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By Onder Guney, Erdem Demirkesenm

"In this study, the crystallization behavior and thermal expansion coefficient of a lithium disilicate (LS2) based glass-ceramic derived from SiO2-Li02-AhO3-K2O-ZrO2 system was investigated by using x-ray diffraction (XRD), high temperature x-ray diffraction (HTXRD), differential thermal analysis (DTA) and dilatometer techniques. Analytical reagent grade chemicals were chosen as raw materials for preparing glass batches. Nucleation and crystal growth heat treatments were planned according to DTA results. The amounts of the amorphous and crystalline phases developed during the heat treatments were determined by quantitative XRD. XRD results of crystallized samples showed simultaneous formation of lithium silicate (LS) and quartz in the early stage of the crystallization followed by formation of lithium disilicate (LS2) at higher temperatures. The thermal expansion coefficients of glassceramics were also measured depending on the applied heat treatments.IntroductionSignificant developments occurred in all ceramic materials provide the fabrication of high quality dental implants [1]. Glass ceramic based dental restorations like dental inlays, crowns, bridges and veneers are becoming increasingly popular with their reliable and durable performance [2,3]. In addition to their advanced functional properties, glass ceramic implants especially lithium disilicate glass ceramics also face the esthetics expectations of patients and dentists and in this way they are starting to take the place of metal based restorations today [1,3,4,5]. Lithium disilicate glass-ceramics derived from multicomponent glass systems have some superior mechanical and optical properties comparable to natural teeth [ 6]. In restorative dentistry, mechanical characteristics of biomaterials play very crucial role in order to resist the masticatory forces occurred during biting and chewing [7] According to three point bending test results of Roland, flexural strength of the lithium disilicate glass-ceramics were 400±40 MPa and their fracture toughness (K1c) are approximately 3,3 MPa m112 [2,6]. In addition to high mechanical strength, aesthetic appearance is another important prerequisite as material for dental restorative applications. Translucency and light transmission of the LS2 glass ceramics mimic enamel. Moreover, opacity of the material can also be adjusted depending on the restoration types [2,6, 7]. These superior properties of the LS2 glass ceramics are directly related with chemical composition of the base glasses and controlled crystallization heat treatments [ 4, 7]. The aim of the present work is to determine the effect of heat treatment schedules on the crystallization behavior and thermal expansion of the LS2 glass-ceramics."

Jan 1, 2011

By James A. West

Near East region countries continued to supply a large share of the world's energy requirements in 1965. The area accounted for nearly 27 percent of estimated total world crude oil output and for about 60 percent of world exports of this commodity. Also, it was the source of more than 40 percent of the world's petroleum refinery products exports. Although other mineral industry activities remained relatively in? significant in comparison with petroleum, regional production and export of certain metallic and nonmetallic mineral commodities were of world significance. Of these commodities, chief in importance were chromium, copper, mercury, antimony, boron, potash, and phosphate Tack. The Near East region contains the largest and most productive oil resources in the world. Petroleum exploration and development operations during 1965 resulted in crude oil reserve additions of almost 8 billion barrels to increase proved reserves to 219 billion barrels at yearend, an amount equal to nearly 68.5 percent of the world's proved oil reserves. Near East countries' production of crude oil averaged a record 8.337,575 barrels per day in 1965, an increase of nearly 11 percent over that of 1964. On an annual basis, Kuwait continued as the leading oil producer in the Near East; however, Saudi Ayabia was a close second and its rate of production in late 1965 exceeded that of Kuwait. The major oil producing nations and their percentage of total area crude oil output was Kuwait, 26.0; Saudi Arabia 24.3; Iran, 22.3; and Iraq 15.9.

Jan 1, 1967

By A. Deneys

This paper reviews industrial gases used in primary copper production. Copper smelting industrial gas demand has steadily increased since the first commercial oxygenconcentrate smelting in 1952 [1]. In copper production oxygen for smelting is the dominant industrial gas use followed by oxygen for converting. Nitrogen is finding increased use in copper smelters. Nitrogen is used for porous plugs for copper converting and anode refining [2-5]. Nitrogen can be used for concentrate drying [6,7] and is also used in some Ni-Cu smelters as a coolant in Peirce-Smith converting [8,9]. Industrial gas supply options of cryogenic or adsorbent based on-site plant or cryogenic liquid delivery are detailed.

Jan 1, 2007

By Seung-Chul Lee

Transparent conducting tin(1V) oxide thin films have been studies and developed for the electrode materials of solar cell substrate. Fabrication of tin oxide thin films by sol-gel method is process development of lower cost photovoltaic solar cell system. The research is focused on the establishment of process condition and development of precursor. The precursor solution was made of tin isopropoxide dissolved in isopropyl alcohol. The hydrolysis rate was controlled by addition of triethanolamine. Dip and spin coating technique were applied to coat tin oxide on borosilicate glass. The resistivity of the thin film was lower than 0.18-cm and the transmittance is higher than 90% in a visible range.

Jan 1, 1999

By Frank Rieber

THE discovery that strongly magnetic bodies localized near the surface of the earth could be detected by the distortion which they produced in the resultant magnetic field marked the beginning of magnetic surveying methods. From an original ability to detect bodies of magnetic iron ore and the like when located very close to the, surface, these methods have been extended until today they promise to give much information with regard to the structure of such slightly magnetic material as sedimentary rock containing only a very small proportion of iron.1 The recent extensions have been made possible through the development of more delicate instruments, and of methods for their use. From the original compass and dip needle, the design of apparatus has progressed until equipment Is typified by magnetic balances capable of measuring the components of the earth's field to an extremely high degree of accuracy. It seems unlikely that the limit of such instrumental development has been reached. Just as the change from compass and dip needle has enabled the location of relatively minor changes in magnetic materials, so additional developments in the direction of increased sensitivity, as well as in greater dependability and constancy of operation, should reveal positively many slight changes which either escape notice in the present surveys or are so small that they cannot with certainty be separated from uncontrollable errors due to inconstant operation of the equipment. The ability to read smaller and smaller variations does not mean, of course, that deductions as to the causes of these variations will be made as accurately and definitely as -is possible with the more pronounced anomalies.

Jan 1, 1928

By S. H. Boshlov

Los problemas del diseño estructural de minas se basan en numerosas complejidades como el de una incapacidad para definir explícitamente los parámetros, físicos in situ del medio rocoso y sus materiales asociados, el comportamiento del sistema bajo alguna descripción bosquejada de la aplicación de la carga; otras proceden de la incapacidad para especificar con precisión el estado inicial de la tensión en el medio. En ese sentido, el presente texto señala un modelo de diseño estructural manipulable donde se refleje el comportamiento del prototipo que representa. Así, el análisis por elementos finitos, en el cual la estructura se considera como una reunión de numerosos elementos, cuyas propiedades individuales pueden señalarse a voluntad, indica la posibilidad de un problema de diseño de una estructura minera como un ejercicio de análisis de sistemas. Tal sistema rocoso podría incluir todos los factores naturales y los medios ambientes artificales que afectan la resistencia de las estructuras mineras de superficie interior.

Nov 1, 1971

By W. A. Roliff

The renewed interest of the past few years in the Appalachian and Michigan oil provinces has not, as yet, created any marked increase in activity in Southwestern Ontario. During 1960 development drilling in-creased somewhat over 1959, but exploratory drilling decreased slightly. More attention was devoted to the deeper horizons, but lake drilling de-creased considerably. Oil production reached a new peak and gas production increased slightly. During 1960 an interesting oil and gas discovery was made in the Cambrian and gas discoveries six miles off-shore in the eastern part of Lake Erie were made in the Clinton-Cataract zone of the Silurian. This paper reviews activities during 1960, summarizes the discoveries made to-date and the pertinent exploration data relating to the prospects of the region and discusses some of the economic aspects of exploration and development. D URING the last few years there has •been a marked renewal of interest in the old petroleum

Jan 1, 1961

The Minerals Data Source Directory is a compilation of descriptive information on the availability, content, and location of minerals data in the Federal Government. It is intended to assist Government personnel and the general public in locating and acquiring minerals information. Included in the Directory are descriptions of data bases, publications, information systems, and information offices containing data pertaining to ail aspects of mineral production, consumption, trade, and related information. These mineral data sources include the Federal agencies such as the Department of the Interior's Bureau of Mines and Geological Survey whose major mission is the collection and dissemination of mineral information. Also included are agencies such as the Departments of Agriculture, Commerce, Labor, State, Transportation, and Treasury, the Central Intelligence Agency, the Environ- mental Protection Agency, the Federal Reserve System, the interstate Commerce Commission, and the Securities and Exchange Commission, whose primary mission is the collection of data in nonmineral subject areas, but in which the mineral industry is a component.

Jan 1, 1983

By Bruce Maxwell

The deformation modulus of coal mine pillars theoretically can be reduced by drilling holes in advance of the mining face. This reduction of modulus along the edge of the pillar has the effect of decreasing the stress concentration in the roof; control of roof caving is thereby predicted. Initial field work indicated that a high horizontal stress field existed at the field test site: Subsequent field work was undertaken to confirm the high horizontal stress field and to attempt to relieve the horizontal stress in the immediate roof. A method of softening pillars in conjunction with normal mining activity was developed. Instruments to measure horizontal roof strain, roof parting, roof tilt at the rib, and changes in vertical and horizontal stress in the roof and in the coal were used. These instruments were installed in both softened and unsoftened entries and in locations to indicate the effect of vertical slots in the roof. Significant stress reduction due to pillar softening was indicated, but the effect of this reduction on roof stability was not established. The vertical roof slots relieved the horizontal stress in the immediate roof very effectively, and observations of roof conditions indicated that the slots definitely improved roof stability.

Jan 1, 1977

By Will H. Coghill, I. L. Feld, G. D. Coe

"INTRODUCTION During the course of research on the beneficiation of the Big Seam iron ores of Birmingham, Ala., an urgent need was felt for quick iron assays of grab samples for mill control. Since the gangue minerals in these ores - quartz, limestone, and clay - all have about the same specific gravity, the use of a specific-gravity method was anticipated as a means of measuring the iron content. The idea of estimating the composition of a mineral mixture by measuring its specific gravity is by no means new. However, the usual method of carry in out this idea proved unreliable when applied to the Big Seam ores. The usual rapid method of determining specific gravity consists of measuring the volume of a known weight of sample that has been dried at high temperature. The inadequacy of this method led to the development of the rapid, modified, specific-gravity determination described in this paper.This work- was an incidental development resulting from research on beneficiation of iron ores by the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama and ore producing companies of the Birmingham district."

Jan 1, 1946

By Richard E. Gray

Virtually all structures show some signs of distress due to deterioration of the building components, to changed loads, or to changed support conditions. Changed support conditions result from ground movements. In mining regions many cases of structural distress are attributed to mining without considering alternative causes. This is particularly true of coal mining since it occurs under extensive areas. Coal mining is estimated to have already undermined more than eight million acres and may eventually undermine 40 million acres in the United States (HRB Singer, Inc., 1977). Other nonmetal and metal underground mines impact much smaller areas. Although it is sometimes difficult, even with careful study, to identify the actual cause of damage, persons responsible for underground coal mining should at least be aware of possible causes of building stress other than mine subsidence. This paper presents information on distress to structures and briefly reviews a number of causes of ground movements other than subsidence: Mass movements, dissolution, erosion, frost action, shrinking and swelling, yield into excavations and compressibility

Jan 1, 1986

The Barmac autogenous crushing mill is one of the most successful new comminution technologies to become available to the mining and industrial minerals industries in this decade.The Barmac autogenous crushing mill is an innovative Vertical Shaft Impactor which operates in essence like a high intensity dry ore centrifugal pump with the reduction occurring primarily as a result of high velocity rock to rock impact in a fully rock lined crushing chamber. With applications in a wide range of mining and industrial minerals operations the Barmac autogenous crushing mill presents an opportunity to enhance reduction and liberation whilst providing many cost savings and production increases in new and existing plants.This paper briefly describes the operation of the Barmac autogenous crushing mill and reviews its benefits.

Jan 1, 1990

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present study the effect of using different grinding media, viz, ceramic balls, forged steel balls, 15% Cr steel balls, stainless steel and mixture of stainless steel and 15% Cr steel balls (50:50) on the flotation performance of a Platinum Group Mineral (PGM) UG2 ore was investigated. Test work was conducted using a laboratory scale horizontal tumbling mill and a batch flotation cell. Power draw to achieve a specific P80 was determined for each media type. Changes in flotation behaviour were evaluated in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. pH, Eh and DO levels were also measured. Grinding products of five different media produced similar solids and water recovery, which is indicative of the froth characteristics, but the grades and recoveries of PGE and chromite were different. The product obtained when using ceramic media showed the best flotation performance, producing the highest PGE recovery and the lowest Cr2O3 recovery. The products obtained when using stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery. The paper proposes possible reasons to explain these observations which may have significant importance for the operation of a PGM concentrator.

Jan 1, 2015

By John Hillman

The reconstruction of the British mining industry which began shortly after nationalisation in 1947 continued until well into the 1950s with the support of the Government. This support diminished as plentiful supplies of cheap oil from the middle East made many coalmines un¬economic. The planned rundown which followed was foreshadowed in the 1965 White Paper which outlined the financial measures to speed the closure of uneconomic collieries. The decline appeared likely to continue into the 21st century as the role of coal in UK energy requirements became less and less significant. This policy was well on course in 1973 when the oil crisis led to a complete reappraisal of the position. A Government examination in 1974 of the coal industry then supported the National Coal Board's general strategy of major capital investment as set out in its 'Plan for Coal' (1). Plan for Coal aimed at halting the intended decline in the industry's capacity and restoring it to 120 million tons of deep mined output in 1985. The Plan proposed action along the following lines (a) increase output by major Investment in construction at existing collieries with sufficient reserves to give 13 million tons per annum extra output (b) invest in extending the life of existing collieries by gaining access to additional reserves, to give 12 million tons per annum extra output © by sinking new mines, produce an extra 20 million tons per annum. Figure 1 shows the contribution (2) expected from each of the three sources up to 1990/1. The measures taken were expected to offset the inevitable exhaustion of existing pits and provide the additional 40-42 million tons capacity needed to restore annual output in 1985 to 120 million tons. Parallel to this programme for expansion of deep mined output, opencast mining was to produce 10-15 million tons per annum. A recent review however, indicates that new mines are likely to yield only 10 million tons per annum by 1985, mainly owing to the need for public inquiries into proposals for new mining and the resultant fact that planning approval takes 'much longer than originally expected. Nevertheless the objective of 120 million tons deep mined output by 1985 is still considered achievable of means of a greater contribution from existing mines. This programme was originally estimated to cost 2,-56 million dollars at March 1974 prices, out revised estimates of the cost of Plan for Coal indicate that it may now exceed 6,960 million dollars at mid-1977 prices. Plan for Coal includes a substantial investment in new and reconstructed coal preparation plaints. At mid-1977 prices more than 322 million dollars Ls so be invested in coal preparation projects in the UK, at the rate of, about 70 million dollars a year. This rate 3f capital expenditure has been maintained over the past three years and covers investment in a wide range of coal preparation coals for the power station, coking and domestic markets.

Jan 1, 1978

By B. D. Sartwell

The formation of alloyed regions near the surface of metals using ion implantation is being investigated by the Bureau of Mines as a means of providing corrosion resistance using much smaller amounts of the strategic alloying metals. Two ion implantation systems that can implant low-energy chromium, nickel, or aluminum ions into low-cost substrate materials such as iron or carbon steel have been designed and constructed. The development of the ion source, ion beam acceleration stage, mass analysis system, and target chamber are described in detail. The ion-implanted alloys have been characterized using proton-induced x-ray emission to give the total number of atoms implanted and to determine the extent of any surface contamination introduced by the ion implantation process. Research conducted at other laboratories on metallurgical applications of ion implantation is given.

Jan 1, 1980

By R. A. Campbell

The electric smelting of five lowgrade Canadian manganese ores has been investigated at the Mines Branch, Department of Mines and Technical Surveys, Ottawa. Ferromanganese, silkomanganese, and spiegeleisen were produced 1by special smelting processes from these ores since the latter were too low grade to be treated by conventional smelting methods. In one case the results were considered to be sufficiently promising to justify the construction of a pilot plant, by the Company concerned, for the further development of the process.

Jan 1, 1956

By C. W. Davis, L. R. Messer

THE name fuller's earth, which was derived from its early use in "fulling" or removing grease from woolen goods, is a term that is generally considered to designate mineral matter, containing hydrous aluminum silicates of the clay group, which has a high capacity for removing colors from oils, whether of animal, vegetable, or mineral origin. Fuller's earths are usually dried and may be "tempered" by heating or may be treated with water or reagents to improve their efficiency. For our purpose the term "acid-treated earths" will include those products from the partial decomposition of mineral water by acid which are equal to or more efficient than an untreated fuller's earth from Quincy, Fla., when used in bleaching mineral oil by the "contact" process. In general, the contact process for treating oils consists of heating and agitating a mixture of oil and finely divided adsorbent, the latter being subsequently removed by filtration. The term "adsorbent" is used because, although there has been a great deal of controversy over the mechanism of removal of impurities from oils by mineral matter, there is no doubt that adsorption, which involves the surface of the solid, plays a major part.' The properties that make fuller's earth useful in the treatment of petroleum products by "percolation1' and in the purification of edible oils by the contact process have long been studied, but the comparatively recent adaptation of the contact process to the bleaching of petroleum products has made desirable the further investigation of fuller's earth and other adsorbent earths.

Jan 1, 1929

By O. C. Wheeler

In order that the series of reports on oil and gas in Colombia may be complete, the report for the year 1941, which was not available for Volume 160 of the TRANSACTIONS, is given here. The report for 1945 begins on page 4o6.

Jan 1, 1946

By F M. Senda

This paper highlights strategies used at the Barrick operated Kibali Gold Mine (KGM) to improve the drilling accuracy and blasting effectiveness for longhole open stoping. The mine currently uses Solo DL421 for the required stope drilling and has experienced an average deviation of 10 per cent. Strategies are raised to eliminate or at least mitigate the adverse effects of blasthole deviation and the impact of blasting induced effect at the stope faces including the stope crown. The integration of deviation trends in the design would allow the actual blastholes to be established within their required positions to then facilitate a proper energy distribution with the eventual production blasting. The implementation of stope undercutting reduces the hole length from 35 m to 30 m which in return decreases blasthole deviation by 3 per cent. Another strategy adopted to improve the drilling accuracy is to slow down the penetration rate with the use of several operating approaches, including 135 MPa percussion pressure, 65 rev/sec rotation speed and 17 MPa feed pressure. To this penetration rate, a constant k factor is applied to increase the rate when the bedding inclination is less than 45° from the horizontal or when the hole length is under 10 m. This reduces deviation by a further 4 per cent. Where the rock mass is highly jointed it is advised to use the average penetration rate over the entire length of the hole. Furthermore, the paper shows the effect of deviation on the blasting results through a prediction of fragmentation blasting model optimised with reduced deviation and highlights the effect of presplit mining and timing delay on the blasting effectiveness. Although the size pattern increases with deviation, a strategy pertaining to timing delay with blasting would be to align to the work of Grant (1990) where the optimum hole to hole delay is found to be between 7–10 ms/m of spacing, while the optimum delay between adjacent ring varied between 110–160 ms. Stabilisation of crowns and wings will perform with the implementation of presplit blasting.

Mar 29, 2023

By L. H. Bergmann

THE blasting practices described are fairly representative of those employed in the coal mines of Eastern Canada. As such, they may be of interest to Western Canadian coal mine operators. The treatment of the subject is general, no attempt being made to discuss blasting operations at any particular coal mine in detail. All the mines dealt with are mining bituminous coal and are classified under the Coal Mines Regulation Act of the Province of Nova Scotia as 'closed light' mines. As such, they are required to use only 'permitted' explosives and to apply them in a 'permitted' manner, except where authority is given by the Mines Department to do otherwise.

Jan 1, 1945