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POSITIONS VACANT Wanted, for a new smelting company now being organized in China: one man familiar with the design and operation of a zinc smelter; one experienced in the design and operation of a lead smelter; and a chemist competent to make the usual analyses in connection with lead and zinc smelting and to make clay analyses. Men with their wives preferred. Company will pay all expenses to and from China, medical attendance, salary, bonus per ton of zinc or lead produced, allowance for food, and furnish quarters. No. 120. . . ENGINEERS AVAILABLE (Under this heading will be published notes sent to the Secretary of the Institute by members or other persons introduced by members.) Member, oil geologist, age 33 years, technical education, nine years' experience with oil and mining companies, wishes employment with repu-

Jan 8, 1916

By L. F. Engle, M. A. Hewedi

SUMMARY Initial interest in using solutions of ammonium salts to leach native copper was documented in notes from an AIME meeting in 1871; By 1916-1917, application of the NH3-CO2-H2O system to recover nonferrous metals attained commercial significance, when it was used as a process for copper recovery by Kennecott Copper Corporation and Calumet & Hecla Mining Company. The Caron work in the early 1920s, Freeport Sulphur Company’s achievements leaching Cuban laterites during World War II, out- standing accomplishments in both eastern and western Canada, recovery of manganese related to the work of Dean -- all serve as landmarks as this One Century Review surveys a base for future technology. Current emphasis on compatibility of metals-producing systems with the need to meet environmental protection criteria provides special encouragement to researchers and engineers to find accept- able ways of recovering metals. The ever-present demand of management to design, build and operate facilities on a profitable basis provides additional impetus to apply information from the technical literature to that need. Examination of the general approach to this paper will reveal much that is firm and positive with respect to empirical results -- extractions, recoveries, amenability to familiar proven equipment and materials of construction common to the industry. Although there are many references, there are gaps in the basic scientific data that if filled could lead to even more usefulness; the paper attempts to indicate where further information is needed.

Jan 1, 1973

By Ronald J. Roman, Craig Olsen

Alterations were performed on a previously developed heap leaching model representing sulfuric acid solution leaching of a malachite sandstone ore. The alterations were made in order to approach a more realistic solution to the leaching equations used in the model and to provide a means of obtaining a constant acid con- centration in the model' s simulated heap effluent solutions. This constant acid concentration is desired if the effluent solutions are to be treated in a solvent extraction-electrowinning plant. An economic study was made showing a use of the leaching model for an imaginary heap leach operation. The example illustrates a method of selecting heap leaching parameters if data are available on mining costs, dump costs, capital cost, etc. This was achieved using an incremental investment technique.

Jan 1, 1974

By J. A. Rajala, R. W. Smith

The effect of increasing ionic strength, via monovalent and divalent ions, on alkyl sulfate flotation of hematite and quartz war investigated. The effects of collector chain length and pretreatment on this flotation were also studied. Sodium hexadecyl sulfate was shown to be a superior flotation collector to sodium dodecyl sulfate for recovery of hematite when there was no salt addition. Similar observation were made when sodium sulfate or sodium chloride was used to control ionic strength. Sodium dodecyl sulfate floated hematite better than its longer chutited counterpart under conditions of low pretreatment temperature and increasing calcium chloride concentration. The flotation recovery for all salt containing pulps was almost always improved after preboiling. Most of the results obtained when the pretreatment temperature was raised were attributed to increased solubility of the collector.

Jan 1, 1984

By J. A. Jr. Church

I. EARLY FURNACES. . COPPER blast-furnace construction in America has long recognized a general standard in the rectangular water-jacketed shaft with separate forehearth. The details, however, and especially those relating to shaft dimensions, have had to meet a great variety of conditions, and show no uniformity whatever. Selecting a few of the present day Western plants, we find furnace lengths varying from 12.5 to 87 ft., widths at tuyere level from 42 to 84 in., and heights above tuyeres from 5 ft. 4 in. to 22 ft. 4 in. ; and comparing present designs with those of the past, we meet contrasts no less striking. Unlike its transverse section, the length of a furnace has come to depend rather on the size of unit desired than on the requirements of smelting ; and if the question of length be ignored, several of the various existing designs can be grouped together on the basis of a common transverse section. This section, having a width at tuyere level of 56 in. and a height above tuyeres of 18, ft., was developed at Great Falls, and the story of its development contains some interesting features. Ground was broken for the Great Falls works in the spring of 1891. About a year later, the concentrator was able to begin operation, followed within the next few months by the Brueckner, reverberatory, and converter departments, and in April, 1893, by the first blast fur-

Jan 7, 1913

By Roshan B. Bhappu, Thomas J. Lien

The DYNA WHIRLPOOL Processor (DWP) is a cylindrical dynamic heavy media vessel. It is used to beneficiate fine ore sizes from one and one-half inches in diameter down to 65-mesh. Process units available treat up to 80 tons per hour. Units can be manifolded for higher capacity plants. Finely ground magnetite and ferrosilicon are used for media. , Installed capital costs are from $4,000 to $6,000 per ton hour of feed. Operating costs are from $0.30 to $0.50 per ton of feed. The DWP is used to beneficiate metallic and non-metallic ores and coal. The OCC Vessel is a static heavy media separator used to beneficiate coarse ore up to six inches in diameter and auto scrap. Process units available treat up to 300 tons per hour.

Jan 1, 1978

By B. J. Scheiner, A. G. Smelley

The Bureau of Mines, US Department of the Interior, is conducting research on a dewatering technique for fine particles generated during the mineral beneficiation process that will recover a portion of the water now being lost using conventional waste disposal methods and significantly reduce the time required for land reclamation. The technique utilizes a flocculant, polyethylene oxide (PEO), that forms strong stable flocs that can be dewatered rapidly on static and/or rotary screens. Infield tests, phosphate clay waste has been dewatered from a nominal 2.5% solids to greater than 20% solids. In other field tests, coal-clay waste has been dewatered from a nominal 3% solids to greater than 55% solids. In addition, small-scale continuous tests have shown that bentonitic clays can be dewatered from 12% solids to 40% solids.

Jan 1, 1985

By Philip Schane

THE subject of steel cleanliness has always been a major one in the steel industry and much study and effort have been expended toward improving the cleanliness of steel and meeting the ever increasing demands of customers for steels that will give better performance in service and permit economies in design and efficiency of the final product. Sometimes wee may feel that-these demands are unnecessarily stringent, and probably this is true in some instances. However, the pressure for higher quality has acted as a stimulus toward improving quality and, therefore, has tended to promote progress. In this paper, the whole subject off cleanliness is covered in a general way. In the discussion' on steelmaking practices, remarks have been limited to basic electric- furnace practice in the making of alloy steels.

Jan 1, 1947

By Dave H. Barnett, Brij M. Moudgil

The flotation technique as employed by Florida phosphate producing companies for the beneficiation of fine phosphate particles has been standardized over the years. Lower recoveries of coarse phosphate rock by froth flotation technique, however, led to the development of new methods based on skin flotation of phosphate agglomerates. Recent developments of floating coarse rock in large flotation machines have not yet convinced the rock producers of their higher separation efficiency. It is interesting to note that the selection of a particular machine is still based on equipment preference by an individual company as well as proven performance of a particular machine for upgrading a specific material. Various techniques which have been developed to beneficiate the coarse phosphate rock have been discussed. Performance of the individual techniques is presented.

Jan 1, 1980

Wabush Mines is the largest single supplier of iron ore to the Canadian steel industry, with 42% of its 6 million tpy of iron ore production going to the company's two Canadian owners-The Steel Co. of Canada and Dominion Foundries and Steel Ltd. Six other companies hold interests in Wabush Iron Co. Ltd. These are Lykes-Youngstown, Inland Steel Co., Intrerlake Steel Corp., Wheeling-Pittsburgh Steel Co., Finsider of Italy and Pickands Mather & Co. Field work on Wabush began in mid-1957 when a long-range program of economic, geologic, and metallurgical investigations started. This work was followed in 1959 by the construction of a temporary camp and a 700-tpd pilot plant. At the same time, work was also started on a 38-mi railway connection to Ross Bay, Newfoundland.

Jan 1, 1970

By A. E. Hunt, G. P. Clapp

This paper constitutes in substance a part of a more elaborate chapter, accompanied with extended tables of analyses, prepared for the book of Mr. Fred. H. Whipple on " Water-Supply." In advanee of that use of the material, however, it seemed appropriate to lay a portion of it before the Institute; and this opinion of the authors, the Council, by accepting the paper, has ratified. It may seem at first glance, nevertheless, that a paper dealing chiefly with this subject in its sanitary aspects, and only treating in a subordinate way of the one subject (boiler-scale) usually deemed to concern our professions, is somewhat out of place in our Transactions. But reflection will, we trust, correct this impression. In recent periods, and in continually increasing degree, the managers

Jan 1, 1889

By J. O. Lewis, Carl H. Beal

Introduction ............................... 492 Theories Relating to the Recovery of Oil.................. 493 Methods Commonly Employed for the Estimation of Future Production..... 495 Saturation Method........................... 495 Production Curve Method....................... 496 Production per Acre Method.....................: 496 Appraisal Curves.............................. 498 Derivation and Construction...................... 498 Comparison of Appraisal Curves of the Osage and Nowata Fields...... 505 Use of Appraisal Curves........................ 506 Accuracy of the Apprais?l Curves and Their Sources of Error........ 508 Relation Between Future Productions of Wells of Equal Output....... 510 Use of Appraisal Curves for the Derivation of Generalized Future Decline Curves. 513 Theory of Generalized Curves Showing the Decline in Production...... 513 Suggested Methods for Making Closer Estimates.............. 517 Use of Logarithmic Coordinate Paper.................... 518 Summary................................ 520 Introduction Oil wells usually reach their maximum daily output shortly after they are completed. From that time they decline in production, the rapidity of decline depending on the output of the wells and on other factork governing their productivity. The production curve of a well shows the amount of oil produced per unit of time for several consecutive periods; if the conditions affecting the rate of production are not changed by outside influences, the curve will be fairly regular, and, if projected, will furnish useful knowledge as to the future production of the well. By the aid of this knowledge the value of a property maybe judged, and proper depletion and depreciation charges may be made on' the books of the

Jan 1, 1918

By Edward Estabrook

THE Salt Creek oil field in Natrona County, Wyo., is the largest pool that has been found in the Rocky Mountain region and one of the largest in the United States. Many features of its production records are of peculiar interest, because of the unusual slowness with which it has been developed. This paper is published by the permission of the Midwest Refining Co., whose records have been freely drawn upon. Many mem¬bers of the Midwest organization have assisted in the collection of the material, but Messrs. F. E. Wood and L. E. Smith have been particularly helpful. The Salt Creek oil field is situated on a great dome with a closure of about 1500 ft., which rises at the northern end of a long anticline extending north-northwest by south-southeast for fully 25 miles. The productive area includes parts of townships 39 and 40 north and ranges 78 and 79 west of the sixth principal meridian. The Teapot oil field occupies a minor dome at about the center of the same anticline and adjoins the Salt Creek oil field on the southeast. The Teapot Naval Reserve includes the Teapot Dome and about 760 acres of the Salt Creek dome. In this paper, the Salt Creek oil field will be considered as' including all of the dome, except that part which lies within the Teapot Naval Reserve and the area west of the dome where oil is produced from shale crevices.

Jan 9, 1925

By L. M. Pidgeon

The reactive metals are above manganese on the electromotive series. Their compounds are characterized by large heats of formation and they cannot be reduced from their ores by classical methods. Three general production methods have been used: a) Fused salt electrolysis, b) reduction of a halide by another metal, and c) reduction of the oxide by another metal. Method (a) is highly developed, as in the case of aluminum, (b) in the case of titanium, and (c) has been successful in the case of volatile metals such as magnesium and calcium. It is suggested that future improvements will take place in (a), and particularly in (c), but are rather less likely in the case of (b). THIS year of 1963 is the centennial of the birth of both Charles Hall and of Heroult, the founders of the aluminum industry. Aluminum is the one reactive metal which has reached massive stature in modern industry and perhaps the only such metal to have been produced in any quantity before the turn of the century. It has been joined by others, some on a very modest scale, but all of importance and all of fascinating interest. When invited to give the Fifth Extractive Metallurgy lecture, it seemed appropriate to look back upon the short history of this group to trace the developments which brought extraction methods to their present state and, at great risk, offer opinions as to future trends.

Jan 1, 1963

By M. G. F. Söhnlein

IN THE metallurgical treatment of sulfide silver-tin ores mined at Oruro, Potosi, and Chocaya, the most important and difficult step is chloridizing-roasting. The ores are chiefly mined from veins in rhyolite, a detailed description of which can be found in most textbooks on ore deposits. The chief gangue minerals are Pyrite and quartz, and the silver content is derived from tetrahedrite, jamesonite, stibnite, and cylindrite. Most of the tin is present in the form of a rather impure cassiterite, which forms microcrystalline aggregates of varying richness with quartz and pyrite; occasionally, some tin is found as stannite, cylindrite, and other complex sulfantimonates. The silver content of the minerals that compose the ore is approximately as follows: Pyrite, 3 to 5 oz. per ton; jamesonite, 30 to 50 oz. per ton; stibnite, 30 to 150 oz. per ton; cylindrite, 200 to 300 oz. per-Jon; tetrahedrite, 500 to 3000 oz. per ton. Occasionally, some ruby silver ore is found, but it is very rare. In the mines of Oruro, which are the deepest in the sulfide zone, tetrahedrite has nearly disappeared, stibnite, jamesonite, and, in the deepest levels, cylindrite taking its place. At present, there are six mills treating this ore, two at Potosi, two at Chocaya, one at Poopo, and one at Machacamarca. The ore is crushed dry, given a chloridizing roast, leached with water and hyposulfite solution (or with brine) to extract gold, silver and copper, and concentrated for tin with or' without regrinding.

Jan 8, 1920

By John Garcia

IN some districts of the bituminous coal field the problem of construct-ing bulkheads to seal off water under pressure is becoming increasingly important. Recently this matter has been brought very much to the front by the loss of a large. Illinois mine due to failure of a bulkhead that separated it from several old, flooded mines. As this great misfortune has provoked much inquiry about proper bulkhead design, it is felt that a description of the successful and extensive water-sealing practice at three mines that have different natural conditions will be of considerable interest to those connected with properties having a present or future water problem and to engineers that may have to design safe bulkheads of economical construction. These three mines are the Saxton acid Dresser, near Terre Haute, Ind., and the Hegeler, near Danville, 111. All three have water conditions that make it necessary to regularly seal off till worked-out sections of the mine, and there are considerably over a hundred bulkheads in each. As far as the writers know, these three mines are the only ones in the bitu-minous coal fields of the United States with anything like so large a number of water seals and experience, although a number of other mines are known to have a few bulkheads. More detail will he included herein on the Saxton mine than on the others, as the writers are more familiar with it.

Jan 1, 1937

By J. W. Rutter, K. T. Aust

The motion of individual grain boundaries under a constant driving force was investi,qated for zone-refined lead, with and without solute tin additions. The rate of boundary migration was found to depend strongly on tin content and on the orientation relationship between the adjacent grains. The results are compared with the theory of impurity-controlled grain boundary miqration developed by Lucke and Detert. Evidence was found that grain boundaries separating grains which have the Kronberg-U&apos;ilson orientation relationships of 38 and 22 deg about <Ill> and 28 deg about <100>, correspond to boundaries of high mobility. The results are discussed in relation to the formation of annealing textures in metals and the structure of high-angle boundaries. It is generally known that small amounts of impurities in solid solution greatly influence the re-crystallization behavior of metals. For example, the addition of 0.005 at. pct of tellurium to copper,&apos; or 0.005 at. pct of silver to lead,2or 0.01 at. pct of manganese or nickel to aluminum3 greatly decreases the rate of recrystallization of these metals. However, this effect may be the combined result of a decrease in the rates of both nucleation and growth; recrystallization experiments do not separate these two factors. Bolling and winegard4 determined the effects of small quantities of tin, silver, and gold on grain growth in polycrystalline zone-refined lead.

Jan 1, 1960

By Thomas S. Nye

Mineral exploration in the United States relies heavily on theoretical geologic concepts and indirect methods such as geophysics and geochemical prospecting, as there are few exposed areas of mineralization which have not already been explored. In Mexico, ore grade samples can be cut at the surface on vein, replacement, and disseminated types of deposits in many areas. The problem is not in finding a mineralized area but in deciding which mineralized area can be explored and developed at the least risk and cost, with the greatest profit potential within the framework of Mexican mineral economics and that nation&apos;s government policies. Socio-economic Posture Mexico, prior to World War II, had suffered from more than one hundred years of intermittent wars and exploitation by internal and foreign elements. Consequently, the basic facilities which today&apos;s society takes for granted were scarce or non-existent in most of the country. Travel was largely a matter of negotiating poor dirt roads, riding horseback or walking. Relatively few people were literate and medical facilities were luxuries for the wealthy. Mexico&apos;s leaders were, however, determined to improve the lot of their people, within a system of private enterprise and personal freedom. Long-range programs initiated at about the time of World War II to provide infrastructure-education, health and welfare, transportation, power, water, communication-are now established fully or in part for most of the country and are being continually expanded.

Jan 12, 1972

By Eugene Coste

In a recent paper&apos; I took exception to the opening paragraph of Mr. Hill&apos;s paper, in which he says:— " In endeavoring to interpret the geological occurrence of oil, the geologist is confronted by the fact that science has not yet solved the problem of its origin, which lies at the root of the subject.... For the present we must consider oil as a material in the rocks, the origin of which is still unexplained." I take this occasion to repeat my objection to the above statement, as well as to the similar statement of Mr. C. W. Hayes and William Kennedy in their recent bulletin2 on the same oilfields :—" The origin of petroleum is one of the most obscure problems by which geologists are confronted." I do not hesitate to say that these statements, which claim we know so little to-day of the origin of petroleum, are not warranted in the present state of geological science, and that, on the contrary, geology can to-day most clearly prove the origin of oil to be inorganic and the result of solfataric volcanic emanations. It has been so long assumed that oil or bitumen is due to the decomposition of the organic remains of the sedimentary rocks, that the words organic and bituminous are used synonymously and, accordingly, without attempt at explanation, the origin of oil is in every case ascribed to some bituminous-shale horizon, more or less full of organic matter. Such falla

Jan 1, 1905

Greater automation of facilities is probably the best hope of the mining industry in its efforts to surmount continually rising labor costs. Underground mining, with its inherently low unit labor output, is especially vulnerable to rising costs, and here maximum automation is becoming increasingly important. One area of such operations that has been receiving a great deal of investigation is that of ore haulage and hoisting, two steps that often account for 10-35% of underground operating costs. Innovations and experimentation by mining firms and manufacturers over the past few years have resulted in larger, faster and more efficient tramming and hoisting equipment, but the White Pine Copper Co., at its operation in the Upper Peninsula of Michigan, is preparing to start up an entirely new concept in haulage later this summer. Known as the Dashaveyor System, it consists of individually powered modules (cars) that run on tracks inside a rectangular tube or on an open trackway at predetermined speeds up to 50 mph. At White Pine the Dashaveyor will be used to carry ore (crushed underground to -10 in.) from the mine to the concentrator. Dr. James Boyd, president of Copper Range Co., which is a 25% shareholder in The Dashaveyor Co., has indicated that if the Dashaveyor meets the expectations for surface operation, it will also be used underground for ore transport in place of the several miles of conveyor belts currently in use (Business Week, July 29, 1967).

Jan 7, 1968