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By M. K. G. Vermaak

There are practical indications that flotation recovery of palladium bismuth tellurides is poor. This work tested whether this can be caused by a lack of interaction of the collector with the telluride. Impedance measurements, voltammetry and Raman spectroscopy were performed to determine the interaction of dithiocarbonate collectors (KEX) with Pd-Bi-Te. Impedance measurements showed lower capacitance values in solutions containing KEX, indicating the formation of a continuous surface layer. Anodic and cathodic polarization diagrams show the mixed potential to be higher than the reversible potential of the xanthate-dixanthogen equilibrium reaction; hence the formation of dixanthogen on the surface is possible. Electrochemically controlled in situ Raman spectroscopy did indicate the presence of bulk diethyl dixanthogen on the surface. Raman spectroscopy has confirmed the co-presence of xanthate with dixanthogen, indicating that xanthate retains its molecular integrity when it adsorbs on the surface of the Pd-Bi-Te. As a result, the mineral surface is expected to be hydrophobic and alack of collector interaction with the mineral is not the reason for the low PGM recoveries experienced. Keywords: Raman spectroscopy; Pd-Bi-Te; ethyl xanthate; platinum flotation; Great Dyke; Pd-bearing bismutho-tellurides and moncheite.

Jan 1, 2004

By D Blair, T Scutts, L Fergusson

This paper presents a waste rock treatment and rehabilitation program conducted at a metaliferous mine site in northern New South Wales from 2000–2013. It updates findings from 2005 for Program #1 (which examined acidity, leachable metals and tree growth in a control and three treated areas of waste rock) and includes new results for Program #2 (which examined acidity, plant uptake of metals and trace elements and tree growth in a control and four treated areas compared to undisturbed background levels) and Program?#3 (which examined the treatment and revegetation of submerged mine tailings and an exposed tailings beach).Program #1 showed low soil pH in the control area remained unchanged from years 1–14, and soil pH in the limed and capped areas was initially increased but fell back to starting levels within 12 months and remained low for 14 years. In contrast, soil pH in the Terra B area resulted in soil high pH immediately after treatment and increased in years six and 14 without further treatment. Tree height and density in 2005 and again in 2013 indicated acidity in the control, limed and capped areas suppressed tree height and density; however, in the Terra B area, revegetation in 2013 was comparable to undisturbed forest. Outcomes in the control, biosolids and three Terra B areas in Program #2 were similar to those observed in Program #1.Program #3 showed the submerged and exposed tailings initially had low pH and high concentrations of total and leachable metals before treatment, but these became non-leachable after treatment with Terra B. Revegetation was achieved on the tailings beach, with almost uniform colonisation of bulrush and common reed, along with bottlebrush and golden wattle; a variety of reptiles have also been observed on the revegetated tailings beach, along with migrating ducks, spoonbills and grebes.CITATION:Fergusson, L, Blair, D and Scutts, T, ?2014. Treatment and rehabilitation of acidic waste rock and tailings – a 14-year case study, in Proceedings Life-of-Mine 2014 , pp 247–260 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

The small scale alluvial gold mining industry in Papua New Guinea (PNG) is c.irrently the only form of small scale mining carried out in this country. It already contributes significantly to the economy with current production estimated at 2 000-2 500kg per year. Until recently, small scale alluvial gold mining has been confined to simple panning and sluicing of high grade alluvial and colluvial deposits. Traditionally the small scale miner in PNG has only worked gravels with gold grades in excess of 500mg/m3. Grades of this order are required to justify the hard physical labour involved ~n hand operated small scale mining methods. .he introduction of higher throughput technologies such as trommels fed by hydraulic excavators has the effect of altering what constitutes an economically viable deposit. Mechanised techniques allow for the consideration of grades of almost half that level. The potential and opportunities for utilising this type of small scale mechanised mining in PNG are enormous with large areas of ground with gold grades running in excess of 250mg/m3 and often up to 2000mg/m3 throughout the country. An assessment of the current operating economics of this technology in the PNG context is the principal objective of this paper. Small to medium scale mechanised mining can potentially contribute significantly to the PNG economy particularly as it lies within the react-, of many PNG businessmen. Its potential is currently somewhat limited by a general lack of infrastructure and is also constrained by socio-political factors.

Jan 1, 1991

By S. L. George

The semi-solid metal casting process results in a unique solidification path. The microstructural features that were identified during the characterization of the as-cast microstructure, were used as evidence of the process history in order to determine the solidification path followed during the evolution of the microstructure. The morphology of the grains was characterized using SEM and the extent and distribution of the elemental segregation within the grain structure was analysed using EDS. Keywords Semi-solid casting, solidification path, segregation.

Jan 1, 2011

The Bureau of Mines has reviewed those portions of the "Tariff Schedules of the United States Annotated 1963" that are of interest to the minerals industry. This study shows to what extent rates of duty were altered (increased of decreased), and provides a bridge where possible from the old Schedule A classification system to the new TSUS system of statistical reporting of import data. In general the new tariff has corrected previous classification defects and inconsistencies, but the rates of duties have not been materially changed.

Jan 1, 1965

By B. W. Dunning

This paper describes studies conducted by the Bureau of Mines to achieve its goal of developing methods for increased recovery and utilization of valuable constituents in a wide variety of domestic and industrial wastes, In this particular study, 36 units of obsolete electronic equipment from military aircraft were disassembled into their modular components by hand to determine materials distribution. Further modular disassembly into individual parts was used to identify metal composition. After identifying the metals in some of the more difficult to dismantle modules, similar modules were grouped together, shredded, mechanically separated, and using metal composition data from hand separation, classified along with the hand-separated materials. Although this equipment is normally classified as law-value iron-bearing aluminum, data were obtained that indicated the potential for moderately higher value classification. The electronic units were classified as to precious metals, copper, iron, and aluminum contents, and scrap values were estimated.

Jan 1, 1980

By Arnulf Muan, Egil Aukrust

Activities of COO in the three solid solution series COO-MgO, COO-MnO, and COO-"FeO" have been determined at 1200°C by equilibrating oxide samples with a metal phase (cobalt or a Co-Fe alloy) in atmospheres of known oxygen activities. The systems COO-MgO and COO-MnO are ideal, within limits of experimental error, whereas the system COO-"FeO" shows a slight positive deviation from ideality at the temperature of this investigation. KNOWLEDGE of activities of oxide components in solid solutions is necessary for the calculation of the cation distribution among coexisting oxide phases in many important metallurgical, ceramic, and geochemical systems. Very few activity-composition curves are available for such systems at the present time. A start on the prodigious job of obtaining such data has been made by studies of solid solutions with simple sodium chloride type structure containing NiO or "FeO" as a component.1-3 The present paper describes similar studies for solid solutions with sodium chloride type structure containing COO as a component. For the systems COO-MgO and COO-MnO, the activity solid solution is determined by the equation Here po and are the oxygen activities of the gas phase in equilibrium with the phase assemblages metallic cobalt plus oxide solid solution, and metallic cobalt plus pure COO, respectively. In the system CoO-"Fe07', the metal phase is a Co-Fe alloy rather than pure cobalt. In this case the activity of COO in the oxide solid solution is calculated from the equation where a& is the activity of cobalt in the metal phase. Because the system Co-Fe is close to ideal4 and the metal phase appearing in the present work contains less iron than cobalt even at the lowest COO concentrations of the oxide phases used may be set equal to N . Hence, Eq. [2] becomes The value of Nc, can be estimated from the relative stabilities of the oxides COO (see below) and I) EXPERIMENTAL METHOD Two different but closely related procedures were used in the present investigation to determine the activity-composition curves. In one method, the oxide solid solutions were equilibrated against

Jan 1, 1963

The dissolution of the naturally occurring mineral zircon (ZrSiO4) is examined after ball milling it with magnesium oxide for up to 100 hours in a laboratory mill. There was little effect on the solubility for the initial two hours where size reduction of the zircon was considered to be the dominant effect. Beyond two hours the dissolution increased as a function of the square root of milling time. X-ray diffraction of the powders did not reveal the identity of the soluble phase. However, a nanocrystalline phase was present after milling and this is thought to be the soluble phase.

Jan 1, 2000

By G. Roy Chaudhury

Adsorption techniques are comparatively low cost and effective for treatment of arsenic contaminated drinking water. Various adsorbents such as alumina, ferrihydrite and manganese ores have been used, but there has been little investigation of modifying the structure of ferrihydrite to improve its adsorptive efficiency of As(III) and As(V). In the present study the incorporation of manganese oxide into the ferrihydrite structure was carried out and the prepared materials used in arsenic adsorption experiments. The compounds were X-ray amorphous, but TGA/DTA and FTIR analysis showed some structural characteristics. Sorption studies reported in this paper indicate the excellent arsenic removal properties of the manganese/iron compounds with a loading capacity of 0.3 mmol/g. Adsorption follows first order kinetics and the results fitted to adsorption and mass transfer models. Arsenic levels in water containing 1 mg/L As(V) were reduced by 50% in 20 minutes and 90% in 60 minutes using 1 g/L manganic ferric oxyhydroxide.

Jan 1, 2003

These proceedings consist of an overview of the in situ mining research currently being carried out by the Bureau of Mines. The following papers emphasize two general aspects of the in situ mining method: the environment and productivity. Both areas are extremely important, particularly because in situ leach mining is a relatively new mining method from a commercial point of view. Topics covered include the restoration of ground water, the selection of lixiviants, in situ mining of commodities other than uranium, in situ mining costs, the application of resistance measurements to in situ mining, an acid leach mining case history, and the use of branched boreholes for in situ mining. A bibliography of Bureau of Mines publications on in situ mining is appended.

Jan 1, 1981

By A. J. MOORE

When the writer first saw the square-set timbering, he was at once impressed with the fact that the frames made by the sets, along the lode and across it, were composed of panels with rectangular openings, and it was puzzling to understand howsuch a collapsible construction could resist pressure that came unevenly on it. Later he learnt that the sets did not satisfactorily resist such pressure, but mullock filling had, to a great extent, to undertake this duty for them. So it appeared that the setswere practically an expensive scaffolding, enabling the miners to work in the face and carry the stope forward, till the filling was put in behind them to take the pressure of the roof and sides of the excavation. Of course some of the pressure is takenby the sets, but this is because "the set timbers prevent the filling being done perfectly; if it were practicable to remove the sets before filling, the filling by itself would more effectively support the back and wall, than do the combined sets andmullock. On the whole, therefore, the sets can hardly be said to be of much benefit where pressure has to be resisted. Despite this, the system has been of immense service in mining wide lodes, but for all that, it can only be pronounced a makeshift.This is no reflection on Deidesheimer, the famous originator of the square set, for, as will be shown later on, this way of...

Jan 1, 1912

By J. M. Goris

Cable bolt supports are becoming an important ground control technique in underground mines in the United States and Canada. They show great versatility and are adaptable for use with many mining techniques, they have high load-carrying capacities, they can be installed in small areas with low roots, and they are cost effective. Investigators in a number of research institutes in North America have conducted studies to assess the material and support properties of cable bolts, evaluate their support capabilities under various mining conditions, and provide design criteria for using cable bolt supports as roof control systems under varying mining conditions. While conducting these studies, personnel have collected important information on the history, application, performance, and economics of these supports. This U.S. Bureau of Mines report documents this information so that ground control personnel unfamiliar with cable bolt supports can gain an understanding and appreciation of their use. A comprehensive bibliography of technical information on cable bolt supports was selected by the authors and is also presented.

Jan 1, 1994

By P. H. Morris

To achieve the full potential of sub-aerial co-disposal the properties of the co-disposed wastes must be known and understood. A description is given of the morphology and properties of waste deposits that were formed during 19 field trials of sub-aerial co-disposal at the dual Goonyella-Riverside mine in Queensland and at Hunter Valley No.1 and Warkworth mines in New South Wales

Jun 19, 1905

By J. H. Soulé

"The Copper King copper-gold-silver deposit was discovered about 1880. Various individuals and companies have been interested in the deposit and considerable work has been done, although production, if any, has been small. The deposit is located in the western part of Laramie County Wyo., and is favorably nituated with respect to rail and truck transportation and high-tension power facilities.Mild summers and cold winters characterize the climate. Precipitation averages between 16 and 17 inches annually, with considerable snowfall in the winter. Permanent streams are small and most available water in being stored for use by Cheyenne, Wyo. Range grasses comprise the bulk of the vegetation, with small treed and shrubs common in the most rugged areas.The deposits lie upon land owned by Wyoming, now leased by a group of Wyoming and Colorado businessman constituting the Copper King Mining Co.Primary copper-gold mineralization seems largely confined to an equigranular, relatively fine grained gneiss that is part of a pre-Cambrian complex of metamorphic rocks ranging from schists to pegmatites. The copper minerals are oxidized to a depth of from 100 to 150 feet, with the occasional occurrence of secondary minerals at greater depths. The copper minerals chalcopyrite, malachite, chalcocite, bornite, cuprite(?), and some native copper were observed in Le deposit.In addition to the 4,030 feet of diamond-core drilling in 11 holes done on the deposit by private companies, the Bureau of Mines drilled 3 holes for a total of 2,630 feet. The sample results of this drilling plus available data from previous drilling and sampling are appended to this report."

Jun 1, 1955

By M. K. Larson

The U.S. Bureau of Mines and Cyprus Shoshone Coal Corp. conducted a study of deformation mechanisms in strata around a longwall gate road system at two sites in an underground coal mine near Ham, WY. Of particular interest was timedependent (on the order of several months) roof deformation. Strata above and below the coal seam are very weak, carbonaceous mudstones that have cohesionless planes of weakness oriented along bedding, which dips approximately 8° to 16° at N 49° E. An extensive array of instrumented roof bolts, roof extensometers, and biaxial stressmeters were installed during development mining at these two sites under variable depth of cover [I83 to 335 m (600 to 1,100 ft)], seam dip (10° to 16°), and top coal thickness [estimated to be 0.30 to 0.61 m (1 to 2 ft) on the downdip side of the entry]. Bolt load and roof deformation histories during the entry development periods were compared. Bolt loads at site 2 were less than those at site 1, which is consistent with the amount of overburden. Deformation magnitudes at site 2 were similar to those at site 1, but deformation rates were approximately 44% greater and nearly constant over time, whereas the deformation rates at site 1 decreased exponentially over time. Also, most deformation occurred above the bolt horizon at site two, but extensometer measurements at site 1 showed that a significant amount of deformation occurred within the bolt horizon. The most significant factor that influenced bolt tension and timedependent strata deformation was strength and Young's modulus of the strata. Finite-difference models support this conclusion.

Jan 1, 1996

By E. V. Lilford

Valuators of mineral properties are faced with a range of valuation methodologies, the most important of which are grouped under the headings of the market approach, the cost approach and the income approach. The way in which value is defined and the detail of the different valuation methodologies is examined here. This paper aims at documenting the variety of valuation procedures and applying each method to a variety of gold projects and comparing the outcomes. Any decision to apply a valuation technique will depend principally on the stage to which the project has been developed. The valuation approach to a greenfield project will be substantially different from that applied to a well-drilled, extensively explored mineral property. Furthermore, a valuation exercise may produce different outcomes for the same gold project depending on which method is applied. In order to investigate the variability in valuation methods and to explore the outcomes of different approaches, a series of five gold projects was analysed. The projects differ in regard to levels of capital application, infrastructural setting, depth below surface, in situ grade, and the stage of development, and were valued using the different methods. The most critical aspect of any valuation is the capacity of the valuer to identify the salient issues and ensure that they are incorporated into the valuation. The danger of simply applying ?black box? solutions to valuation problems without a full understanding of the parameters and the areas of uncertainty is emphasized. The importance of the valuator?s experience, insights into best practice and the ability to recognize and submit to the requirements of compliance within the minerals industry is among the most important characteristics of a valuer.

Jan 1, 2005

By Wils L. Cooley

This report analyzes electrical accident data in the metal/non-metal mining industry. Accidents are categorized to determine their root causes. Special attention is given to accidents associated with inadequate or defective grounding of mine power systems. Recommendations are made concerning proper grounding practice, especially for dredges and for quarries in hard rock or sand. The costs of instituting the recommended practices are estimated for model mine power systems which are based on field data obtained from 37 mines and several electrical contractors. The expected benefits of various suggested safety practices are also estimated.

Jan 1, 1981

By Winmill T. F.

The previous papers have been concerned only with the atmospheric oxidation of coals from the Barnsley Seam, for which it has been shown that an adequate explanation of the origin and nature of gob-fires can be based on the reaction between the coal itself and the oxygen of the air without the intervention of any other substance. It becomes of importance, therefore, to ascertain how far a similar explanation will hold good for spontaneous heating in other seams, and with this object in view samples including anthracite and lignite have been taken from a considerable number of pits in different parts of the UK (south Wales, Northumberland and Durham, north Staffordshire, Portrush and Ayrshire), some liable to fire, others not. There is abundant evidence to support the commonly-accepted view that spontaneous heating is due to the heat evolved during the absorption of oxygen from the air by coal or pyrites. The quantity of heat produced by the reaction has been measured and it has been shown that the observed rate of heating of a sample of coal agrees with the rate calculated from the heat of reaction and the rate of absorption of oxygen

Dec 1, 1916

concentrations) and physical nature of receiving streams, which in turn affects the stream ecosystem. Benthic macroinvertebrates are used to illustrate these impacts, and to investigate natural recovery in affected streams. In Charming Creek, a severely impacted stream in the Buller District, the macroinvertebrate community recovers diversity and the proportion of sensitive species (EPT) in the community is more significant with increasing downstream distance from the source of AMD. This is most likely due to dilution of AMD contaminated water by tributaries to the Charming Creek mainstream. Other impacted systems with less dilution from tributaries did not display similar levels of recovery. The effectiveness of remediation products BauxsolÖ and Zeolite was investigated using laboratory trials. Both products mitigated the toxicity of AMD and enhanced the survival of mayflies exposed to AMD contaminated water. Such products may be of use in the New Zealand environment but are likely to be most effective in conjunction with other systems (eg wetlands). Mitigating the impacts of AMD on stream ecosystems needs to include systems to directly address water chemistry issues (low pH, high metal concentrations) as a component of a holistic approach to restoring environmental conditions.

Jan 1, 2003

By John P. Borovsky

A 3-year study was conducted to evaluate the problems and benefits of using vegetation to stabilize tailing from a potential Minnesota copper-nickel milling operation. The project consisted of three separate investigations: a waste characterization study, a greenhouse study and a field study. With few exceptions, the physical and chemical characteristics of the tai ling were found to lie within the range of properties of Minnesota soils. The tailing lacks organic matter; is deficient in nitrogen, phosphorus and potassium; and may contain elevated levels of soluble salts and heavy metals, particularly copper and nickel. Numerous grasses, forbs and woody plants will tolerate the tailing as a rooting medium. Peat incorporation and topsoil dressing provided few benefits to the revegetation process which were not provided by a fertilizer application. With fertilization, grass/legume production in the tailing was comparable to local agricultural yields. Concentration of heavy metals in grasses grown in the tailing were generally below suggested tolerance limits for plants and animal forage. Legumes tended to accumulate higher concentrations of copper and nickel, and metal uptake of most plants was positively correlated with rate of fertilization. Tailing drainage water contained elevated levels of heavy metals, and establishment of vegetation had little effect on the quantity and quality of tailing drainage water. However, topsoil dressing significantly increased drainage water volume when compared to unvegetated control plots. Copper-nickel tailing revegetation recommendations were developed.

Jan 1, 1983