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By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Dialkyl dithiophosphinates are a unique class of collectors used in the flotation processing of Cu- Au, complex polymetallic, and precious metal ores. They are known to exhibit higher selectivity and flotation rates for Cu sulfides, galena, and precious metal values in the presence of other gangue sulfides, than the traditionally used collectors such as dialkyl dithiophosphates and xanthates. They also have an attractive HSE profile. Historically, for most reagents used in flotation, practical methods of chemical usage have preceded detailed scientific understanding of how they work; this applies also to dithiophosphinates. Recently, however, the research community has shown significant interest in this chemistry, and numerous studies have been conducted to understand the fundamentals of interactions of dithiophosphinates with several base metal sulfides and precious metals. A critical overview of fundamental studies, laboratory ore flotation, and plant practice of dithiophosphinates is given in this paper. The findings from these studies are rationalized by drawing on concepts and insights from coordination chemistry. A comparison between the interactions of dithiophosphinates and dithiophosphate analogues with various minerals and metals is also made throughout. We believe that such a critical analysis/overview will be invaluable in identifying gaps in knowledge regarding this important set of compounds, which in turn may provide a basis for the design of studies that can advance understanding of their flotation performance. INTRODUCTIONDialkyl dithiophosphinates are an important member of the class of thiophosphorus compounds that are widely used in flotation beneficiation of base metal sulfide and precious metals ores. Ore flotation studies and plant practice experience have demonstrated their unique properties compared to the traditionally used sulfide collectors such as dialkyl dithiophosphates (their closest analogues) and xanthates. The predominant dialkyl dithiophosphinate used in the industry today is sodium diisobutyl dithiophosphinate (a.k.a. DIBDTPi; AEROPHINE® 3418A1 introduced by American Cyanamid in the late 1970s; Figure 1). The widest application of AEROPHINE 3418A is found in complex polymetallic ores of Cu-Pb-Zn-Ag, Pb-Zn-Ag, and Cu-Zn where it has demonstrated improved recoveries (and flotation rates) of sulfide minerals of Cu, Pb and Ag and selectivity against sphalerite, iron sulfides, and penalty elements (Mingione, 1991). More recently, it has also been used as a collector in the processing of Cu, Cu-Ni, and Ni ores (Guitard et al., 2015) and Cu-Au ores (Dunne, 2005). In general, it is considered to possess the collecting power of xanthates together with the selectivity (against pyrite) of dithiophosphates (Hope et al., 2003a, 2003b), while requiring lower dosages than those reagents (Guitard et al., 2015). AEROPHINE® 3418A has also found an important place in several targeted formulations to improve flotation performance. Other benefits of this reagent include higher flotation rates, having a better HSE (health, safety and environmental) profile2 compared to xanthate, and exhibiting resistance to hydrolysis and oxidation (Guitard et al., 2015). Compared to diisobutyl dithiophosphate (DIBDTP), which is known to contribute significantly to frothing (often leading to over-frothing), AEROPHINE® 3418A is observed to be froth neutral (i.e. it does not alter the existing froth characteristics). As is the case for other flotation reagents, the design and application of AEROPHINE® 3418A has preceded understanding of its behavior at a fundamental level. Recently, there have been numerous fundamental and application studies designed to develop a better understanding of its interaction with sulfide minerals and precious metals. This should help in optimizing its application in flotation and provide a basis to better rationalize its unique selectivity and activity characteristics. Past studies on the interacti"

Jan 1, 2016

By L. Cifuentes, J. M. Casas

The treatment of aqueous CuSO4-H2SO4- As-Sb solutions by electrodialysis in order to separate and concentrate species of interest has recently been studied. Results show that it is possible to separate copper from arsenic in electrodialysis cells. The separation of copper from antimony is also possible. Transport rate ranges that could be achieved, depending on experimental conditions, are 0.2 to 0.6 mol per hour per square metre of membrane for copper, 0.65 to 2.8 for sulphate, and 0.016 to 0.03 for arsenic. Transport rates for antimony were inconclusive due to its very low solubility in the studied systems. Solution agitation and increasing temperature markedly increased the process rates. Advancements in this area require further work in both the thermodynamics (speciation) and kinetics of complex CuSO4- H2SO4-H2O systems, where impurities, other than As and Sb, and additives should be taken into account to gain a deeper understanding of the application of ED to copper electrorefining electrolytes

Jan 1, 2004

By E. Swartzman

"IntroductionGENERALLY, the necessity for mining coals of higher impurity content, the drive for lower costs by intensive mine mechanization, changing market requirements, and the increasing competition of oil and natural gas, have continued to result in an upward rise in coal preparation, and have necessitated a more intensive study of coal preparation problems.Increasing adoption of •continuous mining equipment, for example, is introducing new problems in coal preparation. Limited experimental work in the United States (1) shows that the effect of the continuous miner on size distribution varies with the characteristics of the seam. In some seams, the fines problem is lessened, in others it is greatly aggravated. Generally there is a decrease in the relative amount of the top sizes (plus 2 in.) and a substantial increase in the intermediate sizes (down to about 1/8 in.). Contrary to expected results•, where continuous miners with vertical-moving cutting heads are used, an increase in impurities in the slack sizes does not necessarily occur where draw-slate is taken. This is because the draw-slate tends to be kicked out in lump form. However, if a seam contains bands •and lenses of impurities they are bound to be in the mined product."

Jan 1, 1952

By G. Plascencia, C. López, J. González, D. Jaramillo, M. A. Barrón

Air jet and molten matte interaction within a Peirce - Smith converter is analyzed during the first stages of blowing using Computational Fluid Dynamics (CFD), by means of the Large Eddy Simulation and Reynolds Stress turbulence models. Jet velocities ranging from 5 to 150 mis, which involve the bubbling and open jet regimes, were considered in 2 and in 3-D numerical simulations. As a result of the computer simulations, it was found that low velocities results in gas bubbling in the molten copper, whereas higher gas velocities results in well defined plumes. The consequence of such different behaviours results in an increment in the rate of refractory wear or in copper splashing respectively. The analysis of the results may lead to improve the design of the tuyeres currently used in copper converting. Bottom blowing of air is also explored in this work. Numerical results show a strong non-linear parabolic behaviour of the jet velocity on the average velocity of copper; which means that beyond certain jet velocity, the copper de-accelerates thus reducing its velocity. This may be due to the open nature of the jet, which prevents the momentum transfer from the injected gas to the molten copper.

Jan 1, 2007

By Vanessa C. Koppe

During ore body modeling normally additional samples are required to improve resources evaluation and mining planning. At this stage one rises the question about where additional samples should be located. Regular sampling pattern seems to be a reasonable choice, since all the regions within the deposit receive the same number of samples without a clear clustering. Nevertheless, values for certain attributes (grades for instance) from a mineral deposits may behave more erratic in some regions than others. Consequently, by adding samples to these regions could bring more benefit for reducing the uncertainty related to a transfer function such as Net Present Value (NPV), instead of adding samples to location of low grade uncertainty. Thus, for a given number of additional data, the test of a regular pattern and a pattern which add samples on areas of high uncertainty of the attribute of interest is worth. This paper presents an algorithm that allows the construction of these two patterns, automatically, on a software commonly used in the mining industry. The algorithm leads to a fast analysis on the efficiency of the two patterns in reducing the uncertainty associated with a transfer function.

Oct 1, 2009

By R. J. Munday

Although uranium deposits in northern Saskatchewan are clustered around the Athabasca basin, basement lithostructure determines their distribution. Basal Wollaston Group pelites are invariably graphitic and carry uraninite in felsic segregations and biotitic pegmatite. Where these intersect the Athabasca Formation, remobilized uranium concentrated as pitchblende. Uranium is also concentrated in silicified and hematized sandstone where the Athabasca Formation overlies post-orogenic faults. Presumably, pregnant solutions associated with the fault were stripped of their metals as they emerged into the contrasting physico-chemical environment of the sandstone basin. Both these types of mineralization correlate with a Grenvillian (-1,000 m.y.) heating event and associated diabase intrusions. However, the rich pitchblende veins at Uranium City appear to predate the Athabasca Formation, but display spatial correlation with the Martin Formation. They are tentatively associated with a syn- to post-D3 retrograde metamorphic event which thoroughly leached crystalline basement and generated uraniferous fluids which escaped, and precipitated metals, into fractures associated with faults that define the grabens in which the Martin Formation was deposited. Remobilization events allowed some of this uranium to move upward into fractures within Martin sediments.

Jan 1, 1979

By J. A. Haskin

The Engineering Department at Flin Flon has the following responsibilities: 1. Underground Surveying. 2. Open-Pit Surveying and Supervision of Blasting. 3. Mine Geology and Examination of Prospects. 4. Design of Plant Additions and Improvements. 5. Miscellaneous Field W ork, Reports, etc. The entire surface plant, as well as the underground workings, are located by co-ordinates based on a triangulation system covering an area approximately one mile long by one-half mile wide. The origin of this system and one end of the base-line is the southwest corner of Township 67, Range 29, west of the Principal Meridian. The bearing of the base-line was determined from the township boundary, which runs true north, so that all other bearings are almost astronomical. This is a great convenience when our surveys must be tied to mineral claims, rights-of-way, and land subdivisions. As the base-line extends across Flin Flon lake, its measurement across smooth ice was simple and accurate. The length, slightly over 1,600 feet, has been adjusted for the temperature and tension of the standard tapes used and checked sufficiently to ensure a maximum error of 1 : 15,000. Each angle was repeated ten times, but as no special refinements were used, errors of as much as four or five seconds are possible. The elevation of the origin of the triangulation system was approximately 1,050 feet above sea level. The use of this true elevation in our surveys would have resulted in negative elevations underground as soon as the mine reached a depth greater than 1,050 feet. To avoid this complication we therefore added 4,000 feet to this elevation. The collar of the Main shaft, for example, which is actually 1,072 feet above sea level, appears in our records as at elevation 5,072. Underground surveying, which follows standard practice, is done by two mine surveyors who share three helpers. The meridian is taken underground from two wires hung in either of the two vertical shafts.

Jan 1, 1935

By R. J. Traill

Introduction Following the discovery of high-grade deposits of pitchblende in the Great Bear Lake area of the Northwest Territories by Mr. Gilbert LaBine in May, 1930, samples were submitted to the Mines Branch for examination and investigation as to suitable methods of treatment (1). The purpose of this paper is to present, briefly, the results of the investigative work conducted on the ores and an outline of the methods developed for the extraction of the radium content and recovery of the by-products. The paper is presented in two parts. Part I gives a review of the history of radium production and of the principal processes used in other countries. Part II describes the work and gives the results of the Mines Branch investigation. Part 1-Radium Production In Other Countries Historical Outline Uranium was discovered in 1789, and more than a century later Madame Curie, while studying the physical properties of this element, observed that the ore of uranium exhibited greater activity than the pure uranium com-pounds she had prepared and traced the cause to the presence of a new element which she named radium. Eventually, research proved radium to be a disintegration product of uranium, and always present in uranium ores.

Jan 1, 1933

By Richard Jundis

At the Vale Inco Ontario Operations, the working environment is rapidly evolving with organizational changes, new business systems and software tools. These changes are required in order to meet today?s challenging business environment. Mining professionals are focusing on the development of safe and achievable mine plans to maximize mining value while reducing the potential of project delays and production shortfalls. This paper explores how new design tools, techniques and system designs in mine planning are being developed to optimize the value of every ton of ore mined and processed. To differentiate from other papers on long-term planning, this paper focuses on the concept of business planning at the mines. Business planning is the understanding and optimization of the relationship between mine plans and the value it adds in the overall process. The management and key stakeholders of Vale Inco have recognized that the development of a robust mine planning system and programs are essential for the long-term sustainability of the operations.

May 1, 2009

By F. H. Hueston, R. S. Barclay

"Depending on the application, zirconia, fused magnesia and graphite have been found to be the most suitable crucible materials for melting uranium metal and its alloys. Although graphite has been found to be satisfactory for uranium and uranium alloy castings with cross sections of 4 square inches or greater, ceramic-type molds are superior for small sections and those shaped castings which prohibit the economic use of machined graphite molds. Heating cycles, addition mechanisms and furnace conditions for melting are discussed."

Jan 1, 1967

By Galen Bauer

"Up until the mid 1960's, the only available methods for making continuous weight measurements were through the use of mechanical and electro-mechanical weigh scales. It was during this time period that a new concept in weighing was introduced. It was known and is still known as the nuclear belt weigh scale.During the early days of its appearance in the market place, many things were learned about its advantages and disadvantages for weighing various materials. As with many new devices, it had to go through a ""wringing out stage"" before it became accepted by the weighing industry. Even today, even though it is a proven device, there are skeptics who believe the nuclear belt weigh scale will not survive. Let me assure you, it is here to stay.. 'PRINCIPLE OF MEASUREMENTThe nuclear belt weigh scale consists of a ""C"" Frame assembly which houses the radioactive source (Cesiwn 137) and the radiation detector (Ionization chamber). The ""C"" Frame assembly is put in place around the conveyor belt as shown in Figure 1. The radiation source emits a fan shaped beam of radiation which covers the full width of the material being conveyed on the belt. Radiation which has passed through the material on the belt is detected by the ionization chamber which is located in the lower arm of the ""C"" Frame assembly. The ionization chamber changes the radiation energy into an electrical signal which is related to pounds per foot belt loading. This signal is transmitted to a highly stable amplifier which combines the pounds per foot signal with a belt travel signal from a digital tachometer which allowed the scale user to be able to monitor total mass being conveyed. Many so-called conventional type scales use belt speed rather than travel to obtain mass per unit time, and then integrate the signal to obtain their weight signal. This unnecessary step tends to erode the overall accuracy of the weighing system."

Jan 1, 1975

By Eduardo A. Pérez, Alejandro R. Alonso, Rosa María Luna-Sánchez, Gretchen T. Lapidus

Rare earth elements have been widely used in various sectors, from the aerospace and steel industries, to electronic applications, particularly in displays and batteries for portable devices. The high demand for newer and better equipment, such as cell phones, tablets and lap tops, has increased the consumption of the rare earth elements and at the same time the need for its recovery from electronic wastes. For that reason, the recycling of batteries is important, principally the Ni-HM batteries, due to their elevated content of rare earths elements, in addition to the high concentrations of cobalt and nickel. The current processes are based on dissolution in strong acid solutions (sulfuric acid concentrations from 2 to 4 mol/L), and temperatures from 30 to 90°C. In the present work, electrodes from spent Ni-HM batteries were leached using 1 mol/L H2SO4, in the presence of ozone as the oxidant, where recoveries of 96% for La, Ce and Nd were obtained at room temperature. The separation of Ni and Co from the leach solutions was performed using an electrochemical reactor, after which rare earth elements were precipitated, obtaining a mixture of its hydroxides with impurities below 1%, according to EDS analysis.

Jan 1, 2014

By A. J. Paul Laprairie

"ADVANCE planning of mining methods, from the first development openings to stope layout and pillar recovery, has long been accepted as a normal method of operating a mine. Recently, mine managers have become increasingly aware that advance planning of cost and accounting controls can also be considered a normal method of operation. The use of such controls is wide-spread in manufacturing industries. In mining, the gold mines of South Africa have pioneered, with marked success, in this field and have been closely associated with most of the research and field work in accounting control. Canadian mine managers are also beginning to realize the advantages of using planned costs. The control procedures which subsequently have been introduced at various mines have come to be known by such names as ""Responsibility Costing"" or Budgetary Control"".Budgetary control, the term used in this paper, is based on the concept of decentralized authority with centralized control. ;The control is achieved by measuring results against yardsticks which are in the form of budgets or standards. Bud-gets are made for the future activities of each possible operation as planned by the department head, and attention is directed to variations from this plan. Furthermore, the control process charges to each operation only those costs which are incurred directly for that operation, and which can be controlled by the person in charge. Thus, budgetary control relates results to the officials responsible for those results. Expenditures are analyzed according to the organizational structure of the mine and the people who run it, and not according to production processes."

Jan 1, 1960

By M. Kolahdoozan, H. Noori

"Molybdenite flotation at the Sarcheshmeh Copper Complex has been studied as a function of pulp potential controlled using two types of sodium sulfide (mineral and chemical origin). Air and either plant or laboratory nitrogen was used as a flotation carrier. Potential measurements were taken in the rougher cells as it was proved to be vital for molybdenite flotation. Flotation test with reducing potentials between -525 and -575 mv gave the highest molybdenum recovery (93%) and the lowest copper recovery of between 4 to 15% can be achieved. These potentials did not change considerably by adding increasing amounts of sodium sulfide. At more oxidizing potentials, i.e. more than -450 mv, the recovery of copper increases while the recovery of Molybdenite drops.INTRODUCTIONThe average copper ore feed grade to the Sarcheshmeh flotation circuit is typically set at about 1.2% Cu. to be delivered to processing unit is set at 1.2%. There is no control of molybdenum (Mo) which usually varies between 0.01 and 0.04%. During concentration, a Cu-Mo concentrate is produced by one stage of roughing, one stage of scavenging and two stages of cleaning. Final concentrate contains 0.5% of Mo and 32% of Cu while the particle size is 90% under 42 microns (325 mesh). Because of the high grade of Mo in this concentrate and economic interests, a molybdenite flotation circuit plant was built in 1984. This plant was designed to treat 1432 tons of Cu-Mo concentrate (on dry basis) and consists of one stage of roughing followed by seven stages of cleaning. After dewatering the concentrate contains 53.7% Mo which is dried and shipped overseas.The majority of molybdenite production worldwide comes as byproduct of copper porphyry ores. The Mo grade typically varies between 0.01 and 0.06% and accompanies chalcopyrite and chalcocite. Due to the hydrophobic nature of molybdenite, it can be floated along with copper sulfides. Thus the overall concentrate of Cu and Mo contains 0.2-1% of molybdenum as well as 20-42% of copper. To separate the Mo, Cu and Fe minerals, depressants are used. The most important of which are sodium sulfide, sodium hydrosulfide, Anomal D, sodium cyanide, ferropottasium and ferro-cyanide. The first three regeants have been extensively used for successfully treating porphyry ores [1]. In the molybdenum plant of the Sarcheshmeh Copper Complex only sodium sulfide has been used to date."

Jan 1, 2006

While this paper is directed towards the ?Bellambie? type of rope attachment, the principles can be applied to any brand of rope fitting however, it is a only a broad outline and the specific installation and maintenance procedures can be obtained from the attachment supplier. The types of attachment to be discussed are:- ?Thimble Type rope cappel ?Wedge Type cappel ?WRC Rope Clamp ? (Rope Glands) ??Hoist and Balance Rope Sockets In each case, the assembly and stripping (disassembly) plus the basic maintenance procedures is briefly described. A guide for Risk Assessment is also included but because of his familiarity with the installation, the end-user is in the best position to draft the final version.

May 1, 2003

By M. Fan, H. E. Wyslouzil, J. Kohmeunch

Eriez HydroFloat(TM) separators and Canadian Process Technologies (CPT) flotation columns have been developed to overcome the limitations of traditional flotation cells in recovering coarse and fine particles, respectively. The flotation column can effectively separate 30-5 µm phosphate. Several industrial-scale HydroFloat separators have been installed in phosphate and potash beneficiation plants. Industrial-scale ultra-coarse (+850 µm) phosphate separation results suggest that a more-than 40% BonePhosphate- of-Lime (BPL) recovery increase and a 37% collector consumption reduction can be achieved. The paper describes the applications of Eriez HydroFloat separators to coarse particle separation and the CPT flotation column to fine/ultrafine particle flotation.

Jan 1, 2009

By T. G. Joseph, K. Barron

A strain-softening constitutive relationship is introduced that describes the post-failure stress-strain curve for rock regardless of whether the rock is intact or broken. The core of this relationship is an “apparent friction” concept that relates the post-failure apparent cohesive and frictional characteristics of the rock to the strain. The relationship can be determined for a given rock via a series of triaxial strength tests establishing the peak strength and corresponding strain for a range of confining pressures, together with the determination of the base angle of friction via a simple tilt test. The postulates and assumptions used in deriving this relationship are verified from results of tri-axial tests on both intact and broken rock. This strain-softening relationship is then applied to coal. Having determined the post-failure stress-strain curve for coal specimens, this information can then be used in a finite element program, such as Phase 2, to examine the post-failure characteristics of coal pillars. Using example data, the strength of coal pillars of different width/height ratios are estimated and compared with well-known empirical pillar size-strength relationships. In addition, the post-failure stress-strain behaviour of a coal pillar is compared with an empirical relationship reported in the literature.

Jan 1, 2003

By R. Hamilton

"Louvicourt mine began operation in 1994. It is located in northwestern Quebec, 20 km east of Val d’Or. The mine is owned by Aur Resources (30%), which operates the mine, Teck/Cominco (25%) and Novicourt (45%). By the end of 2002 there were approximately 280 employees working on the site, including contractors. Production averages 4300 tons per day, working a massive sulphide body located between 415 m and 920 m underground.Maintenance expenses represent 27% to 29% of the operating costs, and the maintenance personnel represents 34% of the total workforce (including electrical, mechanical and concentrator maintenance staff). Considering these figures, in addition to capital costs and indirect costs, such as energy (electricity, fuel, gas, etc.), it is worthwhile to pay attention to how things are done in order to protect such investment. Every task performed to help understand the impact of Louvicourt’s practices must to be seen as an investment in the reliability of its operation."

Jan 1, 2003

By Terry Braden

"Meeting probable world mineral demand in the years ahead will almost certainly require an ability to economically treat lower grade and more complex ores. Achieving this will require extensive research and technical development across the full spectrum of mineral processing.For mid-sized or smaller companies the most effective way to participate in such extensive programs - and gain access to the technology required to stay competitive - may be through collaborative research.This paper explores the recent history of collaborative research in mineral processing and in particular its ability to attract world-class multi-institutional research teams with sufficient resources to make step-change advances. It chronicles the advances achieved, but also explores the research architecture and administrative structures required to deliver research outcomes and technology transfer mechanisms to a range of often disparate sponsoring companies.INTRODUCTIONIn medieval times the dream of alchemists was to turn base metals into gold. We modern alchemists, of course, don’t waste our time on that sort of foolishness: we turn base metals into dollars. When I see the profit reports filed by some companies recently, I can only conclude that a lot of those present today must be pretty good at this.But the fact that we are here at this conference reminds us that an alchemist’s work is never done; turning base metals into dollars is not a one-trick wonder but an art that we must extensively refine year after year if we are to survive in a competitive marketplace.It is not that demand for metals is likely to slow; most people seem to think that China, India, Brazil and other emerging economies are still at the lower end of their demand curve. They will need significantly larger volumes of metals in the years ahead. The challenge for us as processors is that to supply increasing tonnages of those metals profitably we will almost certainly need to process more complex or lower grade ores and probably to do so with reduced energy inputs."

Jan 1, 2009

By B. Galy, L. Giraud

"This paper compares Canadian provincial mining safety regulations regarding the use and testing of cage safety catches, including a brief history and evolution. Regulations are similar across provinces, with only slight variations. Currently, the “Ontario-type” safety dog is the most commonly used safety catch in Canada. Performance estimation of the compensation mechanism for different safety-dog shapes and tooth angles show this shape works well and has consistent braking results, but the best efficiency is obtained for initial tooth angles greater than 10°. Miner safety is questionable for lightly loaded cages, an issue that should be addressed technically and legislatively.RÉSUMÉ Le présent article compare les diverses réglementations de sécurité minière concernant les parachutes des cages dans les provinces canadiennes ainsi que les essais qu’ils doivent subir. Il semble que les réglementations soient semblables à travers les provinces avec quelques légères différences ou divergences. Un bref historique des parachutes et de leur évolution est présenté. De nos jours, le parachute de « type Ontario » est le plus fréquemment employé à travers le Canada et il présente des résultats de freinage uniformes. Une estimation de la performance du mécanisme de compensation pour les diverses formes de taquets de sécurité et les divers angles des dents montre que cette géométrie fonctionne bien; cependant, la meilleure efficacité est obtenue pour des angles de dents supérieurs à 10°. La sécurité des mineurs est mise en jeu pour des cages faiblement chargées et ce point devrait être traité du point de vue technique et du point de vue législatif."

Jan 1, 2016