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By R. A. Cattell

With the activities of the Petroleum and Natural Gas Division geared chiefly to problems directly connected with the war effort , the emphasis of the work under oil and gas development and production was to make engineering studies of selected reservoirs for the Petroleum Administration for War , to determine the extractable quantities of components in them, and to study the characteristics of these components for use in the manufacture of aviation gasoline and other products . The needs of the Petroleum Administration for War and the operators for specific data from gas - condensate fields were fulfilled , and , in addition , engineering data along lines of a forward - looking program of research on reservoir behavior were collected , which should be of great value in the postwar period . It is planned to publish many of these data as soon as conditions permit . The work of the Secondary Recovery Section had as its objectives in- . creasing the rate of production of crude petroleum and , which is more important , preventing the premature abandonment of wells in " stripper " and marginal According to the National Survey of Stripper Wells by the National Stripper Well Association in cooperation with the Interstate Oil Compact Commission , a total of 67,460 stripper wells was abandoned from January 1 , 1935 , to July 1 , 1942 , inclusive , with an estimated loss in proved reserves of approximately 216 million barrels . This survey also indicates that over 1.2 billion barrels of oil would be recovered by primary production from more than 290,000 stripper wells then in operation , and an additional 2.5 billion barrels of oil could be recovered from them by secondary production methods . The work of the Chemistry and Refining Section was oriented towards the optimum utilization of crude oils in the manufacture of aviation fuels for spark-ignition and jet - propulsion engines . The work involved intensive studies of superfractionation , hydrocarbon analysis , and the engine testing of fuels . Particular attention was given to the effect of sulfur compounds in the crude oils and in the fuels made from them . The research on thermodynamics is concerned with the experimental determination of precise and accurate values of the fundamental thermodynamic constants of pure hydrocarbons and related compounds . The data obtained in these investigations will be utilized for devising and improving chemical processes in which petroleum hydrocarbons are the raw materials . Without such data , much time and expensive material and equipment may be wasted in attempts to obtain reactions under conditions that the laws of thermodynamics rule out of consideration . Thermodynamic data are useful and required in the petroleum industry for calculations of heat balances in the design of furnaces , fractionating towers , and heat- transfer equipment . It is of utmost importance , also , to know the heat requirements of cracking and other chemical reactions so that heat may be supplied or dissipated in the proper proportions . These needs for thermodynamic data are being recognized more and more by petroleum -refining engineers . The responsibility for the production of helium for the Navy , the Army , other governmental agencies and non-Federal users is vested in the Bureau of Mines by an Act of Congress ( 50 Stat . 885 ; 50 U.S.c. 161-166 ) . The Helium Subdivision of the Petroleum and Natural Gas Division continued to meet all demands for helium .

Jun 1, 1949

By James R. Boyle

The value of Alabama's nonfuel mineral production in 1980 was $328.6 million, a decrease of $7.8 million from 1979. Cement, crushed stone, lime, clays, and sand and gravel continued as the major commodities produced. Alabama led the Nation in the production of crushed marble; was second in bauxite; third in native asphalt, ferroalloys, kaolin, and oyster shell; fourth in dimension marble, masonry cement, and bentonite; and fifth in fire clay and lime. Alabama ranked in the top 20 States in total value of non-metallic minerals produced. Adverse economic conditions in the construction and metals industries impacted on the minerals industry in Alabama. Mineral producers supplying raw or finished materials to these industries experienced periodic reductions in sales during the year. Unit price increases did not keep up with inflation.

Jan 1, 1982

This report, the second in an annual series, summarizes information on latest technological developments and advances, and identifies trends in mining and metallurgy based on a review of activities in the minerals industry in 1971. Exploration and mining data obtained from an annual canvass are presented for 1971 and are compared with similar data obtained over the past decade.

Jan 1, 1973

By Fred D. Wright

A compressor and utility station, which is believed to be one of the largest mobile units of this type ever constructed, was placed in operation at the Bureau of Mines experimental oil-shale mine near Rifle, Colo., during. 1949. This mobile unit mounts two 770-cubic-feet-per-minute air compressors, a 2,500-gallon water tank, and a 200-cubic-foot air receiver. The mobile base of the unit is a 30-ton trailer 30-feet long and 12-feet wide. Prior to the construction of this unit, compressed air was supplied to underground workings through pipe lines connecting with a stationary compressor plant on the surface. The power consumed in supplying compressed air to underground drilling crews was 0.531 kw.-hr. per ton of shale broken. Use of the mobile unit has cut this figure to 0.421 kw.-hr. per ton of shale broken and, more important, has eliminated the cost of installing and maintaining underground air and water lines.

Jan 1, 1950

By L. T. MCELVENNY, Robert B. McElwaine, M. Clair Smith

Production of mercury from the cinnabar deposits of the southwestern Arkansas mercury district began in 1931 , reached its peak in 1942 , and ended in 1944. The mines are now idle . Virtually all the cinnabar was obtained from deposits in a belt , about a mile wide , of steeply dipping sandstone beds in the overriding blocks of three thrust faults . The belt was productive for a length of about 27 miles eastward from eastern Howard County, through Pike County, into Clark County . During the early life of the district, Federal agencies watched and recorded its progress as a contributor of a strategic metal, and later, during the war, conducted investigations designed to advance its development . In 1941 , the Bureau of Mines and the U. S. Geological Survey cooperated in investigations on eight mineralized areas in the western part of the district , to wit : Hales mine , U. S. mine , Lulu Bell property, Hopkins Hill , East Gap Ridge , Gap Ridge , Parnell Hill , and Section 17 mine area . U. S. Geological Survey prepared both surface and mine maps and designated the areas to be investigated ; the Bureau did the drilling , trenching, and sampling involved in the investigations . Twelve holes , aggregating 3,539 feet of bore , were diamond drilled on six properties ; 5,309 linear feet of surface trenches were bulldozed in six areas and 19 samples taken from them ; and 86 underground channel samples were cut in two adits on one property . In 1944 , the Bureau of Mines measured mine dumps and calcine dumps in the district in an investigation of their mercury content . Two mine dumps and one calcine dump were sampled . The data pertinent to the work done by the Bureau are included in this report .

Oct 1, 1950

By R. Hogg, T. F. Dumm, L. G. Austin, M. Yekeler

"Dedicated to Professor Kurt Leschonski on the occasion of his 60th birthdayAbstractThe kinetics of batch grinding quartz from a feed of 600 by 425 Jim to a product of 80% less than 10 µm have been determined using screening and laser diffractometer sizing for size analysis. The specific rates of breakage decreased by a factor of about three when the material became less than about 100 µm in size, but the primary breakage distribution function also changed to give proponionately more fine material, so that the grinding efficiency expressed as the development of surface area (B.E:T.) per unit of energy input did not decrease. Analysis of the shape of the particles in the 2S x 38 µm size range showed that particles of this size produced by roll crushing or by 8 minutes of grinding of a 42S x 600 µm feed were not different but at long grinding times the particles were rounded. This suggests that the breakage mechanism changes to give more chipping and abrasion and less disintegrative fracture. As the material approached the ultrafine size range it adhered to the mill case and there was no further size reduction. However, a technique for striking the mill case to dislodge the particles was successful in allowing further grinding to 400Jo by weight less than 2 µm.1 IntroductionIt has long been known that it is difficult to accomplish ultrafme grinding in a tumbling ball mill. It has been reported [12, 13] that there is no further size reduction after some hours of grinding cement clinker in laboratory ball mills. Austin and Bagga (1] and Shah and Austin [16] have given an analysis of the kinetics of dry grinding in a laboratory ball mill, introducing the concept of a slowing-down factor K, which is the ratio of the specific rates of breakage at some long time of grinding to the normal specific rates of breakage. They showed that this factor decreased as fine material accumulated in the mill charge. Cottaar and co-workers [8-10] showed that the movement of solid in a dry laboratory ball mill was influenced by the fineness of the solid and by the presence of air, and that evacuation of air from the mill caused particle sedimentation and low rates of breakage.The concept of the slowing-down factor has also been used in wet grinding [17, 18]. At very .high slurry concentrations it appears to be correlated with a steady decrease of mill power caused by the build up of a layer of deposit sticking to the mill case. This reduces the effective mill diameter and, eventually, the balls start to adhere in the layer and centrifuge. A decrease of mill power always indicates less lifting and tumbling of the media and, hence, less breakage. However, slowing-down of breakage rates was also observed at lower slurry concentrations where there was no change in mill power."

Jan 1, 1990

By Joseph A. DeCarlo

THE TOTAL VALUE of sales of coal-chemical materials in the 10-year period 1948-57 increased 34 percent or at an average annual rate of approximately 3.5 percent. According to the Chemical Industry Facts Book, third edition, 1957, published by Manufacturing Chemists' Association, Inc., the production of industrial chemicals since 1939 "has grown at au average rate of about 10 percent" a year (p. 7). The rapid growth of the chemical industry increased requirements of chemical raw materials at a faster pace than could be supplied by coal carboniza¬tion, and view sources of supply became necessary. The petroleum industry in the past decade increased tremendously the flow of chemical raw materials to the chemical industry through the processing of crude petroleum and natural gas. Whereas coal carbonization supplied most of the raw materials for manufacturing synthetic organic chemicals before World War 11, coke ovens supplied only about 40 percent of the total used in 1957. Although the proportion of chemical raw materials supplied to the chemical industry by coke-oven operators declined, this source of supply is large and important to our economy. In 1957, the value of coal-chemical materials sold, including surplus gas used by producing companies, totaled $358 million, compared with $267 million in 1948. Major factors that contributed to this gain were (1) increased production of all coal chemicals and (2) higher prices for tax and light-oil products. Gains in output of coal chemicals resulted principally from expansion in carbonizing capacity of coke plants owned and operated by the iron and steel industry, as yields of the basic coal¬-chemical materials (tar, ammonia, light oil, and gas) varied only slightly during the 10 years under review.

Jan 1, 1959

By Henry P. Wheeler

Natural gas was first stored underground in Welland, County, Ontario Province, Canada, in 1915.3/ The following year natural gas in the United States was first stored underground successfully in the Zoar field near Buffalo, N, Y. Only three additional storage fields were in use in the United States in 1930, but by 1940 the number had increased to over 30, and since that time growth has been more rapid. At least 80 fields, with a combined storage capacity of 440,828 MM c. f ., were being utilized by 1949.4 / In May 1952, 142 storage projects having a capacity of 915,000 MM c.f. were in operation .5/ These fields are distributed from New York to California--from Michigan to Texas. In the Appalachian region alone, there are 101 storage fields with a combined capacity exceeding 526,000 MM cu. ft. Why Natural Gas is Stored Natural gas is stored in order to be readily available to meet the needs of consumers.

Jan 1, 1952

By Irving Hartmann, Edward Thomas

"INTRODUCTION Adoption of rubber-tire shuttle cars underground in conjunction with mobile coal-loading machines has introduced new problems in the control of dust on mine roadways. Where this type of loading and transportation is used, development and extraction are generally rapid, with the result that much coal is spilled from the shuttle cars during normal operation, Coal in the roadways from this source and from sloughing of the ribs is ground to fine dust by the wheels of the 'shuttle cars and by the treads of the loading and mining machines. The coal dust usually is somewhat contaminated by pulverized rock, and the mixture could not be loaded with the run-of-mine coal without undue contamination of the product even if it were cleaned up promptly.The presence of large quantities of fine, loose dust, which is constantly stirred up and kept in suspension in air by the traffic, constitutes a grave explosion hazard, reduces visibility along the roadways, and is physiologically harmful to the workmen who breathe the air. From the operating standpoint the loose material is undesirable along the roadways because it provides poor traction for the trucks and thereby increases wear and power consumption. The dust-explosion hazard could be eliminated or reduced by frequent application of sufficient rock dust on the roadbed; but this would not remedy the other difficulties, and in fact it might intensify them. Where practicable, the most direct and effective safety measure is to clean up and remove promptly all dust that forms and settles on the roadways. Unfortunately, in many cases this procedure is not feasible. A third Suggested remedy is to prevent dispersal of the dust into the air and to promote its consolidation on the floor by wetting the dust particles.During the past few years several mines have used calcium chloride on shuttle-car roadways to allay the dust thereon. When exposed to the' humid atmosphere of the mine this salt absorbs Moisture from the air and deliquesces, and in this way wets the dust on the floor of the roadway. In a survey conducted in coal mines in southern West Virginia and in eastern Kentucky where calcium chloride has been in use, somewhat conflicting re- ports were received regarding the merits of the application, and several operators have abandoned the practice either because of actual or assumed disadvantages. The purpose of the study described in this report was to collect and correlate evidence and, on the basis of experimental data obtained in the field and in laboratory tests, to present a clearer picture of the factors involved in the allaying of dust by use of salts."

Sep 1, 1945

By William H. Pomroy

Fires in underground metal and nonmetal mines pose a threat to the safety of underground miners and to the productive capacity of this Nation's mines. Contaminated air (smoke, carbon monoxide, and other products of combustion) is the primary life safety hazard created by a mine fire. The most reliable defense against the hazard posed by the rapid spread of contaminated air underground is early warning fire detection and rapid evacuation. This Bureau of Mines report describes the design and operation of four prototype early warning fire detection systems, for underground noncoal mines, presently undergoing prolonged in-mine testing by the Bureau. The systems are described within the context of the underground mine environment.

Jan 1, 1985

By L. B. Pankratz

Heat contents, measured above 298.15° K, and derived entropy increments are presented in tabular and equation form for the two crystalline forms of zinc sulfide (sphalerite and wurtzite) and for four solid solutions of iron and zinc sulfides having the compositions Zno.,,6Fe0.302S, Zno.750Fe0.250S, Zno.650Fe0.3505, and Zno.498Feo.502S.

Jan 1, 1965

By C. J. Walker

The Bureau of Mines undertook a theoretical and laboratory study to determine the feasibility of using ethylene as a tracer for natural gas in underground gas-storage reservoirs. The study indicated that ethylene was a useful gas tracer in underground gas storages. Tracer losses were not excessive. Laboratory tests were conducted at pressures as high as 500 psia in both wet and dry consolidated-sandstone cores, evaluating tracer loss with gas blends containing natural gas with different concentrations of ethylene tracer. Under certain conditions losses were less than 17 percent.

Jan 1, 1966

By Gary P. Sames

The Bureau of Mines recently initiated a study of geologic features that contribute to roof instability in western U.S. underground coal mines. The purpose of the study is to provide information for use in ground control planning and safety hazard reduction in that region, where mining activity has been increasing. Hazardous geologic conditions were surveyed in selected underground coal mines in Utah and Colorado, and both depositional and structural features were identified as potential ground hazards. Although the conditions found do not differ in kind from hazardous geologic conditions in the Eastern United States, they do differ in intensity of occurrence and relative importance. Three depositional features dominate where unstable roof occurs in western underground coal mines: paleochannel deposits, crevasse splay deposits, and flood basin deposits. Three structural features identified as hazardous, but not so widespread or common as the depositional hazards, are faulting, jointing, and igneous intrusions. This survey establishes a foundation for future studies aimed at reducing and preventing ground control accidents in western coal mines.

Jan 1, 1988

By Ned H. Snyder

In recent years the Government and other large consumers of coal have appreciated more and more the desirability of definitely determining by chemical analysis and test the character and quality of the coal they purchase. Higher prices for coal point forcibly to the need of giving more study to engine room and boiler room efficiencies and economies; this implies an intimate knowledge of the character and quality of the fuel used. Analyses and tests of delivered coal furnish data whereby power plant results can be comprehensively studied and a continuous check maintained on the coal and on the conditions of plant operation. Under authority of acts of Congress making appropriations for technologic investigation of fuels and the analyzing and testing of fuels belonging to or for the use of the United States Government, a laboratory is maintained at the Pittsburgh station of the Bureau of Mines, where samples representing deliveries of coal purchased for Government use are analyzed and tested. The Bureau of Mines has been active in promoting the purchase of coal by the Government under specifications/ that is, by contracts that make definite requirements regarding the heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analysis. Under many of these specification contracts the bidders guarantee the quality of the coal offered, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled and analyzed to determine whether the coal is of the quality guaranteed by the contractor, and if it is not, the price to be paid is decreased in proportion; but if the coal is of higher quality, the price is proportionately increased. The known analyses of coals or the guaranteed analyses offered by the bidders may sometimes be used for determining the award of a contract, but if the coals offered differ widely in characteristics, it may be difficult to determine which would prove the cheapest fuel without data on their relative evaporative efficiencies. Hence, the making of evaporative tests under service conditions may be necessary in order to determine which coal is particularly adapted for successful and economical use in a certain plant. Once a particular coal is selected, however, regardless of the procedure of determining the award of a contract, then the greatest advantage of the specification method is realized, for it guarantees the purchaser receiving coal of uniform character and quality, thereby insuring the best results in the plant. The success of the specification method for the purchase of coal and the reliability of analysis now rests largely on sampling.3 Improper sampling leads to controversies, with resulting condemnation of the specification method in general and of the value of laboratory analyses and tests in particular.

Jan 1, 1922

By Peter H. Toepfer

Hydraulically emplaced, classified mill sands long have been used for stope fill. Entrained water drains rapidly from this type of fill through openings between the sand grains. Slimes are removed to facilitate drainage of the water, thereby lowering dangerous hydrostatic pressures in the fill. Use of unclassified mill tailing as practiced at the Dayrock mine is a recent development and represents a fundamentally different approach to the problems of inhibiting the development of hydrostatic pressures within the stope fill. At the. Dayrock mine, mill tailing is used to form a densely packed fill of sand and slime particles relatively impervious to additional water.

Jan 1, 1952

By J. Howard Bird

The purpose of this publication is to describe the power-distribution system of the mine and refinery of the Duval Sulphur & Potash Company at Carlsbad, N. Mex. This distribution system has been excellently predesigned to meet requirements and fit special conditions encountered at the property. In presenting the material, the authors point out various features that would be desirable for incorporation in other systems under similar conditions. Central location of switchgear in pressurized vaults and ventilation of such equipment with filtered air prevent salt accumulations and contribute to trouble-free operation. The simplification of power-distribution circuits and overload protection, as a result of centralization of switchgear, the use of individual control circuits enclosed in conduit (which aids troubleshooting), and central location of control panels, are factors which contribute to efficient, safe operation. Those features are applicable to many operations where fire or explosion hazards are encountered, or where dusty conditions may exist, as well as in operations where numerous individual drives are involved.

Jan 1, 1959

By K. J. Liles

The Federal Bureau of Mines conducts a comprehensive test program on clay and shale at the Tuscaloosa Metallurgy Research Center. All samples are subjected to standard preliminary ceramic tests, which include firing formed briquets at temperatures ranging from 1,000° to 1,250° C to identify firing range and colors, and quick-firing to determine bloating characteristics. Materials that shop potential as structural products are further tested after either extrusion or dry-pressing. If the quick-fire test is positive, bulk samples can be fired in a rotary kiln to evaluate their potential as light- weight aggregate A number of miscellaneous tests also can be conducted if requested. These tests determine properties such as refractoriness (pyrometric cone equivalency), oil-bleaching characteristics, oil absorbency, viscosity for drilling-mud applications, sand-bonding properties for foundry usage, and pelletizing characteristics.

Jan 1, 1977

By W. J. Crawford, P. M. Gruzensky

"Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step.With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C. and contained at least 100 grams of bismuth per liter. An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.The hydrochloric acid electrolyte had the greatest tendency to yield rough, dendritic deposits. Best deposits were obtained at cathode-current densities below 2 amperes per square decimeter. A small amount of glycerin helped to produce a smoother deposit, and adding sulfuric acid or methyl sulfuric acid retarded the deposition of impurities. Very good results were obtained in electrowinning bismuth from a bismuth trichloride-hydrochloric acid electrolyte.Smooth and adherent deposits were obtained from a hydrofluosilicic acid electrolyte, with very good refining as regards lead and silver impurities; however, higher reagent costs and slow decomposition of the electrolyte have discouraged its use.INTRODUCTIONMethods of recovering bismuth from ores and byproducts were underdeveloped for many years because of the limited uses for bismuth, the pharmaceutical industry being the chief consumer. In the past decade or so additional uses for bismuth, particularly in the metallurgical field, have brought about increased demand for the metal with the result that bismuth is being recovered from byproducts that were once discarded. In addition to such uses as low-melting alloys, solders, bearings, die setting, etc., some interest has been indicated in bismuth as a possible coolant for nuclear reactors. The advent of ductile bismuth and bismuth-alloy thermocouple wire has contributed greatly to temperature measurement, particularly in the below-zero range."

Jan 1, 1956

"The present and possible futures commercial production of potash from various sources in the United States is discussed below under the following heads:1. Potash from the saline lakes.(a),Nebraska lakes.(b),California lakes.(c),Other lakes.2. Potash as by-product from the cement kilns.3. Potash as by-product from the iron blast furnace.4. Potash from silicate rocks.(a),Feldspathic material.(b),Leucite rocks of Wyoming.(c),Sericite slates of Georgia.(d),Glauconite (greensand) of New Jersey.5. Potash from Alunite.6. Potash from organic sources other than kelp.7. Potash from kelp.In this discussion very little more than passing reference, if any, will be given to those projects which up to date have been de¬veloped only slightly, if at all, beyond the small scale laboratory stage, or for the development of which there appears to be very little financial and technical backing at the present time. Nether or not many of these proposed projects have merit can be determined only by an actual operating demonstration.Generally speaking, the potash industry of the United States has been hardly more than marking time since the armistice. This is, largely due to the fact that the consumers of potash have been expecting that heavy shipments of foreign potash to the United States would be resumed soon at somewhere near the pre-war prices, and they have not been buying domestic potash at present prices for many months. The result has been that domestic producers have been unable to sell their product at even cost and many producers of potash have been obliged to close down. Thu Nebraska lake plants were closed down in February. The California saline plants were operating at below capacity, and the only large alunite plant is closed down. Even the cement plants have little or no inducements to recover the potash being lost in their waste gases, and the production is very small at present."

Jan 1, 1919

By Ronald B. Hollenbeck

The value of mineral production in Alabama continued to increase and reached a new high of $260 million, 3 percent above the previous high established in 1967. Record high values were reported for bentonite, crushed marble, lime, miscellaneous clay, portland cement, salt, sand and gravel, and scrap mica. The value of coal, total cement, petroleum, and stone accounted for 87 percent of the State's total value of mineral production. Alabama ranked second among the States in the production of bauxite and scrap mica and third in kaolin, masonry cement, and native asphalt.

Jan 1, 1970