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By E. Demedde

Carbon anodes in aluminium reduction cells are continuously consumed during electrolysis. In prebake cells the anodes are replaced at regular intervals. The spent anodes, called butts, are often allowed to cool in air while emitting fluorides into the building from the hot alumina cover and the adhering bath. In modem smelters spent anodes are placed inside enclosures and fluoride emissions during cooling are effectively reduced. Fluoride emissions from spent anodes were estimated by considering the kinetics of fluoride formation, a heat transfer analysis of the cooling anode butt and the ventilation flow from a cavity. Fluoride emissions from large anode butts cooling inside enclosures were compared with those cooling in air. Good agreement with published experimental values was obtained for enclosures having different leakage opemngs, when a hydrofluorination reaction of the spent anodes was included.

Jan 1, 2006

By K Komori

Naoshima Smelter and Refinery has treated shredder residue and incinerator fly ash in Japan since 2003. As a highlight, a new incinerating and melting furnace, as well as fly ash washing treatment plant were newly constructed for pre-treatment of shredder residue and fly ash respectively, and the pre-treated materials are ultimately treated in the existing Mitsubishi continuous copper smelting and converting process line. Since wastes such as shredder residue tend to vary in size and in shape, and contain some chlorine, the installation of a new pre-treatment line was required. The combination of the new pre-treatment line with the existing Mitsubishi Continuous Copper Process line has created a highly efficient and environmentally friendly system for recovering and recycling of valuable metals that previously used to be sent to a landfill. This paper reviews the approach that Naoshima took to establish its current recycling business strategy.

Jan 1, 2007

By A. Haque

"This paper describes an improved formulation of an analytical shear strength model developed by Haque & Kodikara (2012) by incorporating the failure of regular concrete/rock joints subjected to CNS condition. Sokolovskii’s analytical solutions developed for failure stress of slopes have been found to be effective in this regard. The analytical models have been validated for predicting the shear behaviour of concrete/rock joints subjected to various CNS loading conditions. The model has been found to accurately predict the dilation, normal stress and shear stress behaviour for a regular triangular saw-tooth joint up to the peak shear stress. Moreover, the peak shear stresses of concrete-rock joints with asperity angles ranging from 5 to 27.5o compared reasonably well with the available laboratory test results.INTRODUCTIONA new shear strength model for elastic regular triangular concrete/rock joints loaded under Constant Normal Stiffness (CNS) boundary condition has been developed by Haque & Kodikara (2012). The salient feature of this model is its capability of accurately estimating the normal and shear stresses of joints with shear displacements under CNS condition by incorporating the elastic deformation of asperities. However, the shear strength model of Haque & Kodikara (2012) for the elastic asperities cannot be directly employed to predict the peak shear stress of a joint experiencing plasticity under applied loads. Therefore, the model inevitability requires articulation of an appropriate shear failure criterion simulating the boundary conditions of the loaded asperity to predict the peak shear stress and corresponding normal stress and dilation behaviour of concrete/rock joints. Sokolovskii (1960) developed a set of analytical solutions for failure stress of slopes comprising c-??soils, which can be exploited effectively to simulate the failure condition as encountered for loaded regular triangular concrete/rock joints (Seidel & Haberfield, 2002)."

Jan 1, 2015

By P. Momni, D. Ersenkal

Equator Principles (EPs) are a set of guidelines developed and adopted by a series of financial institutions for assessing and managing social and environmental issues in project financing. Established in 2003, EPs are now adopted by some 68 financial institutions from 27 countries. As more and more financial institutions join this global initiative, it is important for project owners to have a logical framework embedded into the project lifecycle to reduce the risk of non-compliance which could result in costly delays. This paper outlines a proactive approach for project developers in order to integrate environmental and social aspects into entire project lifecycle.

Jan 1, 2010

By Z. Sun

The hydrogen embrittlement and stress-corrosion cracking (SCC) behavior of an a -titanium alloy and its two kinds of welding samples have been investigated. The results show that this alloy has very low susceptibility to SCC, and the values of Kiscc for the alloy are 46.4 MPa ? m' 65.86 MPa ? mu2 in the direction of T-L and L-T, respectively. The scanning electron fractographs show transgranular and quasi-cleavage fracture. The hydrogen embrittlement results show that the notch sample of the alloy is not sensitive to hydrogen, but the electro-beam welding and diving-arc welding samples are sensitive.

Jan 1, 2005

By H. J. Glass, J. G. L. Bekkers

"In order to determine the feasibility of a hydraulic ore hoisting installation, the optimal operating conditions were calculated for applying such a system at the Detour Lake Mine of Placer Dome Ltd. Next, a financial analysis was conducted in order to estimate the cost per tonne for hydraulic hoisting of the ore. Subsequently, the cost per tonne was compared with the hoisting costs associated with a new borehole hoist. Installing a hydraulic ore hoist at Detour Lake Mine was found to be feasible with considerably lower costs per tonne of ore. The applied research method appears to be very functional and can be used to do similar research for other mining operations. IntroductionThe principle of hydraulic ore hoisting is well known, yet hardly accepted in hard rock mining. Application of the system would result in a smaller diameter shaft requirement and a flexible, easily expandable system. However, underground ore size reduction might be necessary and practical experience with the system is limited. Following recent innovations in the field of pumping hardware, e.g. new GeHo and Siemag Transplan equipment, hydraulic ore hoisting should be seriously considered for certain mining operations. As a case study, a design was made for the development of the newly found QK-Zone at Placer Dome Ltd.’s Detour Lake Mine. Hydraulic ore hoisting has been compared with conventional skip hoisting by establishing the optimal operating conditions and pumping equipment requirements for similar capacities at a selected mining operation. Generally accepted equations for slurry transport were used to predict the variation of pressure and power requirements as a function of hourly production and pipeline diameter. These data are used to select suitable equipment and estimate cost figures in order to make a financial assessment."

Jan 1, 1998

By K. Chotruangprasert

This paper explores Global Reporting Initiative (GRI) reporting practices within the mining industry. Specifically, this paper investigates how and why a mining company makes voluntary reporting decisions to include the GRI indicators that may be considered ?negative? to the company?s reputation. Due to the voluntary nature of the GRI Guidelines, a GRI adopter is not legally obligated to report every GRI indicator. Not surprisingly, empirical studies that evaluated the extent to which companies? sustainability reports meet the GRI requirements (Guenther, Hoppe, & Poser, 2006; Morhardt, Baird, & Freeman, 2002; Samy, Odemilin, & Bampton, 2010; Skouloudis, Evangelinos, & Kourmousis, 2009) have found that reporting practices of the companies under their studies are well below the standards reflected in the GRI Guidelines. An influential study by Clarkson et al (2008) uses economic-based and socio-political theories to explain variation in companies? environmental disclosure. They have found that, as predicted by economic-based theory, superior environmental performers disclosed more ?hard? (i.e. verifiable) environmental information. Inferior environmental performers are found to disclose more ?soft? (i.e., not easily verifiable) claims, which is consistent with socio-political theories (Clarkson, Li, Richardson, & Vasvari, 2008). However, this study and the existing literature do not adequately explain why a company may act in a way that cannot be explained by economic-based and socio-political theories, for example, why it would report some negative soft data that it is not required to report. This paper intends to address this literature gap. GRI reporting by a Canadian mining company, which I would like to call ?Company C?, is used as a case study for this paper. Company C was selected for this research because in addition to ?positive? information, its GRI-based sustainability report also includes both hard and soft ?negative? information such as grievances. Research methods include interviewing Company C?s employees who are involved in preparing GRI reports and reviewing documents prepared both by the company and by external parties. I find that integrative social contracts theory (ISCT) offers a valuable explanation to Company C?s reporting practices. From the ISCT perspective, Company C?s management appears to feel that the company is obligated under social contracts to be transparent. Therefore, Company C disclosed both positive and negative social and environmental information to the public because the management appeared to think that it is the right thing to do. At the same time, being transparent about the bad news gave the company an opportunity to conclude that it had done something to avoid future occurrence of the negative incidents. Therefore, I propose that, in addition to the economic and socio-political theories that are more often used in literature, insights from ISCT are instrumental in improving our understanding of the corporate non-financial reporting practices phenomenon.

Aug 1, 2013

By Don Ritz

Smart leaders focus on safety even in tough times. Businesses that retreat into survival mode and ignore safety do so at their peril, risking loss of employee and stakeholder confidence and exposing themselves to financial and reputational loss they can ill afford. It?s a moment of truth when employees and stakeholders learn whether safety is truly your priority or just a convenient cliché for good times. Visionary leaders who build safety culture even in a downturn maintain people?s trust, prevent loss, and position the organization for enhanced success as times improve. Safety is the right business focus in good times and bad.

May 1, 2009

By Y. Dong, L. Li, L. Yu

Converter slag has become an important secondary raw material. Consequently, vanadium bearing converter slag is of great interest for the recovery of vanadium. Solidified converter slags are made up of three main mineral components: dicalcium silicate, calcium ferrite and wustite. Vanadium in modified slow cooling down converter slag of Magang is found mainly concentrated in a separate mineral phase. The mineral phase with high content of vanadium (24%, wt, V205), concentrating 83% of vanadium, can be separated from the slag for economical vanadium recovery. Some characters of the mineral phase were discussed comparing with dicalcium silicate, one of the typical mineral phases in converter slag studied well.

Jan 1, 2004

By Xiao Huang, Dongmei Wang, Prakash Patnaik

Further increase in gas turbine engine temperature necessitates continuous development and advancement to thermal barrier coatings. While tremendous effort has been devoted to developing new thermal barrier coating materials and processing methods in order to decrease the thermal conductivity, limited attention has been paid to radiative thermal transport through coatings. It is the purpose of this study to develop a new layered coating structure that can be used to effectively reduce the both radiative thermal transport as well as thermal conductivity, and to demonstrate the mechanism and effectiveness of the proposed multilayered structure. Mathematical modeling based on the multilayer quarterwave stack and simulation results are presented.

Jan 1, 2004

By Z. S. Abisheva

The Zhezkazgan copper sulfide ore deposit in Kazakhstan contains both rhenium and the rare osmium isotope "osmium-187" (187Os) in the high isotopic purity of 99.4 ± 0.2%. This isotope is believed to have originated as a result of the disintegration of one of the rhenium isotopes, according to the reaction: 187Re75 ?> 1870576 + B- + v~ (where B is a 13-particle, v~ is a 3-disintegration antineutrino). The distribution of osmium and rhenium in metallurgical byproducts produced during the recovery of copper from these ores has been studied and process flowsheets for the processing of rhenium and osmium-containing byproducts have been developed.

Jan 1, 2007

In semi-enclosed coastal areas in Japan, phosphorus is often observed in the level of limiting phytoplankton growth, causing alteration of species composition from useful diatoms to nuisance dinoflagellates. On the other hand, the sediment quality is still degraded with organically rich reduced conditions. The latter is the major cause of oxygen-depleted bottom water formed in summer, and it makes benthic organisms difficult to live. Steel-making slag can be a source of phosphate and silicate that induce growth of diatoms, and further may remediate the reduced condition of the sediment through the formation of iron hydroxide that works as a kind of oxygen pool.

Jan 1, 2004

By K. Chomyn, R. Veenstra, P. Zangeneh, Hatch Ltd., C. Van der Woude, H. Ghorbani

"The furnace is the heart of smelting operations, and therefore the performance, reliability, and campaign life of the furnace are critical considerations. Furnace refractory is exposed to high temperatures and other harsh operating conditions causing brick erosion, crushing, and cracking, typically limiting the furnace campaign life and requiring costly furnace shut-downs for refractory re-lining. Despite extensive study, the in-service thermal / mechanical stresses in these complex refractory systems are not generally well understood. Hatch has developed a thermal-mechanical finite element analysis (FEA) based furnace refractory modeling approach that allows for the quantification of refractory movements, load distribution, and thermal / mechanical stresses.Due to the complexity of the refractory system, a range of models are used to identify and assess damage mechanisms and design improvements, including: 2D models, to capture expansion and movement of individual bricks, changes to load paths, and thermal stresses; and 3D models, to include the effect of differential expansion between bricks in each course, and assess overall load distributions. The 2D and 3D analyses include the effect of nonlinear temperature-dependent properties, thermal expansion, movement of individual bricks with frictional contacts (i.e., gaps can open, bricks can slide), and brick tensile or compressive failure. Both as-built and damaged conditions can be investigated (e.g., after bath zone brick erosion), for circular and rectangular furnaces. 3D models also include papering and brick joint & interface action.Analyses using these models have shown the importance of thermal stresses, papering, and geometry / arrangement of individual bricks. Results have been used to identify and assess damage mechanisms, showing good alignment with furnace autopsy observations. By using this FEA-based approach to quantify the refractory design, the risk of damage can be significantly reduced, low-cost design changes can be identified, and the furnace campaign life can be extended.INTRODUCTIONThe furnace is the heart of smelting operations and therefore the performance, reliability, and campaign life of the furnace are critical to the success of the smelting operation. Furnaces are inherently exposed to high temperatures, often in excess of 1600°C (Holappa, 2004), and furnace operating power has progressively increased over time (Voermann, Gerritsen, Candy, Stober, & Matyas, 2004). The refractory system must withstand high temperature, high heat flux, and other harsh operating conditions. These conditions are particularly significant for the furnace hearth, and can lead to damage including brick erosion due to molten material flows, crushing due to thermal expansion loads, and cracking due to severe thermal gradients within the bricks. Refractory damage typically limits the furnace campaign life, requiring costly furnace shut-downs for refractory re-lining (repair or replacement). In some cases the refractory may lose integrity causing damage to nearby equipment and harm to personnel."

Jan 1, 2016

By J. Dubinski

Passive tomographic imaging is a technique that can be used for assessing seismic hazard in mines with high seismic activity induced by mining. The basic idea behind such an interpretation is the assumption that there is a relationship between high values of seismic velocity and high values of stresses in the rock mass. This relationship was confirmed both in laboratory an in situ measurements and constitutes the basis for rock-burst and seismic hazard evaluation. In the paper seismic tomographic images of seismic P wave velocity and seismic P wave velocity gradient have been presented to determine rock-burst hazard and locate high seismic activity zones in the area of coal panel 306 in Zabrze Bielszowice mine. The zones of high values of P-wave seismic velocity gradient have been found to correlate with the distribution of high energetic seismic events. Passive tomographic images were obtained using modern bent ray tracing tomography algorithm with regularization. Recent study give rise to observation that not only high values of P-wave seismic velocity is important in seismic hazard assessment as many strong seismic events are located in the areas of high values of velocity gradient. This recent observation permits to increase quality of passive tomographic imaging for detection of seismogenic zones and is presented in the paper. The advantage of passive tomography comparing to active tomography is that sources of seismic waves are generated by rock mass itself and costly controlled explosions are not necessary. Another practical limitation of active tomography is the size of study area which usually do not exceed 200 m by 200 m. This restriction does not appear in passive tomography where area of study is usually 2000 m by 2000 m and the tomographic images delineate velocity structure in locations where mining induced seismicity take place. Passive tomography method utilized in analysis of rock mass state in underground mines encounter some difficulties concerned with the numerical stability of optimization algorithms. In the presented approach to passive tomography problem numerical stability is obtained by special regularization method and by application of very stable numerical seismic ray-tracing algorithm.

Aug 1, 2013

By David W. Smith

"This paper is devoted mainly to a discussion of the hydrocarbon potential of the offshore, with a few brief remarks concerning the inorganic mineral potential.OFFSHORE OIL AND GAS POTENTIALIN ORDER TO HAVE HYDROCARBON ACCUMULATIONS, we must satisfy three basic requirements. First, we re-quire a sufficient thickness of sedimentary rocks which contain some porous and permeable formations to act as reservoirs. Second, we require some type of trapping mechanism, such as faulting, folding or stratigraphie trapping. Finally, we require that large quantities of hydrocarbons have been generated within the sedimentary rocks and have migrated to the traps."

Jan 1, 1969

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By Ting An Zhang, Chengzhi Jiang, Xiujing Zhai, Feng Xie

The extraction and concentration of nickel from aqueous solutions by emulsion liquid membranes (ELMs) using tributylphosphate (TBP) as extractant has been investigated in this research. The emulsion liquid membrane consists of a diluent (kerosene), a surfactant (Span 80), a mobile carrier (TBP), and a stripping solution (ammonia solutions). Important factors influencing the separation process including membrane composition, feed composition, and mixing speed have been examined. The results show that more than 90% of nickel in the feed solution could be extracted by ELMs under the experimental conditions, indicating the feasibility to use the designated ELMs to detoxify nickel-containing industrial waste solutions.

Jan 1, 2014

By K. T. Aye

An investigation into the leaching of chalcocite and covellite in cyanide solutions at concentrations typically encountered daring gold cyanidation has been conducted. The results indicate that, for both minerals, the extent of leaching is greater under anoxic conditions, but is still incomplete even in the presence of free cyanide ions, with undissolved copper solids remaining in equilibrium with solution species. The speciation of the sulfur and cyanide reaction products in solution are interpreted in terms of the fast formation of a copper(I)- cyanide complexes in solution and a sulfur-rich copper(I) polysulfide solid phase, which then reacts more slowly to produce thiocyanate ions.

Jan 1, 2011

By L. H. Thorleifson

Demand for both gem and industrial diamonds is very strong. Synthetic production supplies industrial uses, but synthetic gems remain inferior and expensive, so the large gem market is supplied by mining. Several major mines have been depleted, and the market is receptive to new sources of high quality gems. Canada's Precambrian terrane, extending across the Canadian Shield and under the Phanerozoic cover of the Plains and Hudson Bay, has excellent potential for diamonds, but exploration conditions are difficult due to recent glaciation. Early world exploration relying on recognition of diamond in alluvial sediments was adequate to launch pre-1900 production from India, Brazil, and Africa. Exploration success in Canada, as was the case in Russia and other more recently discovered sources, however, had to await large investments in effort supported by advanced science and technology. Canadian exploration in many ways is similar to that in other regions, relying on analysis of tectonics, indicator minerals, geophysical surveys, and multiple stages of drilling and sampling. Very different from other regions, however, is Canada's surficial environment, in which recent glaciation has caused fresh indicator minerals to be transported hundreds of km. Exploration accelerated in Canada after 1960, first in Ontario and the Arctic Islands, then in Saskatchewan in 1988, and most importantly after the Chuck Fipke - Stew Blusson discovery at Lac de Gras, Northwest Territories, in 1991 that led to the billion-dollar BHP - Dia Met Ekati Mine that opened in 1998. In 2003, production from Ekati is expected to be supplemented by that from the similar and nearby Diavik Mine of Rio Tinto and Aber, currently under construction. These mines will bring Canadian output to over 10% of world supply, and will position Canada with Botswana and Russia as world leaders in production of high quality gem diamonds. There could be other mines as well, as sites across the Arctic and in the south from Alberta to Québec are being explored by an array of companies, including De Beers, other majors, and several juniors.

May 1, 2001

By H. Yasuhara, N. Kinoshita, S. Nakashima, K. Kishida

"In this study, flow-through experiments in fractured rocks have been conducted under different stress, temperature, and pH conditions so as to understand the evolution of permeability induced by these conditions. Throughout the experiments, the confining pressures and temperatures are well-controlled. Effluent concentrations are also measured for the ten elements of Si, Al, K, Fe, Ca, Na, Mg, Ti, S, and Cl that are included mainly in the targeted rocks. In the early stage of the experiments, the fracture permeability measured abruptly decreases with time, and subsequently reaches quasi-steady state within a relatively short period. In contrast, the permeability in the intact rocks monotonically increases with time. The permeability increase and decrease are attributed likely to the relative dominance of mineral dissolution in the pore spaces and to that of mineral dissolution/crushing at the propping asperities within the fracture and/or mineral precipitation onto the free surfaces, respectively. The evolving rates and magnitudes of the permeability are likely to be controlled by the stress exerted over the contacting asperities, temperatures, and pH of the permeant. Thus, this complicated behavior should be attributed to the coupled chemically- and mechanically-induced effects, which should be examined in more detail for longer period to contribute to the safe entombment of radioactive wastes. INTRODUCTIONUnderstanding of the flow and transport characteristics of porous/fractured rocks is required for the safe and long-term geological isolation of energy-related by-products (i.e., high level radioactive wastes and anthropogenic CO2). Notably, under relatively high temperature and stress conditions, mechanically- and chemically-mediated processes may alter the pore structures in rocks, resulting in an irreversible evolution of the flow and transport behavior. Augmentation in permeability may result from mechanical dilation due to shearing and mineral dissolution within the pore spaces, while reduction may result from reversible or irreversible mechanical compaction, mineral dissolution at the contacting areas, and clogging of pore spaces by precipitation of secondary minerals."

Jan 1, 2015