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By J. Gogal

Cameco's Cigar Lake Operation (CLO) started commercial uranium ore production in 2015. Initial mining was focused in areas of the ore body with relatively low concentrations of elements of concern (EOCs). As mining progressed into areas of the ore body that were richer in EOCs, some statistically significant behavior of certain analytes was noted in the water treatment circuits. It was ultimately found that the CLO ore body natively hosts numerous alkyl arsine compounds in addition to inorganic arsenide minerals. The alkyl arsines were found to be recalcitrant to typical adsorption on ferrihydrite, with the degree of recalcitrance associated with the degree of alkylation. A number of changes to the process circuits and water balance were performed and planned in order to inhibit the transport of alkyl arsines from the ore stream into the process water stream, and to optimize the overall site water usage. In some instances, the interactions of equipment in conjoined circuits of the process had controlling effects on the behavior of the overall circuit. Work continues to iterate upon the capital design features in order to further tighten the water balance, and to optimize water usage and operating costs.

Jan 1, 2020

By José L. Carvalho

"Time-dependent swelling deformation of several shaley rock formations in Ontario is a wellknown phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. The swelling phenomenon appears to be related to ion exchange between the rock porewater and the surrounding water.The swelling potential is expressed as the percent swelling strain that occurs per log cycle of time, in either the vertical (perpendicular to bedding) or horizontal (parallel to bedding) directions. In addition, the swelling potential is also noted to be stress dependent. In practice, therefore, the conditions required for swelling are (i) the accessibility to water, and (ii) an outward salt concentration gradient from pore fluid of the rock to the ambient fluid. The relief of in-situ rock stress during excavation serves an initiating mechanism (Lo and Micic, 2010).INTRODUCTIONTime-dependent swelling deformation of several shaley rock formations in Ontario is a well-known phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. Swelling is also controlled by the inter-particle bonding; if the bond strength exceeds the osmotic pressure, swelling will not occur, and vice-versa. The bond strength can be reflected by the calcite content which forms cementation bond between rock particles."

Jan 1, 2015

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By E. Krause, V. G. Papangelakis, S. Garg, R. Mahadevan, E. Edwards

"Bioleaching uses iron and sulfur-oxidizing bacteria to extract base metals from sulfide minerals. As bioleaching involves breaking the iron-sulfur bonds by ferric attack, the biologically mediated rate of iron oxidation is recognized to play a key role in influencing the overall kinetics. In this study, we investigate the catalytic ability of an indigenous AMD culture for oxidizing Fe(II) in solution. This culture was subsequently adapted on pyrrhotite tailings (0.6% Ni) by gradually increasing the solids loading. Results from this study show that such an adaptation reduces the initial lag phase in the biotic oxidation of Fe(II), thereby allowing for a higher Ni extraction when compared to experiments with an un-adapted culture at a similar solids loading. The use of adapted cultures also helps to reduce the residence time for bioleaching of Ni from pyrrhotite tailings. INTRODUCTIONAs the world demand for pure base metals grows; the mining industry is increasingly faced with the burden of processing lower grade ores and mining waste streams in order to recover the occluded metal VALUES ((Watling, 2006). The extractive metallurgy of nickel from sulfide minerals focuses on using a combination of mineral processing, pyrometallurgical (smelting) and hydrometallurgical techniques to extract Ni from its ore bodies.Pyrrhotite (Fe1-xS) is commonly found in association with pentlandite and chalcopyrite in sulfidic Ni ores, such as those found in Sudbury, Ontario, and in Russia, e.g. Norilsk. The vast majority of this pyrrhotite needs to be removed using mineral processing techniques, in order to minimize the Fe and S contents of the concentrates that proceed on to smelting. If all pyrrhotite were left in the concentrate, much more slag and SO2 would be produced, and the smelter throughput would be limited. Beneficiation of Ni sulfide ores leads to the rejection of unwanted constituents as mining wastes, which may still contain extractable amounts of Ni (Edgar Peek et al., 2010)."

Jan 1, 2012

By G. Deschênes

"In 2013, as the prices of precious metals dropped, investors moved their positions to equity markets for higher returns. As a result, the price of gold dropped further to below US$1200 per ounce, prompting additional substantial outflows from gold investments. In response to lagging gold prices, major gold producers initiated large asset write-downs and cost-cutting programmes. In 2015, this trend continues and gold mining stocks are close to lows not seen since the global financial crisis (GFC) of 2008. In the current economic climate many projects have marginal economics, and the number of projects that have competitive development and production costs is declining. A competitive edge is particularly important with the decreasing grades of orebodies, increasing complexity of the mineralogy, and increasingly demanding environmental constraints. In addition, higher cost producers seek to optimize their process t o reduce operating costs.This paper presents some highlights of three case studies on optimization of gold leaching strategies that improved the economics of brownfield projects. Processing of sulphide-bearing ores was optimized by using the synergy between cyanide, lead nitrate, and oxygen. The outcomes were significant reduction of retention times while maintaining or increasing gold extraction and reducing cyanide addition and effluent treatment costs. A stirred tank reactor experimental programme led to direct implementation of reliable leaching strategies from laboratory scale to production. This approach resulted in savings of $2.2 million to $15.2 million on the three brownfield projects discussed in this paper."

Jan 1, 2016

By K. Esmaieli

ABSTRACT We conducted a series of numerical experiments to investigate the influence of rock mass foliation on impact-induced damage on ore pass walls. The 2D Particle Flow Code was used to simulate three distinct rock masses surrounding an ore pass, characterized by foliation angles of 60°, 90°, and 120° (clockwise from horizontal). Subsequently, we projected a rock fragment against the ore pass walls at a constant impact angle and velocity. The resulting damage increase

Jan 1, 2014

By Edouard Asselin, Tasawar Javed

This study was conducted as a part of ongoing work to characterize sulphide concentrate leach residues generated under CESL (Cominco Engineering Services Limited) and Vale pilot and demonstration plant medium temperature (150 °C) process conditions. Three different samples were analyzed. Derivative samples were prepared by extracting gypsum, sulphur and amorphous/poorly crystalline iron oxyhydroxide phases from the leach residues. Thermal behavior of the samples was studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) in the temperature range 25 to 800 °C in both air and nitrogen atmospheres, with XRD analyses both before and after heating. Thermal transformation temperatures for different iron oxides/oxyhydroxides present in hydrometallurgical leach residues vary over a wide range which suggests the variable crystallinity of the phases. Raman spectroscopic analysis was carried out to help identify the type of iron phases in the residues. Furthermore, hydroxylamine hydrochloride (HaHC) and oxalate extractions were used to compare the fractionation of the amorphous/poorly crystalline iron phases in the residues. Given the compositions of the residues, any thermal events in the temperature range of 200 °C to 480 °C were attributed to amorphous/poorly crystalline iron phases.

Jan 1, 2014

By J. B. Hamilton

The advantages of generating and distributing electrical energy direct from the coal-fields so closely affects the mining industry that a few remarks on the unbalanced phases of coal distribution is worthy of attention. The value of coal imported into Canada from 1912 to 1921 exceeded the sum of $580,000,000. In 1922 Ontario imported 1,640,000 tons of anthracite and 9,440,000 tons of bituminous coal. I submit that the use of Saskatchewan lignite in an electrical super-power plant equipped for the carbonizing of coal, and disposal of excess gases would be the commencement of a solution of the fuel shortage in Ontario. As Saskatchewan becomes more and more populated and manufacturing increases, the amount of by-product carbonized fuel available for shipment to Ontario will increase, and its shipment to that province would decrease the trade deficit of the national balance sheet. If and when this is carried out it will mean a better and wider market for Alberta fuels in Saskatchewan and Manitoba.

Jan 1, 1924

By J. M. Cummings

The importance of controlled sand properties to the production of quality castings has been recognized by foundry men for many years, but the maintenance of requisite standards results in a relatively high sand consumption, which in steel foundries, for instance, may range from half a ton to over one ton of sand per ton of finished casting. During the war, obtaining and maintaining adequate sand supplies became a serious problem in many foundries, owing to increased wartime production and serious 'bottlenecks' in transportation. As a result, considerable interest was aroused in the possibilities of various sand reclamation systems by which up to 85 or 90 percent of discarded sand may be returned to a usable condition. During the past five years or so, a number of sand recovery installations have been made by both ferrous and non-ferrous foundries in Canada and the United States, and have resulted in substantial reductions in sand costs in every case. The possible benefits of sand reclamation are particularly apparent in British Columbia where no suitable sands for steel and heavy iron foundries occur naturally, and where freight costs on imported sands are considerably higher than initial selling prices. This is well illustrated by the fact that silica sand, which sells for about $2.00 per ton at pits in Illinois, is laid clown in British Columbia for around $11.00 or $12.00 per ton. The operating costs quoted for certain of the reclamation schemes, i.e. $0.25 to $1.50 per ton, may actually be no higher than the cost of waste sand disposal in city-located foundries. In view of the foregoing considerations, the British Columbia Research Council has undertaken a study of the possibilities for sand reclamation, with particular attention directed to its application in local steel foundries. No commercial occurrences of silica sand are known in the Province, and, with this in view, the Council previously investigated the possibility of recovering silica sand from local impure sands. Results were definitely encouraging, but it was felt that the present market is too small to permit economical production by the method developed.

Jan 1, 1947

By Reinis Sipols

AGENDA ? Introduction ? Definitions and Key features ? PEA - Preliminary Economic Assessments ? PFS ? Preliminary Fesibility Studies ? FS ? Feasibility Studies ? Costs and Risks ? Cash Flow, Economic Analysis and Reporting ? Recommendations for Improved FS accuracy INTRODUCTION ? The reporting of material information on mineral deposits has been governed by NI 43-101 legislation for almost a decade. ? The investment sector depends on the independent, professional QP to provide objective observations, comments and recommendations through all levels of geological, engineering and financial evaluation until a mine construction decision has been made.

May 1, 2013

By Åke C. Rasmuson, Mahmood Alemrajabi, Kerstin M. Forsberg, Kivanc Korkmaz

"In the present study the recovery of a Panasonic Prismatic Module 6.5 Ah NiMH 7.2 V plastic casing hybrid electric vehicle (HEV) battery was investigated, separately processing the anode and cathode electrodes. The composition of the electrode materials was determined by total dissolution and analysis using ICP-OES. Nickel is the dominant metal in the active materials (65% by mass in the anode and 70% by mass in the cathode). Most of the rare earth elements (La, Ce, Nd, Pr and Y) are located in the anode active material, whereas only a small amount of Y is found in the cathode material. The electrode materials were further characterized by SEM-EDS and powder XRD. The electrodes were leached in sulfuric acid and in hydrochloric acid under different conditions. The dissolution was followed by taking out samples and analyzing the concentration of REE, Co, and Ni using ICP-OES. The results indicate that the dissolution of nickel could be limited by slow dissolution kinetics of nickel oxide. Further, it was found that light rare earths are lost through precipitation during sulfuric acid leaching with increasing extent as the temperature and sulfuric acid concentration increases. The separation of REE from the sulfuric acid leach liquor by precipitation as NaREE(SO4)2.H2O and from the hydrochloric acid leach solution as REE2(C2O4)3.xH2O have been studied by performing experiments using battery leach liquors. INTRODUCTIONIt is well known that the Hybrid Electric Vehicle (HEV) is becoming more common due to economic and environmental reasons. Batteries are widely used in HEVs’ such as automobiles or larger trucks for transportation purposes. The most common type of battery in these vehicles is nickel metal hydride (NiMH), largely due to Toyota's decision to use them in their popular Prius. More than two million hybrid cars worldwide are running with NiMH batteries, such as the Prius, Lexus (Toyota), Civic, Insight (Honda), and Fusion (Ford). Panasonic manufactures HEV prismatic NiMH batteries that have been used by Toyota and GM (among others), while Sanyo manufactures HEV cylindrical cell NiMH batteries, which have been used by Honda and Ford."

Jan 1, 2016

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012

By D. Auerswald, M. Kotze, V. Yahorava, T. Udayar

Uranium can be recovered from lower grade uranium ores (<800 mg/kg U3O8), leach residues, and waste dumps cost-effectively via resin-in-pulp (RIP). Using this technology, no solid/liquid separation or washing of the leach residues are required. Furthermore, the uranium recovery can be higher than with conventional methods. RIP technologies have, however, been perceived negatively due to concerns around potential resin fouling and losses. This paper highlights the advancements made in RIP and discusses a number of potential applications where the technology could deliver economic and consequential environmental benefits by reducing the uranium levels in the waste.

Jan 1, 2014

By C. Allen, V. Hensel, J. S. Stachulak

"Vale has been actively evaluating new technologies to curtail diesel emissions. This paper discusses the selection, installation, operation, and evaluation of the MANN+HUMMEL SMF®-AR diesel particulate filter system to reduce diesel particulate matter emissions in underground mines. The system uses a sintered metal filter element, an iron fuel-borne catalyst with an onboard dosing system, an electric heater that uses onboard power, and a sensor-based control unit. More than 6,000 h of testing demonstrated that the system represents a breakthrough in the successful control of soot emission from light-duty vehicles with differing soot emission levels, exhaust temperatures, and duty cycles.RÉSUMÉ La compagnie Vale évalue activement de nouvelles technologies pour réduire les émissions de diesel. Le présent article discute du choix, de l’installation, du fonctionnement et de l’évaluation du système MANN+HUMMEL SMFMD-AR de filtrage des particules de diesel pour réduire les émissions de particules de diesel dans les mines souterraines. Le système utilise un élément filtrant en métal fritté, un catalyseur à base de fer dans le carburant avec un système de dosage intégré, un élément de chauffage électrique qui utilise l’alimentation incorporée et une unité de contrôle avec un capteur. Plus de 6 000 heures d’essais ont démontré que le système représente une avancée pour réussir à contrôler les émissions de suie des véhicules légers avec différents niveaux d’émission de suie, différentes températures d’échappement et différents cycles opératoires."

Jan 1, 2015

By Robin E. Goad

?Located 160 Km northwest of Yellowknife, NWT, Canada Current winter road access ?New all-weather road planned ?Power within 22 km ?Hwy to Edmonton 80 km south Close to existing infrastructure

May 1, 2006

By L. Yacher

Most metallurgical plants already have sophisticated control systems as well as a process-historian that manage thousands of real-time and historical variables. There exists a huge potential for operational improvement through the inference of patterns, correlations and cause-effect relationships within these records. The ability to run online and offline advanced multivariate statistical analyses represents a great potential for the mining industry, in various areas such as cathode quality improvement in an SX/EX plant, the analysis of the correlation between the ore characteristics and the mill throughput, the determination of early failure alerts for major equipment, etc. The background theory is described, as well as some practical experiences of operations in Chile and Peru. Cu2007

Jan 1, 2007

By V. G. Papangelakis, G. A. Moldoveanu

"Rare earths adsorbed on clay minerals are easily recovered via ion exchange during leaching with inorganic monovalent salt solutions. The leaching efficiency of various salts at 0.5M and 25°C was investigated as a function of cation type and salt system (sulphates vs. chlorides). (NH4)2SO4 was identified as the lixiviant of choice and a procedure was established to investigate the influence of lixiviant concentration, temperature, pH and agitation on desorption kinetics and REE extraction levels. It was determined that the kinetics were fast and the optimum leaching conditions (for >80% total REE extraction) required pH below 5 and moderate temperatures (<50°C). INTRODUCTIONRare earth elements (REE) are at the core of numerous advanced applications due to their various uses in high strength permanent magnets, lasers, automotive catalytic converters, fiber optics/superconductors, and electronic devices (as phosphors in TVs and display screens for computers and cell phones). Because of the ongoing development of new technologies, there is an increased demand for REE in the international market, with emphasis on identifying new resources to insure an adequate supply for present and future use. World production of rare earths is dominated by China, the United States and Australia; however, in terms of resources, China dominates the world potential with reserves estimated to be over 90% of the total (Chen, 2011).The main commercially significant REE sources, as reviewed by O’Driscoll (1991) are bastnasite (carbonate) and monazite (phosphate) minerals, containing up to 70% wt. rare earth oxides (REO). In spite of being high grade, these ores are associated with elevated recovery costs due to difficulty in mining, separation and beneficiation. Moreover, aggressive conditions are required to solubilize the REE from the mineral, such as leaching with hot, concentrated acids or baking in 70% NaOH (Gupta & Krishnamurti, 2005)."

Jan 1, 2012

By L. M. Wang, G. P. Jiang, Y. Jiang, Liao. W. S.

ABSTRACT The authors measured porosities and permeabilities for cores from a low-permeability sandstone uranium deposit in Inner Mongolia. Features studied included fine pore structure, mineral composition, cation exchange capacity, granule appearance, and cementing features. In general, grading of the grains was relatively poor, which decreased the radii of the pore channels. The pore throat distribution was significantly heterogeneous. Pore channels ranged from small to large, but the lack of large pore channels led to low permeability. Cementation by calcite and clays, including montmorillonite, chlorite, and kaolinite, resulted in pore channel narrowing, further decreasing the permeability of the formation.

Jan 1, 2014

By J. G. Cullain

Inco Limited is an integrated mining, smelting, refining and manufacturing company with operations located worldwide. The Ontario Division operations consist of 13 mines and 10 processing facilities located in Sudbury, Port Colborne and Shebandowan. The scope of our utilization of energy in the Ontario Division in 1976 included in excess of 2.2 billion kilowatt hours of electric power, 12 billion cubic feet of natural gas, 60 million Imperial gallons of residual oil and smaller quantities of other fuels. In addition to the primary energy consumption, waste-heat energy is recovered in various operations throughout the Division, thereby reducing our primary energy requirements. Total expenditures for primary energy alone in 1976 exceeded 60 million dollars. Energy management studies were initiated by Inco&apos;s Utilities Department in late 1972, and resulted initially in a program of electric power cost reduction. This program produced significant results by improving the use of the water available for our hydraulic generation facilities and by a comprehensive peak reduction program. Our experience showed that a program of peak power control creates an awareness of both peak and energy costs, and thereby encourages a general reduction in the electric energy consumption as well as lowering the peak demand. Energy management is a continuing program at Inco and, recently, a formal energy management policy and program was instituted. Energy management committees were formed in each plant or mine area to identify the major areas for energy; consumption, thereby isolating areas with large potential energy losses, and determining immediate action which will improve the energy efficiency or reduce the energy waste within their respective areas. A decentralized program with good cross-communication between all committees was felt to be the best method of providing an on-going effective energy management program. In the future, the projections of dwindling fossil-fuel supplies in Canada and the resultant spiralling energy costs will further emphasize the need of sound energy management practices for all Canadian industry.

Jan 1, 1977

By Victor F. Hollister, Robert W. Hodder

"The petrology and mineralogy of porphyry copper deposits are thoroughly described in recent literature and cited as the definitive characteristics for this type of deposit. The magmatic-hydrothermal aspect of genesis is also dealt with in detail. However, descriptions of their internal structure and regional setting are not as rigorous, and the genesis of this structure is simply stated as the release of high fluid pressures in a cooling magma emplaced along large fault zones. Genetic relationships between internal structure, regional setting and the tectonic evolution of continents has been alluded to infrequently in the past, but can now be considered together within the developing concept of orogeny at the margins of drifting crustal plates.Tensional structures, on both local and regional scale, and a Triassic to Tertiary age are described for porphyry copper deposits. We contend that such structure and age are distinct and unifying characteristics for this type of deposit and are genetically related to major crustal movements. British Columbia has porphyry copper deposits contemporaneous with plutons 180 to 200 million years old and 40 to 60 million years old. The former age group correlates with early stages of the continent's westward drift, and the latter group with a change in tectonic style during late development of the Canadian Cordillera. Hence, one can in British Columbia reflect on the genesis of a deposit's structure in the broader context of tectonic evolution. Such consideration should lead to more definitive criteria for area selection in exploration."

Jan 1, 1972