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By G. S. Scott, G. W. Jones

"INTRODUCTION An important phase of the accident-preventing program of the Bureau Mines is the determination of the explosion hazards of various combustible gases, vapors, and liquids encountered in mining and allied industries and the development of methods of eliminating or mitigating them.Recently, isobutane has become a commercially important raw material in the production of aviation gasoline by the alkylation process. 4/ in which isoparaffins are combined with olefins to give higher molecular weight compounds of branched-chain structure.Because of the anticipated commercial importance of isobutane in industry, it has been deemed necessary to study and determine its general explosion haz¬ards. This report gives its limits of inflammability, minimum ignition temper¬atures, and the amounts of nitrogen and carbon dioxide required to render isobutane-air mixtures noninflammable."

Jun 1, 1947

By F. P. Haver

Because of increasing concern with air pollution, the Bureau of Mines has developed a hydrometallurgical procedure to obtain elemental sulfur from chalcopyrite (CuFeS2) by means of the following reaction: CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S. Under optimum conditions, 99.6 percent of the copper and 71.6 percent of the iron were extracted in 2 hours from a typical mill concentrate containing 75 percent CuFeS2 and 15 percent pyrite (FeS2). At the same time, 68.2 percent of the sulfur in the concentrate was oxidized to the elemental form. The leach was highly selective; gangue minerals, including pyrite, were not attacked, thus accounting for the relatively low recoveries of iron and sulfur. To obtain these results, the concentrate was ground to 98.9 percent minus 325 mesh, and 300 grams was treated with 1 liter of boiling ferric chloride (FeCl3) solution. The FeC13/CuFeS2 ratio was 2.7. Cement copper containing 99.9 percent copper was recovered from the leach solution by cementation on sponge iron. Excess iron, dissolved during leaching and cementation, was removed from the stripped solution by crystallization. Ferrous chloride (FeCl2?4H2O), obtained as a byproduct, was converted to high-purity ferric oxide (Fe203) and HCI by an oxidizing roast. The hydrochloric acid was then electrolyzed to obtain chlorine, which was used to regenerate the leach solution. The leach residue, which contained ~50 weight-percent elemental sulfur, was treated with an organic solvent to recover the sulfur and cyanided to reclaim gold and silver.

Jan 1, 1971

By Thomas C. Denton

ALL of the 45 political divisions of Africa were accessible to non-Communist world industry and commerce throughout 1964, although in some of them revolt and political attitudes presented problems. The position of the continent as a whole for mineral and mineral fuel resources, production, and oversea exports continued to improve. At yearend, significant quantities of a greater number of mineral commodities vital to industry and agriculture were being produced than in any other continent. This statement excludes Communist areas on other continents but might well hold true even if such areas were included. Deriving from its exceptionally diversified production, Africa furnished overseas industrialized countries as a w ole a greater variety of key mineral commodities than any other area. In addition, the value of mineral imports from Africa into the United Kingdom and continental non-Communist Europe probably exceeded the value of such imports from any other area if gold is included and mineral fuels excluded.

Jan 1, 1966

By C. A. Alien

The increasing activity in oil shale has had a tendency to direct the attention of the industry to any substance from which gasoline or other oils can be secured . Cannel coal for many years has been known, as a source of oil and formerly it was the only substance from which kerosene was obtained . The name of coal oil was given to kerosene because it was derived from cannel coal before any flowing wells were brought in in the United States . In an isolated region in Southern Utah there is an unusually thick and clean bed of cannel coal which laboratory experiments indicate can be made to yield about seventy gallons of oil to the ton . This coal was first described in Bulletin 341 of the United States Geological Survey under the title of Colob coal field . This field lies at the western and southern base of the Colcb plateau and extends from the town of Cedar City southward to Kanarra and then southeastward to the town of Mount Carmel . Cedar City is 35 miles south of east from Lund on the Los Angeles and Salt Lake Railroad which is the nearest railroad point . Mount Carmel is about 90 miles south of Marysvale , on the Denver and Rio Grande Railroad , which is the nearest railroad point from the eastern end of the field . The Colob coal occurs in Lower Cretaceous rocks and a number of wagon mines have been opened on the seam in the vicinity of Cedar City , Kanarra , and Mt. Carmel , but between these places the field has been very little prospected . The cannel coal , so far as known at present , is limited to a small area on the head waters of the north fork of the Virgin River in Township 39 and 40 South , Range 9 East . In this region it occurs as a bed 5-1 /2 feet thick over which lies a layer of bituminous coal 2 feet and 5 inches thick .

Feb 1, 1921

By Donald J. Keefe

The Remote Working Level Monitor (RWLM) is an instrument used to remotely monitor the Rn-daughter concentrations and the Working Level (WL). It is an ac powered, microprocessor based instrument which multiplexes two independent detector units to a single central processor unit (CPU). The CPU controls the actuation of the detector units and processes and outputs the data received from these remote detector units. The remote detector units are fully automated and require no manual operation once they are set up. They detect and separate the alpha emitters of RaA and RaC' as well as detecting the beta emitters of RaB and RaC. The resultant pulses from these detected radioisotope; are transmitted to the CPU for processing. The programmed microprocessor performs the mathematical manipulations necessary to output accurate Rn-daughter concentrations and the WL. A special subroutine within the program enables the RWLM to run and output a calibration procedure on command. The data resulting from this request can then be processed in a separate program on most computers capable of BASIC programming. The calibration program results in the derivation of coefficients and beta efficiencies which provides calibrated coefficients and beta efficiencies.

Jan 1, 1977

By Len Blackman

The Absaroka-Beartooth Study Area is a tract of approximately 1.4 million acres of National forest land in southern Montana, part of the Greater Yellowstone Area. This study evaluated the mineral potential of four mineral terranes containing undiscovered resources in the area. The geological data is probabilistic, with estimates of the possible number: of deposits and their grades and tonnages. Possible future development scenarios range from no development to many mines, including some very large. As two thirds of the study area is within the Absaroka-Beartooth Wilderness, the future development scenarios reflect the area's mineral potential, not what we expect to see in the foreseeable future. Based on the analysis performed on these four terranes, the most likely future scenario for the study area would include the potential for two medium sized, (predominately) gold, mines, each employing a few hundred workers. There is a small chance, less than 5%, that a large Porphyry Copper or Superior Iron deposit would be discovered and be economically feasible to develop.

Jan 1, 1994

The purpose of Volume II of this study is to provide a general plan for the pilot testing of two materials which could be used to tag explosives for both pre- and postdetonation identification and of tracing techniques which would thereby aid the investigator of an unauthorized bombing or explosion in being able to determine the source and/or user of the explosives. Volume I described the planning factors by which the tagging of explosives could be implemented on a National basis. 1.2 BACKGROUND Tagging explosives at the time of manufacture with a taggant material that could survive detonation, be recovered, and provide an investigative lead has been seriously studied for several years. This concept has gained widespread support among many law enforcement groups because of the scant clues that can presently be found among bombing residue.

Jan 1, 1977

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution3 by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1930, however, was unusually dry and represents what may be termed "extreme" low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscahonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.4

Jan 1, 1931

By W. E. Anable

The Bureau of Mines studied the purification of commercially available vanadium in the 100-kw electron-beam furnace. Purification studies were conducted on a 100-gram button scale by melting and holding the liquid vanadium at temperatures ranging from 2,060° to 2,080° C at pressure of 5(10)-5 torr for periods ranging from 5 to 20 minutes. The effect of doping vanadium with carbon and metallic additions was determined. This study demonstrated that hydrogen was readily removed to 3 ppm or less, oxygen and carbon were reduced to less than 100 ppm each, and the metallic impurities were reduced Co the range of 10 to 500 ppm. The nitrogen content was not reduced in any of the buttons; rather, the nitrogen concentration generally increased as samples were held for successively longer periods. Oxygen was removed much faster and more completely when vanadium was doped with small carbon additions or one of several dopes prior to melting.

Jan 1, 1967

By A. T. Coumbe

This compilation of statistics covering competitive fuels consumed for heating of residential and commercial buildings is in response to numerous requests for data of this nature to show the relative changes in the demands for the different fuels in recent years. The figures presented cover the amounts of various fuels ant electric energy reported as used for heating dwellings and commercial buildings. However, the totals for gaseous fuels and electricity necessarily include amounts consumed for both cooking and lighting purposes, as these associated household uses could not be readily broken out. [ ] SOURCES OF FUEL AND POWER STATISTICS Liquid fuel: Mineral Market Reports of the Bureau of Mines covering annual Pales of fuel oil and kerosine. The fuel oil figures include grades 1 to h, reported as sold for space heating. Kerosine and grade 1 fuel oil delivered as range oil ore also included. Gaseous fuel: "Gas Facts" published by the Bureau of statistics of the American Gas Association. Thin source was used as It is believed that the data shown are representative of the actual market

Jan 1, 1953

By Milton Orchin

There has been a good deal of speculation as to the function of a vehicle in the coal hydrogenation process. One of the most fruitful theories has been the suggestion that a vehicle such as tetralin functions by supplying hydrogen to the coal, and that the high-pressure hydrogen present in the system serves to regenerate the tetralin. In order to obtain experimental evidence bearing on this theory, a series of experiments was planned in which varying quantities of tetralin were used with coal in the presence of high-pressure hydrogen. This paper reports the results of these experiments.

Jan 1, 1949

By Arthur L. Crawford, R. E. Head, Fred E. Thackwell, A. Lee Christensen

"The data in this report are the result of a detailed, microscopic study of composite samples of mill products collected over a 14 day period. The samples were collected and assembled under the direction of W. R. Lindsay, superintendent of the Anyox plant, and are fairly representative of the heads, middlings, tailings, and products peculiar to the scheme of concentration practiced at Anyox in 1930.The work was done in the Cooperative Microscopic Laboratory at Salt Lake City, Utah. This laboratory was equipped by the mine and mill operators of the Salt Lake Valley and functioned under a cooperative agreement between the United States Bureau of Mines the University of Utah. This is the fourth of a series of papers 6/ dealing with a microscopic study of mill products."

Oct 1, 1935

By R. L. Grant

An investigation was undertaken by the Bureau of Mines to determine the relationship between freespace and ignition probability for borehole shots. A series of experiments was concluded which covered six freespace conditions for a pemissible explosive in a 3/4-inch borehole and encompassed some 700 shots. The results were analyzed statistically. From the analysis of variance, it was concluded that the freespace means were different and that this conclusion is not impaired by possible differences in the explosives used. Within the limitation of this experiment, a definite relationship was found between the freespace and the ignition probability. Specifically, the incendivity increases with increased freespace up to a maximum; beyond this maximum there is some indication of decreasing incendivity. Further investigations are in progress to establish whether the effects of freespace on ignition probability reported here are applicable to the large test gallery, INTRODUCTION A borehole loaded with an explosive charge is a common feature of the routine gallery tests for determining the permissibility of coal-mine explosives, of Experimental Coal-Mine shots, and of the small steel cannon shots used in connection with certain research programs on the ignition of firedamp (6, 10).6/ The question of the interrelationship of freespace, weight of charge, and ignition probability of the methane-air atmosphere has been raised

Jan 1, 1959

By L. M. Demers, D. C. Kuhn

"Kuhn, Douglas C., and Laurence M. Demers. Effect of surfactant on basal and silica-induced eicosanoid production by the alveolar macrophage. Am. J . Physiol. 269 (Lung Cell. Mol. Physiol. 13): L165-Ll 70, 1995.-Infiammation and fibrosis subsequent to the inhalation of certain mineral dust particles has been suggested to result from the activation of eicosanoid synthesis by the alveolar macrophage (AM). To determine if surfactant modifies dust-induced generation of eicosanoids by the AM, we evaluated the effect of the surfactant lipid dipalmitoyl lecithin (DPL) on the production of eicosanoids by rat AM exposed to respirable silica dust in vitro. During the first 24-h exposure period, DPL alone significantly increased basal production of eicosanoids but completely inhibited silica-induced thromboxane A2 synthesis. In contrast, leukotriene B4 (LTB4 ) production was only partially reduced by DPL. During a second 24-h exposure period, LTB4 production in response to the highest dose of silica remained significantly elevated in the presence of DPL. Similar results were obtained when the surfactant preparation Survanta was evaluated. These results suggest that 1 ) DPL and Survanta independently activate AM eicosanoid production, 2) DPL and Survanta modulate the response of the AM to silica dust, and 3) L TB4 may be the most important eicosanoid mediator of the long-term effects of silica dust exposure on lung pathophysiology. THE OXYGENATED METABOLITES of arachidonic acid (AA) (here collectively termed eicosanoids) have been implicated as important regulators of lung physiology and are thought to be involved in pathophysiological sequelae such as acute respiratory distress syndrome, asthma, and the pulmonary complications of sepsis (20). This role is manifested through both direct effects on lung physiology as well as through an indirect modulatory effect on the release of other mediators of lung injury, in particular profibrotic cytokines such as the interleukins and tumor necrosis factor (15). Recently, exaggerated eicosanoid production by both the alveolar macrophage (AM) and the type II epithelial cell has been demonstrated to result from the exposure of these cells to several particulates, including crystalline silica (quartz) dust (5, 9, 17). These observations have led to the suggestion that eicosanoids play a major role in the etiology of pneumoconioses.Another secretory component of the pulmonary environment, surfactant, has been shown to modulate crucial AM functions, such as bactericidal activity and the recruitment of circulating immune cells (25). Indeed, an important feature of the lung's reaction to inhaled mineral dust is an increase in surfactant production, perhaps as a compensatory or protective response (1, 16). In addition, the alteration of the surface properties of mineral dust by surfactant or its components has been shown to influence the biochemical response of the AM to the dust, perhaps by altering the surface charge of the dust particle (11, 29, 32). And recently, Wallace et al. (28) have shown that the coating of mineral dust with surfactant, and its subsequent removal by lysosomal phospholipase, unmasks differences in dust cytotoxicity that are not apparent when AM are exposed to uncoated dust. Thus it appears that the inclusion of surfactant in in vitro exposure studies may be important in evaluating both the absolute levels of eicosanoid production by the normal and dust-exposed AM and the temporal relationship between dust exposure and the production of inflammatory mediators by the AM. Therefore, we characterized the effects of the surfactants dipalmitoyl lecithin (DPL; the primary lipid component of natural surfactant) and Survanta (a commercially available surfactant derived from bovine lung) on basal and silica-induced AM eicosanoid production during two 24-h periods after exposure to dust particles to both allow the enzymatic removal of surfactant from the particle surface and evaluate the k"

Dec 1, 1996

By C. Fang, D. B. Kittleson, K. L. Rubow

"Under contract to the U.S. Bureau of Mines, a study was conducted to investigate the feasibility of using the microorifice. uniform deposit impactor (MOUOI) to measure the size distribution of aerosols containing various mixtures of coal dust and diesel exhaust particles. The project objective was to determine if the mass concentration of diesel exhaust particles, in an airborne mixture of coal dust and diesel exhaust particles, could be determined on the basis of the size distribution of the two aerosols. In general, the mass of diesel exhaust particles is in the submicrometer size range while that of the coal particles lie in the larger size ranges.The MOUDI is a cascade impactor with small diameter nozzles to obtain small cut sizes and rotating impaction plates to avoid particle overloading of the deposit. For this study, a 7 stage version was used. At the sample flow rate of 30 L/min, the cut sizes were 0.10, 0.23, 0.70, 1.0, 2.6, 4.9 and 10 pm.Size distributions of aerosols generated in the laboratory and in several underground coal mines were measured. The primary emphasize of the laboratory tests was to ascertain if the diesel exhaust particles could be separated from the coal dust, regardless of mass fraction of the diesel exhaust particles in the total aerosol mixture. Diesel exhaust, from a Caterpillar Type 3304 NA diesel engine, was mixed with coal dust generated with a· TSI Model 3400 fluidized bed dust generator. Experiments showed the size distributions of the mixed aerosols exhibited two definite modes with the minimum between the two modes in the 0.7 to 1.0 um size range. Distinct modal separation was obtained as the mixture fraction of the diesel exhaust aerosols was varied from 3% to 98%.The field study was conducted in three underground coal mines, two utilizing diesel-powered equipment and the third exclusively using electric equipment. Sampling sites were selected to obtain a wide variety in the diesel exhaust and dust aerosol concentrations. Size distribution data showed these aerosols are bimodal. The mass median aerodynamic diameters of the diesel particulate mode and the coal dust mode were approximately 0.15 µm and 3 to 10 un, respectively. The results, in all cases, clearly show a separation between the two modes in the 0.7 to 1.0 µm size range with the minimum in the vicinity of 0.8 pm. The separation was found to be independent of mass fraction of the diesel exhaust particles, total particle concentration and sampling site."

Jan 1, 1989

By N. F. LeJeune

[ ]

Jan 1, 1924

By Richard J. Leary

The inputs of capital and labor to support future iron ore production were developed by the Bureau of Mines from projections of iron demand and estimates of capital and labor requirements. Trends in technologic change and the organization of production were analyzed. Labor requirement schedules for iron ore mining and beneficiating were constructed from aggregate inter-temporal trends and 1970 cross-sectional analysis of mines and mills. A sup-ply schedule of the capital requirement for mine-mill-pellet plants was developed from U.S. and Canadian experience. The structure of demand for iron to the year 2000 was examined as well as the availability of resources. Projections of capital and labor requirements to 2000 were constructed under two international patterns of iron ore supply to the United States. The most likely model is for a continuation of the 70 percent United States-30 percent foreign shares, expanding at an average 2.0 percent growth rate to 2000, and supported by a cumulative gross capital investment of $3.8 billion constant 1967 dollars and a labor force in the United States of 29,800 by 2000. The information content of projections is discussed, and the possible effects of international forces on supply are considered. A generalized methodology for estimating capital and labor requirements in other mineral industries also is included.

Jan 1, 1975

By E. K. Stanek

This report contains results of two major efforts related to electrical transients on mine electrical power systems. The first area concerns the use of digital computers to model mine electrical power systems and predict transients or duplicate field recordings of transients. Two existing general purpose circuit analysis programs were used. The first was the TRW Engineering System Simulator or TESS. The second was Electronic Circuit Analysis Program or ECAP. TESS proved to be superior to ECAP in several important characteristics, including system size limitations and modeling nonlinear elements. The second major topic covered in this report is the evaluation of commercially available surge suppression devices. These devices were found to be quite acceptable and guidelines for the selection and placement of surge suppressors were included. The final important item is a listing of the worst-case transients, from a design point of view, for ac and de utilization systems and ac distribution systems.

Jan 1, 1979

By R. G. Meara, O&apos

The land-pebble district of Florida, wnich in 1928 supplied 96.7 per cent of the phosphate production of that State and 82 per cent of the domestic requirements of the United States, is centered in Polk and Hillsboro Counties about 30 miles east of Tampa The deposits are unconsolidated sediments occurring as beds of phosphate matrix overlain by a mantle of barren sands and clays. The matrix consists of a mixture of sand (quartz grains), clay, and phosphate rock in which the coarsest sand is much finer than the coarsest phosphate; that is, the sand is segregated in the fine material. Before the introduction of classifiers the concentration consisted of log washing, and screening at about 20-mesh, which was usually the finest size that could be taken to maintain commercial grade, 66 per cent B. P. L. (bone phosphate of lime) or more. When classifiers were introduced some of the fines that had escaped at the head of the washery and some of the minus 20-mesh material isolated during the washing and formerly lost supplied the feed. During October, 1927, the United States Bureau of Mines in cooperation with the University of Alabama and the Missouri School of Mines and Metallurgy began to investigate the amenability of phosphatic sands to gravity methods of concentration. The work was under the immediate supervision of B. W. Gandrud, acting supervising engineer of the Southern Experiment Station of the U. S. Bureau of Mines at Tuscaloosa, Ala., and Will H. Coghill, supervising engineer of the ore dressing section of the U. S. Bureau of Mines. More comprehensive testing followed and in the early part of 1930 some of the companies cooperated with the bureau and the above-mentioned institutions in conducting a series of tests on hydraulic classification and tabling. The results indicated that marketable concentrates could be obtained with a recovery of 25 to 45 per cent of the phosphate formerly lost. As a result two companies have introduced hydraulic classification to treat the current tailings, and one of them has substituted classifiers for the 20-mesh screens which had been unsatisfactory. Because the phosphate grains and quartz grains have nearly the same specific gravity, the use of concentrating tables by the customary methods is not applicable. The washeries included in the following report are designated as Nos. 1, 2, and 3.

Jan 1, 1931

By R. Hogg, T. F. Dumm

"A procedure for evaluating the size/specific gravity distribution of ultrafine coal and the distributions of sulfur and ash with respect to particle size and specific gravity is described. The procedure is essentially an extension of the conventional coal washability technique in which special precautions are taken to ensure particle dispersion in the heavy organic liquids, centrifuges are used to obtain adequate separation rates, and micromesh sieves are used for size separation at fine sizes. An example of the application of this technique to the evaluation of the extent of liberation of sulfur and ash in a coal sample ground to 90Z passing 200 mesh (74 um) is described.INTRODUCTIONIn order to determine the potential for deep cleaning of coal by fine grinding to liberate sulfur and ash-forming minerals, it is necessary to obtain data on the distributions of these species by size and specific gravity. In conventional coal processing operations, this information is obtained by means of a standard ""washability"" analysis. Attempts to extend this procedure to ultrafine coal, however, have generally been unsatisfactory and have often led to unreliable and inconsistent results [11. The present authors have described a modified washability procedure in which cumulative specific gravity fractionation is combined with sub-sieve size analysis (by laser diffraction/light scattering) to determine the particle size/specific gravity distribution of ultrafine coal [2]. Unfortunately, because this technique does not involve separation of the individual fractions, only limited information can be obtained on the specific distributions of sulfur and ash.The objective of the work described in this paper was to develop and evaluate a procedure for size and specific gravity fractionation of ultrafine coal and to use conventional analyses for sulfur and ash to determine their relative distribution in the coal. The procedure is essentially a simple extension of the standard washability analysis [3] but incorporating special precautions for treating ultrafine particles.EXPERIMENTAL Material The material used in the development and evaluation of the ultrafine coal fractionation procedure was a medium volatile bituminous coal from the Lower Kittanning seam. A sample of the coal (nominally - 1/4 inch), obtained from the Penn State Coal Data Base, was ground to 90% passing 200 mesh by the following two-stage grinding procedure: About 2 kg of the as-received coal were ground to about 30Z passing 200 mesh in a Model 4-E Quakertown mill (""coffee grinder""). About 1 kg of this product was then ground to about 90Z passing 200 mesh in a Holmes Model 300 Pulverizer."

Jan 1, 1989