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By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By A. L. Karyakin

The report focuses on the process measurements of the mass of rock in the bucket power shovels and dragline excavators. The mathematical models are suggested of AC and DC electric drives of excavators. These models are a basis for calculation methods of the electric drive electromagnetic torque. The design schemes of mechanical equipment of excavators considered to account the situation of bucket in the plane of the boom. The methods of static moment allocation and identification of the excavator technological operations are developed. The results of the work are experimentally tested on power shovels with bucket capacity of 12 and 18 m3.

Aug 1, 2013

By Linruo Zhao, Qi Yang, Akihiro Sato

TiN coating has a wide range of tribological applications from wear reduction of cutting tools to erosion protection of gas turbine engine compressor components. The performance of TiN coating depends on its microstructure, mechanical properties and adhesion strength which are influenced by the coating deposition process. In this study the effects of cathodic arc deposition conditions on the microstructure, hardness, adhesion and erosion resistance of TiN coating were investigated experimentally. It was found that varying deposition temperature, substrate bias and N2 pressure could derive a processing window in which TiN coating with superior erosion performance can be fabricated.

Jan 1, 2010

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By M. Bertrand

Oxalic precipitation is usually applied to process radioactive wastes or to recover actinides from a multicomponent solution. Precipitation reactions being highly sensitive to many operation parameters, the computer simulation appears to be a very effective tool to forecast the evolutions of the system subjected to various operating conditions. This study focuses on the tetravalent uranium oxalate precipitation modelling which combines population balance and hydrodynamics. Both experimental and numerical studies are carried out in order to analyse the reactor design influence on the precipitate characteristics. The simulations taking into account primary nucleation and crystal growth are in agreement with experiments.

Aug 1, 2010

By Shahé Shnorhokian

Numerical modeling is increasingly being used as a tool to examine complex geomechanical issues related to rockmass behaviour and stability of underground openings. The in-situ stress regime and the evolution of mining-induced stresses during the life of an operation, taking into account the planned stope sequence, are topics that can only be handled through the use of a realistic and calibrated numerical model. This paper presents a case study of a deep underground Canadian mine in northern Ontario. A FLAC3D model was constructed and calibrated based on in-situ stress measurements. In the first stage, the evolution of stress regime was studied and compared with the occurrence of rockburst events during a period of three years. The locations of clusters were examined and compared to the mining sequence during that period. In the second stage, stresses within a diminishing ore pillar were examined based on the planned stope sequence and compared to levels deemed acceptable to the mine. Based on the results, an alternative sequence was arrived at to reduce stress accumulation in the pillar, or induce it to occur at a further distance from a brittle dyke in the vicinity of the orebody.

Aug 1, 2013

By E. I. Vargha-Butler

The determination of surface tensions and contact angles of coal particles is of great interest for coal beneficiation processes such as froth flotation and oil agglomeration and for the inclusion of coal particles into oil droplets as a means of enriching the fuel. Methods for contact-angle measurements on small irregularly shaped solid particles have not been available in the past. Therefore, we recently developed a novel technique to determine contact angles and surf ace tensions of coal particles. Two types of bituminous and one type of subbituminous coal particles have been tested. The technique used is called the freezing-front technique and it considers the behaviour of the test particles (in the range of 20-250 pm) at the solidification front of carefully selected, well-defined solidifying melts (matrix materials) such as thymol, biphenyl, naphthalene, salol and 2-phenyl phenol.The results show that the technique works well, providing quantitative and detailed information on the wettability of coal particles. The sensitivity of the method is so high that a difference in contact angle of approximately 4 degrees between the smaller and the larger particles is clearly registered.

Dec 1, 1981

By D. W. Euler, B. J. Clauzier

"Implementation of an effective energy management system will reduce energy costs without impacting negatively on production.The energy management system must be designed to complement the operation and be integrated with the organization. It must be reliable and easy to use but most important, it must have an accurate and timely feedback reporting system to allow the operation to take appropriate action.Falconbridge Limited was one of the first three companies to be awarded the energy monitoring demonstration program in May 1987. The program is sponsored jointly by the Ontario Ministry of Energy and Ontario Hydro.This paper describes the approach taken by Falconbridge Limited to implement the Onaping Area Energy Management System.IntroductionThe objective of the project was to implement an effective energy management system, capable of reducing energy costs without impacting negatively on production.Energy management systems must be designed to complement the operation and to be integrated with the organization. The system must be reliable and easy to use, but most importantly, it must have an accurate and timely feedback reporting system to allow the operation to take appropriate action."

Jan 1, 1990

By R. S. Adhikari

This paper presents an innovative computer vision method for condition assessments of bridges with multiple defects in bridge elements using digital images. This work utilizes 3D model of existing bridges and overlays digital images on 3D model to simulate on-site visual inspection. The analysis of element condition index (ECI) of bridges requires information about the severity and extent of defects in elements. In general, ECI is evaluated manually during routine bridge inspection considering the severity of dominant defects. The evaluation of ECI with multiple defects needs to be addressed with consideration of dominant defect as well as the interaction among defects. However, Image-based quantification techniques largely depend on geometry of objects (i.e. shapes). Shape vectors of a given object change as they are translated, rotated, and scaled with different magnitudes. This work considers shape preserving algorithms such as, affine and projective transformation for proper image alignment. Semi-automated approach for detection and quantification of concrete distress such as cracks and spalling are considered for the defects analysis. The proposed methodology ensures the consistency in reporting ECI and eliminates the shortcoming of traditional approaches.

Aug 1, 2013

By Bruce C. Smart

"Very little attention was given to the regulation of uranium mills by the Atomic Energy Control Board prior to 1974. The ore grade treated by Canadian mills in the past was in the order of 0.08 - 0.3% U and it was not difficult to keep the exposure of workers well below regulatory limits. Furthermore, uranium milling has also been substantially free of occupational illness because environmental control has been generally satisfactory (l).The discovery of higher grade ore bodies in Canada has resulted in higher radiation levels in one mill and this has partly contributed to a need for increased radiation monitoring in the mill. In addition, as greater insight is gained on the effects of radiation, the implementation of the ALARA principle is being stressed at all mills.The concept of ALARA was emphasized by the ICRP (International Committee for Radiological Protection) in 1977 and stands for '""as low as reasonably achievable'"". It is based on the premise that no proven threshold for potential effects of radiation exists and that the actual individual exposure should therefore be kept as far below the regulatory limit as possible, economic and social factors being taken into account."

Jan 1, 1982

By Michael S. Moats, Addin Pranowo, Gerardo R. F. Alvear F., Nigel Aslin

The toxicity of arsenic is well known and documented. However, the presence of arsenic in copper electrorefining anodes and electrolyte is critically necessary to produce high quality cathode. Arsenic as well as antimony and bismuth concentrations vary depending on their relative concentration in the anode copper received from the smelter. This paper will discuss the behaviour and benefits of arsenic in copper electrorefining and the detrimental effects of antimony and bismuth on cathode quality and tankhouse performance. This will include the minimization and mitigation of problems associated with arsenic, antimony and bismuth including cathode contamination, floating slimes, scaling and anode passivation.

Jan 1, 2014

By Aimee Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario, using bacterial metabolic processes are used to enhance the solubilization of the metal(s) of interest. The cost effectiveness of bio-mining in Elliot Lake depends on the bacterially-influenced dissolution metals of economic importance, as well as on the ability to suppress microbiological activity following the release to solution of the economically important elements. This poster provides an overview of elemental recovery results and release kinetics for more than 50 elements. The data is obtained using a combination of advanced spectroscopic tools (ICPAES and ICP-MS) to analyze solutions obtained from a series of environmentally controlled biologically mediated uranium ore extraction experiments. The focus will be on rare earth elements, potential environmentally toxic elements, and metals of economic importance. Furthermore, the importance of these findings will be put into an economic and geologic context for the re-development of the mining industry of the Elliot Lake Camp.

Aug 1, 2010

By Damian Connelly

The option to leach iron from low grade copper concentrates could reduce transport costs and significantly improve the saleability of the concentrate. In addition, it reduces smelting costs and can remove undesirable impurities. The trend to produce cleaner and higher grade copper concentrates is very appealing to the smelters. A recent copper project came on line and there were three serious deficiencies which were not identified in the feasibility study. This came as a surprise and resulted in a number of projects to investigate ways of rectifying the problems in the shortest timeframe possible and using minimal new capital. The first serious issued not identified when commissioning was the lower than expected copper recovery, which was 70% compared to a predicted recovery of 80% to 87% in the feasibility study. This required investigating new flotation reagents and incorporating controlled potential sulphidisation. The second serious issue overlooked is the presence of significant amounts of talc minerals (insol) in the ore which are naturally floatable. This leads to lower concentrate grade and attempts to remove the talc resulted in lower copper recovery. Smelters have limits on the amount of talc in concentrate because it produces viscous slags and difficulties for the smelter. It also incurs higher transport costs. The third serious issue not identified in the feasibility study was the high arsenic reporting to the concentrate. Arsenic is a penalty element for smelters and at levels exceeding 0.3% the smelters may reject the concentrate. Arsenic is a problem environmentally for copper smelters and penalties apply when it is high. This paper describes the options for penalty element removal and suitability to incorporate into the modified flowsheet. It also highlights where the geometallurgy was not properly addressed and how these surprises could have been avoided. INTRODUCTION From 1970 to 1985, a copper company undertook metallurgical testwork on the Peruvian project copper ore. The ores were mined underground and treated over many years previously. Various other groups undertook studies and work until Aker Kvaerner undertook a feasibility study in 2006. Three ore composites were tested and grind-recovery relationships were developed. The feasibility study testwork identified that talc was a possible concern and will have an impact on copper concentrate grade. This was to be managed by blending. The current operating reality is that there is so much talc in the ore body it is not possible to blend it out. There was far more emphasis on molybdenum recovery. No mention was made of arsenic issues other than blending. There was a Concentrate Leach Study and a Molybdenum Hydrometallurgical Plant Study but these options did not proceed to a final flowsheet. A Scoping Study in 2006 looked at a Heap Leach project. The heap leaching gave very poor copper recovery on the sulphide ore. Heap Leaching was evaluated and tested for the high talc and high arsenic ore but recoveries were poor. The Aker Kvaerner feasibility study opted for a simple primary crush SAG/ball grind followed by flotation and sale of a concentrate. This is the current flowsheet utilised and the scale of the project is very large based on processing 117,200 tonnes of ore per day. A feasibility study does not guarantee success and the deviations from the feasibility study suggest there is a lot of technical work required to improve the current metallurgical performance.

Jan 1, 2019

By Y. Konishi

This paper reviews the mechanism and kinetics of bioleaching of chalcopyrite by the thermophilic archae Acidianus brierleyi in batch and continuous-flow reactors. Rate data for the batch bioleaching of chalcopyrite concentrate were collected to clarify mechanism of the chalcopyrite bioleaching with A. brierleyi. The chalcopyrite leaching was markedly accelerated in the presence of A. brierleyi, and greater than 90% copper leaching was achieved within 10 days. Chalcopyrite leaching took place predominantly as a result of direct attack by adsorbed bacteria on the sulfide surface, the chemical leaching with ferric iron being insignificant. Batch rate data collected under a variety of operating variables were analyzed with our batch bioleaching model, in order to estimate microbial kinetic and stoichiometric parameters for the microbial growth on chalcopyrite. The batch model and the estimated parameter values were used to find optimum operating conditions. Moreover, the batch model was extended to describe the bioleaching in continuous-flow stirred tank reactors. Simulations based on the continuous reactor model and the estimated parameter values were used to predict the leaching fraction as a function of the number of reactors connected in series.

Jan 1, 2007

By Edmond Chow

Shovel bucket blast fragmentation analysis is an alternate way to assess blast performance and its effects on downstream mining processes. A camera is installed on the boom of cable shovels, and the stick of hydraulic shovels. Images are captured automatically as the shovel digs, and are processed to acquire rock size information. The automatic data acquisition makes this method safe to use with minimal manual labour. It also allows for a large set of sample data to be captured from both the surface and the interior of a bench face. The system has been deployed in several mines to provide an objective assessment of blasting performance. Images are captured from their cable or hydraulic shovels. The images are grouped into sets based on the shovel location and time to match the fragmentation to specific blasts. Blast fragmentation reports are created for each blast after reviewing the results. Measuring blast fragmentation from the shovel bucket proves to be an effective alternative for blast performance assessment with unique advantages. The blast fragmentation information has been valuable to the mines, and the mines have begun adopting it into their operations.

May 1, 2011

By R. A. S Villegas

The Brazilian government announced in 2007 its plans to reactivate the nuclear program. As a result of this decision, a new nuclear power plant is already being built and there are studies dealing with, among other activities, the building of 4 to 8 new ones until the end of 2030. Such increase on the country?s uranium demand affects INB, the Brazilian state company that?s in charge of uranium supply. This paper describes scenarios predicted to the Brazilian nuclear industry for the next years and the INB plans to meet the country?s needs in terms of uranium exploration and production.

Aug 1, 2010

By D. L. Chen, Q. Zhang

The effect of particle sizes on the low cycle fatigue (LCF) life of discontinuously reinforced metal matrix composites (DR-MMCs) has been widely studied. However, how the particle size affects the LCF life of DR-MMCs quantitatively is still lacking. The aim of this investigation is, therefore, to present an analytical model linking the LCF life to the particle size. This model, based on the enhanced dislocation density in the matrix and the load bearing effect of particles, showed that a decreasing particle size results in a longer LCF life, and the results predicted are in good agreement with the experimental data.

Jan 1, 2004

By I. Zhitomirsky, X. Pang

The outstanding thermal and chemical stability, excellent mechanical properties and biocompatibility of zirconia have made this material an important candidate for fabrication of advanced protective coatings on metals, graphite, carbon fibers and biomedical implants. Nanostructured polymer-ceramic composite films containing zirconia were synthesized on metallic substrates by combining cathodic electrosynthesis of inorganic particles with electrophoretic deposition of cationic polyelectrolytes. Thick crack-free oxide and composite coatings were obtained using this newly developed technique. The deposits were studied by thermogravimetric analysis, X-ray diffraction analysis, scanning electron microscopy and atomic force microscopy. The mechanisms of deposition are discussed.

Jan 1, 2004

By Shamil Shaikhutdinov

CO adsorption on gold particles deposited on well-ordered alumina and various iron oxide films has been studied with temperature programmed desorption (TPD) and infrared reflection adsorption spectroscopy (IRAS). Structural characterization has been performed with scanning tunneling microscopy. Data show that the CO adsorption exhibits a size effect in that small particles adsorb CO more strongly. The effect generally vanishes after annealing to 500 K. For annealed samples, CO TPD and IRAS spectra are nearly independent of the particle size and supports studied. The results indicate that the CO interaction with gold surfaces is essentially similar and involves low coordinated atoms.

Oct 1, 2003

By E. M. Córdoba

The effect of the Fe3+ lFe2+ redox couple on the chemical and biological dissolution of chalcopyrite was studied. All the tests were carried out in stirred flasks with 100 mL of a ferric/ferrous sulphate solution, in the absence or in the presence of bacteria (iron- or sulphur-oxidizing) and at low (35 DC) and high (68DC) temperature. The initial redox potential was controlled between 300 and 600 m V Ag/ AgCI and silver was used as chemical catalyst. The results showed that the oxidizing action of ferric ion on the chalcopyrite was controlled, in all cases, by nucleation and precipitation of jarosites on unreacted particles. The tendency of Fe3+lFe2+ solutions towards equilibrium favours the activities of both ions to be equal. Consequently, the dissolution rate was faster at relatively low redox potentials (between 400 and 500 mY) than at high values (600 mY). In this sense, the presence of ferrous ion in the system is a key factor to control hydrolysis and precipitation of ferric ion. Unlike jarosite, the elemental sulphur produced during dissolution of chalcopyrite was porous and did not act as a diffusion barrier.

Jan 1, 2007