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The recovery of Copper by solvent extraction was arguably the most significant hydrometallurgical development of the 1960's. However, only dilute solutions at relatively high ph. could be treated effectively. ICVAcorga introduced in the 1970's the much stronger salicylaldoxime based reagents, which resulted in a dramatic change in plant configurations. So for example plants which normally use 3 extraction stages and 3 stripping stages could be reduced to 2 + 2 staging or 2 + 1 staging, even for high copper tenors at low ph. Leach liquors up to 40 g A copper are being treated at some locations so that almost any copper bearing liquor can now be purified by solvent extraction. Following a considerable amount of research and development effort ICI/Acorga have made further significant advances in the application of copper solvent extraction. The first of these is in computerised flowsheeting. In conjunction with ICI's Process Technology Department, Acorga have developed the Minchem Computer program, which uses laboratory generated equilibrium data to facilitate optimisation of metallurgical operating parameters. The program can operate in two modes, prediction and assessment so that given suitable extract and strip isotherms plant performance can be predicted for a given set of conditions. Alternatively existing plant performance can be assessed rapidly and accurately, thus providing a valuable quality control tool. Pilot plant work can now be restricted to evaluation of the physical aspects of the SX circuits, and to looking for the unexpected. Secondly using the patented 5-Nonyl Salicylaldoxime in precise admixture with a number of carefully selected strip modifiers, the Acorga M-range has resulted. Reagent selection from these new extractants can now be based on how the reagent can alleviate the remaining problems such as hydrolytic stability, transfer of iron, and organic losses by entrainment which may be related to particular features of the operating plant. Thus the Acorga M-range has enhanced and significantly extended the use of solvent extraction for copper, whilst refinements in the processing of metallurgical data has considerably simplified circuit design and analysis of results.

Jan 1, 1989

Models of the genesis of existing ore oodles and targetting of exploration for new mines are greatly enhanced by an-understanding of the plate tectonic environment existing at the time of mineral emplacement. In areas of recent or active tectonism, a study of the present-day crustal and upper mantle structure is an obvious starting point in unravelling the evolution of the accessible upper crust. Bougainville is the northern-most island in the Solomon Islands arc. A 7km deep trench almost 100km off its western coast marks the commencement of subduction of the Solomon Sea plate beneath the Pacific plate. As outlined by the seismicity, the subducted crustal slab under the southern half of Bougainville reaches the axis of the island at about 100km depth, from which point it dips near vertically another 300km into the upper mantle. Large surface blasts at the Bougainville Copper Mine at Panguna, Bougainville, Papua New Guinea were used to derive an unreversed upper crustal profile of the island. The crust appears to be relatively simple, being comprised of a 5km deep layer with a P-wave velocity of 4.5km/sec, overlying a l0km thick layer with a P-wave velocity of 7.2km/sec. Constraints on the 15km mantle depth were provided by the identification of both P to and S to P phase conversions of seismic waves from local shallow earthquakes at the Moho boundary. An upper mantle velocity of 7.95(¦ 0.15) km/sec was measured from travel times of selected shallow earthquakes along the strike of the island arc.

Jan 1, 1987

A novel approach to validate size distributions obtained from bubble sizing techniques is introduced. The experimental rationale consists in verifying whether the output features the anticipated bi-modality when two uni-modal populations (ca. 0.5 and 5 mm) are mixed in a bubble column. The degree of deviation is quantified by comparing the calculated and real proportions on a volumetric basis. A sampling-followed-by-imaging technique was used to proof the concept. The results showed the anticipated bi-modality in which the real and calculated proportions corresponded with a deviation of less than 15 per cent, considered good given the severity of the test. However, the deviation was correlated to the superficial gas velocity (Jg) in the column and was consistently against smaller bubbles. Possible sources of bias are suggested.

Jan 1, 2005

By Cox N

Fragmentation control is perhaps the most critical aspect of quarrying operations, potentially impacting on the costs of all down stream processes, and sometimes even on the economic viability of an operation. The focal points of studies to control fragmentation are generally the pattern of blastholes, the accuracy of drilling, and the most appropriate powder factor. Recent studies suggest that the performance, and consistency of performance, of explosive detonation in the blastholes may also be a significant factor impacting on blast performance in hard rock quarries. This paper presents the results of studies of bulk emulsion and watergel explosive performance, using blasthole velocity of detonation measurements, and its impact on fragmentation. Field studies show a strong correlation between blasthole VoD and blast fragmentation. Another aspect of explosive performance impacting on ease of excavation of blasted rock is muckpile displacement, from which estimates of effective heave energy have been made for different bulk slurry (emulsion and watergel) products.

Jan 1, 1995

By Davey P. T, Tsambourakis G

Mineralogical analysis of supergene sulphide ore recovered from areas close to the underground workings at the abandoned Mutooroo (South Australia) mine shows that the original sulphide minerals have undergone substantial alteration. The cause of this alteration is believed to be contact with the highly saline, acidic mine water. The copper is now present as a sulphide that can best be described as a copper- and iron-delicient chalcopyrite, CuxFeyS2, where in most cases x < y. The values of x and y vary from point-to-point within each grain.Leach tests under a variety of conditions show that dissolution of the copper from the supergene sulphide ore can be readily achieved, particularly when compared with the behaviour of Mt Isa chalcopyrite concentrate. For the supergene sulphide ore, an increase in the acidity and the iron(lll) concentration of the leachant re ults in an increase in the rate of copper dissolution.The results are briefly discussed in terms of the experimental in-situ leaching operation at Mutooroo, South Australia.

Jan 1, 1986

By Peres EC

The flotability of monazite, zircon and rutile in the presence of sodium oleate, potassium octyl hydroxamate and a commercial hydroxamate was investigated through microflotation tests in a modified Hallimond tube. Zeta potential determinations in the absence/presence of collectors were performed in a microelectrophoretical cell. The microflotation testwork showed that, in general, the flotability characteristics of all three minerals are very similar. Commercial hydroxamate is, by far, a stronger collector than the pure potassium octyl hydroxamate. Electrokinetic studies indicated that the adsorption of collectors shifts the isoelectric point (IEP) of the minerals towards lower pH values. These collectors also are capable of changing the zeta potential values to more negative figures in the pH region above the isoelectric point. An increase of the conditioning temperature, generally, enhances the floatability of the three minerals. A depressant is required in order that selective flotation is feasible in the system monazite-zircon-ruffle. Sodium metasilicate is an efficient depressant for zircon and rutile and affects only slightly the flotability of Monazite.

Jan 1, 1993

By Pathan AG

This research work is concerned with an investigation of the fracture toughness of sandstone, siltstone, and coal. Tensile failure trades have been examined with three different specimen geonetries, i.e; rectangular bar, round bar (in three point bending), and diametral compression discs. The Stress intensity approach, and J-integral methods were used to evaluate fracture toughness. Results from both approaches are discussed. True crack length was determined after pre-cracking, using the compliance calibration technique. Fracture toughness results of sandstone are independent of crack length and the size of the specimen. Fracture toughness may hence be regarded as a material property for sandstone. In cxnntrast fracture toughness values for !siltstone and coal are dependent on crack Length.

Jan 1, 1986

By Turner R. B

The authors have studied and analysed many mineral resource and related projects in Australia. These studies have lead them to conclude that the past performance of many project developers does play a major part in any external financial investment for new or expanding resource based projects. In this paper the authors look particularly at the influence of parties outside the direct control of developers and the effect of-these parties on projects and conclude with a number of points as guidelines for potential project developers. This paper represents the view of the authors only and should not be taken as a representation of the views of the Australian Resources Development Bank Limited.

Jan 1, 1980

During the last century Allis-Chalmers has supplied many screens of various types to industry, from revolving screens to the large capacity highly efficient screen available today. The features incorporated over these years in horizontal and inclined screens are varied and numerous and include many innovations such as tri-and bi-sloped screen decks. Today the emphasis is on wide vibrating screens with good "G" value, with large "throw", to achieve high capacity. Larger screens lead the way to treating a somewhat neglected area of mining operations - that of concentrator mine flotation tailings to allow effective transportation and stacking by conveyor belt. The benefits from a cost, water saving and environment view point are discussed in this paper.

Jan 1, 1984

By Treglown N

In any mining operation the curtailment of rising operating costs is of prime concern to management.One area of activity where costs are often disguised is that of longhole secondary breakage.This paper outlines sane operational techniques that have been considered and tested, resulting in improved fragmentation fran longhole stope blasts at New Broken Hill Consolidated Limited mine, Broken Hill, NSW.

Jan 1, 1985

The curbing of expansion in tertiary level education in Australia and the question- ing of its objectives which are now occurring are likely to have important effects on mining and metallurgical education. Student enrol- ments are low but the serious shortage of specialised minerals industry graduates pre- dicted during the boom of the late 60's has not eventuated. Other manning problems of a less quantitative but possibly equally import- ant kind have been identified. They point to a need for a full and deep review of the education and training programmes available to Australian graduates planning to enter product- ion areas of the minerals industry. An alter- native educational structure providing greater flexibility is suggested.

Jan 1, 1977

By Ormsby W. R, Farrar L

The stratigraphy of the central Pine Creek Geosyncline has been simplified into a three-fold subdivision comprising the Batchelor, Frances Creek and Finniss River Groups. The Batchelor Group consists of a sequence of shallow water coarse clastics and crystalline carbonates and is conformably overlain by the marine carbonaceous shale dominated Frances Creek Group. Interbedded within the carbonaceous shale are turbidites, iron formation, tuffs, carbonate and non carbonaceous shale. The Finniss River Group is a flysch sequence of greywacke and mudstone. The stratigraphic and structural evolution and igneous history are all interrelated. Although the Batchelor Group may have formed in a tensional regime, it is likely that regional compression and accompanying thin skinned deformation began during deposition of the Frances Creek Group. Continued compression resulted in D2 folding d6collement deformation, wrench faulting in compressional zones and thrust faulting. Occasional relaxation of compression is marked by a number of periods of basic intrusion and perhaps distal volcanism. The style of deformation within sediments varies away from granitic basement highs and is similar to that observed around salt domes and found in experimental diapiric models. Sedimentary facies changes also indicate local emergence of basement highs during sedimentation. As compression continued, the deposition of thick sequences of the Finniss River and El Sherana Groups brought about regional metamorphism. Relaxation of compression and waning of associated subsidence resulted in a relative increase in the rate of uplift and partial melting of diapiric sialic basement. In places, granitic magma moved upwards and crystallised forming grossly concordant bodies. Other masses moved laterally and formed extensive granitic sills. Later compression periods caused mainly brittle deformation which may have been strongly influenced by underlying basement fabric.

Jan 1, 1994

By R Berry

This paper looks at two ways to estimate the bulk mineralogy of the rocks for assay intervals. The aim is to find an efficient indicator of the most common minerals in the rock. Phase (modal) analysis has traditionally been done using visual methods such as point counting and image analysis. A modern version of this process is the X-ray point counting routine using the SEM-EDS based software. These methods are too slow and expensive for routine analysis of bulk sample mineralogy at the normal assay spacing.Two sources of data were considered that provide information that can be used to determine the mineral abundance in assay samples. The most widely applied method is (semi-) quantitative X-ray diffraction (QXRD). The QXRD method is most applicable to major minerals and has limited application to minerals at low abundance. The nominal detection limit is 0.5 per cent. Values below five per cent have large errors. A second, less common, method is calculation of mineralogy from chemical assay data. Conversion of chemical analyses to mineralogical analyses depends on the unique chemical composition of each mineral. Elements only found in one mineral are easily accounted for, but many compositions are ambiguous. Deciding on the actual mineralogy is not simple. Recalculation of mineral mode from chemical analyses is more accurate than QXRD when the correct minerals, and mineral compositions, are known.Where only a few QXRD analyses are available they can be used to setup a protocol for calculation of mineralogy from assay data. Linear programming works well in this environment. The best results are obtained when both H2O and CO2 are directly measured. Loss-on-ignition (LOI) should be included if these are not available.Where both QXRD and chemical analysis are available for all samples, the best results are obtained using the least squared method to merge the data sets assuming QXRD has much higher analytical errors than chemical assays. The combined method provides more robust results because the high abundance minerals are controlled by the QXRD measurements while the chemical assays improve the precision for low abundance minerals

Sep 5, 2011

By Merwin RA

The recent development of rare earth permanent magnets has revolutionised the field of magnetic separation. The advent of rare earth permanent magnets in the 1980s provided a magnetic energy product an order of magnitude greater than that of conventional ferrite magnets. This has allowed the design of high-intensity magnetic circuits operating energy free and surpassing the strength and effectiveness of electromagnets. New applications and design concepts focusing on the mineral and metal processing industries have evolved. This technology also led to the development of various magnetic separators specifically designed for mineral processing applications. Applications which were not previously considered are now being applied to primary mineral upgrading and recycling and secondary recovery.

Jan 1, 1993

By Matsushita Y, Maeda M, Sano N

The present study was carried out to explore the possible separate recovery of iron and phosphorus (as gas) from BOF slag using graphite crucibles or graphite powders in the presence of a tin bath. The last is consider- ed to enhance the activity of phosphorus in iron reduced from slag or not to absorb the phosphorus vapour readily. When the slag was reduced in a graphite crucible in contact with a tin bath, the phosphorus reduced from the slag was carried away in CO explosively generated by the reduc- tion of iron oxide. When graphite powder was used as the reductant instead, 78% of the phosphorus was removed from slag, only 3% of which was absorb- ed into the tin bath. The rest left the system as gas. Gaseous dephosphorization depends on the area of contact between slag and reductant as cll n.u the amount of the latter. the reduction behaviour was directly observed, using an X ray transmission technique, to conlirm the reaction mechanism.

Jan 1, 1980

By Theophili CN, Kapenis AP

Seismic tomographic imaging has been applied to determine the blast induced damage zones in bauxite pillars in underground mining. At the retreating stage, when pillar dimensions are reduced from 8 x 8 m to approximately 5 x 5 m, the' seismic tomographies reveal, through measurements of the P-wave velocities which is a measure of the degree of fracturation of the pillar rock mass, the presence of three zones within each pillar. In the external zone, where velocities recorded are below 750 m/s. extensive pillar damage occurs which is attributed to both the growth and coalescence of pre-existing cracks and even the creation of new cracks in the rock mass. This effect is in agreement with literature, when considering the peak particle velocity as a criterion for rock failure in tunnels. In the intermediate zone, where velocities range between 7S0-1000 m/s, damage to a much lesser extent occurs which is due mostly to growth of pre-existing cracks and widening of their apertures. The inner zone, where velocities exceed 1000 m/s, is considered to be unaffected by blasting. Simple remedial measures of low cost, which are based on blasting mechanics are proposed to minimise the blast induced damage zone and consequently the transition zone.

Jan 1, 1995

By de Bruin J H

A method new to Australia was used for sinking a vertical shaft at Broken Hill in the development of Pasminco Southern Operations No 5 Ventilation Shaft. The 6 m diameter shaft of 820 m depth was planned with a construction method which allowed access for ground support as sinking proceeded by mechanical excavation.The vertical shaft boring machine, known as the V-Mole, was originally developed in West Germany. The machine operates in a manner similar to a full face TBM but vertically and the cuttings drop down a previously constructed raise. The raise is subject to stringent tolerance on verticality and must remain stable for the duration of reaming.

Jan 1, 1993

The mining of mineral sands in coastal aquifers is often constrained by other land use conflicts and inappropriate controls imposed through a lack of understanding of environmental interactions and processes. The recent experience with the Tea Gardens mining operation illustrates how increasing our knowledge and understanding leads to more effective management of environmental problems. As well as a source of heavy minerals, the Tea Gardens sand bed serves as a town water supply source. From past experience it was believed that mining could cause undesirable increases in dissolved iron concentrations in the aquifer, but the reasons and mechanisms for this phenomenon were not clear. A water monitoring program was therefore designed for the mining operation which was aimed at protecting the water supply borefield from any detremental effects. After one year the results of the monitoring program were assessed in the light of new knowledge and understanding of iron hydrochemistry. It was found that the existing program was not achieving some of its major aims, and was therefore modified to a more effective and cost efficient program.

Jan 1, 1988

By McKenzie C. K, Stewart R. S, Simpson J

Blast control in small scale underground mining leads to improved fragmentation control, improved control over overbreak and dilution, and the optimisation of drilling and charging operations. Greatly improved control can be achieved through blast monitoring, to confirm proper implementation of blast designs and blasthole charging. Further improvements can be achieved through simple modelling, enabling blastholes to be placed in the correct locations and charged with the correct weight and strength of explosive. Improved design can be shown to significantly reduce overbreak and dilution, and even ground support costs. In one mine in Quebec, open stopes of widths varying from 2.5 metres to four metres and dipping at 36¦ to 38¦ were designed to achieve zero dilution using open sloping blasting practices. The first stope designed in this manner was monitored in detail and achieved its objective.A method for contouring damage around blastholes is presented as a basis for selection of drilling patterns, with particular application to the control of overbreak and dilution. Contouring can be used to provide reliable estimates of either overbreak or damage (where rock is broken het reynainc in nlarr)

Jan 1, 1993

The tankhouse of the electrolytic zinc plant at Nordenham is operating with a very high operating efficiency of 99 per cent. This has been achieved not only by strict control of the quality of the zinc sulphate cell feed solution but also by all the improvements in housekeeping in the tankhouse developed during the past years: aluminium cathode specification, cathode stripping cycle, edge strips, copper contacts, anode isolators, cell cleaning, fittings and washing devices. During 1987 to 1992 the casting department was completely remodelled in order to improve the quality of the zinc products, the safety of the operations and the flexibility. The remodelling includes the enlargement of the area for the casting shop, the storage buildings and the five casting lines on the same ground level. New lines for alloying products and for SHG25 kg zinc ingots have been constructed. The line for galvanising products has new equipment in some parts and the other lines have been modified.

Jan 1, 1993