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By L. E. Gutiérrez

A new filtration model based on porous media transport theory is presented. It predicts capacity and final moisture content in the filtered cake as a function of design and operational variables at the plant. FilterSim® is the computer code where this new model is programmed. Application of FilterSim® to ten-month operation of an industrial copper concentrate filtration plant is shown on a daily basis and using a single set of internal parameters for the whole period. Average error is less than 5%, both in capacity and moisture estimation. FilterSim® abilities to optimize industrial filtration plants as well as to estimate future budgets are illustrated with several real examples.

Jan 1, 2007

By M. Cimenti

Fuel cells have tremendous potential as power sources but much fundamental research is still required. One key component of the research is the experimental set-up used. In particular, the placement of the reference electrode is extremely significant in measuring the half-cell overpotential of solid oxide fuel cells, since differences in area, misalignments, and also differences in the kinetics of the working and counter electrodes can cause both scaling errors and frequency distortions of the measured impedance. The impedance of thin solid electrolyte cells of different electrode geometries has been calculated using the finite element method and the results compared to experimental values obtained for the oxygen reduction reaction on platinum.

Jan 1, 2005

By Jean-Luc Collins

"The paper deals with the impact of fleet imbalance on a deterministic evaluation of shovel fleet productive capacity. It shows that if the fleet imbalance is overlooked, then estimated fleet productive capacity will be overrated.The paper shows that fleet imbalance inflates utilization, and care must be taken when using such statistics which are derived from reported field-equipment-hours. It shows that the utilization must be deflated by a factor called 'balancing efficiency"" in order to estimate shovel productive capacity correctly. The paper also shows how fleet imbalance can be controlled by managing idle time or downtime in an actual operation.The technique used for measuring the balancing efficiency factor is based on statistical analysis of equipment utilization."

Jan 1, 1980

By A. R. Barnes, R. Pandher, T. Shannon, P. Gover

Following the closure of the Glencore Zinc Brunswick mine, the Glencore Brunswick Smelter has transitioned to treating external feeds, and currently treats a number of secondary Pb-Zn concentrates. Processing these concentrates has in some cases been challenging due to the diverse mineralogy of the feeds. Certain feeds are difficult to ignite or show inadequate sulphur removal during oxidation on the sinter strand, while in other cases, combinations of feeds produce a sinter with unsuitable properties for further handling. This paper discusses two methods developed in collaboration with XPS Consulting & Testwork Services to characterize these feeds prior to processing them and to identify which ones are most likely to pose challenges during processing.

Jan 1, 2014

By H. Zniber El Mouhabbis

Ore dilution or stope overbreak increases the cost of production and ultimately reduces the profitability of a mining operation. The adverse economic impact of ore dilution is due to the added costs associated with the mucking, haulage, crushing, hoisting, milling, and treatment of waste rock or low grade ore in the hangingwall and footwall. One factor that could have a significant influence on stope overbreak is the undercutting of the stope into the walls. Undercutting stope walls is often necessary, in particular in narrow vein mines. Moreover, equipment size has a role in drift sizing where stope undercutting may become a must in order to fit the mobile equipment while respecting legal clearances.

May 1, 2009

By H. Gharahbagheri, S. Shafiei Zadeh, H. Hassan Nejad

Waste Electrical and Electronic Equipment (WEEE) is one of the fastest growing types of solid waste in the world, and often contains precious metals, especially gold. Gold processing and recovery from secondary materials, especially WEEE, have been under investigation for more than a decade now; however, a comprehensive review that illuminates the future path is missing in the literature. The aim of this short paper is to discuss the recent advances in gold processing and recovery from secondary electronic materials and why it has not yet become practical. The role of pyrometallurgical and hydrometallurgical methods, as well as their advantages and disadvantages will be discussed; however, the focus will be on Biosorption and recent advances.

Jan 1, 2014

By J. Seidel

In 2009 Newmont Mining Corporation’s annual global spend on grinding media reached $94M USD, having doubled in the five years since 2004. The major contributing factor to the spend escalation during this period was unit consumable price, with total media consumption also rising as a function of annual ore tonnes milled. In an effort to better understand and manage the growth of this expenditure a significant supply chain management program was implemented. This was complemented by a series of technical initiatives focussed on grinding media specifications, quality management and the prediction of grinding media wear rate as a function of physical ore characteristics. This paper discusses the methodology and outcomes of these activities.

Jan 1, 2012

In 2009 Newmont Mining Corporation?s annual global spend on grinding media reached $94M USD, having doubled in the five years since 2004. The major contributing factor to the spend escalation during this period was unit consumable price, with total media consumption also rising as a function of annual ore tonnes milled. In an effort to better understand and manage the growth of this expenditure a significant supply chain management program was implemented. This was complemented by a series of technical initiatives focussed on grinding media specifications, quality management and the prediction of grinding media wear rate as a function of physical ore characteristics. This paper discusses the methodology and outcomes of these activities.

Nov 1, 2011

By J. Seidel

In 2009 Newmont Mining Corporation’s annual global spend on grinding media reached $94M USD, having doubled in the five years since 2004. The major contributing factor to the spend escalation during this period was unit consumable price, with total media consumption also rising as a function of annual ore tonnes milled. In an effort to better understand and manage the growth of this expenditure a significant supply chain management program was implemented. This was complemented by a series of technical initiatives focussed on grinding media specifications, quality management and the prediction of grinding media wear rate as a function of physical ore characteristics. This paper discusses the methodology and outcomes of these activities.

Jan 1, 2012

Presentation Agenda ?Background ?OEM Recommendations before RCM ?Operating Context ?OEM Recommendations after RCM ?Reality of Failure ?RCM Deliverables ?Maintenance program optimization ?Spare part optimization ?Implementation ?Further Considerations -Three scenarios ?Summary and Conclusion Background ?P&H Mining?s LCM division performed a RCM study on a ?generic 4100 XPB shovel?in Milwaukee. ?P&H soon realized that the analysis required context -The recommendations were manufacturer knowledge based. -The outcome based on manufacturer requirements. -The strategy was not applicable to all machines, etc. Operator experience and ?local knowledge? are key to the success of an RCM analysis. P&H approached Teck Coal?s Fording River Operation to assist with ?Operating Context?. Teck provided operator and maintainer experience.

May 1, 2010

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami, G. P. Cole

"The past several decades have seen a steady increase in the use of atmospheric monitoring systems (AMS) in underground mines as sensor technology has advanced and costs for this technology have decreased. The AMS is a reliable tool for early mine fire warning by detecting gaseous products of combustion in underground mines. During a mine fire emergency, mine decision makers rely heavily on the prompt and accurate knowledge of the ventilation and fire situation in the mine, such as fire location, fire size, and the spread of smoke to make effective and efficient decisions on firefighting strategies and miner evacuation. Meanwhile, a prediction of the potential for fire development at a later time, such as whether the currently designated mine escapeways will be contaminated by smoke and toxic gases with the progress of the fire, is critical for effective decision-making to save lives that are in danger. The AMS monitoring data, including carbon monoxide (CO) concentration, airflow rate, smoke, etc., can provide information as to whether the smoke has reached the locations where AMS sensors are installed and if a mine-wide smoke spread has occurred. The National Institute for Occupational Safety and Health (NIOSH) has undertaken a task to integrate real-time AMS monitoring data with the mine fire simulation program, MFIRE, to simulate and predict the spread of smoke and toxic gas in a ventilation network based on the real-time AMS data. This paper reports the developed real-time method for characterizing the size and location of an underground mine fire and for predicting the spread of contaminants throughout the mine ventilation network using sensor data from the AMS.INTRODUCTIONNIOSH conducts research to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions in underground mines. The advancement of senor technology and the increasing demand for real-time mine parameters monitoring have led to extended applications of atmospheric monitoring systems (AMS) in underground mines worldwide. In the United States, AMS is primarily used for early mine fire warning by detecting carbon monoxide (CO) in fire hazard areas, such as belt entries. Mine fires can grow rapidly, and time is the critical element. Prompt detection, timely and accurate warnings to those miners potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground mine fire (Conti et al., 2005). The early detection of a mine fire could gain time for the first responders to put out the fire before it develops into a disaster. An AMS system with CO sensors has especially played an important role in the early detection of mine fires. The continuous monitoring of an underground mine atmosphere with an AMS could generate a large amount of data in a mine fire event. However, the current application of AMS is mainly limited to sending out an alarm when monitored CO concentration exceeds a certain level. An opportunity arises as to whether these data can be further used in fire emergency response. In order to make effective decisions on firefighting strategies, mine workers’ seeking refuges, evacuation and escape, and the timing on when to send rescuers, decision makers need accurate and timely knowledge of the ventilation and fire situation in the mine. Information about the fire intensity, where in the mine the smoke and toxic gases have spread, and whether designated mine escapeways have been compromised by smoke and toxic gases from the fire would greatly increase the effectiveness of these decisions. However, the monitored AMS data only provides atmospheric conditions in the vicinity of sensor locations. What is concluded from the monitored AMS data highly depends on the decision makers’ capability and experience. Predictive insight into fire growth and smoke transport would greatly help decision makers during a fire emergency."

Jan 1, 2019

"The last thirty years have seen enormous changes in all aspects of the gold industry, from the technologies of mining and extracting gold to the role it has played in the fiscal policies of nations. In this time, the market price of gold has increased ten fold and mine production has more than doubled. However, the cost of mining and extracting gold has also increased exponentially, and the industry has struggled with declining ore grades and increasingly refractory ore bodies.With the major economic powers of the world shrugging off the uncertainties of the post cold war era and moving into a period of unprecedented political stability, economic growth and low inflation, gold is also losing its lustre as a hedge against inflation and a backing for national currencies. Consequently, countries that had accumulated and hoarded gold for decades are now disposing of these non-performing assets, resulting in major swings in supply of the metal. Fortunately, this has coincided with the end of communism in many parts of the world and a tentative move to free market economies in most of the developing nations. As a result, people are becoming wealthier, and this is creating more demand for gold, principally in the form of jewelry.On balance, the shift in the role of gold, from one in which a significant portion of new gold production lay dormant in bank vaults as insurance against political or fiscal instability, to one in which most new gold is now freely traded as an industrial commodity, responding to normal market forces of supply and demand, has had a negative impact on the price of gold over the last fifteen years. In that time, the gold price has declined from a peak of $850/oz in 1980 to an average price of about $400 through the rest of the l 980's, to a price of -$320/oz today (1997). In large measure, this has been due to the enormous inventory of gold metal that was held by central government banks in vaults around the world, and which has been dumped on the market as soon as the price has started to trend upwards. Even today, after ten years of fairly steady selling by central banks, about 3 0, 000 tons of gold (or -8 years' supply at the present rate of consumption) is still retained in vaults (Murray et al., 1997).The downward pressure on the price of gold has created exciting opportunities for the development and implementation of new technology. Increasing the efficiency of gold recovery from more and more refractory ore bodies, whilst at the same time lowering production costs, have become critical to survival in this industry. These challenges have been met by the development and implementation of new technologies such as heap leaching, carbon in pulp, resin in pulp and the sulphide ore pre-treatment process of pressure leaching, bacterial leaching and fluid bed roasting. For an industry that saw very little technological change in the first seventy years of the twentieth century, the pace of change over the last thirty years must have seemed bewildering at times."

Jan 1, 1998

By Henry Smith, Stu Brown

"The Williams Mine is Canada's largest gold producer, with annual production of some 500 000 ounces of gold from two million tonnes of ore. Highly mechanized and automated underground mining practices are utilized at the property in order to help achieve high levels of productivity and the most cost-effective mining possible.Planning and design parameters for the underground ore handling system at the Williams Mine are described in this paper. Particular reference is made to the considerations that were built into the system to provide maximum operating flexibility through the use of multiple orepass systems, portable low profile jaw crushers, underground conveyors and automated hoisting equipment.IntroductionThe Williams Mine is situated in the Hernlo area of northwestern Ontario, approximately 40 Ian east of the town of Marathon (Fig. I). It is operated by the Williams Operating Corporation, which is owned equally by Teck Corporation and Corona Corporation, and is one of three adjacent properties forming the HernIo gold camp.The mine commenced operation in October 1985 at a nominal production rate of 3000 tpcd. Through an ongoing capital development program, winch was completed in late 1989, the production rate at the property was increased to its current level of 6000 tpcd. This paper describes the mine planning process and the evolution of current mining strategies with particular reference to the underground ore handling system .HistoryGold mineralization was discovered in 1944 in the Hemlo area of Northern Ontario, near the north shore of Lake Superior. A year later, 11 claims were staked over the showing and subsequently patented by the late Dr. Jack Kerr Williams.Over the next 35 years, other claims were subsequently staked, explored and abandoned in the immediate area of the 11 patented claims . In 1980 a predecessor of the Corona Corporation acquired claims adjoining the Williams property to the east. Drilling on this claim group started early in 1981 and intersected the Hemlo orebody in May of that year. In December 1981, Corona Corporation entered into an option agreement with Teck Corporation to explore and develop the property.A drilling program by LAC Minerals on the II patented claims discovered the Williams orebody in March 1982. The mine started production in 1985, pouring its first official bar of gold on December 6 of that year. Corona Corporation was awarded ownership of the Williams Mine conclusively by a decision of the Supreme Court of Canada on August 11, 1989. The court's ruling ended a legal dispute with LAC Minerals over the property initiated eight years earlier."

Jan 1, 1991

By J. Suarez

The innovation initiatives for world-class mines today and in the future focus on automation and robotics in equipment and machinery. These innovations have benefited from the development of advanced tools in global positioning, the Internet, the capabilities of data storage, transmission and handling, and intelligent systems. Forward-thinking companies have been investing in automated trains and trucks, selfdrilling rigs, intelligent flotation systems, etc. Considering that the emphasis has been mostly laid on improving the performance and reliability of the equipment and machinery, it is not surprising that the visibility was geared toward mechanical, electrical, process, and metallurgical engineering. One of the critical disciplines, mining engineering, has had less shine from the spotlight of automation and robotics. Mining engineering is concerned with the design, the operation, the management, and the reclamation of mines and mining facilities. In essence, it does benefit from the advantages of automation and robotics in equipment and machinery. However, being ?left out? in the innovation process may impede the core capabilities of this engineering discipline, which would create a two-tier knowledge and technology system in mines. For example, shovels in an open pit may be equipped with technology that can send real-time data of actual payload, number of buckets, mechanical status, etc. But, are mining engineers aware of the possibility to incorporate the data into their planning tools in order to have updated forecasts and accurate information? And if they are, are they equipped with the tools to reap the rewards of those technologies? And if so, is the personnel trained to use the tools efficiently? This paper is a contribution to the discussion on the technological advances in mining engineering. For the authors, the roadmap to the future requires a smart integration of technological advances in hardware and software so that mining engineers are not only aware of the possibilities, but also trained and capable of using the available tools. Essentially, this paper believes that automation and robotics in equipment alone will be undervalued and underutilized if the owners and drivers of the mining systems (i.e. the mining engineers) do not possess the tools and training to integrate the technological advances into the functions of mining engineering. The intent of the paper is to analyze the available technologies for the core mining engineering functions of design, planning, scheduling and optimization. The analysis will lead to discussions and suggested solutions on integrative technology solutions that would create optimum value for the mining processes and equipment technologies.

Aug 1, 2013

By S. Avalos, J. M. Ortiz, W. Kracht

Semi-autogenous grinding mills are intensive energy consumers. Current models base their energy consumption inference on operational variables and feeding ore characterization. While they provide adequate design guidelines, they are not suitable for real-time energy forecasting dealing with gaps in operational dataset and up/downstream process bottlenecks. This work explores the capability of Gated Recurrent Units to learn the semi-autogenous grinding mill consumption behaviour. Gated Recurrent Units are trained to forecast different time-support consumptions under a time-series operational dataset. The results show high performance on small supports (30 minutes) to capture local variability and long-trends while larger time supports (8 hours) can only capture time-trends but not local variability. The proposed technique seems promising for further research and implementation on real mine cases since the input variables are low-cost and easy to obtain. INTRODUCTION Current changes in the Chilean energy matrix (Román-Collado, Ordoñez, & Mundaca, 2018), from fossil fuels to renewable energies, have impacted different industries and particularly the mining sector. Solar energy incorporation into greenfield/brownfield projects will help reducing costs and will lead to rethink foundational paradigms (production and processing strategies) (Pamparana et al., 2017). Also, integration of new space-time predicting tools together with automated real-time updating models are some of the main challenges in the geometallurgical framework (Ortiz et al., 2015; van den Boogaart & Tolosana-Delgado, 2018). Those contexts encourage and demand the development of tools capable of predicting the energy consumed by mining systems, being comminution the greatest energy consumer with an average close to 50% of the entire mine consumption (Cochilco, 2013). In comminution, the semi-autogenous grinding mill (SAG) represents the largest energy consumer (~10 nominal each SAG). Theoretical and empirical energy consumption models (Jnr & Morrell, 1995; Morrell, 2004; Silva & Casali, 2015) base their inferences mainly on feed/product size distributions, SAG sizing, bearing pressure, feed hardness, water addition and grinding charge level, and commonly assume steady-state and work isolated from up and downstream processes. While those techniques provide adequate design guidelines, they are not suitable to predict hourly, daily or even weekly energy consumptions on interconnected comminution circuits where upstream/downstream bottlenecks lead SAGs to operate below designed regimes. Forecasting energy consumption is required by short-term energy management, medium and long-term planning energy consumption, designing the nominal capacity of renewable energy sources, among other. Also, when models are input-sensitive and some of those input measurements are expensive and/or time consuming, model robustness suffers when real-time predictions are required.

Jan 1, 2019

By Q. Ricoux, F. Goettmann, A. Maihatchi

"Electrodeposition processes are widely used in the metallurgical industry to produce, extract and refine metals from various feed materials. However, raw materials used to provide non-ferrous metals often contain high amounts of iron. In the presence of iron, while metals are plated at the cathode, electrowinning processes produce corrosive and highly oxidative ferric ions at the anode that are harmful for the process sustainability. In fact, these ferric ions cause dramatic current efficiency loss, induce high maintenance expenditures to limit the corrosion of devices and it results in the formation of impure and dendritic deposits on the cathode. Consequently, the management of iron in electrodeposition process became a major issue in non-ferrous metals production. Actually, numerous methods have been developed to limit the ferric ion concentration in the electrolyte or, at least, to limit its harmful effect. Many methods aim to limit the iron(III) concentration in the electrolyte, generally by coupling electrowinning to extraction process such as solvent extraction (SX) (Bender & Emmerich, 2015), ion exchange (IX) (Gula, Dreisinger, & Horwitz, 1996) or cementation (Kust, 1979) processes to remove ferric ions. Other routes consist of (i) using the ferric ions oxidant properties to leach raw materials, either directly in the electrolytic cell (Fanta & Tributsch, 1975) or through a secondary circuit (Cain, 1950), or (ii) reducing ferric ions through periodic reversal of direct current to enhance the formation of Fe2+ (Loutfy & Bharucha, 1980). On the other side of the spectrum, papers discuss methods to valorize the iron from by-products of the non-ferrous metal industry, that generates vast quantities of iron containing wastes (A. Agrawal, Sahu, & Pandey, 2004). Many studies on iron electroplating and electrolytic iron production from ores have been carried out (Cain, 1950; Mostad, Rolseth, & Thonstad, 2008), but very few have been conducted on waste or by-products. Therefore, we propose to build on the previous literature review to develop a process for the production of electrolytic iron from by-products.INTRODUCTIONNon-ferrous metals and their alloys are used in a large variety of applications. Aluminum and titanium are used for their strength, light weight and corrosion resistant properties in structural applications. Copper has been used in various applications requiring high thermal and electrical conductivity, as kitchen products and electrical wires. Nickel and zinc are commonly used as plating materials; nickel offers a wide range of working temperature and zinc is used for steel plating. Gold, silver, and platinum group metals are used in electrical/electronic applications, jewelry and chemistry as catalysts."

Jan 1, 2016

By Robert J-M Ethier

"Sequential blasting has been introduced at Mines Gaspe to reduce the harmful effects associated with the instantaneously primed blasting method. Three stages of modifications had been tried to improve this method: trials of a rectangular pattern instead of the square one, trials of lengthened hole collars at the perimeter of the blast and trials of increased inter-row delay intervals from 35 to 50 ms. Results showed that improvements to the instantaneously primed blasting method were limited by the probability of increasing the number of bootlegs.Doing these modifications allowed the definition of a general approach to improvements before the sequential blasting method was introduced. This general approach included: planning of the mining sequence, following up on the drilling, loading and tying-in of each blast, compiling and evaluating blast results, comparing results from one bench to the other and moving along with one change at a time. This approach has permitted the successful introduction of the sequential blasting method in two steps: trials of blast by rows of delayed holes and trials of hole-by-hole blasts. The optimum result has been analyzed by high-speed camera and by computer blast simulations, The actual optimum sequential blast is obtained with a CORDLINE priming system using period 15, permitted in a large drilling pattern, with an intersequences delay interval of 230 ms and an inner-sequences delay interval of 50 ms.While these modifications were being introduced, a careful study of the drilling and blasting costs was made, which showed a sharp reduction of drilling cost per tonne. Even though there was an increased use of packaged slurry the blasting cost per tonne also dropped. The reduction in cost per tonne was explained by the fact that the average energy factor was maintained while the blasting pattern was expanded.The sequential blasting method, successfully introduced at Mines Gaspe, permits blasts of better quality, reduces the drilling requirements by more than 30% and helps to achieve improved productivity while minimizing costs."

Jan 1, 1984

By Leonard A. Wolff

"The 1980sfor the mining industry can be characterized as the survival of the fittest. High interest rates, low commodity prices, foreign subsidized competition and decreasing ore grades have contributed to a streamlining of the domestic mining industry in the United States, leading to the shutdown of operations or large cutback of work forces. The purpose of this paper is to look at the impact of a layoff on the employees of what was once a major uranium producer in south central Wyoming, twenty months after the final layoff and mine shutdown. INTRODUCTIONDecember 19, 1985, was the date of the final of three successive layoffs over a two-month period, leading to the complete shutdown of Petrotomics Company, a subsidiary of Getty Minerals Company. The final shutdown was due to a combination of depressed U3O8 prices and the takeover of Getty Oil Company by Texaco in January 1984.The layoffs affected 104 employees and included mine personnel, mill personnel and staff. Both hourly and salary workers were involved. The operation was considered non-union, however, a few mill hourly employees were unionized. At the completion of the layoffs. only a handful of employees remained for administrative and miscellaneous functions.For Getty employees, the terms of the merger agreement provided a generous level of separation benefits. The terms that were insisted upon by Mr. Petersen, Chairman of the Board for Getty Oil, stipulated that employees receive one month of severance pay, for each full calendar year of employment up to a maximum of two year's pay. This was the forerunner of what is now commonly known as the ""tin parachute”. All but the union employees of Petrotomics received these separation benefits. Union employees were covered by their separate, less generous, contract.Much of the literature that has been published in recent months has centred around the effects of layoffs on remaining employees, or the psychological effects on the severed employee. This study will emphasize the economic impact and ramifications due to a layoff, using the Petrotomics employees as a case example."

Jan 1, 1989

By P. Venkatasubramanian

"In recent years, computer based ""expert systems"" have been taking on large complex tasks for which no exact algorithmic solutions are feasible; tasks previously reserved for human experts requiring empirical knowledge, judgment, experience, developing a ""best solution "" by the use of plausible reasoning. Mining method selection is an appropriate area for the application of an expert system because extensive and detailed knowledge is required to make a ""best"" interpretaion of frequently ambiguous geological information. The expert system model presented here would enable users to apply expert knowledge to the evaluation of methods for coal deposits mineable by underground methods. IntroductionIn an increasingly complex and specialized world, human expertise spanning scientific, economic, social and political issues plays an increasingly important role in all branches of engineering. This is especially true of mining engineering. The number of scientific and professional disciplines involved in mine planning and evaluation, illustrates the problem. A conservative list includes geology, geophysics, geotechnics, hydrology, mining, environment, and economics.Engineers are almost obliged to be experts in at least one of the above disciplines if they are to handle the volume of information required in the planning process. Although computers have become indispensable tools in many endeavours, there is continued reliance on the human expert's ability to identify and synthesize these diverse factors, to form judgments, evaluate alternatives , and make decisions . This is especially true with regard to problems that are not easily amenable to precise formulations.The precious resource of human expert is also fragile and transient. The departure of a crucial expert from an organization ma y cause serious dislocations. Senior experienced people impart their knowledge of younger colleagues, but the demand for their talent may not leave sufficient time for such educational efforts. In recent years, computer based "" expert systems"" have been taking on large complex tasks for which no exact algorithmic solutions are feasible; tasks previously reserved for human experts, requiring empirical knowledge, judgment , experience, developing a ""best solution"" by the use of plausible reasoning."

Jan 1, 1988

By Wenbin Zhang, George W. Poling

"Prior or simultaneous addition of ammonium sulphate can, not only enhance the activating effect of hydrosulphide ions on xanthate flotation of malachite but it can also eliminate possible detrimental or depressing effects of excess residual hydrosulphide . Use of relatively inexpensive ammonium sulphate appears to reduce the consumption of the much more expensive sulphidizing agent for optimal flotation recovery INTRODUCTIONOxidized copper minerals float poorly with conventional thiol-type collectors. This is believed to be due to the nonadherent character of the collector coating, which is readily re- moved by particle abrasion. Rosas and Polingr reported emulsion flotation seemed capable of resisting abrasion during the flotation of non-sulphide copper ores. It appears that the most common flotation technique for oxidized copper minerals comprises sulphidization with Na .S and subsequent treatment by sulphydryl collector. The principles of this method are available . Malghan recently reviewed the studies on the role of sodium sulphide in the flotation of oxidized copper, lead and zinc minerals.It is well known that in the sulphidized flotation of malachite, the activation process depends strongly on the concentration of the sulphidizing agent, i.e., insufficient sulphide gives poor recoveries because of inadequate sulphidization; excessive sulphide also causes poor recoveries due to the depressive effect of the residual hydro-sulphide ions in solution. A major difficulty in sulphidization, especially with a varying feed nature, is to establish and maintain the optimum sulphide concentration in solution. In plant practice, vigorous control of sodium sulphide is required and stepwise addition of the reagent is recommended to improve the efficiency of the process. Soto and Laskowskim have found that malachite, depressed by an excess of sulphide ions, can restore its floatability if air or oxygen is introduced to the pulp. They attributed this to the oxidation of the HS - ions on the surface of the mineral. Jones and Woodcockuvi showed that a sulphide ion selective electrode could be used to optimize the conditions (e.g . amount of hydrosulphide, sulphidization time, flotation time) more readily and precisely than existing methods in the flotation of oxidized copper ores."

Jan 1, 1989