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By T. Patching

"A GLANCE BACK AT what has happened in the past is often a useful guide to the future, although it should be used mainly to provide a sense of direction rather than a map that must be followed. As a preamble to discussing some of the questions posed by the organizing committee it may be appropriate to briefly review the distribution and careers of the graduates of our Department since the first degree in mining engineering was awarded in 1916. An attempt has been made to keep a record of the locations and careers of the Department's 540 graduates in mining and metallurgical engineering. Almost all of those who graduated before 1930 have now retired, but a very large proportion held positions as senior executives prior to retirement. A major proportion of those who graduated before 1950 are now in what might be considered senior management positions. Those who have 10 to 20 years of experience are generally in work of senior engineering responsibility or in supervisory or junior management ranks, while those who graduated in the last ten years appear to be generally in staff engineering or junior supervisory positions. This classification is admittedly imprecise because it is difficult to determine from a job description whether duties should be considered of an engineering or management nature - a distinction between the two terms is often over-emphasized. Nevertheless, the trend from technical engineering to management responsibilities with seniority and years of experience is clear in the careers that we have been able to follow."

Jan 1, 1972

Orebodies of the Renison Bell - Mt. Bischoff tinfield in Tasmania are stratabound, conformable lenses of massive cassiterite-bearing pyrrhotite, with underlying discordant, fault-fracture-controlled and more siliceous ore. The deposits occur in eugeosynclinal, trough-deposited sedimentary and mafic volcanic rocks which are stratigraphically equivalent to diff erentiated volcanic rocks that contain volcanogenic massive base metal sulphide deposits in a parallel arc to the east. Textures of the massive pyrrhotite ore suggest that it has undergone metamorphic recrystallization. Although the massive ore contains both monoclinic and hexagonal pyrrhotite, a study of a few samples from one orebody suggests that their distribution is stratigraphically controlled, with the monoclinic variety abundant only at the base. The distribution pattern of rare-earth elements in massive ore is similar to that of volcanogenic massive base metal sulphides in New Brunswick, and suggests that mixing of sea water with exhalative hydrothermal brines occurred during ore deposition. Tin is a common accessory element in many volcanogenic massive base metal sulphide deposits providing strong evidence that it, too, is transported and deposited by volcanic affiliated hydrothermal brines. Sedimentary rocks containing the massive orebodies are fine grained, thinly laminated, compositionally banded and of mixed chemical sedimentary-tuffaceous origin. They include finely recrystallized chert, carbonate-rich and pyritic varieties; and soft sediment deformation structures in these rocks suggest that dense sulphides deformed underlying, less dense chert prior to lithification. Close to ore the chert becomes massive and coarsely recrystallized, as does the carbonate, which is here strongly enriched in Fe and Mn. Apatite is present in pyritic, cherty and carbonate-rich beds and in the ore itself, in all of which it shows a similar pattern of rare-earth element distribution, suggesting that it is of marine sedimentary origin. These deposits have traditionally been considered as epigenetic replacements of favourable carbonate horizons by hydro thermal flu ids derived from later Devonian porphyritic intrusions. Some of these intrusions have associated tinbearing greisens. The above relationships suggest, alternatively, that, like massive base metal sulphides, the tin deposits were of original syn-sedimentary origin. Circulating hydrothermal brines generated during early Cambrian eugeosynclinal subsidence and tectonism rose through steep fault-fractures, there giving rise to the discordant orebodies, and were discharged on the sea floor, where the massive pyrrhotite lenses were precipitated with the associated cherts and carbonates. In some places, Devonian intrusions remobilized the earlier deposits, forming greisens and newepigenetic veins. Finally , the geologic selling of these deposits, in trough deposited sedimentary and mafic volcanic rocks, suggests another favourable environment for massive sulphide exploration which is quite different from the domal felsic volcanic environment so heavily favoured currently in North America

Jan 1, 1979

By K. Hambrice, E. Fauveau

"When it comes to measuring the level of bulk solids, liquids, and everything in between, guided-wave radar technology now offers more level-detection capabilities than ever before. For an ever-widening range of previously hard-tomeasure products such as molten sulphur, liquid ammonia and petrochemicals, guided-wave radar transmitters provide accurate level measurements even under harsh chemical environments, wide variations in operating temperatures and pressures, and low dielectric constants.Great strides have been achieved in making these units easier to configure to a variety of process applications coupled with the simplicity of integrating these devices with most digital communication protocols. These improvements come as welcome relief to process engineers within an expanded range of level applications across several different industries that seek solutions to measuring the contents of tanks, silos, hoppers, bins, mixing basins, and vessels.Because radar transmitters have no moving parts, radar has already established a dominant niche in level measuring that quickly distances itself from mechanical means, which do not hold up as well in dirty service. Radar achieves its nonmechanical level detection capability by measuring the time of flight of the transmitted signal.Known more accurately as time domain reflectometry (TDR), the process involves sending microwave energy down into a vessel. When the pulse of radar energy reaches the product (indicated by a change in impedance), part of the pulse is reflected back toward the transmitter.A receiver measures the exact duration of time between the transmitted and reflected signal — the “time of flight.” The device analyzes this time and ultimately displays the level of the product as a distance in feet, metres, or other engineering units."

Jan 1, 2003

By L. Shang

In conventional continuous hot rolling processes, metals are usually reheated to a temperature such that the workpiece will maintain appropriate hot working characteristics as it proceeds through the rolling mill, assuming that the temperature is continually decreasing. Metallurgically, reheating will reduce micro-segregation in the as-cast material, may increase the as-cast grain size and will affect any second phase particles present in the as-cast structure. All these changes can affect the hot working characteristics, and the final as-hot rolled microstructure. In order to study the effect of reheating on AZ31 magnesium alloy, a plate sample was cast in a water cooled copper mould and a series of compression tests was performed at a temperature of 350 °C, strain rate 0.01 5-1, and strains from 0.2 to 1.0, after different reheating schedules. It was found that there is no significant difference in flow behavior between the as-cast sample and all but one of the reheated ones. The reheat treatment of the 'anomalous' sample was a two stage heat treatment; it was first reheated to 450 °C, cooled to room temperature, then reheated to 350 °C. The effect on the flow curve was to increase the flow stress. This result may be related to changes in second phase particle characteristics.

Jan 1, 2006

By S. Mohammadnejad, M. Olizadeh, B. Mehrabi

A new method using a combination of comprehensive mineralogical and analytical approach which includes optical and electrical microscopy and several analytical techniques with diagnostic leaching has been used to characterize the associations and distribution of gold in a variety of minerals from the Zarshuran refractory gold ore, NW Iran. Zarshuran ore with an average of 7.9 g/t Au-grade and about 8% arsenic with gold recovery less than 20% in direct cyanidation is considered as high arsenic, high au-grade refractory gold ore. In most of the refractory ores, gold is associated with arsenopyrite and co-para genetic ore minerals, while in Zarshuran ore; gold is associated with orpiment, realgar and arsenian-pyrite. Considering its mineralogy and As content, it can be considered as the most difficult refractory ore for characterization and processing. Results from the mineralogical examination and diagnostic leaches indicate that there is only a small amount of free gold (17-19%) that is present in cyanide-soluble sulfo-arsenides compounds, predominantly orpiment and realgar. Diagnostic leaches also indicate that little gold is occluded within the silicate structure (14%). Overall, the gold is mostly included in sulfides, arsenic sulfides and sulfo-arsenides (50%). The results also have shown how the technique can be used to gain a good initial understanding of potential metallurgical problems for a refractory gold ore.

Jan 1, 2005

By Larry A. Morris

The environmental impacts of industrial activities have become very serious concerns of the public over the past few decades. Not surprisingly, governments have responded with legislation and regulations to force industry to operate in a more environmentally responsible manner and, more recently, have prompted industry to initiate voluntary measures in response to specific environmental issues. The concept of Product Stewardship has evolved as a system or vehicle for the industrial sector to demonstrate an active concern about the environmental impact of their products, services and processes.

Jan 1, 1996

By B. R. McEwen, A. N. Samis, J. H. Gray

"The Quebrada Blanca Copper Mine is an open pit copper project located at 4200 m elevation in the Chilean Andes. The deposit is a world-class supergene enriched porphyry with a mining reserve of 89 Mt of 1.3% copper. The supergene zone will produce 6.3 Mt of ore per year for more than 15 years to produce 75 000 t of cathode copper per year.This paper will review the project geology the computer model ling of the deposit, the mine planning process and the property production scheduling. With copper production .fixed by the onsite electrowinning capacity, the planning and scheduling aspects to optimize the project NPV will be discussed. Some of the logistics, equipment. personnel and process difficulties of operating a mine at 42()() m elevation will also be described. IntroductionProject DescriptionThe Quebrada Blanca Copper Mine is an open pit copper project located in the northern part of the Chilean Andes. The project is based on the supergene enriched portion of a porphyry deposit which has a mining reserve of 89 million tonnes at 1.3070 copper. Below the enrichment blanket, the protore represents a further resource.All ore will be leached, the higher grade material will be crushed and stacked for thin layer heap leaching, and the lower grade and oxide material will be dump leached as run-of-mine material. Solvent extraction and electrowinning will be used to produce 75 000 tonnes of cathode copper per year. Power will be supplied by a 40 MW on-site diesel generating plant with the waste heat being used for process heating. The leaching operation will operate in excess of 15 years and may be followed by open pit mining and conventional ore concentration of the underlying primary sulphide mineralization.Because of the dry location water will be piped 37 km from a ground water source at the Salar de Michincha. Water requirements will be approximately 1.5 million m3/year. The operation will eventually employ approximately 550 people on a 7-day-on, 7-day-off rotation with two twelve-hour shifts per day with an on-site camp. Busing will be provided to the port city of Iquique."

Jan 1, 1994

By M. Yao, D. Thibodeau

"Selective mining, such as post pillar cut and fill, is used in large, flat, irregularly shaped ore bodies where ground stability is to be maintained. This selective mining is used to open the stope to the full lateral extent of the ore body in order to minimize the dilution and maximise the recovery. For increased mining depth, design of the post pillar becomes more challenging since those pillars will eventually fail as mining progresses upwards. The post pillar should be designed such that failure does not occur at the early mining stage, such as at the first cut. After mining progresses upwards, the post pillars are expected to fail but be confined by backfill. In order to maximise ore recovery, both drift width and post pillar size must be designed adequately with a consideration of all geomechanic parameters. This paper will describe the process used to design post-pillar cut and fill for one of the ore bodies in Vale’s Copper Cliff Mine using a combination of both empirical deterministic and numerical modelling techniques. By utilizing both empirical deterministic and numerical modelling techniques drift width and post pillar size can be effectively designed. Current post pillar cut and fill design in the existing Vale operations are used to validate the design for Copper Cliff Mine. INTRODUCTIONCopper Cliff Mine is located within the Copper Cliff Offset in the limits of City of Greater Sudbury, Ontario, Canada, as shown in Figure 1. The Copper Cliff Offset extends about eight kilometres south from the Sudbury Igneous Complex into the footwall rocks. Until 2008, the current Copper Cliff Mine was operated as two separate mines i.e. North Mine and South Mine. However, as part of restructuring of Vale Ontario Operations, the North and South Mines were merged in 2009 to form the “Copper Cliff Mine”."

Jan 1, 2015

By M. Xian, M. Jahazi, Y. L. Lin

The 2-mm butt joints of ZE41A-T5 sand castings were laser welded at different defocusing distances on two surface conditions (as-cast or machined) using a continuous wave 4 kW Nd:YAG laser system at a power of 2.5 kW and a welding speed of 6.0 m/min. Two welding modes (conduction or keyhole) have been observed. The adjustment of defocusing distance can greatly influence the establishment of conduction or keyhole modes. On the machined surface conditions conduction welding is obtained at a power density of 4.0 x 105 W/cm2. In contrast, keyhole welding is reached at a threshold irradiance of 1.5 x 106 W/cm2. Neither conduction nor stable keyhole modes have been established at a range of power density from 7.7 x 105 to 1.2 x 106 W/cm2 on the machined surface conditions. On the as-cast surface conditions keyhole is obtained at a power density as low as 4.0 x 105 W/cm2 but good surface quality is obtained at a defocusing of +2 mm. The as-cast surfaces require lower power irradiance for the formation of keyholes indicating that they have higher energy absorptivity for Nd:YAG laser beams probably due to coarse surface morphology.

Jan 1, 2004

By Alan S. Lock

Large scale feasibility studies for the establishment of oil-seed and cellulose producing crops on mine tailings have been successfully conducted over 1 growing season with the purpose of these crops to be used as feedstock to the biofuels industry. An acid sulphide tailings impoundment in Copper Cliff, Ontario and a near neutral pH goldmine tailings impoundment in Timmins, Ontario were both tested by amending half hectare plots to approximately 1 m thick with residual biosolids from the pulp and paper industry and growing canola and corn on these plots. Full scale agricultural equipment was used to cultivate seed and harvest the plots to prove the full scale feasibility of farming on these biosolids. The vegetation development, growth, yield, quality and composition were assessed to identify the best species that would maximize biomass development for feedstock to the biofuels industry and carbon credits for the mining industry. Groundwater, biosolids and tailings chemistries were investigated to identify potential deleterious impacts of degrading organic matter on tailings metal mobility. Preliminary hydrologic investigations using moisture sensor profiles elucidate potential conservation of water in amended plots. Tailings amended with biosolids have the potential to provide the mining industry with carbon credits and supply feedstock to this new industry while reclaiming brownfields to a new level, utilizing industrial and municipal organic waste material.

May 1, 2009

Slurry flow, including flow through the charge, through the discharge grates, along the pulp lifters and its discharge from the mill is an important contributor to the efficiency of the grinding process within a SAG mill. Poor transport of finer ground material can adversely affect grinding leading to excess energy consumption and over-grinding of fine material. This paper extends a 1-way coupled DEM-SPH method to three dimensions and applies it to a 1.8 m diameter by 0.6 m long AG/SAG pilot mill. This provides detailed information on the internal flow of slurry within a SAG mill, including the prediction of dry regions and of slurry pooling. Full 3D analysis also allows the pulp flow patterns into and out of the mill via pulp lifter chamber to be investigated.

Jan 1, 2012

By H. Craig Boyle, Craig H. B. Leitch

"The Trout Lake stockwork molybdenum deposit is located in the Selkirk Mountains of British Columbia, 50 km southeast of Revelstoke. The property is being explored by a joint venture between Newmont Exploration of Canada and Esso Minerals Canada.The deposit is associated with a small granodiorite stock of Upper Cretaceous age (76 Ma) which has variably altered the surrounding schists, argillites and marbles of the lower Paleozoic Lardeau Group to hornjelsic biotite schists and skarn. The intrusive is composed of a small stock and an intersecting network of northeast- and northwest-trending dykes at surface that coalesce downward into a larger stock. There are two main phases of intrusion, with an earlier quartz porphyritic granodiorite cut by an intra-mineral ""quartz diorite"" porphyry. A strong sub-vertical north-trending fault controls the distribution of the mineralized stock work and displays post-mineral movement.Molybdenite, accompanied by pyrite and pyrrhotite, is mainly present along the margins of veins in a well-developed quartz stock work, but occasionally is strongly disseminated in microfractured intrusives. The stock work is strongest in and around the contacts of the intrusive and its apophyses, and occurs over a vertical range of more than 1,000 m. As defined by the 0.10% MoS] contour, the main mineralized zone is up to 300 m long by 200m wide. Preliminary drill-indicated reserves, currently being revised, are approximately 50 million tonnes of 0.23% MoS2, within which are several zones of higher-grade material. Hydrothermal alteration, as defined by quantitative X-ray diffraction studies on composite core sections, is composed of a central quartz/K-feldspar/albite/minor biotite zone coincident with molybdenum mineralization, which is overlapped by a slightly later, antipathetic quartz/ sericite/pyrite zone. Ankeritic carbonate is also a common alteration mineral, but only traces of fluorite, and no topaz or sulfosalts, have been observed. Analysis for trace elements such as Sn, W, Bi, Sb, As, Hg, U, Ag, Au, Mn, Cu, Pb, Zn and F has been limited except for Sn and W, which appear to be zoned inside and outside the Mo zone respectively; the other elements do not show detectable patterns thus far."

Jan 1, 1983

By Nick Vagenas

"Loading and transportation are important activities of the mining process. Automation of these activities in underground hard rock mining has been discussed for a long time. This paper deals with the performance evaluation of a prototype automatic Load-Haul-Dump (LHD) vehicle (a 7-ton GHH LF LHD model) operating in Zinkgruvan mine, Sweden. The purpose of the data analysis is to evaluate the operational and maintenance characteristics of the automatic LHD system in the mine. Graphical and numerical methods have been used for the statistical analysis of the data. IntroductionDuring the past years, the idea of integrated automation and tele-operation on Load-Haul-Dump (LHD) machines (Fig. 1) has attracted considerable interest in the Swedish mining industry. This is mainly due to the demand for improvement in the working environment and due to the rapid development of economic and reliable microprocessors for mining vehicles. Several advantages can be foreseen with the application of a Remote-controlled/Automatic LHD (RAL) system in underground mining. Some of them are (1)':• better utilization of working hours;• less interruption in production at shift changes;• better operational control of a fleet of vehicles;• improved safety; and• one operator may be able to operate more than one vehicle simultaneously."

Jan 1, 1993

By W. Zieman

"The low consumption of reagents can probably be attributed to a good clean type of ore. The cyanide level is kept at 0. 8 lb/ ton of solution and the lime at 1. 8 to 1.9 lb per ton of solution (pH 12. 2 to 12 .3). Experience in cutting down the lime level in half produced troubles in the presses, in the refinery and resulted in higher cyanide consumption. Finally the residue increased under these conditions, High lime always seems to prevent the trouble from occurring.A survey at one mine of the taxable work, performed in the mine shops for use in the mine, showed that under the new regulations, this had increased some 30 times what it was before the new rules came into effect on June 14, 1963.A water softener idea is incorporated at Lamaque with the crude addition of 100 lb of lime per shift to a spare agitator to precipitate the bicarbonates as carbonates from the water before it enters the mill. The lime titration of the softened water is about 0,2 to 0.3 lb per ton of solution (pH 11). This water is used mainly on the filters as washes."

Jan 1, 1964

By Anna Maria Venezia

Bimetallic Au-Pd catalysts supported on amorphous silica-alumina (ASA) with vary amount of alumina (0, 8, 14, 28 and 100%) were prepared by the simultaneous reduction of palladium and gold precursors by ethanol in the presence of the polyvinylpyrrolidone (PVP). X-ray diffraction and X-ray photoelectron spectroscopy analyses indicated formation of alloyed Au-Pd particles. Ammonia temperature programmed desorption measurements were performed to monitor the acid strength and the amount of acid sites on the catalysts after their reduction with 10%H2/Ar at 573 K for 1h. The effect of the support acidity on the catalytic activity was investigated in the simultaneous hydrogenation (HYD) of toluene (T) and naphthalene (NP) in the presence of dibenzothiophene (DBT). Coke formation was also determined. Under the selected conditions (P = 5.0 MPa, T = 523 K, WHSV = 41.2 h-1), all the catalysts were resistant to poisoning with 113 ppm of S (as DBT). The hydrogenation activity of toluene and the HDS activity of DBT were found to correlate with the concentration of the medium strength acid sites. The enhancement of the HYD activity and the S- tolerance was related to modifications of the electronic properties of the metal atom upon interaction with the Brönsted acid sites and upon intermetallic interaction.

Oct 1, 2003

By E. Czech

Hydrogen generated through aluminum-assisted water split reaction is a novel, efficient and environmentally friendly method. It has been found previously that the passivation of aluminum can be prevented in neutral (pH=7) or near neutral pH conditions in water by grinding aluminum with a catalyst, such as A12O3, SiO2 or SiC. Recently, the best results have been obtained by using water-soluble inorganic salts (WIS), ground with aluminum. The massive, rapid corrosion reaction of the Al-WIS system which takes place in regular tap (or marine, or ground) water can be utilized to produce hydrogen by aluminum-assisted water split reaction, in-situ, on-demand. The reaction offers clean, low-cost, environmentally benign and entirely recyclable technology for on-board on-demand hydrogen generation. Besides pure gaseous hydrogen, only pure solid aluminum hydroxides AlOOH or Al(OH)3 are formed as the reaction products. The hydrogen yield and Al-WIS reaction efficiency are high. From 1 g of mechanically alloyed aluminum powder, up to 1.25 liters of hydrogen were generated, i.e. efficiency up to 92% was achieved. The amount of hydrogen and hydrogen generation rate depend on various reaction parameters. The effect of chemistry and concentration of additives, water temperature, powder particle size and milling conditions on the reaction kinetics will be presented and the possible process mechanism will be discussed.

Jan 1, 2005

By P. Lausch, Z. X. He, J. F. Archibald

"Documented underground fill failures have resulted because of the lack of adequate knowledge concerning fill strength and other physical parameters, as well as to a lack of consistent quality of fill materials being used by operators. On the basis of literature review and correspondence with backfill operators at 18 mines throughout the province of Ontario, non-systematic quality control procedures have been shown to exist, both within different levels of single operations and between separate mining operations, which act to provide inferior engineered fill materials and erratic application response in situ.Assessment of existing procedures set by mine operators for determining backfill physical parameters, and recommendation of optimum fill material testing and manufacturing guidelines are presented in this paper.A series of standard fill characterization test procedures are recommended to provide substantial, though not comprehensive, fill behaviour review. The purpose of these recommendations is to propose industry standards for backfill quality review. Data acquired could be utilized for fill design functions and as a means of comparing fill quality parameters between sites in a regular and more systematic fashion than is presently done."

Jan 1, 1993

By J. E. Udd, L. B. Geller

"Mine-shaft wire-rope discard regulations include, among other criteria, a limited amount of permissible loss-of-breaking-strength (LBS). Currently, this parameter is estimated on the basis of non-destrutive-testing (NDT) with electro-magnetic (EM) type instruments. This paper analyses the accuracy with which these estimates have, so far, been obtained in practice.It concludes that while certain types of testers have produced better results than others, the desired accuracy level has not been attained. Also discussed are the putative reasons for this situation, and appropriate actions that the mining industry might wish to take."

Jan 1, 1990

By L. C. Hsu, H. F. Jr. Bonham, M. O. Desilets, P. J. Lechler, J. G. Price, L. J. Garside

Abstract-Geochemical background levels have been established for unmineralized sedimentary rocks that are elsewhere the hosts of Carlin-type gold deposits in the Getchell Trend. The Paleozoic rocks in the Winnemucca Quadrangle consist predominantly of the lower Paleozoic siliceous and clastic sequences that were carried eastward along the Roberts Mountains thrust during the Late Devonian and Early Mississippian Antler Orogeny and the late Paleozoic Havallah and Pumpernickel sequences brought along the Golconda thrust eastward during early Mesozoic Sonoma Orogeny. Over 260 rock samples were collected from the Paleozoic sequences. Major and trace elements were determined by instrumental methods best suited for the specific elements. The general geochemical features of the Paleozoic sedimentary rocks are discussed in detail with reference to the data of average abundances of elements in sedimentary rocks. The background and threshold values of certain trace elements in sandstone, shale, and carbonate rock of one formation, as well as back- ground levels for the entire sequence were obtained. The characteristic geochemical features of the Paleozoic rocks in this area include: consistently high Ba and low Au contents (1.1 ppb, 1.5 ppb, 1.1 ppb Au for average sandstone, shale and carbonate, respectively); generally low contents of those elements which may be of environmental concern such as As, Cd, Hg and Pb. Plots of major and trace elements suggest that the majority of the Paleozoic clastic rocks are related to a passive- margin tectonic setting. Samples with gold values higher than threshold are considered to have been affected by hydrothermal alteration related to gold mineralization. Most of these samples generally also have higher values of Sb, Hg, V and/or As. These observations support the use of such elements as pathfinders for gold, although V has not been identified as such before. Ba is not effective for gold exploration in this area due to the generally high background value of Ba, even though it may be an important pathfinder elsewhere.

Jan 1, 1995

By L. C. Hsu, M. O. Desilets, P. J. Lechler, Jr. Bonham, J. G. Price, L. J. Garside

Geochemical background levels have been established for unmineralized sedimentary rocks that are elsewhere the hosts of Carlin-type gold deposits in the Getchell Trend. The Paleozoic rocks in the Winnemucca Quadrangle consist predominantly of the lower Paleozoicsiliceous and clastic sequences that were carried eastward along the Roberts Mountains thrust during the Late Devonian and Early Mississippian Antler Orogeny and the late Paleozoic Havallah and Pumpernickel sequences brought along the Golconda thrust eastward during early Mesozoic Sonoma Orogeny. Over 260 rock samples were collected from the Paleozoic sequences. Major and trace elements were determined by instrumental methods best suited for the specific elements. The general geochemical features of the Paleozoic sedimentary rocks are discussed in detail with reference to the data of average abundances of elements in sedimentary rocks. The background and threshold values of certain trace elements in sandstone, shale, and carbonate rock of one formation, as well as back-ground levels for the entire sequence were obtained. The characteristic geochemical features of the Paleozoic rocks in this area include: consistently high Ba and low Au contents (1.1 ppb, 1.5 ppb, 1.1ppb Au for average sandstone, shale and carbonate, respectively); generally low contents of those elements which may be of environmental concern such as As, Cd, Hg and Pb. Plots of major and trace elements suggest that the majority of the Paleozoic clastic rocks are related to a passive-margin tectonic setting. Samples with gold values higher than threshold are considered to have been affected by hydrothermal alteration related to gold mineralization. Most of these samples generally also have higher values of Sb, Hg, V and/or As. These observations support the use of such elements as pathfinders for gold, although V has not been identified as such before. Ba is not effective for gold exploration in this area due to the generally high background value of Ba, even though it may be an important pathfinder elsewhere.

Jan 1, 1995