium aluminate formation and precipitation and results in higher alumina recovery . Hydrated calcium aluminates are formed in the aging of lime - soda sinters in the normal atmosphere .

Jan 1, 1963

USBM Contract H0133045 consists of the design, build and test of 50 waveform generators. The waveform generator is a small ULF transmitter operating in the 1 to 3 KHz frequency range for the purpose of locating trapped miners during a mine disaster. This contract provided for the design, test, and building of 50 waveform generators using a discrete component construction with an option of using hybrid construction techniques within 105 days after the effective date of the contract. Because of large quantity economic considerations, this option was not initiated. Two engineering models were designed, constructed and tested and 50 final production units were fabricated using discrete construction. Complete documentation is supplied under a separate package which includes final schematics, parts list, layout information, equipment specification, production test procedures and qualification test procedures. Ten units have been delivered to the USBM. The remaining 40 units are being retained for packaging under contract H0242010 Transmitter Package and Receivers.

Jan 1, 1974

By F. A. Rutledge

"The W. E. Dunkle mine, sometimes called the Costello Creek coal mine, is 8 miles N. 20° W. of Colorado Station on the Alaska Railroad. The presence of coal in this area has been known since the district was extensively pros¬pected for gold between 1911 and 1915. At that time, coal from this deposit was used by miners for blacksmithing. The increased demand for coal resulting from government defense projects in Alaska led to exploitation of this deposit in 1941.The inability of Alaska coal mines to supply the quantity of coal required by public and private consumers and by the armed forces in Alaska was responsible for establishment by the Army of the Coal Procurement Section of its Alaska Department. It proposed to investigate the deposits and to expedite production from the Alaskan coal fields. The Bureau of Mines closely cooperated in this program.The quality of the Dunkle coal and the favorable location of the deposit caused it to be one of the properties chosen for investigation under a joint Army-Bureau of Mines-Geological Survey program.During July 1943, the coal area in the immediate vicinity of Costello Creek was geologically and topographically mapped. by Clyde Wahrhaftig and Jacob Freedman, geologists, U. S. Geological Survey. F. A. Rutledge, mining engineer of the Bureau of Mines examined the property July 18 to 22, 1943, and a project of trenching, diamond drilling, and sampling was initiated on August 4, 1943. During the project Clyde Wahrhaftig remained at the Dunkle mine to interprets drill cores and assist the author in planning the explora¬tory program. The project was completed October 7, 1943.Field investigations were under the general direction of R. S. Sanford, acting chief, Alaska Branch, Mining Division. Coal analyses were made by Maurice L. Sharp, coal analyst for the Alaska Railroad.Special mention is made of the cooperation and assistance received from Clyde Wahrhaftig, geologist, U. S. Geological Survey.The many courtesies received from the owner, W. E. Dunkle, and the members of the Army Coal Procurement Section, Alaska. Department, also are acknowledged.The W. E. Dunkle coal mine is in the Broad Pass region on the south slope of the Alaska Range at an altitude of 2,800 feet (fig. 1). It is situated within the Third Judicial Division, headquarters of which is Valdez, Alaska. The area is situated approximately at latitude 63° 15' N. and longitude 149° 30' W. and is connected with the Alaska Railroad at Colorado Station by an 11-mile gravel road that is passable throughout the year. This road is maintained by the Alaska Road Commission. A private telephone line to Colorado Station connects with the telephone and telegraph service of the Alaskan Railroad.The passenger rate from Anchorage, Alaska, to Colorado station is $12.10. Freight rates are $1.60 a hundred pounds for heavy machinery and $2.66 a hundred pounds for first-class freight.The Costello Creek coal basin is in an area of low relief and has been dissected by numerous creeks flowing down the south flank of the Alaska Range. The Dunkle coal mine is on Coal Creek, a small tributary of Camp Creek, 1,000 feet from their junction. About 700 feet below this junction, Camp Creek joins Costello Creek, which in turn empties into Bull River 1/2 mile above the latter's confluence with the West Fork of the Chulitna River. The location of the mine is shown on figure 1."

Oct 1, 1948

By Federick W. Miller

The Bureau of Mines has investigated the availability of columbium from 19 deposits (3 producers and 16 nonproducers) in 7 market economy countries (MEC?s). Brazil has the largest recoverable columbium resource, posessing approximately 2.39 million metric tons Wmt), or 69 pet of the MEC total (3.47 Mmt). The Western Hemisphere countries of Brazil, Canada and the United States contain 3.14 Mrnt of recoverable columbium or 90 pnt of the MEC total. Columbium recovered as a byproduct of tin mining is not included as part of MEC resources in this study. Currently producing mines are Araxa and Catalao in Brazil, and Niobec in Canada, These three mines have 2.42 Mmt of recoverable resources or approximately 69 pct of the MEC total. It is estimated that these mines, operating at full capacity, could satisfy cumulative MEC demand (based on an annual growth rate of 5.1 pct) for the next 20 yr. The United States is totally dependent upon foreign sources for its columbium supply. The majority of U.S. columbium is imported from Brazil in the form of steelmaking- grade ferrocolumbium. Canada has been the sole source of pyrochlore concentrates since Brazil discontinued exports in 1981. The United States also imports small (but important) quantities of columbium as columbite concentrates from Nigeria and Brazil, as columbite contained in tin slags from Thailand and Malaysia, and as synthetic concentrates from the Federal Republic of Germany.

Jan 1, 1986

By A. L. Engel

Many western ores containing ;old, silver, and copper can be mined and concentrated at a profit only when the recovery of those metals is high and treatment costs are low. Usually, ores containing easily dissolved copper minerals, or copper minerals that become soluble to some extent through oxidation during treatment, present a real problem in cyanidation. Copper cyanide compounds are formed that tend to 'precipitate and that cannot yield regenerated cyanide and metallic copper on contact with zinc. This results not only in some loss of copper through solution in cyanide, but in excessive consumption of cyanide above the amount required for the extraction of Gold and silver. Any moans, therefore, of minimizing the: loss of cyanide while at the same time effecting high recoveries of the several values contained in the ore is of wide interest. A sample of typical low-grade ore of gold, silver, and copper, containing copper-sulfide minerals, was obtained from the MacLaren Gold Mines Co., Cooke, Park County, Mont., for laboratory investigation by flotation and cyanidation.

Jan 1, 1950

By Fred D. DeVaney

The Mesabi iron district of Minnesota has a potential production of over 50 million tons of iron are annually. The large shipments of ore each year are gradually depleting the reserves, and if the present rate of production is to be maintained there must be a growth in the present available ore supply. Growth is a natural course. The growth of a city may be affected by the addition of city blocks or by the improvement of utilities necessary for its betterment. These may go on in the order named or concurrently. The city-block type of growth of the Mesabi has been tremendous, and the "betterment" type has followed in due course. Probably the former has reached its limit, and if so, more time will be allotted to the latter. It is not the in¬tent of this paper to present either a eulogy of the wonderful mining methods or a history of the milling, but it is pertinent to say that if the lean-ore area continues to produce, the continuance will be more the result of further improvement of milling methods non well under way than of extension of boundaries by the city block plan of growth.

Jan 1, 1932

By D. W. Frommer

As one phase of a general problem of recovering sulfide slimes, mineral-dressing research was conducted on flotation tailing from the St. Joseph Lead Co., Bonne Terre, Mo., mill to recover a significant portion of the residual, finely divided galena. Production of a high-grade concentrate was not part of the immediate objective. Only a reasonable ratio of concentration of lead sulfide slime was sought, since the problem of upgrading by mechanical or extractive processes would be considered in the later stages of this study. The results show that, from a feed material averaging 0.20 percent lead (about 70 percent finer than 400-mesh), a recovery of up to 45 percent could be effected by flotation in rougher concentrate analyzing up to 6.5 percent Pb. These results were obtained by using larger quantities of various xanthates and sodium sulfide than used customarily in mills. Sodium sulfide, which is ordinarily detrimental to flotation of galena, was beneficial in this case.

Jan 1, 1959

By Russell R. Trengove

The Bureau of Mines developed by core drilling the Cove Meadow copper property, also known as the Patterson property, from May 6, 1949, to August 6, 1949. It is in the Cove Meadow mining district, northwestern Humboldt County, Nev., 102 miles northwest of Winnemucca. The purpose of the work was to determine possible reserves in a mineralized shear zone in andesite that has been partly explored by several surface cuts and two shallow underground workings. Production from this zone to August 1, 1,949, was 98 tons of hand-sorted copper ore assaying 5.1 percent. The development work performed by the Bureau of Mines comprised a study of the geology, mapping the area, sampling the outcrops, and exploring by diamond drilling the shear zone adjacent to the fault. Seven holes were drilled for a total of 1,246 feet. Mineral reserves indicated by the project are confined to a length of 500 feet along the strike.

Jan 1, 1950

Rapidly identify unstable mine waste embankments and similar dam structures. Approach Aerial photography, geotechnical instrumentation, and telephone or satellite data transmission are used to supplement walk-around inspect ions. How It Works Embankment stability and other indicators of structural integrity are evaluated using aerial photography, and on-site unattended instruments and data transmitting systems. Evidence of external movement and water seepage is obtained from aerial photography and photogrammetric evaluation techniques. Surface points marked by stake- mounted targets are monitored photographically at time intervals of several weeks or months. Photographic measurements of x, y, and z coordinates of these points are obtained from flying a series of photo-runs over the dam.

Jan 1, 1979

By R. Hogg

"Particles play an important role in our environment and in many aspects of human activity. Much of the Earth's surface - sand, soil, rocks - consists of particles, as do clouds in the atmosphere, smoke from fires, and dust in our homes. Many of the foods we eat - cereals, flour, instant coffee - and everyday items such as pharmaceuticals, cosmetics, detergents and other cleaning products are encountered in the form of particles. Inks and paints consist of very fine particles dispersed in liquids. Modem agriculture uses huge quantities of fertilizers and pesticides, largely in particulate form. The list could be extended almost indefinitely; particle systems are obviously an important part of our daily lives. But what do we know about them? For most people, the answer is probably: not much.We are all familiar with the three common states of matter: gas, liquid and solid. In many respects, particle systems should be regarded as a distinct class of their own. The particles themselves may be solid but we all know that a heap of sand is quite different from a solid rock. A cloud of liquid droplets - fog - has much more in common with a cloud of solid particles - smoke - than it does with a bucket of water. There are certain characteristics and properties which are unique to the particulate state. The behavior of any particle system is determined not only by the material from which the particles are made, but also by interactions among the particles and with their environment. These interactions become increasingly important as the size of the particles decreases, and for exceedingly fine particles, smaller than about one micrometer (0.000001 meters or 0.00004 inches), these interactions dominate and we enter the realm of colloidal systems.Particle SystemsA system in which discrete entities - particles -are dispersed in a continuous medium can be regarded as a particulate system. The particles and the medium can consist of a solid, liquid or gas. The various combinations and some common examples are listed in Table 1. The properties and behavior of these systems depend on the characteristics of the particles, the nature of the medium, and the relative abundance of the two phases. In general, it is the latter which determines the kind of behavior exhibited by the system.As a general rule, the behavior of particle systems follows that of the dispersed phase (the particles) at high concentration, and that of the continuous phase (the medium) at low concentration. For example, both powders and smokes consist of solid particles in a gaseous medium. However, in a powder the solids typically occupy over one half of the total volume; in many respects powders behave like solids. In a smoke, on the other hand, the particles may take up only a few parts per million of volume, so that these systems generally behave like gases."

Jan 1, 1989

By John W. Frey

This paper presents one of a series of digests of foreign mining legis- lation and court decisions which is being prepared in advance of a general re- port relative to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the laws of Portugal, prepared from the best available information in Washington, has been slightly amplified in accordance with suggestions trans- mitted through the courtesy of the Department of State by Fred Morris Dearing, American Minister at Lisbon.

Nov 1, 1929

By Richard F. Hewlett

Computing average grade and tonnage either for an entire ore deposit or for individual blocks of ore is a continuing problem in mining. As part of a research program, investigating application of statistical techniques to mine sampling, Bureau of Mines engineers at the Denver Mining Research Center have made extensive use of an electronic digital computer for developing mine sampling theory, simulation of ore deposits, and analysis of mine sample and assay data. This report is one of a series describing use of the digital computer for rapid solution of computing problems in the mining industry.3 4 Development of a computer program to compute ore reserves by the commonly used triangular method was necessary so that results could be made available for analysis within hours.

Jan 1, 1963

By A. D. Garman

This paper presents one of a series of digests of foreign mining legislation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries . This interpretation of the laws of Uruguay has been prepared from the best available information in Washington, but is released subject to correction and amplification , if necessary , by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State .

Sep 1, 1930

By M. J. Ferrante

The standard enthalpy of formation, low-temperature heat capacities, and enthalpy increments above 298 K were determined by the Federal Bureau of Mines for synthetic dawsonite [NaA1C03(OH)21. The enthalpy of formation was determined by hydrochloric acid solution calorimetry, with the result ?Hf°298 = -469.4±0.7 kcal/mole. The low-temperature heat capacities were determined from 6 to 307 K by adiabatic calorimetry. Tabulated are low-temperature values of Cp°, S°, and H.-Ho° from 3 to 298 K. The derived entropy at 298 K is S298 = 31.55±0.3 cal/deg mole. Enthalpy increments above 298 K were obtained by copper-block drop calorimetry. Tabular data of Cp°, S°, H°-H°298, -(G°-H°298)/T, ?Hf°, ?Gf°, and log Kf are given from 298 to 477 K. Enthalpies and Gibbs energies of decomposition are also reported.

Jan 1, 1976