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By S. M. Chentouf, M. Jahazi, N. Bombardier, T. Belhadj

The main limiting factor in the commercial expansion of superplastic forming (SPF) of thin sheet aluminum alloys is the extent of cavitation phenomenon that takes place during the processing. The severity of the cavitation process is mainly dependent on the uniformity of deformation (i.e. level of local thinning) during processing. In the present paper, correlations are made between thickness variations in several formed sheets and the characteristics of the cavities observed in the material. The 1.4 mm thick 5083 aluminum alloy sheets were hot pre-formed at around 450°C for 4 min and then air-cooled. Opto-digital and Scanning Electron Microscopy were used to examine the microstructure and analyse the cavities. Also, grain size measurements were carried out for different location in the SPF formed piece. The surface and volume fractions of the cavities were measured with the aid of metallography image processing (MIPTM) on as-polished samples prior to etching. The results are analyzed in terms of the influence of applied strain and microstructure conditions on the propensity to cavitation of the alloy.

Jan 1, 2015

By Himmelman. Nicholas P.

In this paper, the hardware foundations and data collection methods of a real time collision avoidance system for electric surface mining rope shovels are described. The primary goal of the system is to help a shovel operator avoid accidentally colliding the shovel?s dipper with either a nearby haul truck or the shovel?s tracks. To achieve this goal, the system requires complete and precise knowledge of the shovel?s geometry and movement, as well as the location of any nearby haul trucks. This paper describes the subsystems created to acquire this necessary information. This system is unique in that all of its components are mounted solely on the shovel and that it is designed to be easily retrofitted to a shovel without significant modifications.

Oct 1, 2009

By J. Zhou1

"The extractive metallurgy of gold ores is largely driven by their grade and mineralogy. The concentration of gold in the crust is extremely low and highly variable, resulting ore variability in many gold and copper-gold deposits. More importantly, gold in an ore may occur in two or three forms (i.e. microscopic gold, submicroscopic gold and surface gold), making gold ore processing extremely challenging. Geometallurgy is a technique to document variability within an orebody and quantify and evaluate the impact of many factors including geology and mineralogy on grinding, flotation, leaching and metal recovery processes. The objective of gold geometallurgy is to reduce and minimize the technical risk in project evaluation, plant design, mine planning and production forecasting through geometallurgical modelling, representative sampling and subsequent systematic mineralogical and metallurgical testwork. Gold deportment study is a powerful tool in characterization of various gold ores. Effective and quantitative gold deportment results are critical and useful for predicting gold recovery and building geometallurgical models of gold ores. This paper provides an overview of geometallurgy fundamentals and applications in gold processing, with a focus being on the ore characterization and gold deportment study.INTRODUCTION Geometallurgy is an inter-disciplinary approach which links the geological, geochemical and mineralogical characteristics to the metallurgical performance of an orebody. Combined with mine planning, it has been used in scoping, prefeasibility and feasibility studies, process design and optimization of gold, copper-gold, copper-moly, nickel and iron projects among others (Williams & Richardson, 2004; Dobby, Bennett, Bulled, & Kosick, 2004; Bulled, 2007; Bulled, Leriche, Blake, Thompson, & Wilkie, 2009; Kormos, Sliwinski, Oliveira, & Hill, 2013; Muinonen, Sciortino, Korczak, & St-Jean, 2013; Leichliter & Larson, 2013; Leichliter, Jahoda, & Montoya, 2013; Hatton & Hatfield, 2013; Baumgartner et al., 2011, 2013; Hoal, Woodhead, & Smith, 2013; Zhou, 2013). The goal of a gold or copper-gold geometallurgical program is to characterize and understand the metallurgical variability of an orebody, such as comminution, gravity, flotation and cyanidation parameters and metal recoveries, and to build a geomet model which can be used to assist in mine planning and to predict the plant performance. In any geometallurgical program, representative sampling is the key to ensure the results of a geometallurgical study will reflect future performance once the plant is commissioned. Geometallurgy compliments, but does not replace, the traditional mineralogical and metallurgical approach during the development and operation of a gold or copper-gold project. Geometallurgy is a methodology for testwork design and a framework for mine planning. The first part of this paper provides an overview of geometallurgy fundamentals and application in gold ore processing."

Jan 1, 2017

By D. H. Rousell

"Rocks of the Whitewater Group (Aphebian age) oc ithin the Sudbury Basin and consist of three formations rre, from oldest to youngest: Onaping, heterolithic breccias lus an igneous-textured component; Onwatin, argillite and siltstone; and Chelmsford, greywacke with minor argillite with siltstone. Mineralization in these rocks is as follows:1) Sulphides are disseminated throughout the Onaping Formation. Pyrrhotite, the major sulphide mineral, occurs mainly as fragments; other sulphides are chalcopyrite, sphalerite, galena, pyrite and marcasite.2) Zn, Pb, Cu, Ag and A u mineralization in the Vermilion member, a carbonate-chert unit near the base of the Onwatin Formation (Vermilion and Errington mines).3) Pyrite and minor base metals in the Onwatin Formation .4) Mineralized quartz veins, located at or near the base of the Onaping Formation, include such deposits as Moore Lake (Pb, Zn and Ag), Foisey (Zn, Pb), Papineau (Cu, Au and Co) and Proulx (Pb, Zn, and Cu). Quartz-carbonate veins in a meta-gabbro sill contain Cu, Zn, As and Au. Material from quartz veins from two former ""gold mines"" (Gordon Lake and Creighton) yielded no Au values.5) Anthraxolite veins in the Onwatin Formation .The mineral occurrences can be explained in term of either the volcanic theory or meteorite-impact theory of basin formation. According to the latter theory, the sulphide fragments in the Onaping Formation may have been formed by the brecciation of sulphide-rich pods located in the upper mantle and at the base of the transient crater; some of the sulphides may have been derived from target rocks of the Huronian Supergroup. The Vermillion-Errington deposits may represent sedimentary exhalative deposits of the Remac type; mineral-rich brines, trapped at the base of the transient crater, rose upward and precipitated the mineralized carbonate-chert under reducing conditions. These conditions continued throughout the deposition of the upper Onwatin Formation but pyrite was the only sulphide that formed.The quartz veins were emplaced during the time of basin deformation. Metamorphism remobilized and concentrated carbonaceous material in the Onwatin Formation 10 form the anthraxolite veins."

Jan 1, 1984

By William W. Shilts

"In carrying out a geotechnical survey of a proposed gas pipeline route from the Arctic Islands south to Longlac, Ontario, the Polar Gas Consortium contracted the drilling of several hundred 2- to 2D-m-deep boreholes in drift and bedrock. Samples from these holes were made available to the Geological Survey of Canada, where they were subjected to stratigraphic and trace-element geochemical analyses. The geochemical characteristics of the clay and sand-sized heavy mineral fractions of till samples from these boreholes have been summarized in a series of geochemical profiles.From the proposed pipeline terminus at Longlac northward to the vicinity of God's River in Manitoba, tills contain significant amounts of Paleozoic carbonate rocks and Proterozoic sedimentary rocks derived from the Hudson Bay basin and lowlands. Within this section, two sites were enriched in base metals, indicating the possibility of local mineralization of possible economic interest.From God's River northward to Seal River, Manitoba, no evidence of local mineralization was noted. The heavy mineral fractions of the tills are universally enriched in Mn-rich siderite thought to originate on or in the Paleozoic section of the Hudson Bay lowlands.From Seal River northward to Thelon River, near Baker Lake, tills contain only components originating west of the Hudson Bay sedimentary basin. Near the Keewatin-Manitoba border, all till is enriched in uranium, which probably originates in the ""young"" porphyritic granites underlying much of the region, and produces a distinctive airborne radiometric anomaly.At the Thelon River, multiple till sections are variously enriched in Cr, Ni, U, Cu and Mo in the vicinity of a distinctive aeromagnetic anomaly.From Thelon River northward, several coincident zones of chromium and uranium enrichment are found where the line of boreholes crosses east-west-striking belts of volcanic, ultramafic and sedimentary rocks of the Prince Albert Group.The results of this study indicate that till tends to have characteristic element associations or concentrations over each of several broad regions along the pipeline route. These are related both to large-scale bedrock associations and to largescale effects of glacial dispersal. In addition, the samples, collected more or less at random with respect to local bedrock geology, have intersected several small-scale geochemical anomalies that appear to be related to zones of mineralization of possible economic interest."

Jan 1, 1980

By X. -G. Chen, E. M. Elgallad

Direct chill (DC) cast ingot plates of 2xxx alloys have been increasingly used for large mold applications in the plastics and automotive industries. A novel heat treatment practice for Al-3%Cu-1%Mg DC cast ingot plates has been developed, involving solution treatment, furnace cooling to the desired aging temperature and holding for appropriate time at the aging temperature. The mechanical properties of the plates were studied for different combinations of aging temperature and time, using hardness measurements and tensile testing. The evolution of the strengthening precipitates was investigated under different cooling rates corresponding to cold water quenching, still-air cooling and furnace cooling, using electrical conductivity measurements. The results showed that by applying the novel heat treatment, the cast ingot plates could provide a wide range of combinations of strength and ductility satisfying the design specifications of large molds. This, in turn, offers a practical solution for the fabrication of extremely large DC cast plates combining between good mechanical properties and low levels of residual stress using the shortest possible heat treating cycle.

Jan 1, 2015

By V. Concha, M. Hashemzadeh

"The objective of this study was to gain a better insight into the kinetics of chalcocite leaching in an acidic ferric sulfate media. Chalcocite leaching in acidic media is known to occur in two sequential stages, with the first stage being much faster than the second. The leaching residue from the first stage is typically assumed to be a covellite type of material. This study hypothesized that the mineralogy after the first-stage leaching varies in response to different leaching conditions. We investigated the dependency of the mineralogy of the first-stage leaching residue on temperature and initial ferric concentration. The experimental results showed that chalcocite leaching behavior altered upon temperature and initial ferric concentration. A proposed combined reaction model was found to be able to describe the experimental data. The first stage was described very well by the shrinking core diffusion model while the second stage was described very well by the shrinking core chemical reaction model. This finding has important implications for mine operations to manipulate leaching conditions to create the desirable leaching kinetics.INTRODUCTION The kinetics of chalcocite leaching in sulfate media has been extensively studied (Cheng & Lawson, 1991; Fisher, 1994; Fisher, Flores, & Henderson, 1992; Niu, Ruan, Tan, Jia, & Sun, 2015). Sullivan (John D. Sullivan, 1930) proposed a two-stage process for chalcocite leaching in an acidified ferric sulphate solution. The two-stage leaching of chalcocite is presented as the following reactions:"

Jan 1, 2017

"SART technology is a useful tool for improving the economics of gold recovery from certain types of complex gold ores. SART liberates cyanide consumed by base metals such as copper, zinc and nickel, and enables the newly freed cyanide to be recycled to precious metals leaching while producing high-grade base metal sulphide concentrates for sale. The benefits of SART include the reduction in cyanide consumption, avoidance of cyanide destruction costs, minimization of risks of environmental non-compliance due to residues of cyanide destruction reporting to mine effluents, and generation of extra revenue from the sale of base metal concentrates. Concerns with SART typically include uncertainties around capital and operating costs and proper integration of SART into the overall metallurgical flowsheet. This paper presents two case studies addressing these concerns. The first involves actual costs of the full scale SART integrated into a gold heap leach operation and treating up to 500 m3/hr of leach solution at a mine in Mexico. The second involves field pilot testing and a preliminary cost estimate for integrating SART into a silver mine in Peru using Merrill Crowe.INTRODUCTION One of the current trends in the gold industry globally is the increasing importance of complex polymetallic gold deposits as discoveries of large Carlin type gold deposits become increasingly rare (Sceresini, 2005). The presence of cyanide soluble copper and zinc in complex gold deposits necessitates changes in traditional gold extraction metallurgical flowsheets. One of the tools available to the industry to help deal with interferences of cyanide-soluble base metals in gold extraction is the SART (sulphidization-acidification-recycling-thickening) process. SART breaks the weak acid dissociable (WAD) base metal-cyanide complexes, precipitates the metals as high-grade sulphide concentrates and makes the freed cyanide available for recycle. Although SART is a commercially available technology, it is still relatively new to the industry. Fewer than ten (10) full scale plants have been constructed in the past couple of decades. Some of these SART plants are small, most are located at remote sites, and the majority have not operated on a continuous basis. This has resulted in a general lack of information in the industry about the true costs, operability and metallurgical performance of SART. BQE Water has been involved in the design, construction, commissioning and operation of large scale SART plants in Mexico, Turkey and Chile and has conducted field testing programs as part of the technical assessment of SART integration into various metallurgical circuits. Having built and operated numerous plants utilizing selective sulphide precipitation of heavy metals, BQE Water has gained unique insight into the design and control of the sulphidization stage of SART to minimize costs and ensure high efficiency in cyanide recovery."

Jan 1, 2017

By R. Heikkilä

As a part of a large research and development program in Finland, a system calibration for an UAV measurement method having practical experiments in a Jorvas Railway Yard design and construction project. The Railway yard construction are was measured using an UAV measurement device by Smartplanes (Smartone) and using some reference points measured by a GNSS device. The measured data was cleaned, combined and adjusted through Least Squares Optimization using the software developed by a Finnish company Pieneering Oy. As references, two different laser scans as well as total station surveys were used. For applicability evaluation, the accuracy of measurement, the reliability of measurement, and the economy of measurement were used. Based on the comparisons, the achieved precision of the UAV measurement was high, instead the accuracy of measurement was not sufficient in this case. The principle of this photogrammetric measurement includes a lot of redundant observations making it possible to achieve a high level of reliability. The economy in this Railway Yard Design project was not able to achieve.

Aug 1, 2013

By A. S. H. Kabir, I-H. Jung, J. Su, Yue. S., M. Sanjari

One of the major problems associated with conventional wrought magnesium alloys is the unwanted basal texture that forms during plastic deformation which generally does not change markedly after post-deformation annealing. Formation of precipitates on the recrystallized grain boundaries during annealing may affect the usual rotation of grains towards preferred basal direction resulting in texture weakening. In this study, Mg-Al-Sn alloy was hot compressed at 250°C and annealed at 350°C for various times. The initial as-deformed microstructure was partially dynamic recrystallized with dynamic precipitates on the grain boundaries. After annealing at 350°C, static recrystallization of the bimodal microstructure took place where at this temperature no static precipitates formed. The goal of this work was to study the effect of dynamic precipitation on the texture evolution during the annealing process. Texture evolution was studied during annealing by electron backscattered diffraction (EBSD) technique through a microstructure tracking process. It was found that precipitates on the recrystallized grain boundaries have significant effect on the usual rotation of the grains towards the basal direction, meaning significant texture weakening, which is beneficial for final mechanical properties.

Jan 1, 2015

By V. V. Pankov, W. R. Chen, L. R. Zhao

Diffusion nickel aluminide and overlay NiCrAlY coatings were deposited on single crystal Ni-base superalloy CMSX-4 substrate using the chemical vapour deposition and cathodic arc evaporation techniques, respectively. The NiCrAlY coating underwent a post-deposition heat treatment in an argon atmosphere at 1100°C for 2 hours. All the coated specimens were subjected to furnace cyclic oxidation testing at 1000°C up to 1500 one-hour cycles. The morphology, elemental composition and phase constituents of the oxide scales formed on the coating surface were analyzed using scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction. It was observed that the diffusion aluminide coating experienced accelerated weight gain at an early stage of the test (150-400 cycles), whereas the overlay NiCrAlY coating fabricated by cathodic arc evaporation maintained steady-state weight gain throughout the entire 1500 cycle test duration. This difference in oxidation behaviour between the two types of coatings is attributed to the early development of nickel-aluminum spinel on the surface of the diffusion aluminide coating, in contrast to the stable aluminum oxide scale formed on the overlay NiCrAlY coating during cyclic oxidation testing.

Jan 1, 2015

By L. Narhi, K. Haavanlammi

"Approximately two thirds of annual nickel production is used as a raw material in the making of stainless steel, and about 60% of these nickel products are in the form of metallic nickel such as nickel cathode or briquettes. In the stainless-steel production process nickel is blended with iron and chrome-based raw materials, and metallic nickel is typically only required for final steel fine-tuning. Outotec offers a new FeCrNi technology to enhance the nickel value chain for stainless steel producers. This involves the use of an HPAL-based intermediate nickel product (e.g., mixed hydroxides or NiO) as raw material in the Outotec FeCrNi process, for the production of a FeCrNi Master Alloy. The new process, designated as the FeCrNi process, offers multiple benefits compared to existing technologies such as: higher tolerance for impurities in the HPAL intermediate product, avoiding the need for further nickel refining, and the improved recovery of all metals in the FeCr process. The complete new FeCrNi value chain is based on proven technologies such as HPAL and the Outotec FeCr-process. This new innovative and promising value chain offers improved efficiencies for the HPAL based nickel production process combined with excellent sustainability aspects.INTRODUCTION In today’s global economy there is a constant need to improve the efficiency and sustainability of the metals production. The requirements for modern metal refining are tightening and cost efficient, safe and sustainable operation is the precondition for all investment. Outotec is offering now a novel way to combine FeCr and Nickel production to create a completely new value chain to source nickel to stainless steel. BACKGROUND Nickel The current nickel mine production is in the level of 2,000 tons annually and it is split 44% from sulphide based deposits and 56% from laterite deposits (Figure 1). Most (40%) of the nickel is refined to pure nickel metal whereas other products are FeNi (19%) and Nickel Pig Iron NPI (20%) (Roskill). The remaining part, roughly 21%, is nickel chemicals and intermediates. Most of the new investments in nickel are in the direct shipping of laterite to produce nickel pig iron. HPAL process is considered in few projects but no major HPAL projects have been started since the Ambatovy plant in Madagascar. Ambatovy reached the commercial production in 2014. The main primary nickel used is stainless steel manufacturing. In the year 2016 about 68% (~1,360 kt) of primary nickel production was used in stainless steel."

Jan 1, 2017

By Chris Twigge-Molecey

"Over the last 50 years there has been a dramatic evolution in the metallurgical engineering field in Canada. In the 60s the field was dominated by large American and UK groups, often selling major process and equipment packages. The local content was limited to wrap around facilities and the civil and structural work. The mining and metallurgical companies had strong internal teams to lead these projects. Over the decades and business down cycles the large foreign contractors disappeared or re-structured and the mining companies largely shed their engineering and project management groups. The resulting gap was filled by a cadre of local specialist engineering companies, some of whom have grown to be world leaders in the field. The paper traces this evolution and examines the underlying causes and consequences."

Jan 1, 2015

By Edgar L. Horner

"The objectives of the Wabush Mines tailings stabilization program are to control dust Ii/t-off and to rehabilitate the disposal area. The evolution of the program started with test plots in 1970, these being continued and expanded upon through 1974. In 1976, a 35-acre vegetation field trial was attempted and failed, part of the failure being attributed to lack of adequate equipment. Subsequently, equipment was purchased and during the summer of 1979-80 extensive areas were treated. The program was also expanded to include the evaluation of chemical and water spray stabilization versus vegetation in areas where shorter-term control is required. In addition, during the summers of 1979-80, spruce bog material was spread over about 100 acres and seeded.The approach to reclamation by vegetation at Wabush is one of soil building. Work to this point indicates that iron ore tailings can be converted to a soil capable of supporting plants. Plans for the Wabush tailings disposal area should make dust lift-off from inactive tailings areas negligible within the next few years."

Jan 1, 1981

By D. C. R. Espinosa, P. Aliprandini, F. P. C. Silvas, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel ores are divided into two types: sulfide deposits and lateritic deposits. About 60% of nickel resources are found in laterite ore, while the remaining 40% is contained in sulfide ore. Laterite ore is usually processed via pyrometallurgical means or through hydrometallurgical techniques that include acid leaching and metal value recovery from solution. In this study, copper and nickel adsorption by Dowex M4195 ion exchange resin from an acidic sulfate liquor was investigated. The acidic sulfate liquor was collected from an atmospheric leaching process (AL) of laterite ore. Ion exchange experiments were conducted in a batch system by varying parameters such as pH, time, metal concentration and temperature. Initially, mono-elemental synthetic solutions of nickel and copper were used in the experiments and then a synthetic solution simulating AL liquor was tested. Test results showed that the resin exhibited high selectivity towards copper and nickel, however, a high concentration of iron in the synthetic AL solution interfered with the recovery of nickel and cobalt by the resin.INTRODUCTION Nickel is one of the most important industrial metals in the world. It is widely used in industrial applications, such as the production of stainless steel, magnets, electroplating and special alloys (Dizge et al., 2009). The main sources of industrial nickel production are sulphide deposits; only 40% of industrial production uses lateritic ores. However, it is estimated that 60% of global nickel resources are found in nickel laterite deposits (Kuck, 2016). Since industrial nickel demand continues to grow, the development of new technologies for the extraction of nickel from laterite ores has become an interesting research topic (Agatzini-Leonardou, 2009)."

Jan 1, 2017

By S. Esfahani, M. Barati

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, slags with different basicities were studied during non-isothermal cooling. Their continuous cooling transformation (CCT) diagram were plotted and compared with each other. Then, a mathematical model was developed that predicts the amount of crystallization during cooling. The results were validated by experiments performed by Single Hot Thermocouple Technique and image analysis. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow optimizing the slag/air ratio for both heat recovery and slag glass content.

Jan 1, 2015

A series of small scale tests have been conducted to evaluate the effect of micro-fracture development, imposed by blasting, on the material properties of the rock as well as its resistance to crushing and grinding. The uniaxial compressive strength, tensile strength, Poisson?s ratio, P-wave, Swave velocity, point load test index, crushing and grinding work indices were evaluated for samples without any blasting load and for samples which had received a variety of blast loads ranging from a single impact with low strength detonating cord, to combination of impacts at different times and significant impacts with powder factors close to those used in practical blasts. It was shown that the rock mechanics parameters change even at low impacts, suggesting easier crushing of the rock. Damage values appear to be affected by timing as stress wave superposition affects the damage process. Fragmentation is achieved at higher impact levels while work index modification of the fragments is also observed when high powder factors are used, suggesting improvements in grinding.

May 1, 2003

By C. H. B. Leitch

"The Bralorne-Pioneer deposit produced more gold than any other deposit in British Columbia over its 70 years of operation (130 kg or 4 million oz of Au, from 7 million tonnes of 18 glt ore). Mineralization is related to a suite of late Cretaceous albitite dykes of 85 to 90 Ma age. It thus occurred long after and is genetically unrelated to the Early Permian (275 Ma) Bralorne diorite and soda granite.The major veins strike about 110 degrees and dip north at 70 degrees, with slickensides plunging 45 degrees east that indicate last movement was reverse. Major ore shoots in the veins occupy somewhat less than 20% of the vein and plunge steeply west, roughly perpendicular to the slickensides. The structures that contain the veins probably formed at around 95 to 90 Ma during a strike-slip episode with easterly directed maximum compression.Disseminated pyrite, pyrrhotite, and minor chalcopyrite occur within envelopes up to several metres from the veins. Arsenopyrite is confined to vein selvages. Local sphalerite and galena appear to correlate with gold-rich portions of the veins. Traces of tetrahedrite and stibnite have been observed but tellurides have not. Gold is found principally as thin smeared flakes of the native metal in the black sulphidic septae of the strongly ribboned veins. Hydrothermal alteration envelopes around the veins grade outwards from intensely foliated quartz - ankerite - sercite (±fuchsite) to less sheared calcite - chlorite - albite to unsheared epidote -calcite.Open-space vein filling textures found in the deep (mesothermal) environment at Bralorne can be explained by a fault- valve model. High-angle reverse faults may have acted as fluid-pressure activated valves on geopressured reservoirs, causing large cyclic fluctuations in fluid pressure that promoted mineral deposition in an episodic fashion . The faults that were mineralized were reactivated sub-vertical former strike slip faults, oriented at a high angle to the northeast-directed stress in a compressive regime."

Jan 1, 1990

By S. Usui, Y. Shinohara, C. Tokoro, K. Horiuchi, S. Owada

Process optimization of heating and physical separation for Cobalt (Co) recycling from spent lithium ion battery (LIB) was investigated. LiCoO2 in spent LIB was transformed to LixCoO2 which was more easily decomposed than LiCoO2 by heating. Coexisting materials of aluminum and carbon, and sealed atmosphere of the LIB promoted LixCoO2 decomposition. In an atmosphere of Argon, 95 % of LixCoO2 in the spent LIB was decomposed to 76 % of Co oxide and 19 % of Co metal in 10 min at 823 K; a lower temperature than the theoretical value for LiCoO2. The Co oxide and Co metal exhibited magnetic properties and could be recovered by wet magnetic separation. Furthermore, slow heating was effective for grain growth of Co oxide and Co metal. At 2 K/min rate of heating, average grain size of Co oxide and Co metal were 239 µm and 28 µm respectively, whereas at 30 K/min they were 190 µm and 15 µm respectively. Therefore, separation efficiency for Co recovery by wet magnetic separation was increased when spent LIB was slowly heated at 2 K/min.

Jan 1, 2015

By G. Granata, C. Tokoro, M. Matsuoka, K. Horiuchi

"Given the high demand of copper and the lack of new high-grade deposits, low grade copper ores containing copper oxides and refractory sulfides need to be processed as well. However, in order to recover copper from refractory copper ores, the leaching performances should be improved. In this study, we investigated the effect of the mechanical activation in the leaching of copper from covellite. The influence of a mechanical treatment by planetary ball milling on leaching rate in sulfuric leaching media was evaluated by using X-ray diffraction (XRD), mineral liberation analysis (MLA) and X-ray absorption fine structure (XAFS). Results showed a significant increase in copper leaching from around 50%up to 100% along with an improvement of the leaching kinetics when using planetary ball milling. XRD spectra showed the disappearance of the covellite peak from (101) face, thus suggesting the amorphization of covellite associated with the use of planetary ball milling. XAFS results showed that the coordination number of Cu changed from 6 to 3, thereby confirming the effectiveness of the mechanochemical effect.INTRODUCTIONDuring the last decades, while the copper grade in copper ores has been decreasing, the concentration of impurities such as arsenic tends to increase, thus requiring for the processing of low grade copper ores. For a suitable processing of copper minerals, hydrometallurgical processes are preferable due to the lower costs, the lower environmental impact and the easier implementation (Watling, 2006). However, for an economical recovery of copper, the leaching performances must be improved.Among the recent advancements in leaching technologies, the mechanochemical activation allows for an improvement of the leaching performances by means of high-intensity grinding(Mohammadabad et al., 2016). In the first place, the improvement is the result of the dramatic decrease of particle size, which results in an increase of the mineral surface area and the consequent enhancement of leaching kinetics. Furthermore, the intense mechanical stress due to the high-intensity grinding could induce the rupture of the crystal structure producing a decrease of crystallinity. Such changes of the mineralogical structure, also known as mechanochemical effect, can lead to more leachable mineral, thereby resulting in a greater dissolution of copper. Last but not least, whereas the mineral surface might undergo passivation during leaching, the high-intensity grinding can continuously refresh the surface of the mineral, thus exposing portions of unleached bulk mineral."

Jan 1, 2017