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By G. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment. The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate. The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By A. Vervoort, A. Govaerts

Geostatistical concepts are often difficult for students to understand, even those with a strong mathematical background. One of the main problems is the link between the variation of the parameter value in space or time and the calculated experimental semivariogram. Another challenge is differentiating between directional and omnidirectional semivariograms and their interpretation. For these reasons, interactive tools were developed based on the free public domain software R. The use of these interactive tools is limited to educational situations only (i.e., to visualize basic concepts). The interactive modules can be accessed at www.bwk.kuleuven.be/geostatistics.

Jan 1, 2014

By M. A. Stogran-Baker, S. Cole

"Fluorspar mining occurred in the St. Lawrence area from the 1930s until the mid 1980s. In 2013, CFI discovered a new ore body, the AGS vein, which proved amenable to more economic open pit mining methods. A new mill was designed to produce 200,000 tonnes per year of high quality, acid-grade fluorspar concentrate. The simple mill flowsheet includes crushing, dense medium separation (DMS), grinding, sulphide flotation, pulp thickening, fluorite flotation, thickening, and concentrate filtration. The type of flotation cell used is being installed for the first time in North America. Site clearing commenced in the spring of 2016, followed by mill building erection completed by the fall of the same year. Civil and mechanical installation as well as site-wide construction was completed by the end of September 2017. Commissioning commenced, and at the time of paper submission mill production is on track to ramp up to full capacity by the beginning of 2018. This paper will focus on the use of fluorine NMR analysis applied to fluorite and the development of on-stream analysis, flotation cell selection and the decision to install the new cells, and the water control program designed to maintain process control with the least possible environmental impact.HISTORY St. Lawrence is located on the south-eastern coast of the Burin Peninsula in Newfoundland and Labrador. The first occurrence of fluorspar in the St. Lawrence area was recorded in 1843 by British geologist J.B. Jukes (DNR 2010). Fluorspar was likely extracted in small quantities prior, however commercial fluorspar mining did not commence until 1933 at the Black Duck Mine. The Black Duck Mine operation processed ore by washing and screening – acid-grade was hand-picked from the oversize, the undersize was sold as a lower grade product. The Black Duck Mine was closed in 1941 (Wilson 2010). The American Fluorspar Limited (New Fluor) commenced operations on the Director vein in 1936, and was bought by Alcan in 1942 (Cooper 2012). Alcan also developed the Iron Springs as well as the Tarefare deposits. The Black Duck Mine mill had closed, and a new mill was built. This new mill crushed the ore prior to dense medium separation, the sinks of which were sent to Quebec for use in Alcan’s aluminum smelter (CFI 2016). Alcan shut down it’s mining operations in 1977 due to the dropping price of fluorspar as well as labour disputes. In 1986, the British-based Minworth Limited began producing ore from underground at Blue Beach North and Blue Beach South, as well as from open pits at Tarefare and Director veins (Cooper 2012). A new mill was built by Minworth in order to process the ore using flotation to produce an acid-grade concentrate. The low price of fluorspar caused Minworth to shut down operations in 1990. Whilst exploration has been ongoing, no mining had occurred in the area since 1990."

Jan 1, 2018

By Sarah R. Hindle

Carbon capture and storage has jumped to the forefront of climate change mitigation efforts for its capacity to sequester large amounts of carbon. Mineral carbonation is one prominent option, mimicking and accelerating the natural weathering process of certain silicate minerals. This has the ability to produce stable carbonate minerals that can store carbon on geologic time scales with little to no risk of leakage. Commercialization of this process is ideally suited for integration into the proposed mining operations at the Turnagain Nickel site in Northern BC. This is due to the abundant supply of suitable ultramafic feedstock material, as well as the economic benefit of sharing costs while reducing net emissions and bringing value to otherwise valueless and costly waste rock. While studies have shown this process to be technologically viable on a laboratory scale, assessing the economic and financial viability of such a process on an industrial scale is necessary. An evaluation of the financial feasibility of integrating mineral carbonation into the mining cycle at Turnagain under a proposed cap-and-trade system is presented.

May 1, 2010

By R. D. Browns

In his Budget Speech on March 31, 1 977, the Honourable Donald S. Macdonald expressed concern about the financing of investments through new equity issues. He mentioned the need to render more attractive participation in the equity market by investors in all in come brackets. One of the measures introduced in the budget to accomplish this goal is the proposal to increase the dividend gross-up and tax credit in respect of most dividends received by an individual from Canadian companies. The following comments and tables serve to illustrate the impact of this particular proposal.

Jan 1, 1977

By Dong-Hyeun Koh, Yun-Soo Lee, Min-Seok Kim, Hyoung-Wook Kim

High strength AA7068 (Al - 7.88 wt.% Zn - 2.68 wt.% Mg - 2.07 wt.% Cu) aluminum alloy strip was successfully fabricated by horizontal-type twin roll casting. A simulation technique was used to obtain the range of casting conditions for fabricating strip without defects. The cast strip with thickness of about 5 mm was hot rolled, intermediate annealed, cold rolled to final thickness and subsequently annealed at various temperatures. Tensile properties of annealed and the aged specimens were evaluated at ambient temperature. Tensile strength and elongation of the annealed sheet are about 365 MPa and 28%, respectively. Also, the tensile and yield strength after the aging at paint baking condition (180 °C x 0.5 h) are 586 MPa and 551 MPa, respectively. Therefore, it is expected to show good formability prior to press or stamping and also provide high dent resistance after paint baking treatment.

Jan 1, 2015

By M. Sukhram

This paper presents a technique to determine the direction of velocity in liquid aluminum (Al) by measuring the temperature distribution within a cylindrical rod while it is inserted into the flow. The heating pattern of the rod is a result of the interaction of the thermal fields of the rod with the liquid Al. This interaction freezes aluminum onto the cylinder in a characteristic pattern and as a result the temperature response within the rod also follows a distinctive heating pattern. Monitoring the temperature within the cylindrical rod as a function of spatial and temporal coordinates, the direction of velocity can be inferred. Experimental research work involving liquid Al was conducted at the University of Toronto using the Revolving Liquid Metal Tank (RLMT). The RLMT is a resistance furnace which can hold up to 50kg of liquid Al. In this RLMT tangential velocities up to 0.35m1s can be generated. Experimental data for different superheat and magnitude of velocity demonstrate that the sensor records different heating patterns under different fluid flow conditions. Using the transient temperature information, the direction of velocity of the molten Al flow field can be detected.

Jan 1, 2011

"Industry Guide 7 contains the Securities and Exchange Commission’s basic mining disclosure policy. It provides guidance for Registrants on various matters including the definition and disclosure of proven and probable reserves and the definitions of exploration, development and production stages. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures. As NI 43-101 is law in Canada, the SEC allows mineral resources and mineral reserves prepared under CIM Definition Standards for issuers that are reporting in Canada but are also registered with the SEC. The SEC places conditions on the disclosure of these estimates. US shareholders are cautioned that the requirements under NI 43-101 and the CIM Definition Standards differ significantly from those of Industry Guide 7.Note: this Guide contains the Commission's basic mining disclosure policy. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures pursuant to the rules of Regulation S-K. Questions regarding the application of these definitions and rules to specific situations should be asked of the Commission's mining engineers or geologists at either the Office of Engineering, Division of Corporation Finance, 202-272-3252, or the Branch of Geology, Central Regional Office, 303-844-1000.(a) Definitions. The following definitions apply to registrants engaged or to be engaged in significant mining operations:(1) Reserve. That part of a mineral deposit which could be economically and legally extracted or produced at the time of the reserve determination.Note: Reserves are customarily stated in terms of DoreD when dealing with metalliferous minerals; when other materials such as coal, oil shale, tar, sands, limestone, etc. are involved, an appropriate term such as Drecoverable coalD may be substituted.(2) Proven (Measured) Reserves. Reserves for which (a) quantity is computed from dimensions revealed in outcrops, trenches, workings or drill holes, grade and/or quality are computed from the results of detailed sampling and (b) the sites for inspection, sampling and measurement are spaced so closely and the geologic character is so well defined that size, shape, depth and mineral content of reserves are well- established.(3) Probable (Indicated) Reserves. Reserves for which quantity and grade and/or quality are computed from information similar to that used for proven (measured) reserves, but the sites for inspection, sampling, and measurement are farther apart or are otherwise less adequately spaced. The degree of assurance, although lower than that for proven (measured) reserves, is high enough to assume continuity between points of observation.(4)(i) Exploration StageDincludes all issuers engaged in the search for mineral deposit (reserves) which are not in either the development or production stage."

Jan 1, 2003

By K. M. Ed

MR. J. C. NICHOLSON: The author has discussed his subject in a very thorough manner. One difficulty is the tendency to regard a 'permitted' explosive as a 'safe' explosive. There is no such article as a safe explosive; any explosive is only as safe as the man who handles it. In making up the primer, the method illustrated in the paper is alright for the ordinary explosive but not so for the sheathed explosive, for the sheathing would be punctured. MR. T. L. McCALL: I fee! quite certain that there would be little, if any, trouble from flame shots or misfires if the author's suggestions were carried out. There is a tendency on the part of the shot-firer to over-shoot, so as to bring clown more coal for the miner, and frequently a shot has not sufficient burden imposed upon it. Shooting one hole may not only lessen the burden on an adjacent hole, but may practically release it altogether, in which case the second hole should be fired with a very small charge, or perhaps it might not be necessary to shoot it at all. While the paper refers to shooting in the coal only, it should be under-stood that the instructions given are equally applicable to brushing shots. I do not wish to bring up any contentious point, but would the author say a word on cushioning with air gaps and on multiple shooting? Single shooting in rock might open up a feeder of gas which could be ignited by the ?second shot.

Jan 1, 1940

By C. Pichler, S. Luidold, C. Wagner, C. Sagadin, D. Kreuzer

Engineers and scientists have been combating the attack upon refractory materials of molten metals/matte and slags for hundreds of years. The details in many cases are still questionable or at least debatable. The corrosion is a major concern for furnace operators as refractory wear or failures inevitably results in reduced production efficiency and furnace reliability. Also the cost to industry is considerable and only a thorough understanding of all the complexities of the process will help to minimize that cost. One of the critical questions to overcome is the correct selection of refractories for the individual process steps to provide long and predictable refractory life together with high furnace availability. To understand the nature of the reactions involved in refractory corrosion, it is crucial to determine the complex thermo- chemical equilibria of the reactions occurring between the refractory materials and the process phases. A simulation model coupled with commercial software like FactSageTM is demonstrated aiming to understand the corrosion mechanisms between refractories and the molten process phases and draw implications for improving the performance of refractories and refractory lifetime. INTRODUCTION The extraction or recycling of valuable materials, e.g. metals, can be done by two main routes, pyro- and/or hydrometallurgical processing, depending on the chemical behavior of the used ore, scrap or pre-treated concentrate. Sometimes it is also necessary to use both process routes for the extraction or the recycling of valuable materials. In the case of a pyrometallurgical treatment, the usage of refractory materials is inevitable. This is mainly caused by high temperatures, prevailing during processing. The interaction between refractory material and slag, metal or matte leads to different reactions and interactions. As a main result corrosion of the furnace lining (refractory material) takes place. Hence, recurring furnace shutdowns occur for renewing the refractories. This leads to reduced production efficiency. Such refractory lifetimes are between some hours and decades, depending on the processes.

Jan 1, 2019

By Hiwa Salimi, Foley. Stephen R, Loghman Moradi

Common water-miscible organic solvents including DMSO, DMF, methanol, ethanol, acetone and THF in combination with HCl and low concentrations of H2O2 were investigated for dissolution of gold. THF showed the best result demonstrating that gold powder could be completely dissolved in 1.5 hours in 1.0 mol/L HCl and 0.2 mol/L H2O2. No complete gold dissolution was observed for the rest of solvents even after 24 hours. The rate of gold dissolution was measured by dissolving gold wire in THF/HCl/H2O2 mixture. The rate of gold dissolution in optimised condition was 75 g m-2 h-1 at room temperature and significantly increased to 590 g m-2 h-1 by raising the temperature up to 60 oC. Although a THF/HCl/H2O2 mixture showed a slower dissolution rate in comparison with aqua regia, however the applied conditions are considerably milder which is highly promising for gold leaching in an industrial scale.

Jan 1, 2015

By Neda Zangeneh

Production efficiency from low permeability gas shales require techniques to optimize hydraulic fracture completions. One completion strategy involves the simultaneous or near simultaneous hydraulic fracturing of multiple horizontal wells to maximize the fracture network area and stimulated reservoir volume. However, changes to the in-situ stress field caused by an earlier hydrofrac on subsequent hydraulic fractures are not accounted for in traditional hydrofrac design calculations. Presented here are the results from a set of transient, coupled hydro-mechanical simulations of a rock mass containing two wellbores using the discontinuum-based distinct-element method. The results demonstrate the influence of stress-shadows generated by a hydraulic fracture on the development of subsequent hydrofracs from an adjacent well. It is shown here that these interactions have the potential to change the size and effectiveness of the hydraulic fracture stimulation by changing the extent of the hydraulic fracture around the secondary well.

Jun 1, 2012

By R. A. Parra, Fuentes, C. Godoy, L. E. Arias, C. A. Toro, M. Marin, E. Balladares, V. Parra, G. Reyes, S. N. Torres, D. Sbarbaro

In this paper, we report on the detection of spectral molecular emission of iron oxide (FeO) and copper oxide (CuxO) emitted by reactions occurring in a laboratory scale flash smelting process of pyrite (FeS2) as well as copper concentrate. The novelty of the technique is that, the molecular spectral emission sensing is achieved by using a low spectral resolution and low sensitive radiometer, enhanced with signal processing and matrix factorization techniques. The method was validated using a highly sensitive spectrometer, with a high spectral resolution; achieving a similar FeO spectral pattern as the one obtained after signal processing techniques over low resolution spectral signals. INTRODUCTION Visible-near infrared (VIS-NIR) spectroscopy is an optical contactless sensing technique commonly used to capture information about the emitted, absorbed, transmitted or scattered radiation in a physical or chemical process, with the presence or absence of an excitation light source such as a laser or a broad spectral band source. These techniques coupled with signal processing and machine learning algorithms, sometimes referred as chemometrics (Pisapia et al., 2018), can be found in processes such as: pharmaceutical (Kandpal et al., 2016); food (Coelho et al., 2016); combustion (Ballester & García-Armingol, 2010); siderurgy (Strakowski et al., 2014) industry, among others. In the extractive copper industry there are several technological developments using optical sensing techniques aimed to retrieve information about copper ore and concentrate mineralogical composition such as X-Ray Fluorescence, Qemscan® (Quantitative Evaluation of Minerals by Scanning Electron Microscopy) and X Ray Diffraction (XRD) analysis, however, because of the manual procedures to analyze the samples with these laboratory instrumentation, only discrete information during a daily based operation can be retrieved, making impossible for the operators to take decisions over the involved processes in real time. The aim of our research work presented here is to contribute with sensing and data analysis procedures based on VIS-NIR spectroscopy for the flash smelting process characterization, particularly in this paper, with the detection of FeO and CuxO molecular emissions in a laboratory scale setup.

Jan 1, 2019

By B. K. Choi, G. E. Kim, S. Noh, T. K. Kim

Oxide dispersion strengthened (ODS) steel has been developed as the most prospective core structural material for next-generation nuclear systems because of its excellent high strength and irradiation resistance. In ODS steel, finely dispersed nano-oxide particles with a high number density in the homogeneous grains can be very attractive to achieve superior mechanical properties at high temperatures, and these favorable microstructures can be significantly changed using process parameters during the mechanical alloying procedures. In this study, the effects of mechanical alloying times on the microstructure of 10Cr-1Mo ODS martensitic steel were investigated. Pre-alloyed powders with Y2O3 powder were mechanically alloyed for various milling times using a high energy horizontal ball-mill apparatus (model: symoloyer CM20). Powder properties such as the mean particle size, size distribution, and crystallite size were evaluated. Uniaxial hot pressing was employed to consolidate the milled powders. The results of a microstructural observation after the MA and UHP processes indicated that the homogeneity of the martensitic structures was considerably increased with the longer milling time. It is thus concluded that the mechanical properties of the ODS martensitic steel are greatly dependent on the mechanical alloying times.

Jan 1, 2015

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015

By L. R. P. de Andrade Lima, D. Hodouin

The paper presents a survey of the possibilities of the simulation techniques for improving the design and operation of gold processing plants. The procedure to construct kinetic models that are used in simulators is first reviewed, and examples are given for cyanide gold dissolution and gold adsorption on carbon. Then, an overview of the structures of the plant simulators is proposed, and the simulation equations formulated for a carbon-in-leach process. Finally, the potential of simulation methods is illustrated by four examples. The first one shows how it is possible to use a simulator to design a cascade of leaching tanks while optimizing an economic performance criterion. The second one illustrates the role of simulators for optimal tuning of the cyanide addition strategy in a leaching circuit. The third example focuses on the power of simulation to design carbon transfer strategies in a carbon-in-pulp process. Finally, the last example shows the role of on-line simulators for optimally supervising the automatic control of cyanide addition into leaching tanks.

Jan 1, 2005

By Hämäläinen M., O. Hyvärinen, E. Jääskeläinen

HydroCopperTM is a new hydrometallurgical process for the treatment of copper sulphide concentrates, which has been developed by Outokumpu. The process includes chloride leaching of copper concentrate, solution purification and precipitation of copper(I) oxide, an intermediate product, which is reduced and cast into copper products. The reduction can be carried out by pyrometallurgical methods or hydrometallurgically in an autoclave. This paper discusses the thermodynamic and kinetic aspects of the hydrogen reduction of copper(I) oxide in an autoclave. The results of the laboratory tests are presented and discussed. Finally, the autoclave method is compared with other options.

Jan 1, 2004

By D. D. Tannant, H. Ozturk

Thin spray-on liners are increasingly being used as rock support in underground mines. The adhesive strength between the liner and the rock surface is an important design parameter. Adhesion tests were conducted to assess the impact on adhesion of the presence of oil, water, and dust on a substrate, and the roughness and grain size of different substrates. Other factors such as curing time, loading rate, and liner thickness were also considered. Adhesion was measured using a pull test of a 33 mm diameter elevator bolt attached to an over-cored section of liner with strong epoxy. Most tests were performed using Tekflex liner material, although five other liner products were also tested. Adhesive strengths of about 2 MPa can be achieved with Tekflex under optimal conditions. Long-term creep tests showed that the adhesive strength could drop by at least 50% when the liner carries load for about a month. Where the rock surface is contaminated with dust or the rock is weak in tension, it may be difficult to reach adhesion strengths of 1 to 1.5 MPa. As the thickness of the liner increases, the adhesive strength to a substrate appears to decrease.

Jan 1, 2007

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001

By R. Guimarães, L. Silva, J. Milboume

The São Bento concentrator was built by Gencor in 1985 to treat refractory gold-bearing flotation concentrate. The plant was the first commercial application of pressure oxidation for refractory gold ore following about a year after the first use of pressure oxidation on a whole ore at Homestake's McLaughlin operation in California. Ore from the Sao Bento mine is remarkably consistent in gold grade and arsenic and sulphide concentration as is typical in banded iron formations (BIF) (l). Gold content is approximately 9 g/t with approximately 30 - 40% free milling. The balance is associated with arsenopyrite and pyrrhotite. An expansion of both process facility and mine was undertaken between 1996 and 1998, raising the treatment capacity from 32,000 t/mo to 45,000 t/mo.

Jan 1, 2004