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By B. Simser, V. Falmagne

"Noranda’s Brunswick mine is a 10 000 t/d producer of lead-zinc-copper-silver ore that has been in operation since 1964. Mining of this multiple lens deposit is primarily by blasthole stoping techniques between 400 m and 1200 m below surface. The combination of a high overall extraction ratio, an overall steeply dipping tabular shape, and high horizontal stresses (twice the vertical) have elevated the induced stress regime to levels comparable to much deeper operations. Improved mine design, and a better understanding of how the rock mass responds to mining in high-stress environments is essential to improve overall recoveries and maintain safety. Seismic monitoring has proven to be an essential tool at Brunswick, for both short-term safety of workers, and long-term strategic planning.Practical case studies illustrate how seismic data, particularly source parameter information, can be used to measure the rockmass response to mining and improve mining layouts in difficult regions. As the global trend continues toward mining in deeper, higher stress environments (e.g., South African Witswatersrand Basin, Sudbury Basin) and as local extraction and thus ground stresses continue to increase in existing deposits, seismic monitoring will play a critical role in mining safely and economically."

Jan 1, 2004

By B. Simser

Noranda?s Brunswick mine is a 10 000 t/d producer of lead-zinc-copper-silver ore that has been in operation since 1964. Mining of this multiple lens deposit is primarily by blasthole stoping techniques between 400 m and 1200 m below surface. The combination of a high overall extraction ratio, an overall steeply dipping tabular shape, and high horizontal stresses (twice the vertical) have elevated the induced stress regime to levels comparable to much deeper operations. Improved mine design, and a better understanding of how the rock mass responds to mining in high-stress environments is essential to improve overall recoveries and maintain safety. Seismic monitoring has proven to be an essential tool at Brunswick, for both short-term safety of workers, and long-term strategic planning. Practical case studies illustrate how seismic data, particularly source parameter information, can be used to measure the rockmass response to mining and improve mining layouts in difficult regions. As the global trend continues toward mining in deeper, higher stress environments (e.g., South African Witswatersrand Basin, Sudbury Basin) and as local extraction and thus ground stresses continue to increase in existing deposits, seismic monitoring will play a critical role in mining safely and economically.

May 1, 2004

By J. T. Furey

"A pilot plant study was conducted to evaluate the performance of column flotation in the recovery of gold from a gold/tellurides bearing sulphide ore, and to compare the performance of column flotation to conventional ""mechanically agitated"" flotation.Tests were conducted in a 60 liter glass column with ground flotation feed split from a concurrently operating conventional pilot plant, thus permitting direct comparison between the two processes. During the test program, the effects of wash water rate, gas holdup, froth depth, residence time and flow bias were examined in detail.The ore had an average ""as tested"" feed grade of about 5 g/t gold and 1 % sulphur, with the gold occurring primarily as inclusions of montbragite (Au2Te3) in pyrite, with minor amounts of native gold. Conventional flotation using 60 minutes residence time across four roughing stages recovered about 97% of the gold into concentrates grading about 50 g/t Au. A single stage of column flotation roughing using 25 minutes residence time matched the conventional circuit recovery of 97%, but produced grades of+ 150 g/t Au. INTRODUCTIONColumn flotation is the most significant innovation that has occurred in the mineral processing industry in recent years and has become an important alternative to mechanical flotation. Column flotation has been most widely accepted and applied in cleaning service where it has frequently proven to be superior to mechanically agitated flotation. Roughing in columns has not been ignored, but early testing indicated that columns may not be capable of achieving adequate recovery and, to date, columns have not been seen as serious competitors for mechanical roughers."

Jan 1, 1990

By J. J. McDougall

Until quite recently, the coal in the Cape Breton field was won from comparatively thick seams with light cover, and from submarine areas, and the system of mining naturally followed was pillar-and-stall. This sytem permitted of cheap extraction, and enabled production from localities where other methods could not be employed to good advantage. Thus the pillar-and-stall system, applied to conditions as stated, justified its adoption. Our working seams today, however, are practically all under heavy cover, or are moving in that direction, and with this gradual increase in cover came the increased cost of roadway maintenance. At Princess colliery, the system of pillar-and-stall was followed until roof and bottom conditions became such that further operations were unprofitable, and the longwall method was then adopted as an economic necessity. This fact should be borne in mind when operating costs of both systems are being compared. The longwall method is not held as a cure for all difficulties of heavy cover, but through it these difficulties can be overcome with less expense than by pillar-and-stall. The longwall system of mining, strictly speaking, is one by which a seam of coal is totally extracted in one operation. There are, however, many modifications of longwall, and in some cases it is difficult to determine whether certain practices should be classed as longwall or pillar-and-stall, or a combination of both.

Jan 1, 1928

By Micheal Mayhew

"This presentation will provide information and facts on the drilling and blasting within a frozen shaft using a full face methodology. The Author will briefly discuss the history of the sinking of a frozen shaft in Saskatchewan, the challenges faced, and the solutions delivered. The case study will include a discussion describing the series of events that led to the decision to adopt a full face blasting methodology. The case study will describe key elements such as the drilling pattern, hole size and depth, explosive products and blast vibration monitoring systems. INTRODUCTION During the shaft sinking process at a project in Saskatchewan, it was recommended that a drill & blast benching method be utilized. Following an evaluation of the site, the geological conditions proved amenable to a ground freezing system that would stabilize the rock formations and prevent inflows of water into the shaft (Table 1).The shaft sinking process required that the ground surrounding the proposed shaft be frozen by drilling several near vertical freeze holes radially at a specified distance from the edge of the proposed shaft excavation. This would allow for the circulation of a chilled brine solution down the freeze holes. The circulation is achieved by means of stainless steel pipes encased within each other to provide a delivery and return conduit for the brine (Figure 1). As a result of this periphery freezing, the ground within the shaft excavation is also predominately frozen.The finished internal diameter of the shaft was 5.5 meters with varying overall excavation diameters to facilitate different liner designs used for various rock formations. For the most part, the fully unsupported/unfinished excavated diameter of the shaft varied from 6.9 meters to 8.5 meters depending on the zone excavated. The challenge was that the proposed drill and blast excavation method posed a significant risk due to the potential to damage the freeze wall and pipes during blasting. The decision was made to commence the excavation through mechanical excavation (i.e. chip and cut) methods then change to a drill and blast method utilizing a split benching design. Through this process, the team encountered five main challenges: 1. Sub-horizontal geological structures and slips that affected blasting performance and sometimes resulted in a sloping surface to the top of the bench; 2. Confined working area for the crews and equipment due to a limited work area as a result of utilizing the split (half) bench drill and blast methodology; 3. Mechanical chipping and cutting of the one-meter buffer zone to the final shaft diameter; 4. Crews working on extremely slippery uneven frozen rock and ice surfaces, which affected safety and efficiency; 5. Establishing a blast vibration monitoring system to determine if the drilling and blasting of the full shaft excavation diameter were acceptable."

Jan 1, 2019

By Lian-Jin Tao

With fast development of China modernization, road construction obtains great achievement. However, in the construction process of highway, especially the high-grade highway in mountainous area, there are many unavoidable high cut slopes. Specifications for Design of Highway Subgrades, China, prescribe that the design scheme of slope with height more than 30m should be compared with bridge scheme and tunnel scheme economically. In spite of the existing guidelines, it is still quite common to see many high slopes due to engineering geological conditions, highway line shape, cost and issues related to traditional design ideas. Actually the traditional way with ?high backfill, the high cut? for mountainous highways seriously damages the original ecological environment and groundwater system, especially to those area with weak ecology, where the damage is unrecoverable. It is quite common practice to use artificial vegetation for cut slope virescence, however it still has problems such as low ratio of survivor, high maintenance cost and lack of species diversity. Now people are more and more aware of the importance of ecological environment, it becomes urgent to decrease the damage to ecological environment after ensuring the stability of high slopes. With the aim to reduce ecological damage, we proposed a new design approach which is ecological environment friendly by decreasing cut slope height with steep excavation scheme. This approach requires that (1) the geological condition is good, and the rockmass can be sTable itself; (2) excavation should not badly damage the rock, which means blasting must be controled by using buffer blasting, smooth blasting and pre-splitting blasting; (3) if local geological condition is not very good, excavation should have intervals for one bench, the advised space is 20m; (4) to ensure the slope stability in construction process, the cut slope should be reinforced more strongly than usual and in time. Finally, the deformation of the slope and the working condition of the reinforcement structure should be monitored to ensure the slope stability. The new design is used to a roadside cut slope of provincial trunk highway S223 in Guangdong Province. Based on intensive geological investigation and borehole tests, it is found that the slope rock mass is intact and sound, and the rock strength is quite high. Results from numerical modeling by UDEC reveal that compared with the traditional design scheme with 90.23m high slope, the steep scheme with only 23.46m high is characterized by its relatively large deformation and stress concentration, however the influenced area only appears at the upper slope and tends to sTable. With cable reinforcement, the stability of slope excavated steeply can be guaranteed. Deformation of the slope and the cable force are monitored in details in the period of construction, which show that the deformation of the slope decreases gradually and the final deformation is very small, and the cable tensions change small after the cables were tensioned. It is optimistically estimated that the steep slope should be sTable during operation. Comparison analysis between the steep scheme and the common scheme affirms that the steep excavation is better than the traditional scheme in terms of ecological environmental effect, slope height, the excavated amount, the excavated quantity of slope surface, engineering cost. It is concluded that if geological condition permits, the steep cut scheme should be used with better benefits.

May 1, 2009

By R. N. Murarka

"Hydrocyclone modelling and selection procedure is illustrated. Computerized procedure for hydrocyclone cut size determination for grinding and non-grinding applications is described.A standard procedure for evaluating operating hydrocyclones is described in detail. Many case studies are illustrated comparing actual plant performance with the computer simulation output in terms of overflow product size distributions.INTRODUCTION Cyclones are widely used for applications such as: close circuit grinding, backfill, tailings and dewatering. Normally, cyclones are used for very fine separations where screens are not suitable or too expensive. Figure 1 shows the separation size range of various classifying devices. Cyclones are popular because of their low capital and operating cost. Cyclone selection procedure for different applications depends on the amount of information available on the cyclone feed slurry characteristics. Closed circuit grinding applications will be discussed in detail in this paper. The Cut Size:The size of the material in the feed which reports 50% to each product stream (i.e. underflow and overflow), after correcting for the feed solids by-passing with the underflow liquid, is termed the cut size or ""d50c"". This is often used as the criterion and the basis for cyclone design.When the corrected recovery to underflow of each mesh size in the feed is plotted against the geometric mean size in microns on a log scale, the micron size corresponding to 50% recovery is the d50c size."

Jan 1, 1992

By J. R. Eastwood

"H.D.P.E. Piping in the Mining IndustryThere has been much use· ms.de of high density polyethylene pipe in the mining industry over the past several years. This is not only in new installations but al.so in areas where other piping materials such as wood, transite, concrete and steel have worn out and failed.The uses of H.D.P.E. in the mining industry are as follows:Tailings disposal linesMine water supply linesTailings water return linesHydraulic backfill linesPit drainageCorrosive liquid supply and disposal linesH.D.P.E. pipe has many advantages for both underground and above ground installations. It is tough, flexible, weather resistant and inert which makes the pipe suitable for many installations."

Jan 1, 1975

By Martin Landwehr

"Dust samplers are based on different principles. The konimeter is based on the number of particles counted; mining applications are based on routine sampling; and the photometrical evaluation of samples is used after the pre-separation of particles above 5 micron by the mining konimeter. In special cases, the Draeger sampler is used for quantitative analysis. General trends are toward larger samples, concentration on a weight basis, fractionation into size groups by different techniques and an analysis of composition. Standards or TLVs already exist in all industries. Surface industries base their criteria on concentrations and quartz contents in particles below 5 micron. The mining industry uses the tyndalloscope routinely to determine concentrations; concurrent] y, the rock content, as deter-mined by ashing samples, is obtained by konimeter.Threshold limits are related to the rock content in respirable fractions and tyndallometrically determined concentrations. The TL Vs are based empirically on Landwehr's ""dust values,"" as agreed upon with the Mines Inspectorates. Recently, and in accurate sampling, dust samplers have been used that count the dust in two fractions -above and below 5 microns. Mineral composition is determined either for all minerais or just for quartz. In assessing the dust hazard by Landwehr's ""dust values,"" all minerais are taken into consideration; in coal dust sampling, however, only the quartz content is taken into account. Efforts are now being made to co-ordinate the different assessment methods, arriving at uniform MAC values in agreement with those of other countries."

Jan 1, 1969

Aur Resources is Canada's leading copper mining company with producing mines and development projects in North, Central and South America. Copper production from Louvicourt Mine in Quebec, Quebrada Blanca and Andacollo Mines in Chile was a record 245 million pounds in 2001. Located 600 km North of Montreal, Louvicourt Mine is a joint venture between Aur Resources (30%), Novicourt Inc (45%) and Teck-Cominco (25%). Aur Resources is the mine operator with 280 employees working to produce a copper and zinc concentrate. In operation since 1994, the mine has produced a total of 12,606,000 metric tonnes of ore grading 3.6% Cu, 1.5% Zn, 26 gr./m.t. Ag and 0.9 gr./m.t. Au. This highly mechanized mine reached full production in August 1995 at 4,000 tpd. From 1996 to 2001, the average mine production rate was more than 4,300 tpd. The Louvicourt Mine continued its record of solid performance in 2002 and is expected to continue to do so for the balance of its 2.5 years mine life.

May 1, 2003

By P. N. Saavedra, E. A. Salamanca

"The maintenance strategies in the mining industry are changing from operative and periodic inspection strategies to a condition-based, predictive maintenance strategy centred in vibration analysis plus complementary techniques. Condition monitoring can also help to improve availability by being able to pinpoint and diagnose problems on operating machinery at an early stage. This reduces unscheduled downtime and production losses.However, in mining, for shovels operating in transient modes, with variable load and/or speed, the FFT (Fast Fourier Transform) standard approach is not directly applicable for analysis. This work illustrates how spectral order analysis and new transforms, called time-frequency transforms (TFT), allow us to monitor the shovel when it is working. Some practical examples showing the application of these analysis techniques to occasional vibrations measured on hoist and crowd transmission of a shovel are also presented. It is shown that at present, it is possible to carry out the vibration monitoring in the mining shovel while it is working, therefore avoiding the high cost of a loss of production which can occurr in traditional monitoring, where the measurement is taken while the shovel is out of production."

Jan 1, 2002

By Phil Thwaites

"The mining industry uses many types of mineral and metallurgical plants to produce saleable product from ore mined. Plant design history has left current operations with a mixture of manual operation and various forms of automated process controls. Consequently, we typically see high variability in the continuous operations together with a shortfall in the attainment of full capacity, or higher utilization of consumables.At a level of best practice, “Operational Performance Excellence” focuses on process control, using automation and control systems to deliver process optimization. This more sophisticated delivery is a great deal more difficult than the first stage of equipment selection / installation. It includes the appropriate selection of the right instrumentation, control system, key process knowledge, individuals with a solid control engineering background/experience, and the essential backing/ support of the operations management team together leading to higher value delivery. Robust solutions can be realized, considerably minimizing process variation, thus leading to process optimization. This approach results in an easier, efficient and safer process while providing considerable returns for the plant owners.How variable are your processes, and do you maintain optimized process performance with dedicated resources, modern instrumentation, ‘best practice’ control systems and performance monitoring tools? In this lecture, these questions and their possible answers are discussed.357"

Jan 1, 2013

By Xiaoqiong Wang, Daobing Wang, Fanbao Meng, Jianbo Wang, Hongkui Ge

"Shale gas has become an important unconventional oil and gas resources. Its effective development relies on comprehensive and accurate understanding of shale gas reservoirs. Rock mechanical properties is one of the important components of reservoir evaluation. Two adjacent black shale samples, which are cored from the depth of 1145 meters in Chongqing, southwest China, are subjected to acoustic emission(AE) test under uniaxial stress and compared with coarse grained granite. The results of synchronous AE, stress-strain and ultrasonic velocity experiments show that shale has weak anisotropy. Compared with granite sample, two shale samples are similar, but their strength, velocity and brittleness are quite different, indicating that shale has strong microscopic heterogeneity. TOC, XRD, SEM microstructure analysis show that total organic content, mineral composition and natural fractures are the main impacting factors for mechanical heterogeneity. INTRODUCTIONShale gas is a typical low-grade marginal resource, which is characterized by ultra-low matrix permeability and small single well control volume. In order to enable commerical development, complex hydraulic-fracture networks must be created in the shale to allow gas to escape from the micro/nano-pores and natural fractures where it is trapped in the rock (C. Clark et al.,2013; Ge et al., 2013). The development of shale gas requires accurate evaluation methodologies to evaluate shale reservoir properties and predict production. (Jarvie et al., 2007). Rock mechanical properties are an important part of the reservoir evaluation. It is significant for efficient drilling, completion and hydraulic fracturing to understand mechanical behavior of shale gas play (John, 2011; Wei, 2013).Rock mechanical properties mainly include heterogeneity, anisotropy, brittleness and acoustic emission activity (Lockner et al., 1992; Jerome et al., 2009; He et al., 2010; Liang et al., 2012). Shale mechanical properties are evaluated from laboratory tests following a complex workflow that covers tasks from sampling to testing (Md. Aminul Islam et al., 2013). It is common to include various experimental methods such as stress-strain curves, ultrasonic velocity and acoustic emission when evaluating the mechanical properties (Rao et al., 2006). Because of the presence of organic-rich matter, mineral composition orientation and natural fractures, shale tends to have strong anisotropy and heterogeneity (Deng et al., 2004; Wang et al., 2013; Hathon et al., 2013)."

Jan 1, 2015

By Muhammad Usman Siddiqui

Managing and analysing the vast amounts of data collected in a mining project effectively is crucial for enhancing the project's economic feasibility. The efficient utilization of this data is critical to minimising the time spent on projects and increasing project value. Process engineers can effectively integrate geometallurgical data into plant operations by employing analytical tools like Python, significantly optimizing the mine-to-mill process. This practical approach is a game-changer in the mining industry. Classifying a geomet dataset into units of similar characteristics (properties of the ore) is an important outcome of a geomet study. This approach simplifies data classification, allowing for class-by-class process modelling, which improves the decision-making process in mine planning and development. Classifying a geomet dataset involves using grade, lithology, and test work data (if available) to create blocks of similar characteristics, known as ‘geomet units.’ Compared to conventional methodologies, these units provide context and empirical evidence that can be more accurately mapped onto block-by-block process flowsheet development and net present value (NPV) estimation. This robust classification method reduces a project's technical risks and influences the initial mine planning sequence to maximise profitability. Defining robust geomet units with data sets with similar material is challenging due to the vast amounts of data available and the database's high heterogeneity. The methodology's purpose is to minimise time-consuming low-value-adding aspects of geometallurgy. The approach is different for a greenfield and a brownfield study, as all the valuable data in a brownfield process can be utilised to define the geomet units. Python has various libraries providing multiple machine-learning algorithms to assist in classification. The k-means algorithm is used for clustering, and the SHapley Additive exPlanations (SHAP) method is used to quantify the effect of each feature on the clustering results. However, even with automation, the methodology still requires a keen eye to account for the nuances that appear from project to project.

Oct 1, 2024

By David H. Searle

This paper will discuss the common trends existing in various Canadian jurisdictions for the closure and reclamation of mines. Included will be a discussion of the requirement to post security as well as its form and how security is calculated and refunded. Reclamation can no longer be left to the end of mine life. Progressive reclamation must occur throughout mine life and must be part of the mine plan from the beginning.

May 1, 2006

By W. G. Johnson

"As we move into 1983, Canada is not only in a deep recession, there are major changes taking place.International competition is growing fiercer.Major core industries such as automobile, steel, mining, oil, agriculture, forestry, fishing, major manufacturing and others are just not expanding.If and when recovery comes starting in mid-1983, as many predict, don't expect industries to suddenly resume former growth patterns. It's just not possible.Companies, by necessity, are becoming lean and mean, and they are still in the process of reducing staff to meet changing times and conditions. Many of the staff now being released may never return to fulltime work with a single employer, particularly if they cannot measure up to more exacting performance standards and management expectations.There are clear cut instances of people who lose a job for reasons beyond their control. A merger, the loss of function, or a major reorganization sometimes creates casualties of people who were excellent performers. Such people can survive well, based on the tongue of good report and with some help from associates or others. However, even good performers often have difficulty in adjusting to the rigors of finding a new job and to become their own personal salesman."

Jan 1, 1983

By Seppo Lähteenmäki, Pertti Koivistoinen, Jaakko Levanaho

"This paper describes the benefits and disadvantages of fully autogenous grinding when compared to grinding with steel grinding media. The study is a real case study based on a low tonnage, high grade mining project in a remote location in a developing country. The study compares the capital and operating costs of using either SAG mill, Ball mill, Crusher (SABC) or fully autogenous (AG) grinding circuits and produces an economical analysis of the project for both options. The economics have been developed for the overall project, including mining, processing, environmental and the infrastructure as well as for the additional cost of constructing a fully autogenous grinding circuit instead of the original plan of a SAG Mill, Ball Mill circuit.The paper also describes the development of the autogenous grinding circuit at Outokumpu Oy, Pyhäsalmi mine. This experience was used to design the autogenous grinding circuit for the case study. Pyhäsalmi Concentrator has over 30 years of experience in operating autogenous grinding circuits and therefore provides a sound base for the new circuit design.INTRODUCTIONGrinding of ore using steel grinding media is currently the most commonly used method in the mining industry. Autogenous grinding, ore replaces iron media, is also common especially in Europe and Africa. Iron ore industry in North America uses autogenous grinding in primary and/or secondary stages extensively. In gold, copper and other base metal industries, autogenous grinding is not as common, although there are operations where pebble grinding is or has been used in the secondary grinding stage. There are many variations of autogenous grinding in use in the mining industry. These variations include different mill sizes, mill length to diameter ratios, ore lump sizes, screening and pebble crushing configurations."

Jan 1, 2000

Material scheduling, sequencing planning and execution are the core tactical mine plan for achieving production targets that maximize the objective function of any mine production entity. This objective function is constrained by several exogenous and endogenous constraints including geological, operating, technological, marketing, financial, political, social and local field constraints. Linear and dynamic programming techniques have been used to formulate algorithms to solve the problems associated with scheduling and sequencing operations. These algorithms possess the mathematical rigor for dealing with the fundamental problems but they fail to provide adequate answers to random and dynamic process problems. Materials scheduling and sequencing are carried out within the bounds of random and dynamic fields. The functional relations between the output and dependent variables are random, and thus, current algorithms are limited in their abilities to address the problems arising from these random field processes. In this study a production simulator is developed to capture the random field process associated with materials scheduling and sequencing in an open pit environment. The algorithm incorporates a geometric pit evolution model, using solid geometry of an ellipsoidal frustum to capture material displacement dynamics. Taylor series expansion about the dimensions of the initial frustum is used to provide numerical solutions to the resulting partial differential equations governing the pushback dynamics. A production simulator, derived from the stochastic and dynamic models, is developed, validated and used to simulate the changes in the pit volume resulting from periodic incremental pushbacks and the random field process. The hybrid stochastic-optimization algorithm provides a powerful tool for addressing the random field and dynamic process problems. Combined with a hybrid stochastic-optimization dispatch system, tactical production planning and execution will be efficient and economic for achieving desired.

May 1, 2004

By A. W. Stradling, M. J. Fairweather

"The selective flotation of lead, zinc and iron sulphide minerals is key to the economic performance of concentrators treating zinc-lead ores. Diagnostic metallurgy is a tool to quantify mineral behaviour as a function of particle size and liberation. The result of such analysis may be used to select preferred strategies to improve metallurgical performance. The zinc flotation circuits at three Teck Cominco operations: Sullivan, Polaris and Red Dog are compared here. This paper analyses operating data from each of these circuits. The effects of mineralogy and performance by particle size are emphasized. Metallurgical performance at these three concentrators varies substantially. Liberation size is the major factor in determining metallurgical performance. Complex mineralogy requires a fine grind to achieve effective liberation. Fine grinding results in offsetting decreases in concentrate grade through entrainment. The economic treatment of complex fine-grained deposits requires optimisation of regrind size for liberation without unduly compromising concentrate grade through gangue entrainment.INTRODUCTIONUntil recently Teck Cominco Metals Ltd. operated three mines treating zinc-lead ore. In order of increasing mineralogical complexity they are: the Polaris Mine on Little Cornwallis Island in Nunavut in the eastern Arctic, the Sullivan Mine in southeastern British Columbia and the Red Dog Mine in northwestern Alaska. Both the Polaris and Sullivan Mines have recently ceased to operate due to depletion of ore reserves.The ore type and associated gangue, mineralogy and iron solid solution vary significantly between these deposits. Table 1 summarizes some of the important differences"

Jan 1, 2003

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951