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By Francis R. S, Campbell J. J

Aberfoyle's Hellyer Division has filtered very fine flotation concentrates using two different makes of pressure filter. At the Luina concentrator a Larox pressure filter was used to treat a combined Pb + Zn or bulk concentrate. At the Hellyer concentrator two Lasta pressure filters are being used to filter copper/silver, lead, zinc and bulk concentrates. Operating parameters and performance at both operations are described. In both concentrators it was found that correct cloth selection was critical and that cloth failures contributed significantly to downtime. Thorough preventative maintenance progammes were required to ensure adequate availability of both makes of filter.

Jan 1, 1989

By I Elias, E Moya, S Chaffer

This paper is based on a case study from a mine site that operates two gyratory primary crushers. These crushers were encountering problems, which included inconsistent P80, reduced liner life tonnage and, on some occasions, catastrophic failure of the liners.As part of an evaluation process, both crushers were ‘mapped’ using a technology for condition monitoring and modelling of the crusher’s wear components. The technology provides comprehensive coverage of the crusher’s concaves and mantle at 100 mm intervals. It also automatically assesses wear rate between inspections and determines the highest wear areas. Outcomes include projected optimum reline dates at target replacement thicknesses, the identification of asymmetrical wear patterns, and the accurate measurement of open and closed (OSS/CSS) side settings.A comprehensive study was performed to optimise the performance of both these crushers at site. Over a period of seven liner service lives, the strategies to improved performance included liner analysis (concaves and mantle profile analysis), tonnes per day (t/d) and tonnes per hour (t/h) analysis, mantle reutilisation, detection and control of loose concaves, and detection and control of uneven wear and hot spots.These strategies resulted in the improved mechanical and operational performance of both crushers through concave and mantle redesign, OSS/CSS control, accurate wear forecasting plus other initiatives.As a result of these initiatives, the site now experiences benefits which include consistent product size, increased tonnes per hour (t/h) for both crushers and the liner life tonnage has doubled. Additionally, further benefits include less downtime for crusher liner maintenance and the reduced cost of inventories by mantle reutilisation.CITATION:Elias, I, Chaffer, S and Moya, E, 2015. Improvements in service life and cost reduction for gyratory primary crushers through mantle and concaves optimisation – a case study, in Proceedings Iron Ore 2015, pp 115–128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By S Mitchell

Jetcrete Australia Pty Ltd, shotcrete contractor took the initiative in 2008 to discontinue the use of ‘road registerable’ concrete trucks for all underground works in Australia and internationally.The rationale for this decision was basic, safety. Historically these vehicles have been and still are involved in far too many accidents; this obvious trend needs to be addressed by engineering out the root cause of the problem which in this case is suitability for purpose.Road registerable concrete trucks have been widely used for the delivery of concrete in Australian mines for many years prior to and after the inception of wet shotcrete as ‘in cycle’ ground support in underground excavations around 1992. With this inception came a wide interest in the shotcrete process and an influx of new shotcrete contractors, all using road registerable concrete trucks to deliver the large volumes of Shotcrete required for these services and in turn largely increasing the use of these vehicles underground. The road registerable concrete trucks were difficult to control and each trip underground required the operators to maintain good management of the inherent risks. We virtually had no reasonable alternative for the industry and could only encourage the operators to drive with soft controls such as, reducing overall speed to a maximum of 15 km per hour when declining, regardless of the road conditions, coming to a complete halt prior to turning into any sharp corners, remaining in the same gear both inclining and declining.

Mar 21, 2011

By H von Blottnitz, A C. Keith

The influence of the life of a mine extends beyond its immediate vicinity both in geographic and temporal terms. Decisions around mine approvals are generally made based on economics, for the mine owner and immediate environmental and social impacts by governments and communities. The value from life-of-mine planning can also be viewed in a holistic frame across the entire value chain from mine to product user. This research examines the Carmichael Coal Mine in light of the holistic benefits and impacts along its value chain from the mine to relieving the lot of energy poor in India.CITATION:Keith, A C and von Blottnitz, H, 2016. Can Australian coal alleviate energy poverty in India – a case study, in Proceedings Life-of-Mine 2016 Conference , pp 52–56 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By S S. Kanchibotla, E J. Sellers, L Julian, A Musunuri

Fume events in coalmines are typically associated with wet conditions, soft ground and deep holes. An ACARP research project used laboratory and field testing combined with literature reviews, numerical models and field investigations to characterise the influence of these conditions on the propensity for fume. This paper highlights the results for soft ground and wet conditions and proposes a proactive fume mitigation methodology. A simple numerical model is used to show how fume arises in soft rock that yields more under the loading of high-pressure, water-resistant explosive blends than for ANFO. The blends cool more rapidly after detonation into the lower temperature zone favourable for NO2 production. Low-pressure, high detonation temperature explosives are loaded or charged into soft ground. Water resistance must be considered because soft, faulted and fractured ground can lead to fume from degradation by water flow and non-ideal detonation of product in cracks.A suite of tests were developed to quantify ANFO and emulsion blend performance over time that can be carried out in a mobile laboratory on-site. Index tests such as viscosity measurement and water resistance in beakers are proposed to quantify long-term product performance because small components, such as surfactant, prill impurities and prill fines, contribute to inconsistent product performance. Water ingress experiments and detonation tests aligned with field investigations identified and characterised the role of groundwater in damaging ANFO and causing fume.Fume risk management is achieved using a proposed proactive fume mitigation methodology to characterise influences such as seasonal rain variation, groundwater flow hydrogeology, rock mass strength and structure well ahead of blast design. The design of blasts and selection of explosive products to consider expected conditions will reduce fume, improve efficiency in the mine and offer cost advantages.CITATION:Julian, L, Musunuri, A, Sellers, E J and Kanchibotla, S S, 2015. Mitigation of post-blast fume in soft ground and wet conditions, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 511–518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Tack K

During its 28-year life the MHD ISP smelter has gone through two phases, each of about a dozen years. The first phase was a learning one; in the second phase the lessons were applied and throughput and production rose strongly. Early experience revealed the robustness and the flexibility of the Imperial Smelting Process. The experience was demonstrated by strong increases in the throughput of mixed lead-zinc concentrates and of secondary (oxide) zinc materials. Purchased material quantities rose from 175 000 tonnes/year to 200 000. The required capacity increase of the IS furnace to smelt the higher throughput was achieved by relatively minor modifications; for instance a change to the internal furnace profile gained an extra two square metres in cross sectional area. The furnace hearth area has remained practically unchanged over its entire history. The paper concludes that there is still more potential to be drawn from the process and MHD intends to sustain raw material input at a new level of 240 000 tonnes/year. However, this rate will have to be achieved under the imposition of more stringent environmental and product quality standards than ever before.

Jan 1, 1993

By E Mofya, R Kaunda, P Lever

One of the fundamental requirements for being able to optimise blasting is the ability to predict fragmentation. An accurate blast fragmentation model allows a mine to adjust the fragmentation size for different downstream processes (mill processing versus leach, for instance), and to make real time adjustments in blasting parameters to account for changes in rock mass characteristics (hardness, fracture density, fracture orientation, etc). A number of blast fragmentation models have been developed in the past 40 years such as the Kuz-Ram model (Cunningham, 1983). Fragmentation models have a limited usefulness at the present time because:The input parameters are not the most useful for the engineer to determine and data for these parameters are not available throughout the rock mass. Even if the input parameters are known, the models still do not consistently predict the correct fragmentation. This is because the models capture some but not all of the important rock and blast phenomena. The models do not allow for ætuningÆ at a specific mine site. This paper describes studies that are being conducted to improve blast fragmentation models. The Split image processing software is used for these studies (Kemeny, 1994; Kemeny et al, 1999).

Jan 1, 2001

By S B. Fitch, S A. Wilson, A J. R Barr, P R. Searle

Improving the safety culture and performance of any operation is a fundamental goal of every mine operator. Methods of implementing, or changing a culture have developed from the early methods of operant conditioning, for example rewarding crews for achieving nominated safety milestones i.e. 3 months Lost Time Injury (LTI) free through to the current model of engaging a workforce through education and empowerment. As a large scale and mature operation with multiple contractors, Telfer has been exposed to numerous programs throughout its history. This has provided the opportunity to build on and complement these systems by integrating key elements from each. SAFE 360° is a new approach developed to engage the workforce in a holistic approach to encourage positive behaviours across all facets of an individual’s life which results in a focus on situational awareness at all times, rather than being workplace specific. It is based on three key modules: • Emotional Intelligence • Mindfulness • Situational Awareness Each module has a series of modules that help enhance the individual’s sense of self, leading to an ability to self-reflect and self-manage whilst empowering them with the moral courage to challenge their peers to raise standards. Since commencing this SAFE 360° behavioural safety risk management journey in November 2017, we have witnessed a change in the way our workforce engages with each other, their workplace and with management. There has been an increase in hazard perception, identification and ownership of issues, and we have seen a significant decrease in site TRIFR rate from 13.7 to 5.7 (as of April 2019). This paper will provide an overview of the program, how it has been implemented, case studies to demonstrate outcomes and KPIs used to measure effectiveness.

Mar 15, 2021

By L Ding, B Xu, C Wang

In this paper, we introduce the term ‘LJC’ to refer to the LJC Automatic Magnetic Flotation Separator, which is an advanced technology developed by Longi Magnet, integrating various techniques such as hydro separation, magnetic flocculation, and magnetic columns. This technology combines gravity, hydro separation, and magnetic separation to achieve efficient and reliable separation processes. With its low maintenance requirements and high reliability, the LJC technology has proven to be effective in magnetite processing. The LJC technology offers two primary benefits when compared to traditional magnetic drum separators. Firstly, it can enhance the quality of the targeted or improved concentrate at a coarser product size by minimising the carryover of gangue minerals into the concentrate. Secondly, it can significantly improve the concentrate quality (eg achieving >67 per cent Fe) while maintaining similar liberation size and mass yield. In China, this technology has been widely adopted in magnetite processing, replacing traditional magnetic drum separators and fines flotation in the final stage of the process. Through collaboration with a magnetite producer in Western Australia, Longi Magnet successfully implemented the next-generation LJC Automatic Magnetic Flotation Separator to replace the original stage 3 magnetic drum separators. The application of the LJC technology resulted in an increase in product P80 from 32 μm to 43.1 μm, while maintaining a final concentrate grade of 65 per cent Fe. Additionally, the power consumption, measured in kWh per tonne of concentrate, was reduced by 10 per cent. By eliminating the bottleneck caused by the requirement of a coarser liberation size to achieve the desired concentrate grade, the plant’s throughput was increased by significantly. The LJC technology has demonstrated its ability to reduce the carbon footprint, improve concentrate grade and enhance mass recovery, offering an alternative solution for magnetite processing. The high-grade magnetite produced by the LJC technology is particularly suitable as a raw material for Directed Reduction Iron and green steel production. This paper introduces the principles of the LJC Automatic Magnetic Flotation Separator and provides details of its application in a magnetite operation in Western Australia.

Sep 18, 2023

By M Haest, O Dominguez, D Mittrup

Technological innovations and emerging analytical capabilities are transforming the way drill samples are analysed, with real-time mineralogical analysis made possible. In addition, new business/technical requirements are challenging long standing processes to incorporate more sources of information during planning in order to improve compliance to plan during mining and processing. Unfortunately, the new sources of information that are added do not always have adequate protocols in place to ensure quality data is collected.Spectral data covering the visible – near – short wave – midwave – longwave range are routinely collected by the Geoscience and Exploration department at BHP Billiton Iron Ore for accurate mineralogical identification. These data are used for geological interpretations (logging and modelling) and prediction of physical variables (metallurgical and geotechnical properties).This paper introduces how sampling and quality assurance / quality control concepts have been applied in the spectral data process. The described routine for sampling, data collection/management and reconciliation has been developed to track system precision and accurately and consistently ensure the data is of high quality before it is used across the mining chain.CITATION:Mittrup, D, Dominguez, O and Haest, M, 2017. A new approach to implement quality assurance and quality control to technological innovations – quality of spectral data capture and processes in the minerals industry, in Proceedings Eighth World Conference on Sampling and Blending , pp 265–270 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By G Booth

Whilst communications systems in the mining industry have evolved over the years, the premise remains consistent that reliable communication is vital for safety and operational efficiency. TodayÆs open pit mines are benefiting from advanced developmental efforts based on mesh networking hardware and software technology. This paper highlights Rajant CorporationÆs adaptation of technology, originally developed for the defence and first responder industries, to provide wireless network connectivity in open pit mining applications. Featured is the large-scale deployment of over 300 mobile, meshing access points in the Bingham Canyon Copper mine near Salt Lake City, Utah, the worldÆs largest open pit copper mine. Many companies have positioned themselves, their technology and their product line in the arena of rugged outdoor wireless broadband mesh networking infrastructure. However, Rajant Corporation has combined specialised command and control software and portable networks which offer network extensibility and redundancy that are not available in any other networking solution. Rajant CorporationÆs BreadCrumb« offers unique traits in portability and non-line-of-site networking nodes which intelligently route and broadcast in standard 802.11 protocol. The advantage of RajantÆs solution is especially valuable for users needing equipment moved easily and rapidly into and out of the theatre of operations with uninterrupted network availability. The main differentiators that set the BreadCrumb« network apart from the competitors are mobility (continuous availability), simplicity, ability to properly load balance and power options. In 2007, RajantÆs BreadCrumb« wireless mesh system was selected by the Kennecott Utah Copper Corporation (KUCC), a wholly owned subsidiary of Rio Tinto, as its primary communications platform for operations within the Bingham Canyon Copper mine, the worldÆs largest open pit copper mine. The Rajant BreadCrumb« technology enables KUCC to gain additional operational efficiencies by tracking, monitoring and managing its copper mining operations. The primary goal of using the BreadCrumb« wireless mesh system Kennecott was to streamline its complex mining operations. KUCC required a high number of moving wireless nodes for improving mine monitoring and control. The Rajant InstaMesh« software running on the wireless BreadCrumb« units connects hundreds of devices to each other while rapidly transporting critical operational data. Kennecott has successfully implemented a large number of BreadCrumb« radios in an interconnected network that allows loader trucks, shovels, pumps, laptops and other production equipment to communicate with each other in real-time. These systems are a mix of secure access nodes that enable data and voice communications across a meshed, self-healing network for fleet dispatch, health monitoring and other critical mining applications. Many of the devices that require wireless communications are moving at all times throughout the wireless mining infrastructure. The BreadCrumb« nodes rapidly adapt to any changes in the network topology, assuring that IP traffic uptime and bandwidth are maximised. The installation layout and data network specifics, as well as maps and data network efficiencies will be detailed in the paper.

Jan 1, 2008

By F Shi, W Valery

WMC Fertilizers (WMCF) operates a Beneficiation Plant at Phosphate Hill in Queensland, Australia. The plant consists of two-stages of crushing, followed by a wet scrubbing and desliming circuit. Ore is then fed to a tertiary crusher and a milling/classification circuit, with the final product going to a swing-lift thickener and storage tanks. From the slurry storage tanks, the phosphate rock is fed to a horizontal belt filters which dewater the phosphate rock ahead of a hemi-hydrate phosphoric acid plant. The water soluble recovery of phosphate in the phosphoric acid plant is dependent on the moisture content in the filter cake, as this governs the wash water addition to the hemi-hydrate filters. Since commencement of operation, the moisture content of the filter cake fed to the phosphoric acid plant has been higher than design reducing the phosphoric acid plant recovery and at times reducing the throughput through the phosphoric acid plant. The moisture content in the filter cake can be decreased by reducing the generation of fines in the milling and classification circuit (classified as û38 micron material). This paper identifies the causes of fines generation in the Phosphate Hill beneficiation plant. It discusses the options that were assessed to minimise fines generation, and outlines the results to date of circuit changes undertaken at Phosphate Hill.

Jan 1, 2003

By V Gumba, S Narendranathan, C Barker, R D. H Thomas, G P. Bungard

This paper presents the positive outcomes on an EPCM project, which was undertaken in a challenging environment, whereby the design team had to generate a design with a number of stringent serviceability criteria, any deviation from which would have had significant implications to the proposed design performance. The success of the design implementation within the tight time frame hinged upon the precise installation by a skilled contractor. The overall objective was achieved as a result of close collaboration between the designer and contractor ensuring all stringent quality assurance/quality control (QA/QC) aspects were met and opportunities to optimise design without compromising on performance were identified and implemented, resulting in a cost saving of over A$13 M.CITATION:Narendranathan, S, Thomas, R D H, Bungard, G P, Gumba, V and Barker, C, 2012. The importance of collaboration between designers and contractors in implementing a design in challenging conditions, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 97-102 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By B J. Hutchison, S Gannon, J Chambers, D Oko-oboh

The Kanmantoo copper mine is located in the Adelaide Hills area of South Australia and is owned and operated by Hillgrove Resources (HGO). The mine is a drill and blast, truck and shovel operation mining sulfide (chalcopyrite) ore located in chloritised andalusite biotite schist. The initial Kanmantoo open pit operation occurred in the 1970s, before falling copper prices closed the mine. In 2010 the mine was reopened by HGO and the Kavanagh cutback of the Kanmantoo pit was undertaken. The Spitfire, Nugent and Emily Star satellite pits were also mined through to 2015 before the latest steep wall Giant pit design was developed to take mining out to 2019.There are no major fault structures and only two significant shear zone structures exposed in the open pit walls. The main Garnet Andalusite Biotite Schist (GABS) unit is quite competent so the pit designs have therefore mainly been controlled by four distinct joint sets. This paper is a case study on the influence of the joint regime on the wall stability of the main GABS unit and how a better understanding of the joint regime and the use of rock reinforcement has allowed the steep wall design to be adopted.The paper also describes the remote geotechnical mapping and slope monitoring techniques used to manage the rockfall risks associated with the steep walled slope design.CITATION:Hutchison, B J, Chambers, J, Gannon, S and Oko-oboh, D, 2017. Case study of joint structure and the design and performance of open pit walls at the Kanmantoo copper mine, in Proceedings Tenth International Mining Geology Conference 2017, pp 355–364 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By C E. Woolley, A Hosseini, J Foster

Northern Star’s Thunderbox Open Pit C-Zone cutback was designed to maximise extraction in a short life excavation; In fresh rock on the western wall this included 20 m to 30 m bench heights with 6.5 m to 10 m berm widths and a 90° pre-split angle. Rock mass quality in this area is generally fair to good, however, there are sections where the dominant foliation runs parallel with the designed pit wall, and more closely spaced, altered, foliation is present: these areas are difficult to predict and prone to failure. Stringent controls and monitoring were required in order to safely access below these areas, in particular the use of slope stability monitoring radar, Trigger Action Response Plans (TARPs), re-entry procedures, visual inspections, drone inspections and day-to-day personnel awareness of the hazard. Robust and comprehensively planned remediation was also required after two significant slope failure events where long reach equipment and rope access techniques were utilised to remediate the areas in question safely, but also in a timely manner, such that expected production targets were impacted as little as reasonably practicable. This combination of rigorous risk management and well planned remediation resulted in a successful and complete extraction of the C-Zone cutback with no impact to operational safety.

Jun 22, 2022

By L Xiong, W J Shi, J H. Wei

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Baizhangzi gold deposit is located in the northern North China Craton. The structural and lithological controls on the location and geometry of orebodies were studied through geologic survey, ore spatial configuration analysis and structural analysis. The orebodies of the deposit comprise auriferous quartz-sulfide veins and disseminated gold-bearing sulfides. The auriferous quartz-sulfide veins are dominantly hosted by the NNE- (and NE- and NW-) trending faults, which are subsidiary structures of the regional NNE-trending F2 fault. The subsidiary NNE-trending faults, having sinistral reverse kinematics, are associated with the sinistral reverse kinematics event of the F2 fault, which happened under a regional S–N-oriented compression stress field. The subsidiary NE- and NW-trending faults appear to be compressive and extensional respectively. These NE- (and NW-) trending faults are restricted to the granite intrusion and are associated with a sinistral strike-slip event of the F2 fault, which reactivated under a NW–SE-oriented compression stress field. It makes significant influence on geological evolution and distribution of different ore types that the strike of the F2 fault presents significant transition from NNE- to NE-trending in vertical. The ore-bearing disseminated host rocks, with widespread silicification and pyritisation, distribute in the lower inner contact zone of the granite intrusion, especially in the lower wavelike boundary of granite intrusion.CITATION:Xiong, L, Wei, J H and Shi, W J, 2015. Structural and lithological controls on the location of orebodies in the Baizhangzi lode gold deposit in western Liaoning Province, China, in Proceedings PACRIM 2015 Congress, pp 193–200 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By E M. Gama, L Resende

The tailings are waste from mineral processing operations. The type of tailings of iron ore processing are classified into sandy tailings and mud. Already the overburden are showing significant levels of useful mineral. Both iron ore`s waste have in your composition phyllosilicates/clay that indicates the potential for use in niche markets as paving and cement. According to several studies, there are various technologies in bench and pilot levels that could be used on a large scale but there is not an economic environment, tax, regulatory and tax set. Many of these technologies are associated with the reuse of tailings and overburden in construction. All these factors influence for that so many initiatives remain in search formats and cannot advance to the new business format. There is no way to set goals of reuse of this waste, as already occurs in China, if there is not a fiscal, tax and economic structure to support such measures. The way to foster and ensure that reuse of tailings and overburden is an incentive for promoting a culture of circular economy that would allow the emergence of an ecosystem between the private, public and Government sectors with the objective of accelerating and subsidize the entire network of reuse of this waste. The closure of the mine could be the tool used to ensure and boost this ecosystem of reutilization to align it with the vocation of the area of the mining law. Following this model, the end of the mining activity could provide a financial return to the local population, a more effective environmental compensation and a reduction in costs related to the closure of the mine. In this study are shown how the Vale is working in the reuse of tailings and overburden.CITATION:Resende, L and Gama, E M, 2018. The challenges of the reuse of tailings and overburden, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 117–125 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By M Bouare, C Holland, K N’Diaye

Two adjacent open pits in Mali hosted by deeply weathered saprolitic materials were mined consecutively over the course of approximately 12 months. During excavation, both pits experienced significant displacement and tension cracking as the result of deeper than expected depth of weathering coupled with relatively steep slope angles and significant groundwater. In response, geotechnical and operations teams overcame numerous monitoring challenges with prisms and radar to develop a simple and effective monitoring system coupled to a Trigger Action Response Plan (TARP) which enabled continued safe operations while reducing ore loss. Observations of previous slope performance of these two pits allowed for greater confidence in empirical failure runout calculations that was used to specify the standoff widths for the exclusion zones in the pit. Back analysis of the slope as-built performance after the first indications of slope distress was also conducted. The back analysis was used to confirm rock mass parameters for modelling while being utilised as a reality check for the stability analysis. The stability analysis indicated that leaving a large step-out or buttress would not prevent the displacement, resulting in some ore being sacrificed to ensure the safety of personnel. Key learnings from this experience highlight the importance of: • up-to-date geological interpretation of the depth of weathering • ensuring slope design guidance is reviewed and updated as latest information (ie geology and monitoring) is received • having multiple complementary slope monitoring methods to ensure redundancy • ensuring visual observations and as-built performance are utilised as a reality check to provide greater confidence in stability analysis and design guidance.

Jun 22, 2022

By Jephcott S

The McArthur lead-zinc-silver deposit is of the stratiform type. It consists of a mineralized bituminous shale sequence containing some tuffites, numerous graded beds and isolated slump breccia horizons. The principal sulphides; pyrite, sphalerite and galena, are essentially restricted to the shales and the genetically unrelated turbidites contain only minor mineralization. The geochemistry of the deposit has been investigated with respect to the stratigraphio column and mineralogy of the sediments.

Jan 1, 1980

By Grady B. V O, Cavell K. J, Ault A. R, Newman O. M G, Malcolm J. McPhersqn

Cyclic voltammetry (CV) has been evaluated as a technique for monitoring the quality of an industrial zinc sulphate electrolyte. The basis of the method involves measuring a change in the polarisation of the zinc nucleation reaction at an aluminium surface and relating this to the impurity content and/or the overall quality of the electrolyte. Specifically, the technique aims to be able to indicate and quantify detrimental synergism between impurity elements, something which traditional analytical techniques are incapable of providing. The technique has found some success with regard to monitoring glue additions in a range of metal electrolytes. It has been found that investigations by a number of workers over the past 15 years have produced variable and often misleading results due to the inadvertent use of commercial purity aluminium working electrodes. It has been shown that impurity elements in the working electrode can give rise to a range of responses that are not obtained when pure aluminium is used and that the response is variable due to the lack of surface homogeneity of commercial purity aluminium electrodes. Furthermore, it was demonstrated that previous detection limits reported in the literature were based on the presence of additional peaks in the cathodic scan and not polarisation effects. The results of this study have shown that when a pure aluminium working electrode was used, the method was incapable of detecting any change in polarisation for an electrolyte containing three common impurities (Co, Ni and Ge), at concentrations that would significantly reduce optimum electrolytic performance. A range of methods was tried to sensitise the technique, including raising the temperature and acidity, and adding antimony in order to induce some synergism. In all cases the polarisation response was unchanged. Consequently, apart from the commercialised application for monitoring additions of antimony and levelling agents such as glue, CV has very limited application as an electrolyte screening technique.

Jan 1, 1993