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By Gonzalez-Dominguez J. A, Dreisinger D. B

At Cominco's Zinc Refinery at Trail, British Columbia impurities are removed from zinc sulphate electrolyte by a two-stage purification process using zinc dust. Copper, cadmium and thallium are removed in the first stage whereas cobalt is removed in the second stage. Cobalt removal kinetics are affected by soluble antimony and copper additions to the electrolyte. This study was focused on the kinetics of cobalt removal by zinc powder cementation. Experimental variables included copper and antimony concentrations, pH and temperature. Common organic additives employed in zinc plants were studied to determine potential interactions with the cobalt removal process. Cementation products obtained from laboratory experiments and plant practice were studied using SEM. A number of significant results were obtained: 1. Copper and antimony ions were sustantially removed from solution during the early stages of the cementation reaction (within the first 15 minutes). Cobalt cementation kinetics are slow and follow a first order kinetic regime. 2. A drop in the cobalt removal rates can be correlated with a rise in the Eh of the slurry. 3. Ligninsulphonate, Percol 351 and animal glue at levels of 2 mg/L significantly impede cobalt cementation.

Jan 1, 1993

By Quinlan M. J, Ratcliffe J. S

Chemical kinetics is a dependent process which usually correlates the rate at which a reaction proceeds with the mechanism descriptive of the manner by which reactive particles interact. Given the latter, the object gen- erally is to find the reaction rate dependency in terms of an intensive property of the system - number of reactive particles present, and of the energetics of the system - usually temperature. Chemical kinetics depend on a dem- onstration that reaction considerations alone control the phenomenological process under study. For these rea- sons, chemical kinetics are usually involved in homogeneous gaseous systems. Even in liquid homogeneous sys- tems earliness or lateness of reactant mixing rather than chemical kinetics may be controlling. Considerations of transport phenomena are involved in heterogeneous systems and often control the observable rate:an additional problem in such systems is to apportion the rate due to mass transfer - usually a linear process - and that due to reaction which may be linear or non-linear. Experimentally, conditions are often chosen so that only one consideration controls but this becomes more difficult where solid phases are involved. Kinetic modelling involves considerations of chemical kinetics, transport phenomena, and factors attributable to the physical environment in which the process takes place. The latter two considerations may be quite different as between experiment and plant. The kinetic model may be a mathematical representation of a conceptual mech- anistic model of the reaction. Alternatively, it may be an empirical relationship resulting from, for example, some curve fitting procedure applied to experimental data. The latter approach may be necessary where the system is particularly complicated.

Jan 1, 1975

The Manto Verde copper mine (Atacama Region, Chile) is due to go into production in 1996. It will produce 40 000 tonne/year of copper cathode by heap leaching/SX-EW. Mineralogical studies were undertaken in conjunction with the metallurgical testwork program to characterise the ore and its response to leaching by dilute sulphuric acid. The leachable copper mineralogy is dominated by the oxide copper minerals: brochantite and malachite with minor chrysocolla and atacamite. The gangue minerals include abundant orthoclase, specularite, quartz and chlorite with minor muscovite and trace smectite clay, calcite and limonite. The study showed that complete or partial decomposition of calcite, chlorite, smectite and wad consumed acid and generated solution impurities (Ca2+, Fe2+, Mg2+, A13+, K+, Si4+ and Mn4+2+ ). Although these were manageable at Manto Verde, their uncontrolled build-up could have affected the operation in several ways: the degradation of heap penneability and fonnation of crud in the SX plant from the precipitation of gypsum, goethite, colloidal silica and jarosite; and the entrainment of contaminated pregnant leach solution in the SX organic resulting in the transfer of impurities to the electrolyte and subsequent effects on cathode quality and electrowinning efficiency. In conclusion, process mineralogy played an important role in understanding and managing potential mineral-related problems in the heap leaching and SX-EW recovery of Manto Verde ore.

Jan 1, 1994

By Savage E. N

Two genetic types of base metal deposits occur in the Wainivesi area of central eastern Viti Levu. The Wainivesi deposit is now considered to be a stratiform volcanogenic type, and the Wailotu and Wainiviti deposits are described as contact metasomatic with some hydrothermal manifestations. The Wainivesi mineralization is correlated with the Tertiary "e" stage, i.e. uppermost Oligocene-Iowermost Miocene. Tertiary "e" stage rocks in Fiji are therefore potential ore producers of stratiform volcanogenic type. On the basis of plate tectonics with Fiji part of the New Hebrides Arc prior to rifting apart in the late Miocene, stratiform volcanogenic deposits of the Wainivesi type may also occur in rocks of comparable type and age in the New Hebrides.

Jan 1, 1976

By Schon RW, Stephens CJ

The Whitsunday Volcanics occupy most of the offshore islands from the Whitsunday Group, southeastwards through the Cumberland and Northumberland Groups, possibly extending to the mainland adjacent to Shoalwater Bay, a distance of 370 km. Some of the islands of this group are granitic, but preliminary Rb-Sr data indicate these to represent Permo-Triassic basement. Cretaceous volcanism is interpreted to have occurred during initial rifting prior to the continental breakup of northeastern Australia and subsequent development of the Tasman Basin.The volcanics comprise mainly lithic ignimbrites, with local development of inter-bedded surge and bedded tuff, accretionary lapilli tuffs, lithic concentration zones, and lag deposits. Isolated fluidual rhyolite and dacite domes occur. The deposits are considered subaerially emplaced. A Rb-Sr isochron age for volcanism of 110 Ma is determined from new data. The total thickness of the volcanics is unknown, but a minimum thickness of 4-5 km on Whitsunday Is. is suggested. Eruptive centres are inferred to be distributed throughout the volcanic zone. The volcanics are cut by numerous, dominantly near N-S, dykes ranging from dolerite through to rhyolite in composition.Chemically, the volcanics and dykes exhibit a continuous range of compositions from basaltic andesite, through andesite, dacite, to rhyolite, with minor more alkalic compositions. Phenocryst mineralogy in the silicic rocks is mainly plagioclase, augite, and Fe-Ti oxides, with less frequent quartz and hornblende occurrence. Sr and Nd isoptic compositions for volcanics and dykes are close to mantle values. These data are tentatively interpreted in terms of a lower crustal magma arc source separated from the mantle only a geologically short time prior to Cretaceous magmatism.

Jan 1, 1990

By Dredge K, Becker G

The successful dissolution of the valuable metal components of a solid phase is often a basic requirement for a successful hydrometallurgical treatment process. Sulphide concentrates are often an intermediate product in the production of refined metals. These concentrates need to be further processed to realise the contained metal values in a useful form. Pyrometallurgical techniques have tended to dominate, at least the initial treatment of metal sulphide concentrates. The technology described, Activox«, has been developed specifically for the hydrometallurgical treatment of these sulphide mineral concentrates, in particular those containing copper, nickel or gold. The Activox« dissolution technology coupled with the use of existing, or newly developed, downstream processing techniques, offers alternative processing options for the recovery of full value, saleable metal products. The technology is suitable for application down to relatively small scales opening up the opportunity for on-site production of metals even at modest scale mining Operations.

Jan 1, 1995

During induration of iron ore pellets produced from magnetite concentrates, there are many reactions occurring simultaneously. While the magnetite is being oxidised to hematite, carbonate fluxes are being calcined, leading to the formation of complex oxides. Calcination of fluxes and the formation of calcium and magnesium ferrites and silicates during the preheat stage can influence the magnetite oxidation process. As the calcination reaction proceeds quicker than oxidation at temperatures experienced during the preheat stage (700 - 1200¦C), the bulk flow of CO2 emanating from within the pellet should disrupt the diffusion of O2 to the magnetite reaction as the gas fluxes are similar in magnitude. This increases the time required for the oxidation of the pellet. Using an infrared rapid heating furnace, experiments were performed on heating individual magnetite green balls in an air atmosphere. These experiments showed that time played an important role in the extent of oxidation and calcination and temperature significantly influenced the initial evolution of high temperature phases such as magnesioferrite, calcium ferrites and calcium silicates. Understanding the kinetics of all these reactions for a particular pellet feed, and their interaction, is important for optimising the design of the induration furnace.

Jan 1, 2005

Computers represent substantial capital investment. A better return on that invest- ment comes from more effective use of the computer's facilities. By using Telecom's data communications facilities, more people in more locations can have ready access to those facilities.

Jan 1, 1983

The orebodies at Kambalda are complexly faulted, folded and intruded. It is realized that the ore reserve calculations will be wrong and steps are taken to minimise the errors. The calculations are a combination of computer data handling and manual input. Initially Geological Ore Reserves are calculated and then production data and experience are used to produce a Planned Mining Reserve. At all stages maximum professional judgement is incorporated. The basis of the calculation is the polygonal method of area estimation, and production reconciliations together with the style of data available indicate that it is a most suitable technique. It is also a tech- nique that is easily communicated to all levels from operators to management.

Jan 1, 1979

By Baird G. R, Jurak R. N

In this study Dynamic Finite Element Modelling is used to investigate the distribution of peak particle accelerations (PPA) induced in a rock mass by a vertical decked column of explosives. The rock mass is assumed to be viscoelastic. The influence of the delay time between decking charges, the viscosity attenuation (quality factor Q), the decking configuration, and the velocity of detonation (VOD) on PPAs is examined. The results of this paper are relevant to fragmentation since the nature of the fragmentation is related to the stress magnitude and hence the PPAs. It was found that increasing the VOD, and increasing Q increases the PPAs in the neighbourhood of the blasthole. However, the VOD and rock quality factor Q have little influence upon the distribution of PPA. It was also found that an even distribution of PPAs, at a fixed distance from the blasthole, could only be obtained by increasing the ratio of charge length to stemming length. The study showed that the amplitudes and distribution of PPA surrounding the blasthole was approximately independent of the delay time between the decked charges. The modelling also shows that the particle accelerations at locations below the bottom of the charge are relatively small and so the model predicts no substantial damage below the bottom of the charge after blasting.

Jan 1, 1995

Au airway hteat and moisture exchange .,Jgorithm is described which is generalised to suit most mining situations and can be run separately on a microcomputer or used within a network simulation. The main difference between this technique and other simplified methods is that a non-uniform boundary condition is allowed for. This permits radiative heat transfer between surfaces of different wetness in addition to evaporative and convective heat and mass transfer.

Jan 1, 1988

By Craw D

Quaternary warping and uplift of antiformal schist ranges in Central Otago, New Zealand, has resulted in recycling of alluvial gold from widespread, generally weakly auriferous, Miocene fluvial gravels that unconformably overlie the schist, into aprons of fan sediments along the range margins. Basement erosion during uplift has been limited and so gold input from sparse gold-bearing quartz veins in the schist has been relatively minor. In an eluvial cycle on the slopes of the ranges, chemical remobilization of gold occurs during oxidation and erosion of the Miocene sediments. The typically fine-grained (300-400¦m) gold undergoes chemical modification and grain size enhancement of up to two orders of magnitude, and much of it is redeposited in a large number of relatively small alluvial fans along the range margins. Groundwater mobility within the fans results in minor additional gold mobility and grain size Enhancement.

Jan 1, 1995

By Palmer G, Dennis R, Clark A

The Ravenswood Mine in North Queensland is the first gold mine developed by Carpentaria Gold Pty Ltd, a wholly owned subsidiary of MIM Holdings Ltd. Carpentaria Exploration Pty Ltd began exploration at Ravenswood in 1978. However initial exploration of the main gold producing area (Buck Reef East) commenced in March 1987 when exploration rights to four key leases were secured. A rapid, co-ordinated exploration and development program produced gold from a heap leach operation nine months after the first costeans were dug at Buck Reef East. To treat higher grade ore found at depth in the Buck Reef East pit and the metallurgically more difficult Buck Reef West ore, a carbon in pulp plant was commissioned in May 1988. The mine is currently producing at a rate of approximately 40 000 ounces of gold per year. Ore at Ravenswood is hosted by hydrothermally altered diorites and tonalites of the Ravenswood Granodiorite complex. Alteration is controlled by planes of permeability formed by joints, shear zones and dilational breccias. The complex orebody geometry resulting from these controls required very detailed surface and drill exploration for adequate definition. Carpentaria's need for early cash flow meant that economic, mining and metallurgical considerations governed choices of exploration techniques, program timing, material and data collected. The initial reserve of 1.1 mt @ 2.87 g/t Au was defined by sectional polygonal methods. Grade control is based on geologic mapping and blast hole or channel sample assays. Ore is batched through the crusher and sampled to monitor grade control and mining performance. Minimal dilution has occurred. Gold content is greater than predicted by the reserve. Sprinkling of heaps commenced in November 1987. Changes have been made to the pad design and to the method of heap construction. Heap leach ore is treated at a rate of 400 000 tpa.

Jan 1, 1989

By Stewart A. M, Price D

This paper presents recent findings concerning longwall caving mechanisms relating to Australian mining conditions and their effect upon longwall support requirements and behaviour. The findings are based on a program of intensive hydraulic support monitoring in a variety of Australian mining conditions coupled with geotechnical observations.

Jan 1, 1992

The present Pacific Ocean arose from rapid sea-floor spreading that commenced in the late Mesozoic, and continues to the present day. It started within what is here called the Medusa complex of seaways, basins and troughs with spreading ridges and volcanic arcs, that girdled the earth, including the Palaeotethys and Neotethys of Eurasia between Gondwanaland and Laurasia. Detailed mapping and analysis of palaeofaunas and volcanic arcs indicate that several seaways, rather than one or two, extended throughout Tethys, and into areas now occupied by the Pacific Ocean. The Medusa complex developed under a long sustained wrench regime, right lateral at least from New Zealand to Eur.ope, and saw the origin, maturation and closure of elongate and oval basins under erratic sea-floor spreading, in which no Eulerian pole of rotation remained fixed for long. The name Medusa stems from the analogy of snake-like writhing hair to the constantly shifting development of basins and orogens within the complex. The Indian Ocean split and opened up Gondwanaland concomitant with the later development and deformation of the Tethyan segment- of Medusa, whereas, to the east, the Pacific Ocean opened within Medusa itself, and dispersed Medusa around the rim of the Pacific through sea-floor spreading and strike-slip faulting.

Jan 1, 1987

By Eupene GS

The Early Proterozioc Pine Creek Geosyncline hosts a large number of gold showings. Mineralisation types include stratiform, synsedimentary deposits within iron formation and carbonaceous mudstone; disseminations in granophyric intrusives; and quartz vein related concentrations in the form of shear fillings, saddle reefs and stockworks. Stratiform gold deposits preferentially formed near penecontemporareous faults during periods of basin instability. Intrusive basic magmas later assimilated some stratiform mineralisation and subsequently redeposited it within differentiated phases. Gold was again remobilized during regional deformation and metamorphism. Stratiform mineralisation was upgraded insitu in high strain zones and gold was mobilized into metamorphic fluids. Fluid induced fracturing during prograde metamorphism and later uplift caused the deposition of extensive gold rich vein systems. The genetic relationship between gold deposit types is reflected in the clustering of showings along regional anticlines, and provides a powerful exploration tool. The large volume of 'exhalative'òmaterial in the Geosyncline with elevated gold content suggests significant economic stratiform mineralisation may be present, and probably provides a source for later disseminated and vein deposits.

Jan 1, 1984

By Das S. C

A detailed study was undertaken on the effect of Fe+3 in combination with LIX64N during copper electrowinning from sulphate electrolytes. The results show that the presence of Fe+3 not only affects the current efficiency during copper electrowinning but also affects the cathode quality. The effect is enhanced by electrolysis parameters like temperature, circulation rate, current density, etc. No significant effect was found from the presence of Fe+2. The presence of Fe+3 along with LIX64N causes a synergistic effect and results in a drastic fall in current efficiency. Moreover, cathode quality is also affected. A pyramidal structure is favoured in the presence of Fe+3 but the presence of LIX64N along with Fe+3 promotes a ridge structure. Addition of thiourea not only causes modification of cathode deposits, but also a rise in current Efficiency.

Jan 1, 1992

By Black LP, Law SR, Oversby BS, Mackenzie DE, Wyborn D

Three volcanic sequences of different ages occur close together in the Burdekin Falls area, southeast of Charters Towers in northeastern Queensland. The oldest is equated with the Cambro-Ordovician Mt Windsor Volcanics, and consists mostly of strongly deformed, regionally metamorphosed rhyolitic lava and minor feldspathic to quartzose sandstone. This unit is overlain by folded but unmetamorphosed Upper Devonian-Lower Carboniferous volcanics (DCv) of the lowermost Drummond Basin sequence. The primary volcanic facies of (DCv) principally comprises andesitic and rhyolitic lavas, and dacitic ignimbrites. Similar volcanics are widespread in the lowest formations of the Drummond Basin sequence elsewhere, and dominate that sequence east of the Anakie Inlier. The youngest volcanic sequence is Late Carboniferous and composed of lower, more deformed, compositionally diverse ignimbrites, lavas and conglomerates, overlain by generally less deformed rhyolitic ignimbrite sheets. The upper part is equated with the Bulgonunna Volcanics which extend 90km south to the Mt Coolon area. The Burdekin Falls area contains an ignimbrite stratigraphy different from that in the south. However, one of the most voluminous ignimbrites (Locharwood Rhyolite) in the southern stratigraphy is also present in the north, enabling the two to be correlated.Each of the three volcanic sequences reflects proximity to eruptive sources. Both the volcanics at the base of the Drummond Basin sequence and the Late Carboniferous volcanics are largely the products of subaerial eruptions. The former were erupted from several intermediate-composition volcanoes, and the latter from multiple-vent silicic calderas. All three sequences are considered to be prospective for precious and/or base metal mineralisation. Polymetallic massive sulphide deposits occur in the Mt Windsor Volcanics farther west, and many epithermal gold prospects and mines are hosted by the volcanics at the base of the Drummond Basin, especially east of the Anakie Inlier. The Late Carboniferous volcanic sequence is deeply eroded, and co-magmatic high-level plutons are widely exposed; this sequence may therefore be more prospective for deeper-than-epithermal mineral deposits.

Jan 1, 1990

Design of cemented fill in mining is often carried out without any consideration of the structure of the fill. The composition of cemented fills varies in the stopes due to the placement method, and the strength of the fill in the laboratory depends on the density, orient- ation, moisture content and drainage conditions. Within each stope there are definite zones and the structure of both cemented rockfill and cemented hydraulic fill has to be defined for each zone and the field conditions simulated in the laboratory. Structure also affects fill permeability and compressibility. From a study of the cemented fill in place, the effect of changes in the placement methods can be seen and then controlled to improve fill performance and economy. These features of cemented hydraulic fill and cemented rockfill behaviour are discus- sed and illustrated through reference to field and laboratory work undertaken at Mount Isa.

Jan 1, 1973

By Duncan GR

Having passed through a number of previous phases the best longwall results in Australia have shown a significant increase in the last two years. The results expected from a longwall face can be estimated from the ideal production rate, determined by the capacity of the equipment and the conditions in which it is installed, the utilisation, and the available operating hours. Back analysis of the results achieved suggests that, on average, recent improvements arise from the higher capacity equipment recently installed; the utilisation has in fact reduced slightly. Review of the constraints which limit the longwall results, i.e. shearer speed, AFC capacity, support, advance rate, and man travel speed, shows that little improvement can be expected in the ideal production rate in thinner seams. In thicker seams the AFC often proves the overriding constraint and further increase in equipment size could lead to increased future ideal production rates and is expected. In all cases a concerted effort to increase the utilisation achieved is likely. For deep mines with thin to medium seams this offers the most viable path to improvement; by contrast thick seams with highwall/shallow access may benefit from further increase in equipment size.

Jan 1, 1988