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By Eugen Gluck, Gus Van Weert, Peter Kondos

"Microwaves have the capability to heat up sulphides, especially clusters of particles of approx. 1 mm. Some sulphides absorb microwaves more readily than others. Molybdenite is especially effective in this regard, possibly due to its flaky nature and/or electrical conductivity. Even where it occurs in low concentrations in a deposit, individual rocks may be ore grade due to the high monetary value of MoS2. Such rocks often result from crushing mined veinlets or stockwork, or are contained in the cutoff grade fraction of ROM. Machine segregation of rocks high in MoS2 by infrared sensors after microwaving could therefore advantageously be used to upgrade lower grade ore between Mine and Mill. This would reduce the size of the latter, and thus its CAPEX and OPEX. Such upgrading could also yield shipping ore for a distant Mill, or extend ore reserves.Barrick Gold Corp. has been supporting the development of MW/IR sulphide sorting for the past three years. The results of MW/IR sorting work on molybdenite and other (pyritic) ore samples from a variety of sources are being presented here.INTRODUCTIONThis paper looks at mechanized, i.e. machine ore sorting technologies currently available and under development, and what conditions would be needed for the potential application of such ore sorting to sulphide mining and milling. Current machine sorting involves no-contact sensing technology for rocks, and signal processing after sensing to activate airblast segregation of certain rocks, normally the smallest mass to keep compressed air costs down.The forerunner of modern sorting is probably magnetic separation, which utilizes an inherent property of certain ores to divert it into mag and non-mags fractions. Radiometric ore sorters, which have been applied successfully for decades in the pre-concentration of uranium ores (Wotruba and Riedel, 2006) initiated modern sorting. In the 90’s, sensor-based machine sorting became a viable means of increasing the overall economic recovery of a resource. This technology became driven by the availability of low cost computing equipment and the concurrent development of algorithms, and by the availability of extremely fast response sensors and air actuators, allowing the sorting equipment to run faster, dropping the cost per tonne. It has been in industrial minerals processing that rock sorting has been most widely adopted, not really surprising. Liberation occurs on a different scale than in the base metal industry. Most industrial minerals are mined from massive deposits, requiring (in the past) no upgrading. Many of these operations now run into product contamination problems, which ore sorting can solve. One illustration: in Finland, a quarry is separating limestone from dolomite at 500 tonnes / hour, with individual rocks weighing up to 15 kg. Many of these industrial minerals operations have stockpiles of earlier discarded below-quality rocks, now being reprocessed with the help of ore sorting. The economics of this are very favourable, going from zero or negative value (stockpiles can not be left when closing the mine) to full product value for at least a portion of the stockpile. This suggests that in the future the economics of overburden sorting could become attractive under the right circumstances and such treatment could well become an integral part of open pit mine development."

Jan 1, 2009

By R. V. Ramani

One area of study in the Coal Mine Injury Analysis project was to illustrate and enhance the ability of mine safety management personnel to apply analytical techniques to injury experience data and to justify requests for funds for safety enhancement actions on a cost/benefit and other quantitative basis. Four volumes of this final project report detail (1) the objective and scope of the mine safety management research, (2) the results of literature review, and case studies, and (3) models developed for mine safety management. The four volumes are titled as Volume III: Mine Safety Management, Volume IV: Analytical Techniques for Mine Safety Management; Volume V: Mine Safety Management Case Studies and Volume IX: Training Cost Model. In this volume, the following material is presented: (i) review of related literature, (ii) mathematical models to perform quantitative analyses of accident/ injury experience data using the tools and techniques of risk analysis, time series analysis, and the Markov process, and (iii) descriptions of the HDBSEL and ACIM programs which are used to perform accident/injury experience analyses and cost analyses, respectively.

Jan 1, 1993

By Ramin Motamed, Joseph A. W. Toth

Evaluation of the capacity of large-diameter drilled shafts using current load test methods present challenges when considering the magnitude of loads required to fully mobilize their capacities. Often, these full scale tests do not fully mobilize the capacity through side resistance. Therefore, the need for innovative solutions to extrapolate side resistance and interpret nominal capacity are of key interest. In this study, we evaluate three methodologies for extrapolating unit side resistance based on bi-directional load test data. Fellenius (2001) presented these methods for interpretation of pile capacity using static load tests. Our interpretations are based on the evaluation of 116 load tests. Unit side resistance was calculated and reviewed for each load test and categorized using three criteria of mobilization; (A) full, (B) partial and (C) linear. This study specifically focuses on load tests that showed fully mobilized unit side resistance behavior (Criteria A). The three methodologies were applied assuming Criteria (A) load tests were mobilized to 50% of their measured values. Subsequent comparisons of each extrapolation were then compared against the full measured values for each test and generally showed good agreement. INTRODUCTION It is widely accepted that conducting load tests such as standard top-down tests or bi-directional (i.e. O- cell) tests can help designers understand load-settlement behavior and the nominal resistance of drilled shaft foundations. These load testing methods provide the advantage of confirming design assumptions as well as improving the reliability of the foundation design. The potential cost savings from the application of these methods for mid to large size projects is self-evident. For example, in a recent project in Northern Nevada, an O-cell test on a 6.9 ft diameter, 114.8 ft length drilled shaft imposed an initial cost of $125k to the project, resulting in a 15% reduction on the total foundation cost; equivalent to $1.3 million in overall savings (Pease, 2014). However, the costs of implementing such methods on smaller projects can be prohibitively expensive (Hagerty et al, 2016). Despite the clear advantages of drilled shaft load testing, the current practice is not without limitations. Performing load tests on large-diameter drilled shafts with high capacities is a challenge considering the significant loads required to fully mobilize the capacity of such foundations. In some cases, the feasibility of these tests is impractical because the associated initial cost is not guaranteed to outweigh the final savings. As a result, large scale load tests are sometimes ruled out from the design phase of projects. Furthermore, in the majority of load tests the magnitude of loads applied are specifically selected to not approach failure, so the shafts can be used in the future foundation system (i.e. production shafts). This practice of field testing restricts our knowledge of the true capacity of the drilled shaft at failure; hence the nominal resistance remains unknown.

Jan 1, 2018

By Frank Chase, M. Terry Hoch, George Karabin, Joseph C. Zelanko, Christopher Mark

Pillar recovery continues to be a significant ground control hazard. During the past decade, 10 miners were killed during pillar extraction operations in southern West Virginia. Studies conducted during the past decade have identified a number of “risk factors” that can be used to evaluate pillar extraction plans: •Cut sequence •Final stump •Timber or Mobile Roof Supports •Roof bolting •Intersection span •Depth of cover •Roof quality •Age of workings For each of these factors, rock mechanics science suggests which alternative would be expected to be more risky. For example, numerical models were used to evaluate different cut sequences, and indicated that less roof convergence occurred with the outside lift method than with the Christmas tree in the particular environment simulated. For many of the risk factors, accident statistics confirm the science. One finding was that currently almost 70% of the retreat coal in southern WV is being mined with MRS. In contrast, timber supports were used in 70% of the past decade’s pillaring fatalities. This paper discusses each of the risk factors in turn, presents the relevant accident statistics, and shows how the risk factors can be combined to estimate the overall hazard. It also addresses the use of pillar design to minimize the risk of global stability hazards including squeezes, massive collapses, and bumps.

By C. E. Birchenall, H. M. Schadel

THE purpose of this study was to measure the vapor pressure of silver as the first step in the determination of activities in silver alloys and to test the limitations of the method adopted. In order to work at low pressures, below 2x10-2 mm of mercury, the orifice effusion technique was employed. To shorten the time of collection of silver from the atomic beam, radioactive silver (Ag110) was used as a tracer. The rate of effusion of a monatomic vapor from an "ideal" orifice, where the thickness of the orifice edge is negligible compared with the orifice diameter, can be readily calculated from the kinetic theory of gases, G = vM a p/v2pRT where G is the weight of material effusing from the orifice per unit time; p is the vapor pressure at oven temperature, T; R is the gas constant; M is the molecular weight of the vapor; and a is the orifice area. Consolidating constants and expressing as the weight of material effusing from the orifice in a period of time, t, (5.83)(10-2) (vM) (a) (t) (p)/vT where GT is total weight of monatomic vapor effused (g); M is molecular weight of the effusing tracer vapor; a is orifice area (cm2); t is time of effusion (sec); p is vapor pressure of effusing material (mm of Hg); and T is oven temperature (OK). The vapor effuses from the orifice in a hemispherical pattern, and the intensity of the beam in any direction is given by the cosine distribution law.' Considering this, the weight of effused material can be calculated from the amount of material passing through a circular collimator intersecting the beam. If such a collimator is in a plane parallel to the plane of the orifice and with center on the normal to the orifice center, GT = G?/1-cos2? = G?/sin2? where G? is the weight of effused material passing through the collimator, and 0 is one half the apex angle of the cone defined by the collimator circumference and the orifice center. Reducing eq 3 to the more directly measurable quantities of orifice to collimator distance, d, and collimator diameter, D, the expression becomes,

Jan 1, 1951

By Thomas H. Wilson

Common offset and refraction seismic data have been collected over four longwall panels at two different locations within West Virginia. Surveys prior, during and after mining were made in both areas. The velocity of seismic wave propagation in the overburden rocks is observed to decrease in response to panel emplacement. Variations in the magnitude of this reduction, apparent as an additional first arrival time delay in the after mining common offset surveys, do not appear to correlate directly to the amount of subsidence that has occurred. Velocity reduction and signal absorption zones are also produced in the cover beyond the panel face over the adjacent unmined areas. Signal absorption and velocity reduction zones have also been observed over room and pillar entry areas between mined panels. Velocity reduction zones have been- observed beyond the panel face in both shallow and deep mines, but the signal absorption zone has not been observed over the deeper mine. Changes in the compressional wave velocities of the cover rocks are associated with changes in their elastic moduli. Differences between borehole derived and surface seismic derived interval velocities, are related to differences in the properties of the bulk volume sampled by each method.

Jan 1, 1988

By José R. Parga

In some parts of the Comarca Lagunera with population of about 2.5 million people, situated in the central part of northern México, chronic arsenic poisoning is endemic and severe adverse effects attributed to As exposure have been reported. Lifetime exposure to arsenic will develop classical symptoms of arsenic poisoning such as skin pigmentation changes, gastrointestinal disturbances and neurological changes. There are several methods available for removal of arsenic from well water in large conventional treatment plants, however a very promising electrochemical treatment technique that does not require the addition of chemicals or regeneration is Electrocoagulation (EC). The EC operating conditions are highly dependent on the chemistry of the aqueous medium, especially conductivity and pH. In this study, Powder X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Transmission Mössbauer Spectroscopy (TMS) were used to characterize the solid products formed at iron electrodes during the EC process. This study will provide an introduction to the fundamental concepts of the EC method. Finally the results of this study suggest that the presence of maghemite and magnetite particles can be used to remove arsenic (III) and arsenic (V). In the field pilot plant scale study more than 99% removal of As species from groundwater is achieved.

Jan 1, 2005

By M. E. Poad, J. K. Whyatt, T. J. Williams

Researchers at the U.S. Bureau of Mimes monitored rock mass response to mining of an experimental underhand longwall stope in Hecla Mining Co.'s Lucky Friday Mine, Mullan, ID. This stope design, the Lucky Friday underhand longwall (LFUL), was proposed as a means of controlling rock bursting while also allowing increased mechanization of mining operations. Instruments were specifically manufactured to monitor three geomechanical factors (backfill performance, ramp stability, and rock mass response) that directly affect the success of stope design. Despite considerable difficulties with instrument installation and survival in the harsh mine environment, especially within the stope fill, sufficient information was collected to suggest that the LFUL method was successful in achieving project goals. This conclusion, in addition to favorable economic and operational evidence, led the mine to adopt the method throughout the mine. Indeed, this study and mining experience suggest that underhand longwall mining could be considered a feasible mining method for rock-burst-prone ground throughout the Coeur d'Alene District. Further Reports of Investigations (RI) in this series present in-depth analyses of the effects of backfill on rock bursting and calibration of a stope numerical model.

Jan 1, 1992

By Natalie J. Shackleton, Deryck de Vaux, Cyril T. O’Connor, Vratislav Malysiak

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. The objective of the study was to investigate the effect surface passivation and inadvertent activation have on flotation and how this can be managed so as to increase the separation of pentlandite and pyroxene. The aim was to minimise the percentage pyroxene reporting to the concentrate and simultaneously maximise the pentlandite recovery. The testwork incorporates the addition of an activator (copper sulphate), a complexing agent, such as DETA (diethylenetriamine) and a dispersant (polyphosphate) at pH 6 and pH 9 in an attempt to alleviate the surface passivation of pentlandite and inadvertent activation of pyroxene. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion."

Jan 1, 2003

By Y. Wang, K. S. E. Forssberg, A. Johansson, X. Lu

This paper presents the desulphurisation of a fine graphite powder below 80 µm by high gradient magnetic separation. The removal of pyrite (FeS2) and pyrrhotite (Fe1-xS) from the fine graphite powder was carried out with a modified version of the Sala dry HGMS with vibration assistance. In addition, a comparative study with dry and wet HGMS systems has also been performed. In order to establish the performance of the desulphurisation, a test series of varying parameters such as magnetic induction, matrix type/configuration and vibration were performed. As an equipment/process for removing sulphurous impurities from the fine graphite powder, the dry HGMS is deemed useful and comparative with the wet HGMS.

Jan 1, 2002

This report is the 25th in a series summarizing Bureau of Mines research and technologic work on coal and related investigations, and the 7th of these reports to be issued on a calendar-year basis.3 It reviews briefly work in progress during 1960, and furnishes references to publications by Bureau personnel during 1960 and also to a few older papers that were not cited in prior reports of this series. Details about some of the researches mentioned can be found by referring to the publications cited in the footnotes or in the further list in the Miscellaneous section; other phases of work are reported here for the first time and will be covered in more detail by later publications, Coal programs of the Bureau of Mines extend over the wide range of theoretical and applied studies indicated by the table of contents. Fundamental research on coal structure and on the properties of coal will, over a period of time, increase the general knowledge about coal Which scientists and engineers may use in answering practical questions and in solving problems in the mining and utilization of coal. More applied studies are conducted in connection with the developement and evaluation of new mining techniques and the effective processing and utilization of coal and of coal products. Health and safety activities, analyses of coal being mined, and technical advice and assistance to Federal agencies in connection with fuel and boiler-water problems are among the practical services handled by the Bureau.4 5

Jan 1, 1962

By Steven R. Munts

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 39,420 acres of the 60,960-acre Skedaddle Wilderness Study Area in order to evaluate its identified mineral resources. There are no known mines or mining operations in the study area. None of the prospects or claims in or within a 1 mile peripheral zone around the study area have recorded production. At least 276 recorded lode, 6 unrecorded lode, and 29 placer claims have been located in and within about 1 mile of the study area. Approximately 191 of the claims are in the study area. Four of these were current in 1985; all four are wholly or partly inside the study area. None of the study area was being explored by private industry in 1985. Metallic and nonmetallic commodities present in the study area consist of gold, mercury, perlite, basalt, pozzolan, stone, and sand and gravel. Perlite is represented by a single deposit which contains 184,000 tons of subeconomic resources in and adjacent to the study area. No other sites contained identified resources. There are no other identified nonmetallic resources in the study area. Occurrences in and near the study area contain small amounts of gold and mercury in vein-type deposits and show characteristics similar to bulk-tonnage, low-grade gold deposits. No base-metal resources were identified. The gold and mercury mineralization and perlite deposit are spatially related to a volcanic center located in the Skedaddle Mountains. Prospects in the Skedaddle Mountains may contain both precious metals and perlite resources, but additional work is required to adequately delineate these areas.

Jan 1, 1987

By E. Esponosa-Gomez, J. A. Finch, A. R. Laplante

"Water quality plays an important role in oxide flotation. The effects on selective flotation of fine (1-16 um) pyrochlore of two types of water used at the Niobec concentrator, potable and plant recycle, were assessed. Several pyrochlore collectors and silicate depressants were tested. Water effects were different for each mineral-reagents) combination. In general plant recycle water decreased selectivity and increased reagent consumption. Interpretation of results is given in terms of electrokinetic effects, hydrolysis of cations, and mineral-collector interactions. Two techniques of treatment for plant recycle water, cation precipitation and zeolite adsorption were assessed. The former was found to be more effective under the tested conditions but recycle water continued to give poorer selectivity than the potable.INTRODUCTIONWater quality plays an important role in selective flotation. Specific effects have been reported by many workers (1-6) and in general the better the water quality the more selective is flotation. Water composition depends on origin and the minerals being processed. For example pulp containing salt-type minerals (calcite, apatite, dolomite) will contain more Ca and Mg cations than that from a sulphide deposit. Another source of water contamination is the flotation reagents added to the pulp, particularly if water recycling is practiced."

Jan 1, 1986

By J S. J van Deventer

Geopolymerisation is a new technology that processes and transforms aluminosilicate minerals into mechanically strong and chemically stable products. In this investigation, minerals such as fly ash and kaolinite were used as the solid raw materials for geopolymerisation. Inorganic salts were added to the geopolymeric pastes to simulate ionic contamination during processing for building and construction applications. The resultant products were examined and characterised physically. It was found that the early strength development of geopolymeric pastes could be changed according to the nature as well as the extent of the contamination. At a small dosage, the effect of the contamination on the early geopolymeric system depended heavily on the nature of the artificial surfaces that were created in the geopolymeric solution through the addition of the chemical additives. For example, the samples containing MgCl2 and Mg(NO3)2 had shown the same yield stress developments due to the similar surfaces that were formed. The cations of these salts were expected to hydrolyse and form magnesium hydroxide precipitates immediately after the addition to the early geopolymeric systems. The calcium cations of CaCl2 also precipitated upon addition, but the nature of the surfaces of these hydroxides was quite different to those of the magnesium hydroxides and gave rise to different yield stress development. The samples that contained the insoluble salts (in water) demonstrated different yield stress development when compared to each other because of the different nature of the additive surfaces that were exposed to the geopolymeric solution. These results suggested that heterogeneous nucleation could be responsible for the change of the rheological behaviour upon inorganic salt addition. When the extent of the ionic contamination was large, the anions released from the insoluble salts (in water) changed the nature as well as the concentration of the geopolymeric solution and the setting processes were retarded. Oxides, in general, behaved very differently from other salts, indicating the uniqueness of the oxygen anions in a system rich in hydroxyl and silicate anions. The inorganic salt contamination in geopolymers did not show any significant signs of structural change according to the XRD diffractograms collected. The seven-day compressive strength was not lowered by the inorganic salt contamination and it could sometimes be beneficial to the product performance, for example, an increase of 20 MPa was induced by the addition of calcium oxide. Inorganic salts as chemical additives have demonstrated the potential to modify setting times of geopolymers without sacrificing much of the productsÆ strength and integrity.

Jan 1, 2000

By Cocquio D. S, Bauchau C

In the course of an integrated airborne survey in 1975, a uranium-molybdenum deposit was discovered by Minatome Australia Pty Limited in North Queensland, Australia, approximately 70 km by road west of Townsville.The mineralization occurs in a welded tuff unit within the Carboniferous St James Vokanics. It is structurally controlled by a complex of subvertical east-west fractures and is exposed over a strike length of 350 m. Drilling has traced a further 150 m extension underneath a barren capping consisting of a thick pile of vokano-sediments. The maximum width of the orebody is 150 m, and its vertical thickness is approximately 100 m.The primary ore minerals are coffinite, pitchblende and molybdenite, accompanied by various alteration products (particularly uranium molybdates).The vein-type mineralization is considered epigenetic.A comprehensive program of surface drilling and underground exploration is in progress to establish the uranium and molybdenum reserves.

Jan 1, 1980

By Ian McFeat-Smith

Despite a present, short-term economic recession, a remarkable enthusiasm exists in Hong Kong for building infrastructure including major tunnel projects. This paper provides details of current and recent bored tunnel works together with an insight into the impressive list of future underground projects planned by the MTRC,KCRC, Highways Department and Drainage Services Department for the next decade. Risks for each of these works including pipejacking, mixed face and rock tunnelling generally in Hong Kong are also identified. From this is evident that the scale and difficulty of such works continues to increase, requiring the use of more sophisticated methods of construction, the need for better methods of assessing and managing risks and for Government to utilize improved, more equitable Conditions of Contract for such major tunnelling projects.

Jan 1, 2001

By T Do, J Siliezar, M Larson

With the expansion of magnetite projects in Australia has come the opportunity to take advantage of newer technologies that were not necessarily available when the magnetite industries of North America and Europe were maturing. One of these technologies is the IsaMill, originally developed for the economic treatment of ultra-fine grind (UFG) duties of Mount Isa Mines. As understanding of the IsaMill has increased, so too has the ability to process coarser feeds while maintaining the same energy efficiency advantage and tight product size distribution that originally made the IsaMill so attractive. In the case of magnetite the hard non-elastic ceramic grinding media is ideally suited to the grinding duty when compared to steel grinding media. The centripetal separator and naturally steep product size distribution curve provide a mill discharge that maximises the critical concentrate grade. This paper analyses the effect of the IsaMill grinding technology on the full-scale Ernest Henry Mine (EHM) magnetite operation along with pilot and lab scale demonstrations of optimisation. Issues encountered and the solutions to maximise the mill throughput and quality are examined in an effort to promote better understanding across the industry. CITATION:Larson, M, Do, T and Siliezar, J, 2013. Enhancing magnetite returns - the benefits of IsaMilling, in Proceedings Iron Ore 2013 , pp 411-416 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

Ohio has an estimated 46 billion tons of coal beneath 12,000 square miles of the eastern third of the state. Recoverable coal reserves within this vast area are estimated at 21 billion tons, 3.2 billion tons of which have been mined since 1800. Ohio is the eleventh-largest coal- producing state in the nation and ranks third nationally in coal consumption. Coal resources in Ohio lie in as many as 60 identifiable coal seams along the northwestern flank of the Appalachian coal basin. Except where interrupted by minor faults and erosional discontinuities, these rocks dip gently and uniformly to the east, simplifying the mining methods needed to extract the coal. Fourteen of Ohio's 60 coal seams are considered to be important, although only a small number of seams are currently being mined. Ohio first enacted a surface coal mining law in 1948, requiring in part a $100 per acre reclamation bond. Ohio progressively strengthened its surface mining law in 1949, 1955, 1959, 1961, 1965,1972,1975,1978, and 1981. At the time of its enactment, Ohio's 1972 mining law was one of the most stringent in the country. This law also created a state coal severance tax of four cents per ton to be used for abandoned mine land reclamation. Ohio received primacy to regulate the surface coal mining operations within the state August 16,1982. Its Abandoned Mine Land Program was approved on the same date.

Jan 1, 1992

By Hale Y. M

Multielement reconnaissance geochemistry coupled with ground scintillation gamma ray measurements has been used to investigate the dispersion patterns of uranium and other major and trace elements in the arid Palmyrides region of central Syria. This region occupies an interplatform depression in the northern part of the Arabia Plate, upon which sediments up to 10 km thick have accumulated. Outcrops of strongly fractured Mesozoic and Cenozoic rocks form two major mountain belts, the northern and southern Palmyrides, between which is located the closed Ad-Daww basin, with a thick Neogene and Quaternary clastic cover. Among the various lithologies, phosphorites are well represented. Uranium and associated elements have been incorporated into the Upper Cretaceous and Lower Palaeogene sediments, especially the phosphorites, which are well represented in the region. These elements are derived from three possible sources, namely, sea water, Lower Cretaceous volcanism and metalliferous fluids leaking along taphrogenic lineaments. In and around the phosphorites, numerous traces of secondary uranium mineralization occur. Over 500 geochemical samples of outcropping rock, wadi and playa sediments, overburden and groundwaters were taken over an area of approximately 9000 sq km. Most samples were analyzed for 25 major and trace elements by nebulization ICPAES; for As, Sb, Bi and Se by hydride generation and ICPAES; and for U, Th and La and other REE by neutron activation analysis.

Jan 1, 1988

By C. Restarick, R. G. Robins, R. M. Taylor, I. Ennis

Lime addition to acid mine drainage waters (AMD), possibly accompanied by aeration, has been the basis for their remediation by precipitation of predominantly metal hydroxides. An efficient novel alternative technique causes precipitation of double M(II)-M(III) hydroxy sulfates which readily precipitate and are easily dewatered. When the Fe(II)/Fe(III) + Al(III) ratio of the AMD is appropriate, the Green Precipitate (GP) Process provides a more effective alternative to normal liming/aeration. The process can be adapted to give a continuous in-line treatment by the choice of suitable computer-controlled reactors designed to improve the liming efficiency, reduce scaling and control the rate of treatment. The processes are described in terms of the chemistry involved.

Jan 1, 2000