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By Tran T

The kinetics of cementation of silver chloro-complexes from sodium chloride solutions onto copper and zinc was studied using rotating disc electrode system. The activation energies were found to be 10.8 and 30.5 k7/mole, in a 3M NaCl solution on copper and zinc discs, respectively. Higher dissolution factors were obtained on zinc disc, due to hydrogen evolution, whereas, copper dissolved close to the predicted values. Scanning electron microscope studies were conducted both on copper and zinc- cdiscs-to evaluate the deposit morphology and its effect on reaction kinetics. Two stage deposit growth was observed both on copper and zinc discs. Smooth, coherent initial deposit followed by tree-like secondary dendrites formed on copper, whereas, scattered bulbous initial deposit followed by porous dendrites was typical on zinc disc.

Jan 1, 1992

While there is reasonable agreement on the basic chemistry of the slag fuming process, there has been an on-going debate for nearly 50 years as to the nature of the rate controlling factors in its industrial application. There have been advocates in the technical literature for thermodynamic limitations on the one hand or kinetic limitations on the other. The different viewpoints result in very different predictions as to the technical and commercial potential of the process. A resolution of the debate becomes of importance as pyrometallurgical processes are advocated as a means of extracting environmentally deleterious elements from metallurgical wastes. The present paper reviews the arguments in favour of both equilibrium and kinetic control and puts forward the view that much of the evidence for limitation of the process by kinetic factors under all conditions is unconvincing. It is maintained that the process can approach thermodynamic equilibrium under industrial conditions and that this determines the ultimate limitation on its technical performance. It is acknowledged, however, that kinetic considerations may cause the batch process to fall well short of performance predicted on thermodynamic grounds. The strong process limitation arising from the influence of chemical thermodynamics on the likely outcome of a hypothetical continuous fuming process is contrasted with optimistic forecasts resulting from the extrapolation of process models based only on kinetic considerations.

Jan 1, 2000

By Deverux M

Heavy mineral deposits accumulate on shorelines with interrupted sediment input. Beach deposits, which form on shallowly dipping coastal plains, are most favourable. However, shallow shelves seaward of cliffed coastlines are known to contain economic deposits. Significantgeologicalconditions are defined, from review of the stratigraphic and geomorphic controls on known deposits , for heavy mineral accumulation on the Swan Coastal Plain.

Jan 1, 1986

Underground mechanized excavation in New Zealand has become more commonplace in civil and mining applications during the last three years. At one stage up to seven Dosco Road- header machines were being used on different projects around the country. The Huntly West Mine Drifts inclined at one in four were by far the most severe grade conditions that the machines were subjected to; however, other operations posed their own particular problems for the machines. Two major interrelated factors became evident as soon as the machines commenced at Huntly. These were traction problems on the grade and control of water, particularly on the invert.

Jan 1, 1978

Improvements in mechanisation should not be considered independently of safety and of environmental hazards. The need to keep gas contents within statutory limits may make the time needed to partially drain a gassy seam the effective control on face development times. Dust levels may provide an effective control on coal extraction rates on any one face. The combination of gas and dust on high output longwall faces may make it necessary for each one to be treated as a separate mine in terms of ventilation, and the faceworkers may need special protection. Mechanisation and safety can be mutually beneficial when mechanisation combined with systematic safety assessment reduces accidents, and when a thorough study of how to reduce accidents and health risks indicates the best method to improve mechanisation.

Jan 1, 1988

Methods of measuring the frictional properties of rock surfaces, both by direct sliding and in triaxial apparatus, are described. It was found that for some rocks the coefficient of friction remains reasonably constant as sliding is continued but for others it increases considerably.The effect of fluid pressure in the surface of sliding was found in all cases to be adequately represented by the effective stress criterion. Some observations on sliding on two conjugate planes showed that the motion on the two planes may be very different, depending on small differences in the constraints.The coefficients of friction of natural open joints in bore core were found to lie in the comparatively narrow range 0.32 to O.68 although surface coatings were very diverse.A set of diagrams on the equal area projection is given which enables a rapid determination to be made of those planes on which sliding is possible in a given three-dimensional stress field. The influence of the intermediate principal stress on this is of considerable importance.

Jan 1, 1969

The current boom in the mining sector has required mining operations to ramp up production to meet the international demand for minerals. This increase in production is putting enormous pressure on on-site professionals, and in particular the role of the on-site geotechnical engineer is ballooning. Mining engineers are focused on machinery and schedules; geologists concentrate on grade control and resources; everything else becomes the responsibility of the geotechnical engineer. Day to day geotechnical engineering is very different from geotechnical design work, and a practical understanding of both is required to successfully carry out either role. In addition, a successful geotechnical engineer has to have a good understanding of almost all technical aspects of mining. Even more important are good communications skills and the ability to problem solve on the fly. None of these skills are taught at tertiary institutions and therefore need to be learnt in the workplace. However, the shortage of geotechnical professionals means that young engineers do not always receive the mentorship and training they need to develop confidence and technical effectiveness. This paper outlines the changing role of on-site geotechnical engineers and presents some thoughts on how industry and young engineers can adjust to the changes.

Jan 1, 2006

The fluorspar deposits at Okorusu, Namibia are closely related to an alkaline igneous ring complex of late Cretaceous age (125¦7 Ma). The fluorite ores consist of relatively fine-grained purple replacement fluorite and subsequent coarser-grained purple and green vug-filling fluorite crystals. Homogenisation temperature measurements for 38 primary fluid inclusions shows that main stage purple to green fluorite crystals were deposited over a temperature range from 166¦C to 144¦C, and minor late yellow fluorite was deposited at lower temperatures from 132¦C to 128¦C. Homogenisation and freezing temperatures measured for 18 primary fluid inclusions shows that the fluorite-depositing fluids were less saline than Mississippi Valley-Type (MVT) ore fluids and overlap the lower temperature range of fluids that deposited epithermal ore deposits. Mining in three open pits (A, B and C) at Okorusu has gradually provided exposures which reveal that the fluorite orebodies have been emplaced primarily by the preferential replacement of carbonatites. Evidence for the replacement of carbonatite includes: replacement remnants of carbonatite within the fluorite ores; goethite pseudomorphs after the carbonatite minerals, pyroxene, pyrrhotite and magnetite, which are disseminated in the fluorite ores; andpartial replacement by fluorite of a large sill-like carbonatite body in the A pit. Electron microprobe analyses of minerals in unreplaced portions of the carbonatites show that their mineralogy consists of titaniferous magnetite, diopside pyroxene, apatite, biotite and calcite. Magnetite contains 6.97 per cent to 10.46 per cent TiO2, averages 8.44 per cent TiO2, and has an average V2O3 content of 0.35 per cent. At high magnifications under the scanning electron microscope (SEM), the magnetite shows abundant fine ulv÷spinel exsolution lamellae arranged in a cloth texture. Apatite contains moderately high fluorine contents that range from 3.21 to 5.0 per cent and average 4.2 per cent, and apatite crystals range in total rare earth oxides from 1.7 per cent to 2.61 per cent. Pyroxenes in the carbonatites are iron-rich diopside, and they contrast to pyroxenes in the fenites that are aegirine-augite. All of the microprobe analyses for mica crystals in the carbonatites give biotite compositions. Microscopic examination of fluorite concentrates from Okorusu provides mineralogical information important to the resolution of beneficiation problems. Fluorite ores that are related to carbonatites are typically accompanied by phosphorus benefication problems. The cause for the presence of phosphate in some of the Okorusu fluorite concentrates is a function of the presence of binary locked fluorite-apatite particles. The fluorite ores have also replaced marble locally in the A pit, especially along the A band in the B pit, and dominantly in the orebody proposed for the new C pit. Those ores are characterised by fine grain sizes, faint remnant bedding, lack of carbonatite mineral pseudomorphs and local presence of remnants of unreplaced marble. Concentrates derived from those fluorite ores are devoid of phosphorus, but commonly have elevated silica contents due the presence of free quartz. Carbonatite and marble were preferentially replaced by fluorite because the calcite was readily soluble in the presence of the fluorite-depositing fluids and the dissolution of calcite provided calcium for the formation of fluorite. 

Jan 1, 2008

By S N CARRAS

Ore reserve estimation is a procedure involving data collection, data storage and judgement and assumptions about geology mining and metallurgy. Calculations are based on these assumptions and an economic analysis on projected cash flows is carried out. Ore reserve estimation must therefore be subjective and will always depend on the extent to which the assumptions used in arriving at the estimate are correct. This paper is an attempt to summarise the many aspects that can contribute to ore reserve problems and to offer some suggestions on how to minimise these problems. For further details on specific concepts readers are referred to the detailed descriptions in the referenced papers.

Jan 1, 1992

In June 1996, Nord Resources Pacific (Nord) decided to work towards obtaining all necessary approvals from the government of PNG for a mine on Simberi Island in the Tabar Island Group, New Ireland Province. On the 9th of September 1996, Nord submitted a Proposal for Development and an application for a Mining Lease to mine the oxide gold deposits on Simberi Island. The Mining Lease was granted on the 3rd of December 1996 in a signing ceremony on Simberi Island. This was achieved in the extremely short time frame of less than 3 months and this paper attempts to explain the processes which made it possible.

Jan 1, 1997

By Quadrio J. S, MacHunter A. M W

The initial development fl6tation testwork on Mt. Windarra op was completed on composited drill core intersections at the.Australian Mineral Development Laboratory. An exploratory winze provided samples, from the 130 M. level of the Mt. Windarra mine, for pilot plant and bench development tests. A limited test programme was initiated on the South Windarra drill core composites. Detailed mineralogy has been completed on selected samples from both ore deposits.

Jan 1, 1973

This paper summarises some observations regarding the way SAG and AG mills work based on the last ten years of pilot plant operation, grinding circuit design and operational reviews for various projects in Australia and overseas. The main purpose is to promote discussion on key factors influencing breakage in a SAG mill. The focus of the paper is on two questions: How do mill lifters and liners really work and have an effect on grinding? How does the mill charge composition impact on grinding performance? The focus of the paper is on observations of mill behaviour in both pilot plant trials and plant operation, particularly on Cadia ore. DEM, by others, and JKSimMet modelling of SAG mill performance have greatly assisted in forming the ideas expressed in the paper and both are valuable tools in developing our understanding of the comminution process. Put in the æextremeÆ form the major observations and conclusions expressed in this paper are that: the main purpose of mill lifters is to reduce mill liner wear and not to promote rock breakage; the often promoted theory that balls impacting the ætoe of the chargeÆ is a dominant form of breakage is incorrect; and fines production in a SAG mill is primarily a function of the rock load mass, with a secondary dependence on ball load for any given circuit configuration.

Jan 1, 2007

By Lynce AJ

A method has been developed for the prediction 'of 'the- . performance of a multi-stage grinding=cyclone classification circuit of any degree of complexity on any ore for a wide range `of operating conditions, The-.method involves ;the. s` inu ation b'f the circuit on a digital computer by means of. matheinatical' models ":bf the"' individual units:, the. development of which is- also discussed'., At present, in order to establish 'the!'" charac'teristtics of they ¦ore- and the machines. in mathematical terms;. it is necessary to know'the performance of a , simpl,.e. ; system on tri.e ore - for! one known ,,feed rate and.fe.ed s,l-zing, analysis. ' ,Fiiither work on :the- separate identification 'of the terms defining the characteristics of the ore and the machines may permit the method to be, applied directly to the cj.4ta,derived from small scale tests on ores,

Jan 1, 1964

Grade control is an important factor in the on-going success of a mining operation. Grade control criteria will vary depending on the commodity being mined. Financial considerations determine the actual grade control criteria at any one mine site. Mining and metallurgical capital and operating costs are ultimately used in ascertaining cut-off grades employed in grade control. The metallurgical characteristics of the ore, and ultimately the equipment selection and design of the plant, are based on samples provided by the exploration geologist. Ore variability is an important factor in designing the process plant. Ore variations, outside of those catered for in the design, as well as large ore changes on a daily basis, will impact on the metallurgical performance, and hence the economics of a mining operation. Therefore good liaison between the grade control geologist and metallurgist will undoubtedly lead to a more consistent, and more profitable mining operation.

Jan 1, 1993

FOR some reason there is not any extensive literature in print on the electrolytic refining of copper, although the method is in general use in America and Europe. In Australia there are but three plants in existence one small one at Wallaroo, in SouthAustralia; one at Lithgow and one at Port Kembla the last two being in New South Wales. The largest of these is the Port Kembla plant. It is also the most modern, and embodies all the latest appliances and improvements of electrolytic practice.The plant and methods about to be described is that at Lithgow, with which the writer was associated for some years, and the experience gained there may be of interest. Electrolytic refining of copper is one of the simplest operations of metallurgy, but, like all metallurgical operations, it requires constant attention and a large amount of common sense. The man in charge should be endowed with an insatiable curiosity as to why certain things are occurring, and an instinct of cleanliness, whichmy first mentor in chemistry, Mr W A Dixon, once impressed on me was better than godliness.

Jan 1, 1911

Studies of the morphology of seamounts within the Hawaiian, Line Islands, Gilbert and Phoenix Seamount groups indicate that the morphology and size distribution of seamounts vary significantly from one seamount group to another. The Line Islands group appears to be the most complicated of all the groups studied thus far. This group is complicated by reactivation of volcanism, which has superimposed volcanics on sedimentary rocks. These seamounts display abundant volcanic features on their summits. Seamounts within the Hawaiian seamount chain display a marked absence of volcanic features due to the . presence of thick carbonate caps. Reef platforms and sealevel benches are very common on these seamounts but are absent from seamounts in most other seamount chains in the central Pacific. Slope angles vary regionally between seamount groups. The minimum slopes are found on Necker Ridge in the central Pacific basin. The maximum slopes are found on ridge-crest seamounts. Roughness increases proportionally with mean slope angle.

Jan 1, 1987

Legislation, if it is to be effective, must be enforceable by the state and acceptable to the industry. In the mining industry the relationship between the government inspector on the one hand and the mine management and employees on the other, must be one of full co-operation before the system can be effective. To understand our present system, which is-duplicated in most countries of the world, an examination of the history from which it evolved is necessary.

Jan 1, 1975

Project managers must juggle many aspects to bring their project in on time, on budget, and in accordance with the aims of the project owner. Whether the project is a mining feasibility study, a technology implementation or a construction project, it falls to the project manager and his or her team to deal with risk from two standpoints, which may be at odds with one another. First, a project team must deal with risks to the project itself û that is, risks to on-time, on-spec and on-budget delivery against the value promise made to the customer. Second, there is the management of risks within the subject matter of the project, undertaken on behalf of the customer. The project manager cannot dodge this responsibility; yet there is a tendency (particularly in smaller, in-house studies) to avoid digging too deep, possibly for fear of what may be uncovered! This paper investigates the responsibilities of project teams in regard to risk management and reporting. It examines ownership of project risk; the nature of risk management activities undertaken by the team during the course of a project; and outlines some controls to ensure that the two opposing arms of project risk are reconciled for the benefit of both the project team and the project owner.

Jan 1, 2007

By Bezuidenhout M, Moolman D. W

In the minerals industry numerous problems cannot be solved by conventional mathematical models owing to their complexity or a lack of phenomenological understanding. Neural networks provide one way of mapping the ill-defined relations between process variables and functions for such ill-defined problems. Consequently, processes such as leaching and froth flotation are mostly controlled in an empirical way by using rules of thumb. In addition, these processes involve so many independent and dependent variables that the plant operator finds it difficult to visualise or even observe a change in process conditions. The structure of froths developed on the surfaces of industrial scale froth flotation cells has a significant effect on both the grade and recovery of valuable minerals in the concentrate. Although these effects are well known at the process operational level, where considerable heuristic knowledge is available, little work has been reported on a detailed characterisation of the mechanisms and the visual characteristics of the surface froth. Recent results from an on-line observation of froths in several plants have proved the relationships between image features representing froth behaviour and metallurgical results. It will be shown how supervised and unsupervised neural nets are being used on operating plants to interpret computer vision data. In froth flotation the operator is supposed to visually observe process changes from the appearance of the froth, which is an unreasonable demand under industrial conditions. The system described here determines textural parameters on-line, and tracks the changes in process conditions via a Self-Organising Map (SOM) neural net. This monitoring system warns the operator about fluctuations in reagent addition, and gives an idea of the type of froth encountered. In another example, changes in the mineralogical characteristics of gold ores are represented on an SOM map, based on the diagnostic leaching behaviour of such ores.

Jan 1, 1997

By Montagnon P, Dagois G

The use of activated carbon for gold recovery has been known for years, but came industrially on stream since the years seventies.Despite several years of experience, the criteria for selecting a carbon have not been clearly determined so far.This paper will try to highlight the user through his experience, on the most important factors which should affect his decision.We will develop:- Physical characteristics - Adsorption characteristicsand try to show that slight variations on these characteristics may have important consequences on the plant design and profitability.

Jan 1, 1984