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By Andrzej Luszczkiewicz, Aleksandra Potulska

"Flotation is a basic process of beneficiation of mineral raw materials which requires very fine grinding for liberation of valuable minerals. Probably flotation will also play this role in the future. In the case of flotation of difficult-to-upgrade non-ferrous ores, currently one of the most important trends in technology development is solution to fine grinding even down to a few micrometers in size and elaboration of effective flotation technology for such fine particles. Both industrial flotation data and many investigators suggest that the best results of flotation of ore minerals are observed for particle size range from 20 to 100 µm. Many base metal ores require grinding below 20, or even 10 µm, to liberate valuable ore components. However, industrial flotation of particles below 20 µm in size creates numerous challenges. Further complications may be caused by a complex nature of the ore, especially when the valuable metals are present in several different sulfide minerals. This problem occurs in the case of the Polish sedimentary copper ores. In the present study, flotation of the ore of different size distributions and degrees of grinding, having the size of particles below 25 µm, was investigated. The behavior of different sulfide minerals naturally present in the ore was analyzed. The best results of flotation tests were obtained for the ore ground down to 95% below 25 µm. Narrow size fractions -10; 10-15; 15-25; 25-40, and +40 µm were separated using special micro-sieves and mineralogical as well as chemical analyses of each size fraction were carried out for monitoring the behavior of the fine sulfide particles. Differences between flotation of chalcocite-digenite, bornite, chalcopyrite, covellite, galena and pyrite-marcasite naturally occurring in the ore were described. The role of different particle sizes in flotation performance of each mineral was also presented."

Jan 1, 2014

By S. L. Gubin, T. V. Ignatova, A. V. Levshin, D. O. Sharkovsky

"Flotation process applied for concentration of unoxidized ferruginous quartzites by PJSC Mikhailovsky GOK (MGOK) is based on wet magnetic separation of strong magnetic minerals. However quality of the resulting concentrate (Fe65-66%) is insufficient for production of metallics. Quality upgrade of magnetite concentrate via flotation has been implemented by MGOK to produce premium quality magnetite concentrate.Flotation is a challenging process due to sensitivity to varied amounts of reagents, fine and coarse mineral ratio, particle contact (retention) time and temperature of feed. Tomah’s PA-14 reagent (USA) has proven efficient for application in flotation of MGOK’s magnetite concentrate.Objective of this work is to select and prove applicability of selective agents for flotation upgrade of magnetite iron ore concentrate.Series of flotation tests has been carried out with application of new highly selective collecting agents produced by Akzo Nobel (Sweden), Clariant (Germany) as well as Akzo Nobel’s and Tomah’s cationic collector mix to improve performance efficiency of flotation process. Tomah’s flotation agents and Akzo Nobel’s Lilaflotproved to be the most effective for purposes of concentrate quality upgrade to Fe69.0% via flotation.Testing Method: Following scientific research methods were applied for testwork: system analysis, mathematical statistics, observation, comparison, trial (experiment).To determine key process factors a series of pilot tests was carried out. Most of the testwork was performed by PJSC Mikhailovsky GOK’s Central Process Laboratory.Work Results:-optimized flotation performance modes were defined to ensure production of three types of low-silica concentrate, i.e. containing SiO25%, SiO24% and below SiO23% by weight. Most efficient selective agents applicable for flotation have been defined. Mixture of higher aliphatic amines has proven to intensify selective flotation of quartz. It enables higher yield of chamber product maintaining desired quality of concentrate.Achieved process operation and performance factors have been revaluated.Value for Advancement and Expansion of Mineral Processing:Flotation of concentrate has enabled expansion of PJSC Mikhailovsky GOK’s production capacity, improved production quality, helped to maintain sustainability and competitive advantage of the company."

Jan 1, 2018

By John A. Herbst, Ming Song, Xiangjun Qiu

It has been known for sometime that as wear occurs in tumbling mills there is an associated change in mill throughput. These changes have traditionally been simplistically, attributed to “mill volume effects”. New high fidelity simulation tools (involving DEM, CFD and Breakage models) are now giving new “microscale” insights into the complex interactions that occur between evolving lifter/liner profiles and breakage. The study described here shows that these new tools can allow the design of wear part profiles which will maximize mill productivity over the entire life of a liner/lifter system.

Jan 1, 2003

By Chanki Jeong, Heechan Cho

In this study, batch flotation experiments were conducted to recover rare earth elements (REE) from an REE ore deposit in the Mushgai Khudag area, Mongolia. Apatite was found to be the major REE mineral while monazite and xenomite were observed as minor minerals. The main purpose was to float apatite to increase the REE content. Oleic acid was used as collector and MIBC was used as frother. Sodium silicate was used as a depressant for iron compounds. NaOH was used to adjust the pH of the flotation to about 9.5~10.0. The particle size was 90% less than 152 ?m (- 100 mesh). The content of REE elements was analysed by ICP - OES to determine the contents of REE such as Ce, La, Nd, Pr and Y. When sodium silicate was used, the best result was obtained using 0.2 mL of sodium silicate, 2 mL of oleic acid and 2 mL of MIBC. Under these conditions, the recovery of REE was about 78% and the grade of the first froth product was 42,995 ppm Ce, 24,088 ppm La, 14,236 ppm Nd, 4,388 ppm Pr and 1,570 ppm Y. When conducting flotation after iron minerals were removed by magnetic separation, a better result was obtained; with 2 mL of oleic acid, 2 mL of MIBC and no sodium silicate, the recovery was increased to 90% and the grade was also increased to 58,600 ppm Ce, 28,624 ppm La, 17,160 ppm Nd, 5,348 ppm Pr and 1,971 ppm Y.

Jan 1, 2014

By Sashnee Raja, Mehdi Nemati, Ashley Sissing, Susan T. L. Harrison

"Extreme thermophiles, operating at 65 - 90°C, are finding increasing application in biohydrometallurgy These microorganisms have the advantage of exhibiting better oxidation kinetics in terms of reaction rate and extent of mineral solubilisation. These extreme thermophiles are Archae, characterised by a different cell envelope structure perceived to provide reduced structural strength in comparison to bacterial envelopes, and customised metabolic pathways.The active tank bioleaching process, used for high rate leaching, is conducted in a slurry bioreactor. Here sufficient energy dissipation is required to ensure suspension of the mineral phase as well as to sustain high rates of gas liquid mass transfer. It is well known that subjection to hydrodynamic stress of sufficient magnitude may alter the physiological state of a range of micro-organisms through changed viability (ability of the microbes to grow), metabolic activity and integrity.In this paper, we report on studies carried out to quantify the ability of the extreme thermophile Sulfolobus to withstand the hydrodynamic stress environment generated at high pulp densities in the slurry bioreactor. Both a pyrite system (as a model system) and a chalcopyrite system (as an application) were studied. In laboratory reactor systems, the nature of biological responses to stress induced at high pulp density have been identified in terms of ability of the microbes to grow, their metabolic activity and rate of leaching and cell integrity. Critical operating conditions within the laboratory reactor are identified and the mechanism mediating reduced performance considered."

Jan 1, 2003

By Shibayama A.

In this research, an investigation of a process to selectively remove arsenic (As) and antimony (Sb) contained in enargite (Cu3AsS4) and tennantite/tetrahedrite ((Cu1,Fe)12(As,Sb)4S13) copper resources by leaching and precipitation were performed. First in the leaching process, the target was to selectively leach As/Sb and reduce their contents in the ores to <0.5 wt% followed by a second process to remove As/Sb dissolved in solution for environmental control. Enargite ore contained 3.65 wt% As while tennantite/tetrahedrite ore contained 5.40 wt% As and 4.85 wt% Sb. Alkaline leaching using NaHS?NaOH media at varying experimental conditions (temperature, pulp density, time, reagent concentrations) were performed to investigate the process. As/Sb precipitation studies were also performed to control high As/Sb concentrations in leach solutions by using elemental sulphur (So). Results from leaching studies showed that over 99% of As/Sb in the impure copper ores can be removed and their contents in the final solids reduced to <0.5 wt%. It was also established that such very high leaching could be achieved at 80°C within 1?6 h and pulp densities as high as 1000 g/L. The study also revealed that leach solution containing very high As/Sb concentration ranging from 5 to 20 g/L can be used as fresh solution for leaching of fresh ores until concentrations exceeding 35 g/L when it was sent to precipitation circuit for As/Sb removal. Addition of elemental sulphur at 90°C and fast cooling to 30°C allowed over 60% As/Sb precipitation and removed as Na3AsS4 and solution with reduced As/Sb concentration to leaching circuit for continuous use. Keywords: Enargite; Tennantite/Tetrahedrite; Selective Leaching; Precipitation; Sodium hydrosulfide;

Sep 1, 2012

By S. Serranti

A fast, reliable, and low cost characterization of ore minerals products, as they result from different processing actions, represents one of the most challenging targets in the mineral processing sector. Today different techniques are available according to different sampling strategies and analytical principles. In this paper, the possibilities offered by the adoption of hyperspectral imaging based sensing units working both at micro- and macro-scale are presented and discussed. According to the different phases and stages of ore minerals and products characterization, and starting from the analyses of the detected hyperspectral firms, it is thus possible to derive useful information about mineral flow stream properties and their physical-chemical attributes. This last aspect can be utilized to define innovative process mineralogy strategies and to implement on-line procedures at processing level. The present study discusses the effects related to the adoption of different hardware configurations, the utilization of different logics to perform the analysis and the selection of different algorithms according to the different characterization, inspection, and quality control actions to apply. Keywords: process mineralogy, hyperspectral imaging, NIR spectroscopy, surface mapping, textural analysis, quality control

Sep 1, 2012

By Alex Joseph

A tertiary amine containing polyamine in its back bone was grafted to exfoliated graphite oxide by means of a series of chemical reactions.The synthesized amine functionalized polyaniline grafted to exfoliated graphite oxide (EGAMPANI) was characterized using various techniques such as, FTIR, TGA, Raman, and X-Ray diffraction.The synthesized EGAMPANI was blended with carbon paste electrode, and used to study the response of Hg2+ in acetate buffer solution.Preliminary analysis showed that the anodic current intensity using the EGAMPANI modified electrode was higher during a potential sweep and 10-4 M concentration of mercury could be detected which could be improved to 10-6 M using anodic stripping voltammetric technique. Keywords: metal sensor, exfoliated graphite oxide, functionalization, polyaniline

Sep 1, 2012

By I. H. Mukhametshin, E. N. Baranova, I. B. Fadina, E. A. Ashirbaeva

The purpose of the research is the development of a complex of solutions for the maximum extraction of non-ferrous and precious metals from persistent mineral raw materials by heap bioleaching from spent heap leaching (HL) stacks. Methodical recommendations for assessing the suitability of primary and technogenic refractory mineral raw materials for heap bioleaching are developed. Active associations of microorganisms have been created for the conversion from various types of ores to the solution of S, Fe, As, Sb, Cu, Zn, Mn, Ni, Mg, P and other elements, as well as methodologies for their storage, immobilization and preparation of bioreagents in industrial conditions. On a pilot scale, tests were carried out on samples weighing 15-17 thousand tons of refractory gold-sulphide ores (more than 50% of gold is associated with sphalerite), gold-quartz ores with colloidal gold (74% associated with quartz and pyrite) and gold-silver ores with elevated copper and zinc content (1.5 and 3,5%, respectively), as well as man-caused material lying for 4-5 years of spent quarry material of oxidized gold-silver ores. In the pilot-industrial tests of heap bioleaching of gold-sulfide ores, gold recovery of 84-85% and silver was achieved to 89-90%, the possibility of obtaining high-yield solutions of copper and zinc, suitable for hydrometallurgical processing, from gold-silver ores, and the possibility of obtaining waste with a dump content of valuable components, suitable for deep disposal in the construction industry. When comparing two technologies for processing refractory ores after biooxidation under HL conditions, when 1000 tons of ore processed by the bioreagent were re-milled from a size of 40 mm to 0.1 mm and cyanated under the conditions of the factory process, the same results were obtained for gold recovery (85%) and silver (90%), as with the heap version. The copyrights of the development are protected by a patent.

Jan 1, 2018

By M. Mezzetti, E. Anders, O. Popov, P. Hoske, H. Lieberwirth, M. Voigt

"The material breakage induced by high energy electric discharges is known in general as electric impulse technology. This technology can be used for processing solid materials, such as rocks and ores. The electric impulse technology has been around for about 60 years, originally developed and intensively investigated by Russian researchers. However, the application fields have been limited to research and laboratory scale projects. Currently, there are new attempts to transfer this technology into practical industrial applications. Practical examples include drilling of deep geothermal wells with an electric impulse driven drill-head. Traditional comminution implies high energy consumption, hence, high costs. The Electric Impulse Technology is interesting for comminution of mineral and complex ores since it could allow improved recovery and energy reduction, thus resulting in significant savings. Another advantage is the dust free processing, which contributes to make minerals processing environmentally friendly. The use of electrical comminution for processing complex ores is investigated within the ELIZE research project funded by the BMBF (project No. 033R161 A) and industrial partners. The main objective is the development of an industrial scale electrical comminution machine. The first development stages include the investigation and characterization of the electric impulse induced weakening on rocks and ores. The characterization results of the preliminary trials at the microstructural scale on granite, skarn and greisen will be presented and discussed in this article. INTRODUCTION The pioneer work in the area of electric impulse technology was conducted by Russian researchers about 60 years ago [1]. While there have been some successful attempts to transfer this technology into practical applications, such as rock processing [2], laboratory processing of mineral ores [3–5], recycling [5] and geothermal drilling [6–9], the jump into practical industrial large scale application has not been accomplished yet. The Institute of Mineral Processing Machines of the TU Bergakademie Freiberg currently leads a project which can be seen as the next logical step for the technology transfer to industrial applications, namely, the development of continuously operating complex ore processing machines based on the electric impulse technology."

Jan 1, 2018

By Kazutoshi Haga, Batnasan Altansukh, Shirchinnamjil Nyamdelger, Atsushi Shibayama, Narankhuu Ariunbolor, Gunchin Burmaa

In this study, the authors investigated the capability of an acidic thiourea solution and silicon-organic polymers (PSTM-3c, PSTM-3T) as ion-exchange resins to recover of gold from gold-bearing ore concentrates. Firstly, elemental gold present in flotation concentrates was dissolved by leaching with a solution of nitric acid and thiourea under the optimized conditions. The best result on gold thiourea leaching was obtained under a nitric acid concentration of 2 N, thiourea concentration of 2 %, and oxidant (Fe2(SO4)3) concentration of 3 %, solid:liquid ratio (S:L) of 1:20, leaching time of 6 hours at 20 °C with a gold recovery of 93.7 % for a gold flotation (unroasted) concentrate. For the roasted gold concentrate, the dissolution of gold was 94.8% under the optimized leaching condition as nitric acid concentration of 0.5 N, thiourea concentration of 2 %, and the oxidant concentration of 1 %, S:L ratio of 1:10, leaching time of 4 hours at 50 °C. Secondly, a series of sorption tests was carried out on a pregnant leach solution containing gold complex Au[S=C(NH2)2]2+ using silicon-organic polymers (PSTM-3c and PSTM-3T), respectively. The effects of solution pH, adsorption time and temperature in the sorption process are also studied. As the results, the PSTM-3c and PSTM-3T polymers were adsorbed about 94.4 % and 95.1 % gold from the pregnant leach solutions under the optimum sorption conditions, respectively. It was found that the both PSTM-3c and PSTM-3T polymers were effective for the recovery of gold from the pregnant leach solution of thiourea. Adsorption activity of the PSTM-3c and PSTM-3T polymers was confirmed by new peaks near 1700 cm-1 in the FT-IR spectrum of the gold-adsorbed polymers, respectively.

Jan 1, 2014

By Tohru Kamo, Shigeyuki Katano, Hideki Nakagome, Maiko Adachi, Shingo Nakamura, Kaneshi Taniguchi, Zar Zar Hlaing, Takaaki Wajima

Tantalum capacitor is a small-sized and has large capacity, and is indispensable for electric equipment. The demand increases year by year, and a quite large number of used tantalum capacitors is generated. Recovery of tantalum from tantalum condenser is recently important since production of tantalum have not been stable for the price and the quality. However, recovery of tantalum from tantalum-condenser is difficult since tantalum parts strongly cover with the flame retardant resin made of halogenated compound (mold resin). This research investigated recovery of tantalum parts from tantalum condenser using steam gasification with mixed molten carbonate. Mixed molten carbonate (Na2CO3:K2CO3:Li2CO3 = 1:1:1) (3 g) put into the reactor, and heated with electric furnace while flowing nitrogen (160 mL/min) and steam (1 mL/min) warmed by heater. After heating to setting temperature (450 - 650 oC), tantalum condenser (3 g) was put into the reactor, heated for 5-10 min, and then cooled to room temperature to recover the reacted capacitor by filtration after treating with distilled water. At relatively low temperature (550 oC) heating for 10 min, mold resin can be decomposed by using steam gasification with mixed molten carbonate, in comparison with using pyrolysis and steam gasification without carbonate, and decomposition reaction occurred over 500 oC by using steam gasification with mixed carbonate. Recovery of tantalum parts from capacitor is successful using steam gasification with mixed molten carbonate at 530 oC for 5 min, due to the effective decomposition and removal of mold resin from capacitor. Furthermore, most halogen gas generated from decomposition of mold resin can be trapped in molten carbonate not to exhaust halogen gas. These results suggested that recovery process of tantalum parts from used condenser using steam gasification with mixed molten carbonate is expected as a feasible way to recycle the rare metal in electric equipment.

Jan 1, 2014

By Saveliy F. Kaplan, Valeriy N. Tsyplakov, Vasily N. Kovalev, Igor A. Agapov, Nikolai V. Vorob’ev-Desyatovskii

"Based on the experiments, a possibility of successful processing of double-refractory gold sulphide concentrates with a high content of natural organic carbon, which has a high sorption capacity toward gold chloride complexes, has been demonstrated. The proposed approach involves deep burnout of sorption-active organic carbon in an autoclave at a higher temperature and a longer retention time. INTRODUCTION It is known that one of the reasons why gold-bearing ores and concentrates are refractory is the occurrence of fine gold in sulphides (usually in pyrite and arsenopyrite) in ores and concentrates. In addition, refractory gold-bearing ores and concentrates also contain an organic carbonaceous material, which has a sorption capacity towards gold chloride complex, making the ore or concentrate even more refractory. In pressure oxidation, metallic gold is oxidized by Fe (III) aqua-ions and complex Au(Cl)4- ions are formed at temperatures over 180°C, in the presence of chlorides contained in ores. Complex gold anion is adsorbed on the organic carbon surface and then reduced to Au0; the chloride ion is regenerated and gold, adsorbed on organic carbon microparticles, is ultimately transferred to tailings (preg-robbing). Currently, there are several suggestions how to suppress preg-robbing (Simmons, 1998, Pyke, 1999, Rees, van Deventer, 2000, Zhao Jun-wei, 2008). It can be done by reducing the organic carbon content by processing (flotation, etc.),reducing chloride ion concentration by preliminary washing of concentrates in thickeners, reducing the adsorption capacity of organic carbonaceous material by introducing some organic substances that are strongly adsorbed on its surface (blanking agents), and reducing the redox potential of the slurry liquids by introducing neutralizing agents (limestone)."

Jan 1, 2018

By D. Szyszka

During passing gas bubbles through mineral suspensions, some mechanical carryover of fine particles to the froth layer always takes place. The entrainment of mineral particles is influenced by many parameters, mostly by the particle size and the concentration of the frother. The paper deals with influence of selected frothers (methylisobutylcarbinol (MIBC), a-terpineol, and hexadecane tricosaethyleneglycol ether (C16E23)), common laboratory flotation frothers, on the mechanical car-ryover of quartz, a typical gangue mineral component of ores. Entrainment tests were carried out in a laboratory Mechanobr flotation machine with quartz particles suspended in aqueous frother solu-tions. The mechanical recovery of quartz in the presence frother was increasing with time and reached plateau after about 20 minutes of flotation. The plateau level of quartz recovery depended on the frother concentration. Initially an increase of the plateau with frother concentration was observed until the plateau reached the highest level called the maximum recovery emax. The emax can be used as a parameter to characterize the ability of frothers to entrainment. In the studied quartz-frother flotation system the maximum entrainment was 32%, 50% and 80% for methylisobu-tylcarbinol (MIBC), a-terpineol, and monohexadecane tricosaethylene glycol ether (C16E23), re-spectively. A comparison of the maximum entrainment factor emax with other, known from literature, indices such as bubble critical coalescence concentration (CCC), dynamic foamability index (DFI), Jw, e =25%revealed, except DFI, their similarity.

Jan 1, 2014

By P. K. Fedotov

Annually at least 5% percent of world power consumption is involved in the process of ore dressing while ore processing technology. Such rate of energy consumption demonstrates the importance of a given process study in the human life-sustaining activity. Examining of interparticle destruction being under external stress pressure in ore responses this problem solution at the greatest degree. The technology of destruction in the roll press is of great interest. The use of the given equipment allows to save a significant amount of energy by means of the built-in ore destruction mechanism. Examination of stress-strain fields which determine the level of interparticle destruction between the rolls in the ore layer enables to specify both level of ore destruction and power consumption. The mathematical computer modeling for the deformable environment use based on the finite-element method (FEM) allows to carry out the given research. We use FEM solution for elastic contact problem for the most complete study of power consumption employed in ore and interparticle destruction. This problem solution allows also to examine energy consumption expenses spent for ore crushing in the roll press. Also we have identified the mechanism of ore in a layer of the particles under pressure roller press. It is established that high level of performance and reduction of energy consumption in interparticle destruction of ore in the layer due to the appearance of the gradient of normal stresses in contact of particles of mineral raw materials. The algorithm has been developed determining crushing product particle size distribution of fractured particles in the layer, using the Bond’s theory of crushing. The use of our FEM model reduces the time of equipment selection for new plant and at the design stage to reduce the risks of errors in the choice of roller presses.

Jan 1, 2018

By Megha Patel

"The objective of this project was to investigate the application of Prompt Gamma Neutron Activation Analysis (PGNAA) technology to provide real-time on-belt elemental analysis of feed ore in base metal sulphide processing, in this case at the Mount Isa Mines Zinc-Lead Concentrator Heavy Medium Plant (HMP). After initial exploratory testwork proved successful, a Geoscan On-Belt Elemental Analyser was retrofitted onto the existing HMP feed conveyor. Dynamic calibration of the Geoscan was conducted based on laboratory XRF analysis results of the HMP feed conveyor hammer autosampler samples from May to November 2013. Comparison of the Geoscan results to the laboratory XRF analysis results during and after dynamic calibration indicated the technology had acceptable accuracy to be incorporated into HMP process control. The variation between the two sets of data includes all primary sampling, sample preparation and XRF analysis errors as well as the Geoscan errors themselves. The Geoscan instrument precision must be calculated separately through a duplicate sampling campaign and independent laboratory analysis before extending the scope of its range of application beyond HMP process control. The expected benefits of integrating the Geoscan real-time data into HMP process control are optimised HMP metal recovery, improved cost efficiency and improved stability of the downstream processes (milling and flotation). Utilisation of the Geoscan will also enable improved feedback to mines on grade control and dilution, and provide additional information on individual ore types when fed as campaigns to HMP."

Jan 1, 2014

By A. R. Videla, P. R. Brito-Parada, I. Mackay

"Linking results from laboratory scale experiments to industrial flotation behaviour is challenging. Typically, such experiments involve batch tests in which the system does not operate at steady-state, making it difficult to infer the effects that operating conditions have on flotation performance. In order to overcome this limitation a 4-litre recirculating tank was previously developed at Imperial College London. This tank is capable of reaching, and operating at, steady-state by recycling overflowing concentrate back into the feed. As well as instruments to control operating conditions, it is fitted with a system of sensors that allow the surface of the froth to be dynamically monitored. From this information, it is possible to measure the air recovery—a proxy for froth stability. Thus, this bench-scale tank can be used to understand the effect of differing operating conditions on flotation performance at steady state. However, so far, this cell has only been used to investigate idealised systems with only one or two species.Reprocessing of tailings dams is not only environmentally desirable but also increasingly economically feasible due to the declining head grades of primary deposits. There is also the added benefit of no further milling being required prior to flotation. However, the effects of fine and ultrafine particles on froth stability are not yet fully understood. In this work, the bench-scale continuous tank has been used for the first time to determine the flotation response of a complex feed, consisting of samples from a copper tailings dam, to changes in operating conditions. It was shown that the froth stability in the system is comparable to that of previous work and industrial tests, with a peak in air recovery being found at a superficial gas velocity of 1.13 cm/s. There is scope to optimize the froth stability of tailings flotation for enhanced metallurgical performance."

Jan 1, 2018

By C. Y. Sun

Flotation of chalcopyrite and unactivated malachite with xanthates (ethylxanthate, butylxanthate, octylxanthate and dodecylxanthate) is studied in this paper. Minerals interacted with xanthates are detected by FTIR, and simulated by molecular mechanics. It shows that chalcopyrite can be floated with 4 kinds of xanthates, and unactivated malachite can?t be floated with ethylxanthate but can be floated directly with later 3 kinds of xanthates while characteristic absorption peaks of those four kinds of xanthates are all detected by FTIR on chalcopyrite and malachite surface. After simulating the interaction between xanthate and mineral, it shows that H2O and OH-can interact with chalcopyrite and malachite, and their interaction energy may be so called energy bulwark which must be overcome by collector when collector interacts on minerals; the two sulfur atoms in xanthate group interact with copper and neighbor iron atoms on chalcopyrite. It also shows that molecular mechanics results with logP of collectors can interpret the mechanism of xanthate-mineral on atom scale.

Jan 1, 2014

By Sunil Tripathy, Y. Rama, Srinivasulu. A., Amit Ranjan

Process improvements in an operating plant are always challenging. Mineral beneficiation plants based on gravity concentration techniques need continuous evaluation and monitoring of its processes for getting maximum recovery and better grades. But, in an operating plant it is very difficult to control all the parameters due to numerous reasons such as unsteady operation, fluctuation in the quality of run-off-mine ore, overall flow rate etc. For better understanding of the beneficiation circuit, it is necessary to evaluate the critical operating parameters which affect the performance in terms of grade, recovery and throughput including losses of valuable materials into tailing. Accurate data collection and proper data interpretation followed by making necessary change which is implementable in an operating plant play very critical role in performance of the circuit. In case of gravity operated beneficiation circuits of chrome ores where the quality of the feed and physical parameters varies continuously, the operators are required to modify the critical operating process parameters on continuous basis which is very difficult and tiresome. There are many causes of the data variability, including both error (sampling and assay), and real variation in performance due to changes in ore mineralogy, operating conditions and other factors. In this article, attempts made to evaluate the performance of ultra-fine beneficiation circuit in terms of silica reduction in the concentrate of chrome ore beneficiation plant (COB), India are discussed. The approach adopted and practical problems encountered during the study were also discussed. Results obtained from plant audit based on the above methodology has shown that SiO2 content in the concentrate can be reduced to <4%.

Jan 1, 2014

By Carlos Pereira, Fábio de São José, Francielle Nogueira

Votorantim Metals Corporation is one of the leader companies in the extraction of zinc in Brazil. One of its mines, located in the city of Vazante - MG, was composed by zinc silicate ores, but recent studies have indicated a change in mineralization type with arise of zinc sulphide’s ore bodies with disseminations of galena (PbS) and silver. The liberation size between sphalerite and galena in this ore occurs in very fine granulometry (approximately 18µm), fact that has negatively influenced into the flotation process. Aiming to reduce this problem, studies about the use of dispersing in the flotation process have started. Thus, this study investigated the action of different reagents dispersing on the stability of the suspensions. The tests were carried out with samples of mineral galena and sphalerite using four types of dispersing within two different dosages and two pH. The reagents tested were sodium hexametaphosphate, sodium silicate, carboxymethiylcellulose, and sodium polyacrylate. The results of the dispersion tests were analysed in relation to dispersion index. The tests with hexametaphosphate showed high dispersion for both galena and sphalerite. The sodium polyacrylate and arboxymethiylcellulose showed a high dispersion index for galena and a low index for sphalerite implying that reagent can be used in the concentration process of galena.

Jan 1, 2014