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By W. H. Herschel, E. W. Dean

"IntroductoryThe common practice of the petroleum industry is to measure viscosity by the use of instruments of the efflux or capillary tube type. The Saybolt universal viscosimeter has been tentatively adopted as a standard by the American Society for Testing Materials and is used extensively in the United States.Several instruments of foreign origin are also more or less familiar, such as the Redwood, the Engier, and the Baroey.Effina-type viscosimeters are well adapted to the ordinary needs of petroleum testing laberatories as they are simple and rugged in construction and away to manipulate, even in the hands of operators lacking scientific training. They have, however, certain limitations and for certain spacial types of work there are notable advantages incident to the use of the so-called torsion types of type of viacosimeter. The most satisfactory type of torsion viscosimeter now available in the market some to be that of MacMchael, which has been discussed in detail in a recent paper (Herschel, W. H., The MacMichael Torsional Viscosimeter. Jour. of Int. and Eng. Chem., vol. 12, 1920, pp. 282-286). The present paper indicates conditions under which this viscosimeter may be used to advantage in the petroleum laboratory, and outlines simple methods of operation and calibration."

Jan 1, 1921

By Cavallaro. J. A.

This report presents the results of a washability study of 455 raw coal channel samples with special emphasis on sulfur reduction. These raw coals contained on the average 14.0 percent ash, 1.91 percent pyritic sulfur, and 3.02 percent total sulfur. The complete washability data are presented for each sample processed. A statistical evaluation is included for the coalbeds from which more than 10 samples were collected and for the geographical coal producing regions. A graphical summation is presented for the coal producing regions and selected coalbeds. Finally a similar statistical evaluation is included showing composited data interpolated at Btu recovery levels of 50, 60, 70, 80, 90, and 100 percent. Graphical summations are presented for the various coal producing regions. Generally, significant sulfur reduction is achieved if the coals are crushed to a finer size and the higher specific gravity increments are removed. If a 50-percent Btu recovery was acceptable, then 32 percent of the samples tested could be upgraded to meet the current Environmental Protection Agency (EPA) standard of 1.2 pounds of S02 emission per million (MM) Btu when crushed to 14-mesh top size and separated gravimetrically.

Jan 1, 1976

By P. G. Bennett

The Bureau of Mines developed a process using ion exchange to recover cobalt from spent copper leach solutions. A preliminary economic evaluation of the process indicated that about one-third of the capital cost was attributed to the total resin inventory, and one-third of the operating cost was required for reagents to remove iron from the ion-exchange eluates. An agitated Pachuca elution system was investigated in place of a fixed-bed elution system. The Pachuca system reduced the resin inventory by 27 pet when compared with the fixed-bed elution system. Processing fresh spent copper leach solution reduced the resin inventory by 20 pct and resin iron loading by 80 pct. Reagent requirements for removing iron from the eluates were decreased because less iron was extracted. The Pachuca system, along with processing fresh spent copper leach solution, reduced the total resin inventory by 47 pct. A revised cost evaluation of the cobalt recovery process was obtained to determine the effects of these process modifIcations. The estimated total capital cost for a plant processing 10,000 gpm of spent copper leach solution containing 26 ppm Co was $23.1 million. With credits for nickel, zinc, and copper byproducts, the estimated net operating cost was $5.10/lb of cobalt.

Jan 1, 1988

By John B. Gayle

[The coking time exerts a Considerable influence on the throughout of a coke oven, and for this reason a large number of papers dealing with the relation between coking tine and the different operating variables have been published. Although all of the factors known to ink influence the coking time have been studied, agreement leas not boon reached on several questions, 3/4/ and it appears worthwhile to evaluate any data that become available during investigations of the carbonizing properties of various oafs and coat blends, this report, therefore, includes a Study of the relation between coking lime and flue temperature and represents the second phase of overall investigation ion of factors influencing the coking time in slot-type ovens.]

Jan 1, 1956

By Ralph V. Higgins

The present methods of appraising the long-range performance of oil reservoirs are based upon physical properties of the crude oil and the permeability of the reservoir rock. By means of these methods the performance of a reservoir may be estimated throughout its entire life. Before these methods were used, the future performance was estimated mostly by extrapolating pressure-decline curves -a method that is satisfactory for extrapolating only for a short period into the future. One factor that affects satisfactory long-range prediction of reservoir performance is the extent to which small changes in the physical properties of the oil and differences in the choices of relative permeability influence the calculated oil recovery. Selection of the physical properties of the samples to represent those of the oil and rock for the entire reservoir is difficult. This report is concerned with the error in calculated recoveries that may result from these inherent difficulties.

Jan 1, 1956

By Edward L. McHugh

In 1984, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied an 84,165-acre portion of the 84,935-acre Clover Mountains Wilderness Study Area (NV-050-139) in order to evaluates its identified mineral resources. The area studied is in Lincoln County, NV, about 90 miles north of Las Vegas, NV. No mineral resources were identified in the study area. Volcanic rocks are the most common in the study area, consisting mainly of a thick sequence of ignimbrites in a cauldron complex. Cambrian to Triassic marine sedimentary rocks and Cretaceous to Oligocene clastic rocks are along and partly inside the west and south sides of the study area. No mineral production ha s come from the study area, but gold, silver, copper, and fluorspar have been mined nearby. Eleven mines and prospects in or adjacent to the study area were examined. Workings inside the study area include two shafts, 10 and 60 ft deep, and eleven shallow prospect pits at four sites along the west edge.

Jan 1, 1987

By Robert Stefanko

This report abstracts project work performed for the USBM Grant No. GO-133077 during the period 19 June 1973 to 15 October 1974. Five reports have been separately produced and are as follows: 1. Mine Electrical Systems Evaluation - Cable Splicing, 2. Mine Electrical Systems Evaluation - Explosion-Proofing of Mine Containers, 3. Mine Electrical Systems Evaluation - Transient Analysis, 4. Mine Electrical Systems Evaluation - Mine Power System Performance, and 5. Mine Electrical Systems Evaluation - Model Coal Mine Electrical System Specifications. Abstracts of each comprise the balance of this executive summary, and 50 copies of each volume have been forwarded to the USBM under the terms of the grant agreement.

Jan 1, 1974

By D. E. Wolfson

This report presents 900° C BM-AGA carbonization and related data for coals from the principal beds of Nicholas, Randolph, and Webster Counties, W. Va. Thirty-three samples from nine coal beds in three counties were car-bonized at 900° C in the l8-inch-diameter BM-AGA retort, data from which have been correlated with industrial production. Host of the samples were chemically suitable for metallurgical use, and their coking properties were satisfactory. Except for four of the Lower Kit-tanning samples, the ranges of constituents in the coal seams were 1.8 to 9.0 percent ash and 0.4 to 1.1 percent sulfur, values within the range of accept-ability for metallurgical coals. Coke strength indexes were normal for Appalachian coals of similar rank, and the tumbler stability indexes of the coke ranged from 35 to 57.

Jan 1, 1969

By H. H. Schrenk, L. B. Berger, W. P. Yant, F. A. Patty

"The use of small such as canaries and white mice, for detecting carbon monoxide depends primarily on the fact that the volume of respiration of these animals in proportion to their volume of blood is much higher than for man. Accordingly, when animals and men are simultaneously exposed to a given concentration of carbon monoxide the animals will absorb it more rapidly and attain serious poisoning in less time than men. Prom a practical viewpoint the use of the animals depends on the margin of time between observable symptoms in them and serious poisoning in man, during which man can return to fresh air or use respiratory protection. It should be remembered, however, that during the time the animal is incurring a detectable degree of poisoning, man is also absorbing some carbon monoxide, and the margin of time is not very wide. Experience with canaries has shown that an occasional specimen may have a tolerance above the average of the species and fail to exhibit symptoms before man incurs a very discomforting and possibly a serious degree of poisoning.It is also well known that physical activity increases the demand for oxygen by the body, and the respiratory exchange and circulation of the blood are increased to meet the demand. This sets up a vicious condition if carbon monoxide is present in the air because the rate of absorption of carbon monoxide is not only increased by the increase in respiration and circulation, but the absorption of carbon monoxide decreases the capacity of the blood for carrying oxygen at a time when the demand is high. These facts, together with the increase in respiration and circulation which attend excitement, underlie the caution to be calm and to walk slowly and to reduce physical exertion to a minimum when exposed to carbon monoxide. For these same reasons, when using animals for detecting carbon monoxide it is endeavored to keep them active, thereby tending to increase the response of the birds and widen the time between observable effects in the birds and effects in the man. As rule canaries are kept fairly active through fright at the unnatural surroundings and in their endeavor to remain on the perch of the cage when carried into the atmosphere to be examined. They also experience an excitement stage with oncoming carbon monoxide poisoning. Sometimes, however, especially if the air is cold, they tend to be inactive and quiet. Ordinary mice and white mice become inactive with use and also with oncoming poisoning. They huddle in the corner or the cage, and thereby not only reduce their sensitivity but make it difficult to observe signs of poisoning."

Oct 1, 1930

To improve mining safety and efficiency by providing a practical way of detecting faults and channel sands that disturb coal seams. Approach A seismic system using a shallow blasthole has been developed and tested. How It Works A small shock is caused in a shallow hole, sending seismic waves through the ground. These waves are reflected from the top of the coal seam, acid are detected by a line of geophones on the earth's surface. Dampening of the seismic signals by channel sands and other discontinuities in the seam is detected and recorded. See Figure 1. The seismic shock wave can be produced by exploding small charges, dropping a weight, firing a gas gun, or actuating a vibrator. Depending on the soil cover, the shock is usually generated in shallow vertical holes about 10 feet deep. Hole depth depends on the soil mantle thickness because it is preferable that the seismic shock originate below that layer.

Jan 1, 1976

By Eugene T. Sheridan

The United States has extensive reserves of peat. Peat and muck lands are estimated at approximately 79 million acres, with reserves of 13.8 billion net tons. Within the past decade domestic production of peat has increased 2-1/2 times, and apparent consumption has tripled. During the same period imports have increased greatly, and in 1955 they almost equaled domestic production. The substantial increase in the demand for peat in the United States was due chiefly to expanding markets in agriculture and horticulture, for the reason that in this country peat is used primarily as a source of organic matter to improve the physical condition of mineral soils and as a mulch for shrubbery. A valuable constituent of any soil is its organic matter, and its depletion will injure cultivated soils and subject them to greater erosion.

Jan 1, 1957

By T. Kessler

Spark-source mass spectrometry has been used to determine the amounts of minor and trace elements in coal particles of various sizes, including the respirable range (<5 microns). Fifty-six elements ranging in concentration from 0.1 ppm wt to 5,000 ppm wt have been determined. The investigation of coal and coal ash has shown that the organic material in coal does not interfere with the spark-source determination of the various elements.

Jan 1, 1971

By L. R. Burdick

This paper presents a review of published investigation dealing with the importance of sulfur compounds in the deterioration of materials or providing some basis for estimating the extent of loss shareable to such air pollution. Materials included are cement, stone, metals, paint, leather, paper, sand cloth. The investigations may be divided into two classes, one of the laboratory type in which the sulfur content and the humidity of the air were controlled and the other dealing with the exposure of materials to atmospheres not under control. The first type of work has shown that cement is subject to deterioration by the action of sulfur dioxide gas. The experiments with stone indicate that although limestone takes up sulfur dioxide, from the air, moist sulfur dioxide-air mixtures alone cannot be used for establishing- the comparative weathering- qualities of the different types of stone by accelerated test methods. Laboratory tests indicate that sulfur compounds in the air accelerate the corrosion of iron, steel, zinc, copper, and nickel at normal air temperatures and at certain relative humidities. It has also been indicated that certain types of paint are, affected by high sulfur dioxide concentrations, and that paper is attacked by sulfur dioxide in the atmosphere. The investigations of the second type show the amount or variation of corrosion in different localities and under different types of exposure. The investigations (10) (18)4/ during which sulfur determinations were made indicate that sulfur dioxide is a main controlling factor in the corrosion of iron and steel but according to Quick (18) may not be for some nonferrous metals. In general, the laboratory tests do not Jive definite data on the loss due to sulfur compounds at the concentrations normally found in the air. The data from atmospheric exposures are not complete from the standpoint of the exact effect of the sulfur compounds. Damage to materials so exposed is affected by factors such as other chemical contaminants, humidity, rainfall, solid deposits, and sunlight. A simple scheme has been devised in Great Britain which is considered to provide a measure of the attack of sulfur compound, on building materials (1). Small cylinders coated

Jan 1, 1939

By A. Gene Collins

This report discusses some of the chemistry and geochemistry of cesium and rubidium. Knowledge of the cesium and rubidium content of oilfield waters aids in resolving the origin of waters and petroleum, exploring for petroleum and other valuable minerals, discovering water pollution sources, and augmenting the knowledge of geologic formations. The methods described in this report permit the detection of less than 0.01 mg/l of cesium and/or rubidium in a complex oilfield brine or water. Solvents possessing high-dielectric constants were evaluated for their ability to extract cesium and rubidium tetraphenylboron from oilfield waters and for their flame emission characteristics. Nitroethane was selected and used for the extraction and flame spectrophotometric determinations because it gave the highest sensitivity. Cesium 137 and rubidium 86 were used to determine the extraction efficiencies, which were about 87 percent and 58 percent respectively using a single 10 ml nitroethane extraction from a distilled water matrix. The standard deviation of the determination was 0.0008 mg for cesium and 0.0007 mg for rubidium in the 0.01 mg range.

Jan 1, 1965

By B. J. Moore

This publication contains routine analyses and related source data for 374 natural gas samples from 24 States and 5 foreign countries. These samples were collected during calendar year 1966 as a part of a continuous survey of the free world for occurrences of helium in natural gas. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses of foreign samples contained in this publication represent the first samples received as a result of this expanded program. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863 and 576.4 Eight previous publications have been made to present the results of 7,244 gas analyses made? by the Bureau of Mines Helium Activity prior to 1966. The first three, Bulletins 486,5 576,6 and 617,7 contain analyses and related

Jan 1, 1967

By S. J. Broderick

[The discovery in 1934 that carbonaceous materials, such as coal, peat, and lignite, when treated with concentrated sulfuric acid, were given cation or bate-exchange properties opened up a field of new materials with many interesting possibilities. These hydrogen exchangers, as they were called, were so superior to the impractical hydrogen exchangers made from natural and synthetic zeolites tat they were accepted immediately by the water-conditioning industry. A noteworthy advantage of the carbonaceous exchangers is that they are nonsiliceous, hence they do not give up silica to the water as do the natural and synthetic zeolites, especially if the hard water is corrosive. For this reason the new exchangers found immediate favor in boiler-feed-water conditioning.]

Jan 1, 1941

By S. J. Broderick

[The discovery in 1934 that carbonaceous materials, such as coal, peat, and lignite, when treated with concentrated sulfuric acid, were given cation or bate-exchange properties opened up a field of new materials with many interesting possibilities. These hydrogen exchangers, as they were called, were so superior to the impractical hydrogen exchangers made from natural and synthetic zeolites tat they were accepted immediately by the water-conditioning industry. A noteworthy advantage of the carbonaceous exchangers is that they are nonsiliceous, hence they do not give up silica to the water as do the natural and synthetic Zeolites, especially if the hard water is corrosive. For this reason the new exchangers found immediate favor in boiler-feed-water conditioning.]

Jan 1, 1941

By Richard J. Bielicki

This Bureau of Mines study estimates the number of major pieces of coal- mining equipment that will be required to produce 950 million tons of marketable coal in 1980 and 1.2 billion tons in 1985. The coal tonnages were projected in the intermediate coal supply scenario of Project Independence Blueprint (PIB). The equipment projections were determined by consideration of historical trends and by evaluation of information from equipment manufacturers and mining companies. The ability of the manufacturers to meet the projected equipment demands was also determined. It was concluded that equipment supply offers no presently discernible constraint to mining 1.2 billion tons of coal in 1985. A shortfall in projected production for the intervening years, however, is probable owing to anticipated shortages of draglines.

Jan 1, 1976

By N. F. Le Jeuns

For a number of years the Bureau of Mines has conducted semi-annual surveys to determine the changes in motor gasoline being sold in the United States. It was pointed out in the previous survey that there was an apparent tendency toward greater uniformity in the character of gasoline marketed in the United States. This practically uniform tendency which continued from April, 1917 to January, 1923, has been interrupted in the, present survey, as shown by an examination of the column marked "Difference," as given in Table 1. The figures in this table were obtained by averaging the end points of the least volatile and most volatile samples of gasoline. For example, of 850 samples analyzed in 1919, the 10% ,(85 samples) having the highest end points and the 10% having the lowest end points mere grouped, and the end points of each group averaged. These averages are represented in the table as the "Maximum 10%" and the ?Minimum 10%? respectively. The same process was used on the other surveys.

Jan 1, 1923

By A. B. Hooker, R. A. Kearns

Material used for flame safety lamp gauzes should possess the following qualities: (1) mechanical strength, (2) resistance to corrosion under service con- ditions, (3) a relatively high thermal conductivity, (4) a melting point above the ignition temperature of mine gas. Heretofore, three metals have been used for flame lamp gauzes, namely: steel, brass and copper. While each of these has the requisite qualities to some extent, none of them is an ideal gauze material. Copper gauzes lack mechanical strength, especiall, after they have been heated; brass and copper both have comparatively low melting points so that before the gas ignition is reached the gauze metal is attacked and oxidized under the action of the heat. Steel corrodes readily in damp atmos- pheres and if the lamp stands unused under these conditions for some time, the gauzes become unfit for service. Tests of these three materials have shown that steel offers the highest degree of safety. Manel metal, the natural alloy of nickel and copper, is practically noncor- rodible. Its relting point is approximately the same as that of steel. From time to time it has been suggested that this alloy might be a better gauze material than steel, since gauzes made of Monel metal should have all of the good qualities that steel gauzes possess and, in addition, would not corrode appreciably in ordinary mine atmospheres. One advocate of this use for Monel metal, the International Nickel Co., through their development engineer, Mr. Robert J. McKay, cooperated with the Interior Department, Bureau of ines, to the extent of supplying twelve sets of 30 mesh, Monel-metal gauzes for tests. Those gauzes were made up by the same lamp manufactur- er ho rade the steel gauzes used in the previous investigation. Being made by the same processes as the steel gauzes, these Manel-metal gauzes were needlessly given the same anti-rust coating that is always applied to steel gauzes to prevent any corrosion before the gauzes are used. In previous tests the Bureau of Mines had collected data as to the behavior of steel gauzes. In determining the value of Monel metal as a gauze material, it was planned to obtain similar data with Monel-metal gauzes, and thus make a direct comparison with the steel gauzes. In addition, steel and Monel-metal gauzes

Apr 1, 1923