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By P. A. Riveros

Antimony is commonly found in copper electrolytes and can contaminate the cathode deposit. Several methods, such as ion exchange, solvent extraction and precipitation, have been developed to remove antimony from copper electrolytes. However, past research has been carried out almost exclusively with Sb(III), whereas the presence and behavior of Sb(V) in the electrorefining circuit have been largely ignored. In this study, the behavior of Sb(V) species was monitored and compared to that of Sb(III) species, using specially developed analytical and SEM-EDS techniques. Significant differences in the behavior of the two species were noted. Although the solubility of Sb(III) increases with temperature in synthetic copper electrolytes, the solubility of Sb(V) appears to be constant over the range from 30 to 80°C. Whereas Sb(III) forms several crystalline oxy-sulphate compounds, Sb(V) appears to remain as an amorphous oxide. Both Sb(III) and Sb(V) are extracted by aminophosphonic resins, and Sb(III) is readily eluted by HC1 or complexing agents. By contrast, concentrated HC1 elutes Sb(V) inefficiently and complexing agents, such as EDTA and tartaric acid, do not elute Sb(V) to any significant extent. This observation implies that in industrial practice, unless special measures are taken, Sb(V) will accumulate on the resin, eventually impeding the ion exchange process.

Jan 1, 2007

By Barry W. Schmitke, J. M. Marino

"Cigar Lake Mining Corporation is presently operating an underground test mine in northern Saskatchewan, with a view to developing a high grade uranium deposit. The mining test is intended to demonstrate that the innovative mining methods designed are safe and economical. Two vertical mining methods are considered for the test:• box hole boring from the lower level;• blind boring from the upper level.In both cases, it is anticipated to freeze the ground before excavation to ensure hole stability and limit the inflow of water. Special care will be taken to minimize radiation exposure of personnel.Remote controlled equipment will be used where applicable.The access to the orebody was an important component of the test. After shaft sinking to a depth of 500 m, development work commenced at the 420 level in fractured sandstone which was grouted to restrict the inflow of formation water. The drifting continued in a section of poorly consolidated sand, clay and sandstone; this area was frozen to allow stabilization prior to excavation. At the 480 level relatively little water was encountered in the altered basement gneiss and grouting was not necessary; however, extensive ground support was required in the soft ground areas."

Jan 1, 1992

By Richard W. Lawrence, Richard Poulin

"Numerous processes co-exist for metal extraction and for metal removal from effluents of mining operations. Each process enjoys an economic advantage, including environmental cost and benefit, if utilized in a specific situation. This applies equally to biohydrometallurgical processes. This paper will analyze four types of biohydrometallurgical processes for their economic and environmental attributes: biooxidation of refractory gold, extraction of copper from sulfide, metal removal from effluents by active sulfate reduction, and metal removal by the use of wetlands. By examining the economic and environmental advantages of these processes, generalizations can formalized and it becomes possible to define niches of application where biohydrometallurgy can be considered. Our analysis shows that biohydrometallurgy can be efficient at small scale, be more environmentally friendly than conventional technologies and is relatively easier to operate. The higher financial risk associated with unproven technologies at the commercial scale is being eliminated as biotechnology-based plants are put into production.IntroductionBiotechnology can be described as the rational exploitation of the activities of living cells or parts thereof, requiring an integrated multidisciplinary approach between biological and technical disciplines. Microbiology, biochemistry, botany, molecular biology, chemistry and engineering all contribute to practical applications in the extraction, manufacturing and service industries, and in environmental management. Considerable commercial success of biotechnology has been achieved in several sectors, including health care, agriculture, forestry and aquaculture.Over the past 40 years, industry, research organizations, government laboratories, and universities in a large number of countries have participated in investigating the utilization of biotechnology applications in mining. Today, several technologies are used commercially in well understood and engineered systems which can be grouped under the term biohydrometallurgy. Many more technologies have been demonstrated at laboratory or pilot plant scale. Although initial developments and commercial applications were aimed at metal extraction, the dramatic increase in environmental awareness, the practice of sound environmental management demanded by more stringent regulations over the past decade, and the need for low cost treatment in perpetuity, has led to serious investigation of biotechnology for environmental control. In addition, increasing power costs, lowering of ore grades, and decreasing commodity price in real dollar terms require the use of highly efficient and competitive extractive technologies."

Jan 1, 1998

By N. E. Chaouai, M. Lavigne

"Indicator kriging is one of the non-parametric geostatistical techniques, ideal for estimating the reserves of irregular mineralizations (e.g. gold, uranium, platinum, diamonds, etc.). Such mineralizations are characterized by variograms which are very sensitive to extreme values (outliers) and very difficult to model.The classical approach to this problem in the industry is to trim off these high grades using arbitrary empirical upper limits established either from practice or subjectively. Contrary to this simplistic approach, indicator kriging discretizes the histogram of the grades (usually log normal) in several classes and carries out interpolation separately for each class. This paper gives an overview of the differences between ordinary and indicator kriging along with the steps required to carry out indicator kriging. The paper concludes with a case study involving a gold deposit estimation.IntroductionParametric geostatistics (ordinary kriging) has given us satisfactory results over the years in estimating the reserves of well behaved deposits with coefficients of variation close to 1 (e.g. sedimentary and porphyry type deposits). However, numerous problems have been encountered in estimating irregular mineralizations (e.g. small vein deposits of precious metals) with high coefficients of variation in the range of 2 to 5. Such deposits are characterized by a very small proportion of extreme values (outliers) which create distortions on the variograms (pure nugget effect) and render them useless(1,2).The solution often followed by the mining industry today is to trim off these values based on empirical limits. These limits are derived either by comparison with production results (or bulk samples) or by geological interpretations. Needless to say that such manipulations can lead to serious errors in estimating ore reserves (usually underestimation of total metal quantity), especially when production results or bulk samples are absent.On the other hand, the solution followed by the geostatisticians in the past was to smooth out the data using transforms (e.g. normal-score or natural logarithms). Such transforms are nonlinear and they required non-linear estimation techniques such as disjunctive kriging (DK) or multivariate gaussian kriging (MG) which require normal related hypotheses, not necessarily true in geology.Nonparametric geostatistics (indicator and probability kriging) have been -developed in order to handle these problems related to highly skewed distributions."

Jan 1, 1990

By A. Galip Ulsoy, K. V. S. Sastry

"This review paper is intended to provide, the mineral process engineer with an introduction to the concepts, terminology. and practice of mineral process control. It also provides an extensive sampling of the vast body of literature relevant to this topic. The topics discussed include the principles of automatic control, instrumentation, mineral processing unit operations, process modeling and simulation, and process and plant control. IntroductionEconomically accessible higher-grade ores are being rapidly depleted, and at the same time the demand for mineral raw materials continues to increase. Mineral recovery from the remaining low-grade or finely dispersed ores requires grinding for liberation. High energy consumption during grinding and poor efficiency associated with the beneficiation of fine minerals are two important problems facing the mineral industry . These problems, coupled with advances over the last 10 to 15 years in the areas of process modeling, instrumentation, computer technology and control theory, have made automatic control of mineral processing systems an important research area(23,52,66,67,120,129,152)."

Jan 1, 1981

By A. Galip Ulsoy

This review paper is intended to provide, the mineral process engineer with an introduction to the concepts, terminology and practice of mineral process control. It also provides an extensive sampling of the vast body of literature relevant to this topic. The topics discussed include the principles of automatic control, instrumentation, mineral processing unit operations, process modeling and simulation, and process and plant control.

Dec 1, 1981

By Robert B. Parsons

"First down and four to go. In the game Of football, this is not a bad position to be in. However, in this game of political football, it means that there is still a long way to go. The government in Ottawa has concluded an important agreement with one producing province, and now has at least four more provinces to deal with-B. c., Saskatchewan, Nova Scotia and Newfoundland.On September 1, 1981, the federal and Alberta governments took a significant step forward in formulating an oil and gas policy for Alberta and the rest of Canada on signing a comprehensive five-year agreement that covers taxes, prices, incentives and other fiscal matters related to the production and marketing of oil and gas.This month, Tax Notes examines the main features of the agreement, and offers some eye-opening observations of what the new accord could mean for the future of the Canadian petroleum sector in particular and Canadian business in general."

Jan 1, 1981

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By G. E. Agar, W. B. Kipkie

"This paper deals with the prediction of locked cycle flotation results from data developed from individual batch tests. A postulate is made that the distribution of material in a separation stage is determined by the chemical conditions and the flotation time and that this distribution can be characterized by split factors which are constants for a fixed set of conditions. With this premise, it is demonstrated that a steady state balance can be calculated for a circuit.Although the necessary equations can be solved algebraically, a computer program was written that uses an iterative tec1nique to arrive at the steady state balance. The program is written so that a variety of circuits can readily be simulated.A number of examples are examined to demonstrate the validity of this simulation procedure. The sensitivity of the material balance to changes in the split factors was examined. Data developed from different flowsheets is presented on sulfide ores, on copper-nickel separation and on silver flotation,"

Jan 1, 1978

By Ernest Becker

Golder Associates provided overall radiological direction and assistance to the client in their interactions with the Canadian Nuclear Safety Commission and operational radiation protection services for the remediation of a calciner that had been used to process uranium. The project was somewhat unusual in that the radioactivity from within the calciner room was removed from the site and the cleaned steel recycled. The presence of yellowcake within the process equipment required stringent radiation protection measures. This project was completed successfully with minimal radiation exposures to the workers and the effective protection of the environment.

Aug 1, 2010

By Chester J. Kuryliw

"The Geology of the Cochenour Willans mine, Red Lake district, was described by J. P. Nowlan in the Jubilee Volume. The complexity and intense alteration of the rocks obscured any clear relationship between ore and structure, and Nowlan recognized that future work might greatly modify the ideas then existing. This has proved to be the case. Subsequent detailed work has established the stratigraphic sequence in the Keewatin formations which are the host rocks of the orebodies, and has shown that the principal orebodies are confined to two adjoining bands of tuff.On this basis, it is now possible to map the complex structures with greatly increased accuracy. The amount of drilling and underground exploration required to find new ore has been much reduced, and indicated ore reserves are now substantially greater than at any time in the past. Daily production in 1955 averaged 187 tons per day at 0.578 ounces of gold per ton.The sequence of Precambrian events in the mine area is summarized in the following table:Intrusion of post-ore dykes.Ore formation.Intrusion of post-faulting, pre-ore dykes.Deformation: folding and shearing; alteration; faulting.Timiskaming sedimentation.Unconformity.Keewatin: volcanics and sediments, host rocks of the orebodies, described in detail in the next section.KeewatinFrom oldest to youngest, the Keewatin rocks in the mine area can be divided into six formations, which have been given local names:“Grey"" LavaA fine-grained dacitic to andesitic lava, amygdaloidal and locally containing well formed pillows. Certain areas are sheared and chloritized to a degree that makes identification difficult. The rocks are carbonatized throughout; the most persistent carbonate veins parallel the upper contact. Thickness more than 1,000 feet. (Minor mineralization, type 1 I -See section on Ore Formation)."

Jan 1, 1949

By Wengui Su, Qi Zhang, Junce Wang, Zhijun Ma, Xingyuan Weng

"Mesoporous materials with large specific surface area, pore size, and pore volume have been widely used in many fields such as ion exchange, gas separation, adsorption, and catalysis. Mesoporous materials prepared using natural zeolite have the advantages of both acid and alkali resistance. In this work, mesoporous materials were prepared using natural zeolite as the starting material and diethylenetriamine (DETA) as a template. The resulting samples were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption experiments. The influence of the crystallization temperature and crystallization time on the specific surface area, pore volume, pore size, and morphology of the resulting mesoporous materials are also discussed. Our results show that for an increase in both the crystallization temperature and time, the average pore size first increases then decreases, while the specific surface area first decreases then increases. Based on this work, we concluded that the optimal crystallization temperature was 2003 and the optimal crystallization time was 60 h. These conditions gave an average pore size of 17.93 nm, a pore volume of 0.048 cm3g-1, and a specific surface area of 16.48 m2g-1.INTRODUCTIONMesoporous zeolite, as the name implies, is a highly porous crystalline zeolite. This material is of interest due to its high hydrothermal stability, its adsorption and diffusion properties for macromolecules, and its excellent selectivity and activity as a catalyst. In recent years, it has become a hot spot among research of porous catalytic materials and has been widely used in petroleum and natural gas processing, fine chemical processing, various adsorption and separation tasks, and other uses (Carvalho & Urquieta- Gonzalez, 2015; Teh, Triwahyono, Jalil, Mukti, Aziz, & Shishido, 2015)."

Jan 1, 2016

By D. R. Spink, G. L. Rempel, C. O. Gomez Bueno

"A morphological and chemical study of the Great Canadian Oil Sands Ltd. (GCOS) fly ash has been carried out. Extensive scanning electron microscopy, as well as light microscopy, showed that the GCOS fly ash consists of two fractions, one composed of unburnt or partially burnt irregular-shaped carbon particles and an ash fraction composed of transparent and opaque, often coloured, glassy spherical particles-some of them cenospheres (hollow spheres) and the others plerospheres (hollow spheres packed with smaller spheres). Microcrystals (0.1 to 0.3 um long) growing on the inner and outer surfaces of some of the spheres were also noted and found to contain more Fe, Ti, Ni and V than the spheres.The carbon-free GCOS fly ash particle size follows a lognormal distribution, with a geometric median particle size (by count) of3.8um and a geometric standard deviation of 1.84. IntroductionCanada's current energy situation strongly suggests that oil from the Alberta tar sands deposits will probably be recovered more extensively in the future. Today's commercially proven technology to recover oil from the Athabasca tar sands, as practised by Great Canadian Oil Sands Ltd. (GCOS), involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil; the production of significant amounts of petroleum coke and sulphur during the bitumen upgrading process. The bulk of the petroleum coke is burnt in boilers to fulfill the energy requirements of the entire operation. The boiler ash, which contains appreciable amounts of metals, such as vanadium, nickel, titanium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke-fired steam generation plants. Thus, as well as representing a petroleum resource, the tar sands represent a resource for vanadium and possibly other metals providing that metal recovery processes can be developed."

Jan 1, 1980

By Hammenm R., J. Hammen, C. Hammen

"The production of salable Rare Earth Element (REE) products necessitates a sequence of chemical separation steps between the mine and market commodities. The effectiveness of the chemical separations that purify REE salts is critical to the success of the producer, as the purity of REE salt products affects their market price. This is due to the fact that impurities in REE salts, even at low levels, can be deleterious to the function and usability of the end product. The purification of REE by removal of low levels of contaminant has been referred to as "product polishing". The technologies commonly in use for product polishing, solvent extraction (SX) and ion exchange (IEX) are challenged by the availability of separation chemistries to separate the contaminant from the desired REE salt. In simple terms, if a product specification is 99.9% purity, the SX or IEX separation reagents need to have at least a 999:1 selectivity ratio. Significant testing has been carried out on the use of solid phase extraction (SPE) columns to extract low-level impurities such as aluminum or zinc from REE product streams. The SPE columns are nano-composite materials that have rapid equilibration kinetics with the solutes being processed by the columns. The SPE matrices have been modified with chelating ion exchange ligands that bind the contaminating ion with great selectivity in residence times of a few seconds. Thus, REE streams with 1 to 2% of contaminating aluminum ions, have been polished to >99.99% purity. In this paper, results are presented on the removal of aluminum impurity from a didymium (neodymium+praseodymium) product stream using SPE technology. The selection of the SPE medium and the process steps to treat the feed solution for aluminum removal and ultimate stripping and recycle of the solid phase extractant are discussed."

Jan 1, 2014

By Ayako Iwakoshi

Highly concentrated pastes of gold nanoparticles were successfully produced by use of a special kind of protective polymer and a mild reductant. Solid part of the pastes consists of up to 85wt% of gold nanoparticles, 10~30 nm in diameter, and residual protective polymer. This component can be diluted by any kinds of solvent at arbitrary rates. Electronics, optics, catalysts, colorants and surface metal coatings are possible application fields. 1. Introduction Noble metal nanoparticles are of interest in a variety of fields ? such as colorants, metal coatings, electronics(1), optics(2), and chemical catalysis(3). Especially, in the color field, the gold nanoparticle has been known as an aesthetic red colorant for stained glass and fine glassware, such as Venetian glass. The mechanism of coloring is attributed to surface plasmon absorption of gold nanoparticles(4,5). The gold nanoparticle in stained glass shows very clear red color, which is very durable for hundreds years. On the other hand, the red color of organic pigment in paint films often fades away within several years. We intended to reproduce the elegant and stable coloring of stained glass in paint films. In order to color a very thin, 20~50?m, paint film like stained glass, production of highly concentrated dispersion of gold nanoparticle is necessary. To achieve this, there were two issues to be overcome. One is how to prevent the coagulation of gold nanoparticles in highly concentrated solution. So far, several methods to prepare gold nanoparticles(6,7) were reported. But only a few methods succeeded to stabilize the gold nanoparticle dispersion at higher concentration than ppm order. The other is controlling of the particle size, this is because the color of gold nanoparticles is very sensitive to the particle size. Only when the particle size lies around 10 nm, the suspension exhibits red color like stained glass.

Oct 1, 2003

By A. Bhowmik

Uranium Refining is the process in which undesirable neutron absorbing elements such as Boron (B), Gadolinium (Gd), Cadmium (Cd), Europium (Eu), Samarium (Sm) and other heavy metals (Fe, Ni, Co, Ca, Mg etc.) are removed to make it nuclear pure. At present, Uranium refining is carried out by solvent extraction process by using organic based solvent e, g. TBP diluted with Kerosene. The above process generates lot of nitrate bearing liquid waste and degraded organic. In order to eliminate use of hazardous organic and ammonia for Uranium refining altogether, a new process has been developed. In the new process, Yellow Cake is dissolved in nitric acid and uranium peroxide hydrate is precipitated selectively from the solution leaving all the impurities in the solution by using commercial grade hydrogen peroxide at a pre-defined pH, U conc., temperature and stoichiometric quantity of hydrogen peroxide under mild agitation. The precipitate is filtered and washed with DM water to obtain nuclear pure product meeting purity standard as per ASTM C ? 753-99.The product is spray dried and calcined to obtain uranium oxide. The process eliminates use of organic, flammable, toxic chemicals, consumes less quantity of nitric acid and uses environfriendly chemical hydrogen peroxide. The process is simple and can be integrated in the mill. A patent application is entering national phase in several countries including CANADA and abstract/full paper is available in WIPO publication no: WO/2009/013759.

Aug 1, 2010

By C. M. Trigg

"PEC uranium deposit, 100 km southwest of Coppermine, was discovered by diamond drilling in 1976 following ground and airborne geophysical surveys, geological mapping, geochemical surveys and boulder prospecting that were initiated as the result of the discovery of uraniferous sandstone outcrops in 1969 by geologists of Aquitaine Company of Canada Ltd.The deposit is within gently northeasterly dipping medium to coarse-grained Unit 11 quartzitic sandstone of Neohelikian Dismal Lakes Group. The deposit is from 10 m to 70 m above the base of the sandstone which, beneath the deposit, non-conformably overlies weathered and altered Aphebian granite of Great Bear Batholith or unconformably overlies rubble breccia, conglomerate and medium-grained Unit 8 sandstone of Paleohelikian Hornby Bay Group.A northeasterly trending, 500 m wide graben, bounded by the steeply dipping northeasterly striking Imperial and Aquitaine faults, contains the deposit which is 1.1 km long by up to 340 m wide. The deposit overlies a post-Hornby Bay Group, pre-Dismal Lakes Group topographic high. Uranium principally occurs as stratabound, often peneconcordant bands; a lesser amount of uranium is fracture controlled.Stratabound uranium exists in gently easterly dipping, subparallel bands ranging in thickness from 1.5 m to 6.0 m. Pitchblende, coffinite and sooty black uranium oxides occur as interstitial disseminations and grain coatings subparallel to bedding; they also replace pyrite and form narrow veinlets.Small amounts of torbernite, carnotite and cuprosklodowskite coat pitchblende and are disseminated within mineralized bands. Pyrite, marcasite, chalcopyrite, chalcocite, cove/lite, digenite, azurite, malachite, arsenopyrite, glaucodot, niccolite, bravoite (? ), goethite, hematite and magnetite as well as quartz, barite, calcite, biotite, chlorite and clay minerals exist within the mineralized bands. Uranium grades of 0.1 % to 0.3 % U3O8 over thicknesses of 1 m to 2 m are typical.A steeply dipping fracture zone near the Imperial fault contains sooty black uranium oxides, torbernite, carnotite and cuprosklowdowskite as well as sulphides, cobalt arsenides, quartz and carbonate. The zone may reach 70 m long; its true width is about 1.9 m. Uranium grades range up to 5.18% up, over0.9m.Pitchblende and coffinite from PEC deposit have been dated at 1.08 ± .10 Ga with possible remobilization at .45 Ga. The deposit contains an inferred 3,150 tonnes of U3O8."

Jan 1, 1986

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By Alfredo Bambaren

First Encounters between Communities and Mining 1. Importance, meaning and process 2. Antamina?s study case 3. ?Self-organization? theory (NLP) 4. The story we tell, the values we live 1. Importance, Meaning and Process ? First encounter stays in mind as a model. ? First encounter means foundation. ? First encounter builds the story.

May 1, 2010

By S. Kawai

Natural convective flow of the electrolyte solution plays an important role in several electrochemical systems. Copper refining electrolysis is the most important industrial process to produce high purity copper on large scale. Turbulent natural convection develops along vertical plane copper electrodes installed in an unstirred electrolyte accompanying with the electrochemical deposition and dissolution of copper during the electrolysis. It introduces the electrolyte stratification phenomenon. Thus, the electrolyte is circulated in a special way depending on each electrorefining tankhouse. The theoretical discussion is indispensable to understand the coupling phenomenon between the ionic mass transfer rate and the morphological variations of electrodeposited copper. In present study, the mass transfer rate of both Cu2+ and H+ ions as well as the momentum transfer rate is numerically analyzed accompanying with the turbulent natural convection along 1 m high Cu metal electrode surface.

Jan 1, 2007