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By Tatyana Alexandrova

The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Technological aspects of processing precious metal ores are examined in two respects: enhancing gold recovery from double refractory ores; and using carbonaceous ores on a production scale. The dispersed carbonaceous matter (DCM) present in concentrates causes the adsorption of [Au(CN)2]- complex on their surface during cyanidation process. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The possibility of rare metals recovery, including rhenium, from black-shale rocks, has been examined. Comparative assessment of analytical methods of rare metals detecting has been carried out. It has been proved that neutron activation analysis is a promising technique. It has been shown that colloid-salt fraction (nanofraction) with particle size less than 1000 nm makes up to 3 wt% of black shale samples and is extracted by water under special conditions. The use of water instead of chemically active reagents provides insolubility of the mineral matrix and fully reflects the colloid-salt element of the samples. To sum up, the justification of the choice of technology for processing of carbon-bearing ores is based on examining the type of carbonaceous matter and its adsorption behavior. When the content of carbon of high degree of metamorphism is considerable, it is possible to recover platinum group elements and rare elements from this type of ores. The obtained results predetermine the general guidelines for creating new methods and techniques of processing carbonaceous material for integral development of solid minerals in the mining and oilfield areas of Russia.

Jan 1, 2016

By P. A. Riveros

The literature on the arsenic disposal practices of the metallurgical industry and the long term stability of the disposed arsenic compounds were reviewed from a Canadian perspective. The review was complemented with visits to selected operating metallurgical sites to obtain information on their specific arsenic disposal practices and the behaviour of their impounded residues. The arsenic disposal procedure currently favoured by the industry involves the formation of an insoluble ferric arsenate compound which is allowed to sediment at the bottom of tailings or residue ponds. It has been shown recently that this poorly formed crystalline compound is similar to ?arsenical ferrihydrite? which is ferrihydrite containing strongly adsorbed arsenate anions. Despite concerns about its long term stability on thermodynamic grounds, arsenical ferrihydrite appears to be stable for many years in the proper environment which includes a slightly acidic pH and oxidizing conditions. A high Fe/As ratio and the presence of heavy metals appear to increase the stability of arsenical ferrihydrite. High temperature operations, such as those encountered in the autoclave treatment of refractory gold ores, are conducive to the formation of scorodite, FeAsO42H2O, and/or a series of ferric arseno-hydroxy-sulphate compounds depending on the solution composition. Scorodite has several advantages over arsenical ferrihydrite as a disposal compound including a lower iron demand, a higher density and a greater thermodynamic stability. New procedures have been developed to generate scorodite at ambient pressure. These procedures would offer significant reductions in capital cost because of the elimination of the need for autoclaves. Lime precipitation which was widely used in the past is being abandoned as a result of strong evidence showing that calcium arsenate compounds decompose slowly in contact with atmospheric CO2 to form calcium carbonate and soluble arsenic acid. In all cases, the long term stability of the disposed arsenic compounds depends on a number of factors including disposal site characteristics, particle crystallinity and size distribution, the presence of complexing agents and the effect of bacterial activity.

May 1, 2002

By A. L. MacAllister

"Keymet Mine lies on the Elmtree River 4 miles west of Petit Rocher and about 18 miles northwest of Bathurst, Gloucester County, New Brunswick. A good gravel road runs through the property.The deposit was discovered in 1880 when a vein 7 to 8 feet wide was re-ported. In 1883 the first shaft was sunk as part of an exploration program which was carried out sporadically until 1897, when the company dissolved. Activity on the property was intermittent until 1946 when the property was again staked and during the next year diamond drilling intersected the vein in several places. In December 1949 Coulee Lead and Zinc Mining Company optioned the property and held it until its sale to Keymet Mines Limited in June 1952. By July of the same year work had begun on a three-compartment shaft.Early development work was concentrated on the 150, 300 and 450 foot levels but the shaft has since been sunk to I,228 feet to allow for eight levels at intervals of 150 feet. Little lateral work has been done to date below the 600-foot level.The first mill constructed to treat the ore was to go into production in the spring of 1954, but was destroyed by fire. A second mill, having a capacity of 200 to 300 tons a day, was officially opened October 25th, 1954. Present shipments are zinc and copper-lead-silver concentrates.The rocks of the area are shale, conglomerate, limestone, and quartzite with minor interbedded volcanic rocks, all probably of Silurian age. Small plugs of Devonian acidic intrusions occur 3 miles east and about 5 miles northwest of the mine. Minor dykes of both acidic and basic rocks occur on the mine property. In many of the fine-grained sedimentary rocks the more brittle laminre have been brecciated and give the rock the appearance of an argillaceous conglomerate."

Jan 1, 1949

By B. D. Wood, J. A. Fowler, H. S. Grütter, J. M. Kong

Abstract- The phased approach used by De Beers for diamond exploration is briefly outlined. The Victor kimberlite is one of 19 kimberlites in a cluster near Attawapiskat, Ontario. The progress at the Victor kimberlite is summarized, and the operations are described within the framework of this staged approach. An evaluation program is currently under way on the Victor kimberlite, but although results are encouraging, insufficient diamonds have been recovered to permit disclosure of estimates for the grade and value.

Jan 1, 2001

By Kathy Pomeroy

Sharing?? l Maybe not the first image that comes to mind when we think about the historical corporate mind set and track record of many corporations ? ! A Fundamental Change in Relationships l From a worldview of independence to one of recognized interdependence l Collaborative action with communities for long range mutual goals l Acceptance of greater accountability for the whole l Community and government relationships based on trust, mutuality, respect for human rights, equity, sustainable agreements

May 1, 2002

It?s a pleasure to be with you in Vancouver today to reinforce the good work you and your companies do to develop and operationalize new technology as a lever to improve operational performance and reduce our impact on the environment in absolute terms. Although I will use the work we do at Shell to reinforce this perspective, the principles apply to all of us in this industry regardless of whether you are a producer or supplier. I?d like to help demystify the future of Canada?s oil sands based on Shell?s view of global energy developments, including forecasted demand. One of the incontrovertible truths of this era of global energy defines change as an unchangeable law of progress. Another tells us that the art of progress is to preserve order amid change and to preserve change amid order. These axioms help frame the increasingly public debate about the future of Canada?s oil sands. I hope to illustrate how Shell?s commitment and investments create positive progress that embraces change amid order in the oil sands. I?m going to spend a little time today to focus the spotlight on the future of the oil sands to help demystify Canada?s hydrocarbon energy future. To do that, I?ll identify the features of our future energy security, including three hard truths about global energy that drive Shell?s business imperatives. Then, it?s instructive to examine Canadians? current consciousness about oil sands sustainability.

Oct 1, 2009

By C. Graham

Mechanisation has been a predominant theme of the past 50 years in the mining industry, particularly underground mining. As the level of technology employed has increased, the anticipated productivity gains have not been realised and the differences are not explained by the demand for higher standards of safety and security. Now, mining costs are so high and productivity so low that the resultant return on investment for many Canadian operations has fallen to levels considered unacceptable in a competitive capital market. Simply continuing technological development cannot reverse this trend and its financial implications. The focus on technological development has distracted us from some basic truths. Systems that are more complex are more likely to fail and cost-effective processes depend on the continuity of productive activity and the flow of material. When putting these facts together, it becomes clear that in a system that has fixed external conditions, the single most crucial issue is the effective management of the operational cycle. By its nature, technology focuses our attention on what gets done and how it gets done, while the crucial issue is the increasingly longer periods in the operational cycle when nothing productive is being done. What is required is to match the level of technological complexity to the fixed system conditions, which are virtually unchangeable. This paper looks at the overall system and objectives and attempts to present an appropriate level of technology for the Canadian mining industry, now and in the foreseeable future.

May 1, 2004

By G. L. Spence

Prevention of cuprous and cupric oxide formation on stored ETP copper rod is a major concern for copper rod and wire producers. During normal storage periods copper oxide layers can increase from less then 100 A to more then 1000 A exceeding ASTM specifications and discoloring the rod surface. Various types of corrosion inhibitors are tested and compared in effectiveness for prevention of copper oxide formation on stored copper rod. Aromatic triazole compounds are also compared to a non-azole containing compound.

Jan 1, 2007

By F. J. Macias, A. Bruland, F. E. Dahl

"Tunnelling by use of Tunnel Boring Machine (TBM) is gaining a greater presence as a suitable excavation method. Disc cutter consumption has a strong influence on performance and cost when using TBMs and the influence becomes even more relevant in hard rock. Furthermore, good predictions of TBM performance and cost facilitate the control of risk as well as avoiding delays and budget overruns. Since abrasive wear is the most common process affecting cutter consumption, good laboratory assessments are needed. A new abrasivity test method called Rolling Indentation Abrasion Test was developed. The goal of the new test design and procedure is to reproduce wear behaviour on hard rock tunnel boring in a more realistic way than traditionally used methods by introducing wear by rolling contact on intact rock samples. INTRODUCTIONHigh investments are involved in the tunnelling industry, especially in Tunnel Boring Machines (TBMs) projects. Performance predictions and cost estimations are crucial for planning and risk management of TBM projects. Cutter consumption has a large influence in terms of time and cost, and an even greater effect in case of hard rock projects. Many factors are influencing the amount of cutters consumed in hard rock TBMs. Normal TBM operation results mainly in abrasive wear on the cutters and appropriate methods for abrasivity assessment are needed. Rock abrasiveness cannot be considered as an intrinsic property and the complete tribological system should be considered in addition to the geological properties of the rock.In the present paper, a new test method for abrasivity assessment in tunnel boring called Rolling Indentation Abrasion Test (RIAT) is presented. The traditionally used test methods for determination of rock abrasiveness uses sliding or impact contact in order to cause wear while the RIAT introduces rolling contact on intact rock samples. The ambition of the new test device is to have a reliable method to evaluate the cutter wear in hard rock tunnel boring by reproducing wear behaviour on rolling disc cutters in a more realistic way. It has been established by many authors that the abrasion of a cutter ring is proportional to its rolling distance (Rostami, 1997; Bruland, 1998). In the present work, the weight loss of a mini-cutter ring is measured subsequent to testing in order to evaluate wear in the rolling process and could hence be related to cutter ring wear. Indentation of the tools in the intact rock sample is considered as an indication of the surface hardness of the rock or the resistance to indentation by rolling."

Jan 1, 2015

By Ron Tessier, Claude Bazin, Robert Grant, Mike Cooper

"Grinding simulators are now widely available to assist in the optimization of industrial circuits. They provide circuit operating conditions or flowsheet designs that yield a given product size distribution. However, they do not provide information of the impact of a change of product size distribution on the subsequent flotation or leaching stages. This paper presents a method to predict grade and recovery indices for a flotation plant as a function of the flotation feed size distribution. The application of the method to various size distributions allows the determination of the optimal fineness of grind. A case study for a CuPb rougher circuit of a New Brunswick complex sulphide processing plant is presented to illustrate the method.IntroductionIs the grinding circuit product fineness optimum for the subsequent separation steps? This is a question that is certainly very difficult, but critical, to answer. Laboratory and pilot plant testworks can provide clues as to whether grind should be finer or coarser. For a full scale operation there is no other way than trying to change the setup of the grinding circuit and verify the effect on flotation. True effects can, however, be masked by the numerous and unexpected disturbances inherent to grinding and flotation circuit operations. A good preliminary investigation requires a noise free environment to elaborate possible solutions for the question.Plant simulators provide this noise free environment. However, despite grinding and flotation simulators having evolved significantly for the last 20 years, very little is available on the integration of both simulators to analyze the effect of fineness of grind on metallurgical performances. For instance, a grinding circuit simulator may help to find the tuning of a grinding circuit that will yield the desired fineness of grind, but does not inform on the effect the new product size distribution will have on the separation stages. Linking grinding and flotation would require a flotation plant simulator with the rate and infinite recovery parameters for each mineral in each size interval considered. This approach is seldom used because of the tedious work required to estimate the model parameters. Recently Leroux(1992) proposed a method to predict mineral liberation from grinding ore of known mineralogical texture. Although the method is still at its infancy it may provide, when combined with a reagent conditioning model (e.g Niemi et al., 1982; Bazin et al., 1988), a way to simulate flotation without the need of entering the numerous parameters of a flotation model."

Jan 1, 1994

By A. Kozlowski

We present research on cable fault location methods for mines where coal dust and methane explosions are a frequent potential hazard. The methodology and devices for low- and medium voltage cables fault location are well known and applied in classical power distribution networks. They are based on solutions for underground mines with a high risk of explosion. The lack of a safe solution for the location of a fault has contributed to the initiation of a research project by a group of Polish companies. The consortium consists of research institutes (Institute of Innovative Technologies EMAG, Tele and Radio Research Institute, Central Mining Institute GIG-KD ?Barbara?), Silesian University of Technology and a private entrepreneur MARTECH PLUS. Fast and exact determination of fault location is one of the important factors for minimizing power outage time. The lack of technical solutions to obtain measurements in a secure way leads to the use of the methods connected with a high risk of explosion. For example, the application of high energy can lead to arc discharge where there is a fault in insulation, creating the risk of an explosion. Measurements of methane concentration along the analyzed section of the cable reduce the risk; however the shock wave generated by the electric arc may raise coal dust and make an explosive mixture, which is an object of ignition. Low energy methods, like those based on reflection waves, have low sensitivity for high- and medium-resistance faults. This technique has difficulties in joints, which create false echoes. The fundamental problem is to determine the topology of the network using a reflectogram and find anomalies of a different nature ? not only open and short circuit. Included in the scope of the project is an analysis of Polish legal regulations related to fault location and operational work for low- and medium-voltage networks. Two of the methods used on the surface were selected as feasible to implement under explosion hazard conditions. In the process of development of the fault location methodology, installation features characteristic of underground mines were used, namely access to the whole length of a cable. This is the attribute that provides an opportunity to do measurements that are usually not possible for typical surface power nets. To carry out laboratory tests, a dedicated measuring stand with various types of cables was built. The authors describe the principle of operation of the fault locator and the results of the laboratory tests carried out on the cables with built-in damage (prepared for tests). Results of the work will be the basis for the next stage of the project associated with operational analyses of the prototype.

Aug 1, 2013

By R. Phillips, A. G. Doll, D. J. Barratt

"The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less.This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference."

Jan 1, 2012

By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005

By R. A. Walker, G. Scheltgen, T. Javorsky, G. Blackwell

"Recent engineering advances in open pit rock mechanics have resulted in improved pit wall slope design and improved operating procedures in the event of a major wall instability. At the other end of the spectrum, on the scale of single bench failures, considerable discretion is left to the mine operators as to how potential problems are handled. The usual alternatives are either to operate with caution beneath potential hazards, or try to bring the unstable rock down. In specific cases it may be advantageous to attempt to stabilize rock structures for reasons of access and operating safety.A t the Brenda Mines open pit a prominent structure on the north wall had caused recurring bench-scale wedge failures when exposed on each mining level. In spite of operating precautions a shovel was hit by a rockfall causing significant damage. The first section of this paper describes the investigative, design, and stabilization methods which permitted subsequent mining beneath the structure to proceed without incident. Emphasis is placed on the personnel and equipment resources available at the mine site which were used to minimize costs and which would be available at most operating mines.The second section describes an ongoing research project that utilizes radio telemetry to transmit slope monitoring data. As part of this project the wedge structure was instrumented so that it could be continuously monitored with the aid of a computer. The application demonstrated the potential of 'micro- chip' technology to remote data collection and processing as related to rock structure monitoring, slope stability and safety."

Jan 1, 1989

By G. B. Hobbs, S. Saimoto, L. Collins

"Plastic yielding and flow in metals is dependent on the microscopic process of simple shear along crystallographic planes and directions known as slip. Thus, by altering the crystallographic direction of the stress axis or placing constraints in the direction of plastic flow, anisotropy of yield strength for the same material is observed. This phenomenon is called texture strengthening. The application of this concept to highly anisotropic crystal structures such as the hexagonal group of titanium and zirconium alloys, the former in missile casing and the latter in nuclear reactor fuel tubing, seems obvious. The outstanding example in cubic structures is the case of deep-drawing steel. The R value, the width strain over the thickness strain during a tensile test, is taken as a measure of texture strengthening. In face-centred cubic structures, texture strengthening has been completely ignored on the basis that materials with R less than one are not amenable to this beneficiation. This study will review two aspects of texture which will lead to strengthening, first the thermal stability of the deformed microstructure, which is dependent on the stress axis, and second, the texture strengthening aspect of fcc metals.A review of recovery and recrystallization in textured aluminum wires, copper and cupro-nickel sheet will be presented with the view of extending these concepts to the manufacture of heat-exchanger tubing. The superior creep properties of specially processed commercial products such as TD-Ni, TD-NiCr and MAR-M200 will be shown to be a manifestation of the same physical phenomena."

Jan 1, 1981

By A. Zangooi, J. A. Finch

"A frother analysis technique based on the formation of a colored solution with UV-VIS absorbance proportional to frother concentration over a certain range has been developed. The calculation of concentration requires the comparison of the sample absorbance at a selected wavelength with a linear calibration (frother concentration vs. absorbance) constructed with values collected from solutions of known concentration (standards) at the same wavelength. It has been found that concentration ranges for preparation of standards can vary widely. An integration of our experiences into a databank can offer some guidance on the selection of standard concentrations. The databank includes results from the analysis of 37 chemical reagents, commercial frothers, and natural oils used in research work or at industrial sites. Grouping frothers by similar chemical structure or origin provides a good basis for selecting the standards to approach the maximum absorbance range for the spectrophotometer in use.INTRODUCTIONA technique to determine frother concentration on samples of industrial milling streams based on formation of a colored solution with UV-VIS absorbance proportional to frother concentration has been developed. The concentration is determined by comparison of its absorbance, at some selected wavelength, with those obtained by processing a series of solutions of known concentration (standards), at the same wavelength. It is desirable to have linear calibration (frother concentration vs. absorbance) over the widest concentration range. The upper concentration can be restricted by the instrument, as there is a maximum detectable absorbance (minimum transmittance), which can be reliably sensed by the UV-VIS detector (in most cases maximum absorbance is 3)."

Jan 1, 2016

By Y. Hou, E. Arinaitwe, L. Tong

A series of dense medium separation (DMS) tests were performed on four low-grade copper ores from Mount Polley mine in order to determine their amenability to pre-concentration. The tested ores contained disseminated sulphides, mostly chalcopyrite with low copper grades (0.15% - 0.2%) and relatively high iron grades (4.76% - 5.63%). The samples were screened into different size fractions ranging from 9.5 mm to 50.8 mm and DMS tests were performed on each size fraction at various separation densities. The pre-concentration efficiency at different size fractions and separation densities was evaluated in terms of metal upgrading and distribution. Mineralogical tests were also performed on selected DMS sink and float samples in order to understand the influence of mineralogy on the pre-concentration efficiency. The results showed that significant copper upgrading was achieved for intermediate size fractions only at the highest separation density tested. The copper recoveries generally increased with particle size at all separation densities. However, it was impossible to upgrade the copper content in the ores and achieve acceptable recoveries and mass rejections at the same time. Copper recoveries and grades showed a strong correlation with iron recoveries and grades indicating that it is possible to pre-concentrate copper by recovering magnetite and other iron-containing minerals in the ore. Overall, the results suggest that the optimum separation density and pre-concentration efficiency is a function of particle size, and that the ore mineralization properties limit the performance of DMS as a pre-concentration technology for such low-grade disseminated ores.

Jan 1, 2014

By Chris D. Veldhoen

If you ask most diamond drillers if they have ever encountered methane gas, the answer would probably be yes. This paper explores a serious methane gas explosion that the author experienced while diamond drilling at a northerly Ontario mine. It is hoped that by documenting this event, people may be alerted to the hidden danger posed by confined methane in underground workings. Methane gas tends to be a problem the deeper you get in any Canadian gold mine. Common procedure when encountering methane is to take readings at the collar of the hole and at different lengths from the source. Monitoring continues until the readings drop below 0.25 ppm. Methane is a tasteless odorless gas that is usually locked up in the seams of the rock or is a product of decaying organic material. Occasionally, the gas is released abruptly over a short period of time. Sometimes the gas can continue to vent for months or even years. In small concentrations, methane is relatively safe. In concentrations under 0.25 ppm methane gas is considered safe to work around. Concentrations over 0.25 ppm can become dangerous. During the summer of 2001, Chris Veldhoen was drilling at a gold mine in Ontario. There were three electric hydraulic diamond drills on the 39 meter level, approximately 5200 feet deep. Two Longyear LM 55 drills were about 40 feet apart and another LM 75 was about 2000 feet away. The two LM 55?s were set up to drill holes no deeper than 350 meters. All three drills had been set up on the same spot for more than a month. None of the three drills had ever encountered methane gas in the entire time they had been drilling on the level. On the day shift of July 13 2001, the driller on Chris? cross shift hit a small pocket of gas. He tested the hole and got a reading above 0.25 ppm. He proceeded to rope off the area with a ?DO NOT ENTER - METHANE GAS? sign and a rope denying access beyond the sign. On Saturday, July 14, Chris was instructed to install a Margo plug in the hole that was emitting methane gas. Methane is usually odorless, but occasionally when encountered underground, is accompanied by a rotten egg smell. As he walked to the drill, he could not smell methane gas. He proceeded to test the hole and got a reading of 0.22 ppm methane. This number was in the acceptable range for drilling, but he plugged the hole anyway.

May 1, 2004

By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016

By M. Fafard, D. Picard, J. -F. Bilodeau, G. Soucy

To simulate adequately the behaviour of a Hall-Heroult electrolysis cell, a finite element model must take into account the properties of each material. However, it has some lacking knowledge on the mechanical behaviour of materials, like the long-term visco-elastic (creep/relaxation) behaviour of cathode. A three-dimensional model is then proposed in this paper and will be ready to be implemented in the finite element code FESh++. The model was developed using the three-dimensional model based on thermodynamic of irreversible processes where the choice of the internal variables is based on a phenomenological approach. All parameters of the model are represented by constant constitutive tensors and the temperature and chemical dependencies are taking into account through scalar functions multiplying the constant constitutive tensor. The goal of the first part of this project was to determine the parameters of the threedimensional visco-elastic model at the reference state (virgin material at ambient temperature) of three different cathode materials. This paper presents the theoretical model and the results of creep tests at ambient temperature for the semi-graphitic carbon cathode.

Jan 1, 2006