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By T. I. . I. Sibbald, D. E. Jiricka

The Goldfields area on the north shore of Lake Athabasca , was active in the thirties and early fortie . In 1934, Tom Box discovered gold mineralization in quartz veins in pyritized 'granite' at the ite of what wa to become the Box Mine of the Consolidated Mining and Smelting Company of Canada Ltd . In the rush of activity that followed numerou other gold occurrences were found. the most significant of the e being the Athona and Frontier prospects which underwent underground development bur did not reach production. Probable reserve identified to date in the Box and Athona deposits amount to some 3.5 million ton grading an average 0.ITT oz gold/ton . Some 10 to 15 million tons of lower grade, po ible reserve are also reported at the Box. From 1939 to 1942, the mine produced, from underground , 64,066 ounces of gold from ore grading 0.0452 oz gold/ton at a cost of between $1.5 and $2.0 a ton. The Goldfield area is underlain by upracrustal rock intruded by mafic bodies and invaded by ·granite'. The upracru tal . thought to be of Lower Proterozoic age are characterized by a helf-type ucce ion metamorpho ed under lowermiddle amphibolire facie conditions into quartzites, quartz-mica chi ts. dolomitic marbles, diop idic calc-silicates and cordierite-anthophyllite-biotite schi t . Amphibolites of presumed igneou origin form concordant to subconcordant units up to a few ten of metre thick in the upracrustals and occur as le regular masses in the 'g ranite·. Compositionally they vary from gabbroic to granodioritic. with the more mafic varieties being most common. Granitic rocks exhibiting a variety of textural , structural and compositional characteristics underlie most of the area. Four main units are recognized: foliated (older) 'granite', 'leucogranite', feldspar augen 'granite· and pyritic mine 'granite', however, in geological mapping the e are somewhat arbitrarily differentiated due to transitional relationships and admixture of types. Although there is no unambiguous age data available for the e 'granite ' adjacent northshore 'granite' of geologically similar age yield Rb-Sr isochron dates around 2000 Ma. The area is characterized by two major deformation events of which the earliest gave rise to the dominant regional foliation and to rare minor and outcrop scale folds. This foliation which in general parallels compositional layering is folded into the major Goldfields syncline, whose axis plunges weakly to moderately outh. Related open minor folds have subvertical axial surfaces which are locally paralleled by a weakly defined schistosity. Most rock display a pronounced rodding fabric, coaxial with second fold axes and apparently the product of this deformation event. However, a note of caution is introduced into this interpretation, as the rodding fabric is also parallel to first fold axe .

Jan 1, 1986

By T. M. Siew

"This paper begins with a brief discussion of the geology of the Newfoundland Zinc Mine area. The results of groundwater studies and pumping tests are then presented. It was decided that groundwater in the mine could best be controlled by conventional sump pumping and grouting. The system is fully described, as well as plans for improvements on the method. LocationThe Newfoundland Zinc Mine is located in the Great Northern Peninsula of Newfoundland, six miles northeast of Daniel's Harbour. The mine is situated at an elevation of approximately 350 feet above sea level, 5 miles farther inland , west of the long range of mountains which rise abruptly with elevations of over 2,000 feet above sea level.GeologyThe ore deposits occur in lower Ordovician carbonate rocks that form part of the stable St. Lawrence platform, which is mainly composed of (1) the lower Cambrian Labrador group, (2) the upper Cambrian to lower Ordovician St. George group, (3) the disconformity overlying Middle Ordovician limestones and shales of the Table Head formation and, (4) two overlying klippen composed of Cambrian and lower Ordovician rocks.The ore deposit is a Mississippi Valley type of the Tennessee variety, having proven are reserves of 5.3 million tons averaging 9.70/0 zinc from eleven ore zones which exist in an area of 5.5 square miles.Among these ore zones, the L zone is the major underground mining area, and is by far the largest of the known deposits. It has proven are reserves of 3.4 million tons with 11.5% zinc; this underground development has been inprogress since 1974.Stratigraphically, the orebody, which occurs about 300 feet below the disconformities between the Table Head and St. George formations, is situated in the upper St. George formationof lower Ordovician age.The upper St. George formation of the L zone is divided into three main units (Fig . I) : the underlying lower limestone the middle grey dolomite pseudo breccia unit and the overlying siliceous dolomite unit. In this area of the mine, the beds of the St. George formation dip gently west to northwest to 10 to 15 degrees. The orebody, which is generally strata controlled with a southwesterly plunge and which has the form of thin, narrow, but elongate, en-echelon ore bed s, is contained in grey dolomite pseudo breccia. Its dimensions vary from 50 to 900 feet in width and 8 to 120 feet in thickness, and the over-alllength exceed s 6,000 feet.The surficial deposit of the area is a till comprising a heterogeneous mixture of sand, gravel, cobbles and boulders, with an average depth of 20 feet."

Jan 1, 1980

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Grégoire

Abstract -A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (2:3 cm thick), which seems to have been developed over the entire sedimentary basin of >80 km2, consists of pyrite, vaesite (NiSi), and sphalerite. The average grade of the mineralization is about 5.3% Ni, 0.73% Zn, ?770 ppb (PGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE +Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrient­ rich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic­ matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained S04 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich 1arninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesite­ pyrite assemblage crystallized at approximately 138°C. The ?34:S values range from -14.7 o/oo to-10.0 o/oo and are up to 34 o/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The ?13:C values of calcite in the footwall of the mineralized unit ( -12 o/00 to -6 o/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By Ron Bradburn, Derek Perkins

"The Brenda mine is located in south central British Columbia, 22 km north west of Peachland, in the heart of the Okanagan Valley. Situated at an elevation of 1500 metres, the mine area straddles the divide between the headwaters of Trepanier Creek and Peachland Creek. These flow into Okanagan Lake, the chief valley water resource located 1100 metres below. The creeks are of great significance to the water management of the area as they constitute the water supply for the Municipality of Peachland, a thriving retirement community with a population of 5000. A location map is shown in Figure 1.The history of the Brenda Mine operation has been well documented previously. After twenty years of operation, the open pit mine shut down in June 1990 due to the depletion of its ore reserves. During the course of its life, it produced 109 million tonnes of waste rock which is thought to contain approximately 0.10% copper as chalcopyrite and 0.015% molybdenum as molybdenite stored in four rock piles around the pit. Similarly, approximately 200 million tonnes of tailings were produced grading 0.015% copper and 0.005% molybdenum. During operation, tailings were hydrocycloned to produce a coarse sand for dam building with the fine slime stored behind the dam. It is estimated that 40% of the tailings were used for the dam construction. The layout of the mine site is shown in Figure 2.The mine was operated under a zero discharge permit. This was achieved by diverting practically all surface water flowing towards the mine area around the site. Water affected by mine operations, was discharged to the tailings impoundment, and recycled to the mill for reuse. The recycle rate was 90% and seepage from the tailings embankment and saddle dam was pumped back to the tailings pond. Because acid drainage was not a problem with the low grade Brenda rock, runoff from the rockpiles was initially released to the local environment. However, due to the alkaline nature of the waste rock, dissolution of low concentrations of molybdenum in the site runoff waters became evident by the late 1970's. The molybdenum content of Peachland Lake, the water reservoir for the municipality of Peachland, approached the Canadian Drinking Water Standard of 0.25 ppm. By 1979, a series of diversion and collection ditches was completed to direct all runoff water from the rockpiles to the tailings impoundment area. This had a significant detrimental effect on the site water balance causing it to go into a considerable surplus condition. During normal operation, this oversupply was contained by the rate of tailings dam building. An economic shutdown of the mine during 1984 forced a limited discharge from the site to protect the integrity of the tailings dam."

Jan 1, 1995

By Jiahao Xu, Namsoo P. Kim, Guikuan Yue

Iron (ferrous ions and ferric ions) plays an important role in the heap leaching of copper sulfide minerals and copper electrowinning. In our previous study, a novel oxidation-reduction potential (ORP) equation only based on the variables of temperature and nominal ferric/ferrous ratio was developed to predict the redox potential of the quaternary H2SO4-Fe2(SO4)3-FeSO4-H2O system, and its applicability was also extended to more complex acidic iron sulfate solutions, especially those generated during the acidic leaching and bioleaching of Printed Circuit Boards (PCBs) to recover copper. In this work, the broader range of applicability of this equation to other complicated acidic iron solutions containing copper ions has been extended and determined. Specifically, synthetic iron-containing solutions with copper ions according to the conditions of industrial electrolyte during copper electrowinning and heap leaching have been used to measure the ORP and test the developed equation. It seems that this equation can still be employed to predict the redox potential of the Fe3+/Fe2+ couple for the simulated solutions under conditions related to copper electrowinning and pregnant leaching solution generated during heap leaching over a wide range of solution concentration, nominal Fe3+/Fe2+ ratio and temperature. It has shown that the prediction and measurement of redox potential is highly useful to estimate and understand the iron chemistry of industrial leaching and electrowinning processes. INTRODUCTION It is well-known that iron (ferric or ferrous) ions are widely involved in the hydrometallurgical production of non-ferrous metals such as Cu, Au and Zn, mainly in the form of acidic iron sulfate solutions. As far as Cu is concerned, in a typical leaching-solvent extraction-electrowinning process, ferric ion plays a central role in the heap leaching process and is reduced to ferrous ions in the pregnant leaching solution. Ferric ion is the most important surrogate oxidant and the dissolved ferric/ferrous couple plays an important catalytic role in accelerating the leaching rate with oxygen as an oxidant (Peters et al., 1986; Schlesinger, King, Sole, & Davenport, 2011). In addition, during the traditional electro-winning process, oxygen is evolved at the anode, and copper is reduced at the cathode. A common idea is that iron in the electrolyte in copper electrowinning cell (with total iron of 1–4.4 g/L) plays an important role in reducing the current efficiency. According to the published results (Winand et al., 1975; Dew et al., 1985; Moats et al., 2009; Khouraibchia et al., 2010), thecurrent efficiency decreases linearly with increasing ferric ion concentration and the energy consumption increase was mainly caused by the decrease in current efficiency.

Jan 1, 2019

By G. Vibert Douglas

NICKEL minerals are known in New Brunswick but have never been reported from Nova Scotia. The attention of the writers was drawn to an occurrence of pyrrhotite, reported to carry nickel, at the Second Gold brook, Middle river, Cape Breton. The purpose of this paper is to record the occurrence and give an account of the general geological association. In a later paper it may be possible to give greater details? than are available at present. GEOLOGY The area lies at the edge of a plateau of Precambrian rocks which forms the panhandle of Cape Breton island. This plateau has a general elevation of 1,200 feet. Middle river, with its tributaries, the First, Second, and Third Gold brooks drains the area. The lower country to east and southeast of the plateau is underlain by lower Carboniferous sediments. The rocks of the plateau are presumably of Precambrian age but have never been definitely correlated with the Gold-Bearing Series of the mainland. ?There i:s; however, some resemblance, although they have apparently been more intensely mountain-built. They are essentially fine grained, sheared quartzites and slates . The general strike is east and west, with a north dip of 45° to 55°. There are smalllocal drag-folds in the area. The only igneous rock in the immediate vicinity is an intrusive pink porphyry. It has small phenocrysts of quartz and feldspar. It has intruded the sediments generally along the structural planes, but in places crosses the structure . Its intrusive character is further proved by the fact that it contains xenoliths of the quartzite.

Jan 1, 1937

By H. K. Fredrickson

"Midwest Joint Venture (MJV) owns a high-grade uranium deposit in northern Saskatchewan. The deposit is located too deep below surface to be mined economically by open pit methods, and as a consequence, present plans are that it will be mined by underground methods. High-grade uranium ore of the type at MJV, encased in weak, highly altered ground and with radon-rich water inflows, has not before been mined by underground methods.The test mining phase of the project, completed in 1989, had three objectives: 1. to evaluate radiation protection requirements associated with the handling of large quantities of radon-rich water and mining highgrade uranium ore in an underground environment; 2. to investigate the quantity and quality of water inflows into the mine; and 3. to investigate ground conditions in and around the ore zone as an aid in determining the production mining method to be used.With information gained from the test mining project, a mining method for the production mine has been devised. Level plans have been drawn up, ventilation system designed, pumping arrangements made and methods of ore handling considered. All this is to be done in a manner that will be safe for those doing the work underground. Some of the mining methods planned are felt to be unique in that they are designed to cope with mining problems not known to have been encountered before. New problems underground have required new methods to handle them. Remote drilling, blasting, mucking and backfilling form the basis of the planned mining method."

Jan 1, 1992

By W. G. Brown

"Review of prototype testing of two types of three-phase, argon stabilized reactor/furnace indicates specialized advantages for both, as compared with existing metallurgical furnace technology. They are: the direct-arc, plasma-torch furnace (Knipp); and the indirect, plasma extended-arc reactor (PEAR), developed at the University of Toronto.IntroductionA unique type of three-phase AC, plasma extended-arc reactor, (PEAR), shown in Figure la with gravity feed, has been undergoing development at the University of Toronto, during the past fifteen years: argon gas, introduced axially through drilled-holes in ordinary graphite electrodes, increases the length of indirect arcing and improves electrical stability while decreasing electrode consumption as compared with the performance of AC electric arc furnaces (EAF 's). Meanwhile and independently, a three-phase, transferred arc plasma furnace (Fig. 1b) has been developed by the Krupp Research Institute in Germany, using argon-stabilized, water- cooled plasma-torches with thoriated tungsten electrodes.Accordingly, the two types of furnace are similar as to both three phase and stabilized operation, but otherwise they differ in several respects, ranging from indirect versus direct-arcing to principal intended application and current state of practical development. Between them they raise questions: (I) of their present or fore seeable economics in comparison with existing processes they are intended to replace , (see Heinke and Neuschutz, 1986, for a review of the merit s of AC and DC plasma-torch furnaces); and (2) of the state of development and accessibility of their plasma theory-in-common."

Jan 1, 1991

By Tim Robinson, Michael S. Moats, William G. Davenport, Andreas Filzwieser, Andreas Siegmund, Shijie Wang

This survey continues the long tradition of providing a snapshot of operating data from industrial electrorefineries. It is a supplement to previous surveys that were performed in 1987, 1991, 1995, 1999, 2001, 2003, 2007, 2010, 2013 and 2016. Analyses of current data and historical trends are presented. Examples of innovations to reduce costs, improve productivity, and improve quality are provided. In general, refineries continue to increase productivity while treating anodes with more impurities. INTRODUCTION This manuscript analyzes global survey data provided by operating copper electrorefineries. This paper continues a series of surveys of copper refining tankhouses that started in 1987 (Schloen, 1987, 1991; Schloen & Davemport, 1995; Davenport et al., 1999; Robinson et al., 2003; Moats et al., 2007, 2013, 2016). In this installment, data collected from 2015 and 2018 will be presented and analyzed. The 2015 survey data were presented at Copper 2016 in Kobe, Japan. This survey will continue the analysis of previous data to illustrate long term trends in copper electrorefining, which were originally presented at the Davenport Symposium in October, 2014 (Moats, Robinson, & Wang, 2014). Refineries who supplied surveys are listed in Table 1. Cathode production data from 2015 and 2017/18 (from surveys presented in 2016 and 2019) are provided to indicate which plants provided surveys and when. This manuscript presents operating data for ~6.5 million tonnes of copper production, which represents 30–35% of the world’s copper electrorefining production. The detailed survey results are available upon request from the corresponding author.

Jan 1, 2019

By J. H. Reiss, D. F. Bruhn, Idaho National Laboratory, Y. Jiao, D. W. Reed, Y. Fujita, D. L. Daubaras

"Bioleaching offers a potential approach for recovery of rare earth elements (REE) from recyclable materials, such as fluorescent lamp phosphors or degraded industrial catalysts. Microorganisms were enriched from REE-containing ores and recyclable materials with the goal of identifying strains capable of extracting REE from solid materials. Over 100 heterotrophic microorganisms were isolated and screened for their ability to produce organic acids capable of leaching REE. The ten most promising isolates were most closely related to Pseudomonas, Acinetobacter and Talaromyces. Of the acids produced, gluconic acid appeared to be the most effective at leaching REE (yttrium, lanthanum, cerium, europium, and terbium) from retorted phosphor powders (RPP), fluidized cracking catalyst (FCC), and europium-doped yttrium oxide (YOEu). The Acinetobacter isolate, BH1, was the most capable strain and able to leach 33% of the total REE content from the FCC material. These results support the continuing evaluation of gluconic acid-producing microbes for large-scale REE recovery from recyclable materials.INTRODUCTIONAn enhanced recovery, substitute, reuse or recycle paradigm is important for balancing the supply and demand of critical materials (DOE, 2011). The recovery of rare earth elements (REE) from recyclable materials is an important component in this model. REE are used in a variety of modern products. For example, neodymium, europium, terbium, dysprosium, and yttrium are important for applications such as permanent magnets, lamp phosphors, rechargeable batteries, etc. (Binnemans, Jones, Blanpain, Van Gerven, Yang, Walton, & Buchert, 2013; DOE, 2011; Graedel, Harper, Nassar, & Reck, 2013). Cerium and lanthanum are used in glass polishers and additives in fluidized cracking catalysts (FCC)."

Jan 1, 2016

By M. Kaya, A. R. Laplante

"Since the beginning of eighties the use of flotation columns has surged in Canada and abroad; the metallurgical superiority of columns over mechanical cells is in great part due to froth washing, which ensures higher gangue rejection and selectivity. Can wash water, which has proven so beneficial, be used in mechanical cells? Although froth washing technology was widely implemented in Soviet plants for bi tuminuous coal, and alusite, powellite, scheelite, molybdenite, etc. more than 25 years, it has been neglected in the western world. Published data suggest 10 to 15~ increases in grade and/or recovery with wash water in mechanical cells (Klassen and Mokrousov, 1963). There are at least three wash water plant applications in Zaire, Chile, and Canada, but little, if any, published information is available. This research work, which is the first extensive fundamental study related to froth washing in mechanical cells, attempts to answer the questions of how, how much, and where should wash water be added.This project was undertaken in three stages:1. Bench-scale laboratory tests with a 6.5 L Denver cell at McGill using a silica flour and a slime reject from Niobec (St.Honor6).2. Pilot-plant scale tests with a 65 L Denver cell at McGill using the silica flour and a complex Cu-Ni sulphide ore from the Strathcona mill of Falconbridge.3. Plant-scale tests with a bank of 2800 L Denver cells at Falconbridge Ltd. for complex Cu-Ni sulphide ore and Eastmaque Gold Mines Ltd. for Au tailing reclaimation."

Jan 1, 1989

By J. R. del Castillo, J. Ruiz, N. Kuyucak, J. Chavez

Environmental Impact Assessment (EIA) and Feasibility Studies (FS) were carried out to evaluate the potential use of treated acid mine drainage (AMD) occurring at the Kingsmill Tunnel in the Central Andes of Peru. The 11-km long tunnel drains the underground works of the Morococha Mining District and discharges about 1.25 m3/sec of AMD directly into the Yauli River, which is located within the Amazon Basin. The communities living downstream cannot use the Yauli River water due to its low pH and elevated concentrations of metals (e.g., Cu, Zn, Fe, Mn, As, Cd) and sulfate. Studies carried out for this project included technical feasibility, EIA, economic viability and social impact assessment phases. During the "Technical Feasibility" phase, the treated AMD was produced by simulating a high density sludge (HDS) lime neutralization/precipitation process and was evaluated for various potential uses. Mining companies located in Morococha, in particular Centromin Peru S.A., and the Water Works Company of the City of Lima (Sedapal) collaborated with Golder Associates during the studies. The Canadian International Development Agency (CIDA) provided the financial assistance. The results of the physical, chemical, biological and toxicological analyses demonstrated that the treated AMD could be used for supplementing the drinking water supply of Lima and for agricultural (e.g., irrigation and livestock) and recreational purposes. Process design and scale-up parameters were also determined for the implementation of the full-scale treatment facility to the site. The use of the treated AMD as a drinking water supplement would be economically feasible.

Jan 1, 2004

By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004

By A. Sacit Saydam

"Induced polarization/resistivity and magnetometer surveys have been carried out over the Casmo molybdenite deposit in mountainous terrain of northern British Columbia. Molybdenite occurs in quartz-bearing fractures with or without pyrite along a zone of hydrothermal alteration and intense fracturing, believed to be a northerly dipping fault zone, within medium-grained equigranular and porphyritic quartz monzonite.The molybdenite-bearing zone is characterized by a significant resistivity low, a metal factor high and a subtle IP low flanked by highs outside the mineralized area. Magnetic trends, indicated by a magnetometer survey, generally parallel the zone and strike direction of the different intrusive phases, and have been helpful in delineating contacts and faults in the area.IntroductionThe Casmo molybdenite deposit is 6 km southwest of the asbestos mining town of Cassiar in northern British Columbia, at an elevation of 1,550 metres. Molybdenite was first discovered during the early 1950s and the first important exploration work was done in 1964. Between 1964 and 1971, about 25,000 feet of drilling was done by various operators, as a result of which 33.7 million tons of molybdenite ore was drill indicated at a grade of 0.123%. In 1979, Shell Canada Resources entered into an option agreement with the former operator, New Jersey Zinc Corporation. Shell completed 27,000 feet of diamond drilling between 1979 and 1980 and ha s reported 75 million tonnes of drill-indicated ore with an average grade of 0.13% MoS2• This paper is a case history of IP I resistivity and magnetometer surveys done over the Casmo deposit during 1979 and 1980."

Jan 1, 1983

By John Drobe, Robert M. Cann

"Abstract - The Minas de Oro Cu-Au skarn and replacement deposits are located in the highlands of central Honduras, 90 km north-northwest of the capital of Tegucigalpa.The deposits formed in Cretaceous volcano-sedimentary rocks following the emplacement of an early Paleocene granodiorite to dacite intrusive complex. Three types of skarn (Type IA, IB, and IC) and a low-temperature replacement mineralization (Type II) are recognized. Type IA skarn consists of massive brown-green andradite and lesser magnetite and pyroxene. Type IB skarn has magnetite + hematite as the main constituent and garnet <50%. Type IC skarn comprises >50% pyrrhotite + chalcopyrite with interstitial garnet or pyroxene. Au and Cu occur in potentially economic concentrations in all skarn types while other metals such as Ag, Pb, Zn, and Mo are locally present in significant quantities. The highly variable distribution and nature of the skarn deposits is controlled by: (1) intrusive activity, (2) composition of host rocks, (3) faulting and fracturing, and (4) attitude of host carbonates.Type II Au-Cu-As mineralization occurs in calcareous sandstone and conglomerate 2 km distal from skarns and comprises clots of Cu sulfides hosted within a zone of brecciation and quartz flooding. Garnet and/or magnetite skarn is not present and the mineralizing event appears to have been a low-temperature replacement type.The similarity of coeval Au-Cu-Fe skarns in central Guerrero, southern Mexico to Minas de Oro skarns, and the similar local stratigraphy is consistent with the generally accepted theory that the Chortis block originated from southern Mexico and during the Tertiary moved southeast to its present position."

Jan 1, 2000

By John Eggert, Paul Benford

"Since 1982, Placer Dome Inc. -Dome Mine has steadily increased mill throughput. Tonnage has increased from a nominal design capacity of 3000 short tons per day, attained in 1985, to 4130 stpd by the end of 1992. Many minor and major circuit adjustments were tried to maximize tonnage.Having utilized most conventional means of increasing tonnage, further increases required a newer approach. This paper discusses the Dome experience in the development and implementation of an expert system.The Comdale/C system was chosen for a controlled trial. The criteria for acceptance were: increased tonnage had to be sufficient to pay for the system; the increase had to be visibly sustainable and the mill operators had to be willing to accept the system.The criteria for purchase were met during the trial and the system was purchased. The system continues to perform well. The tonnage throughput increase has been sustained while operator acceptance remains high.IntroductionPlacer Dome Inc. -Dome Mine is Canada's oldest operating gold mine. The mine was among the first established in the Porcupine camp in what is now Timmins, Ontario. The City of Timmins is located approximately 500 miles or 800 kilometres north of Toronto. Figure 1 shows a map of the province of Ontario and the mine location.In 1912, milling began at a rate of 350 short tons per day. With two minor exceptions, milling has been continuous since this time. The first of these shut downs was in 1918 during the first world war. The war created labour shortages which forced the mine to stop production for more than a year. The second was in 1930 when fire destroyed the mill."

Jan 1, 1994

By N. M. Steven, J. M. Moore, J. L. Kuyper

Mineral exploration and research has led to the identification of four types of tungsten mineralization in the NE-trending, Iargelyensialic, inland branch of the late Proterozoic/early Paleozoic Pan-African Damara Orogen. The mineralization (mainly scheelite) occurs in a terrane (the Central Zone) that is characterized by multiple deformation, greenschist/amphibolite-facies metamorphism and numerous peraluminous S-type granitic and pegrnatitic intrusions. The four major types of scheelite mineralization are (in ascending stratigraphic order of host rock): (1) thin (5 cm to 2 meter) quartz+plagioclase+diopside ± scapolite calc-silicate granofels with fmely disseminated scheelite (scheelite-bearing granofels; SBG) developed as discontinuous intercalations within the calc-silicate rocks of the Khan, Spes Bona, Oberwasser and Kuiseb Formations (Nosib and Swakop Groups); (2) gamet+pyroxene± vesuvianite+scheelite ± fluorite replacement skarns hosted by Okawayo, Karibib and lower Kuiseb Formation marbles in the aureoles of late tectonic, unrnineralized leucogranites; (3) metaturbidite-hosted scheelite- (and possibly wolframite-) bearing tourmalinites, both stratiform and crosscutting, in the Kuiseb Formation located in the &apos;cleavage fronts&apos; of late tectonic granitoids; (4) scheelite-bearing vesuvianite+quartz+garnet skarnoid rocks (several hundred meters in length) in the calcareous metaturbidites of the upper Kuiseb Formation. These scheelite occurrences were discovered by the follow-up of a large number of tungsten anomalies located during a regional stream sediment sampling program. Detailed mapping, ultra-violet surveys and rock sampling proved to be the most effective surface exploration techniques for locating mineralization; soil sampling and geophysics were of almost no use. The largest, continuous scheelite-bearing skarn of economic interest, Otjua, has a drill-indicated reserve of 250 000 tonnes at 0.53 wt5 WO3 and 8 wt% CaF2•

Jan 1, 1994

By S. Komar Kawatra, Youlian Zhou, Joseph A. Halt

"Bentonite clay has been the most common binder for iron ore pellets. Although bentonite increases pellet strength and durability, it has several disadvantages. For example, its use increases the cost of pellets and decreases pellet purity due to its composition and the higher levels of flux required to meet basicity limits. Several new types of binders have been proposed to replace clay. The binders include starch, modified humic acid (MHA), and dispersants. These binders were used to pelletize a magnetite concentrate from the United States. Typical doses of each binder type were 0.05-0.1 % starch, 0.5-0.75 % MHA, and 0.05 % dispersant. At these doses, the pellets exceeded the minimum recommended values for wet drop, dry compression strength, and fired compression strength. Pellets made with the MHA and dispersants had the lowest abrasion rates of the new binders, and were comparable to pellets made with bentonite clay. In this paper, we compare the new binders, considering pellet quality and the advantages and disadvantages of each binder type.INTRODUCTIONIron ore pelletizers need binders in order to make good quality iron ore pellets. The typical binder is bentonite clay, an alumino-silicate material. Bentonite increases the ballability and strength of iron ore concentrates, but reduces pellet iron grade and reducibility. As high quality bentonites can be expensive to ship, low quality bentonites are often used at significantly higher doses – this reduces iron grade and reducibility even further. Thus, several new types of binders have been proposed to replace bentonite clay.In this paper, we present several new binders for iron ore pellets: starch and modified humic acid (MHA). These have been tested alone and in mixtures with dispersants, or else with bentonite clay. Starch, MHA and their mixtures are briefly described below."

Jan 1, 2016

By Howard Keele

"The Whitewood Mine near Edmonton, Alberta, is owned by TransAlta Utilities Corporation and operated by Manalta Coal Ltd. Approximately 2 million tonnes of sub-bituminous coal is supplied annually to the Wabamun Generating Plant. A high water table, high groundwater pressure, and structural folds contribute to stability problems in the fine-grained overburden. Significant increases in coal recovery have been achieved in recent years through improvements in water management and mining methods. Agricultural capability of the post-mining landscape has also been improved following the completion of mining/ reclamation activities. Introduction The Whitewood Mine, located to the north of Lake Wabamun and seventy kilometres west of Edmonton, Alberta, is owned by TransAlta Utilities Corporation and operated by Manalta Coal Ltd. Figure 1 shows the location of the Whitewood Mine with respect to the city of Edmonton. The mine presently supplies two million tonnes annually of sub-bituminous ""C"" coal to the 582-megawatt Wabamun Generating Plant located adjacent to the mine. The area is characterized by a high water table-, rolling coal seams and an overburden that consists of muskeg, clay and various sedimentary layers of sand, gravel and fine-grained sandstone. These distinctive characteristics require careful attention in order to not only meet the coal delivery requirements of the Wabamun Generating Plant but also to do so economically. Historical Background A small-scale underground coal mine was opened in the Wabamun area in 1910 by the Conner Coal Mining Co. Ltd. Underground operations were continued by several operators until 1948 when the Alberta Coal Co. Ltd. opened a strip mine which was subsequently taken over by the Alberta Southern Coal Co. Ltd. in 1951. The small-scale strip opera"

Jan 1, 1985