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By Peter Cain

The Phalen Colliery in the Sydney Coalfield is extracting the 2.6 m thick Phalen Seam by the panel and pillar longwall retreat method. Abandoned workings occur in the Harbour Seam 140 m above and overlie the Phalen Colliery. Parts of these workings are flooded, and pose a number of questions relating to the safety of operations in the Phalen Colliery. In order to answer some of these questions, the Cape Breton Development Corporation re-entered an abandoned non-flooded roadway in the Harbour Seam directly above a retreat panel in the Phalen Seam to allow the deployment of instrumentation to monitor interaction effects. Fifteen monitoring sites, each 4.5 m apart, were installed in the 5 East Top Level after it had been re-entered and made safe. Each monitoring station included a vibrating wire strain gauge piezometer and a potentiometric extensometer. The piezometers were attached to rock bolts anchored into the floor and were connected by a flexible standpipe to a constant head apparatus. Variations in hydraulic head due to subsidence were monitored to determine subsidence. The extensometer units were mounted on rock bolts anchored into the floor of the roadway beneath the ribside and monitored ground strains. The instrumentation was capable of remote reading in the event that access to the site was restricted after installation. This paper describes the instrumentation, the installation programme, and some preliminary results.

Jan 1, 1993

By Charles T. Ford

In 1971, Bituminous Coal Research, Inc~ established a program to provide the coal industry with the necessary information and technical capability to investigate and evaluate potential problems concerning trace elements in coal and coal-related materials. The initial efforts at BCR in developing or adapting analytical procedures for the precise determination of trace elements in the parts per million to parts per billion range were detailed in a report titled "The Development of Analytical Methods for Determining Trace Elements in Coal and Coal-related Products." A subsequent reports contained descriptions of reliable analytical methods refined by BCR for determining mercury in coal and coal ash and also in coal mine water. his paper reports initial progress in applying recently-acquired trace-element analytical capabilities to solving potential coal industry problems. In this case, the effect of a coal-cleaning process on the distribution and removal of potentially harmful trace elements in coal was evaluated. Coal cleaning offers the possibility of controlling potentially harmful emissions resulting from combustion of large tonnages of coal by removing the pollutants prior to combustion.

Jan 1, 1977

By J. B. Austin, H. H. Pierce

In developing a consistent picture of the thermal expansion of the commercial chromium steels, which cover a range of carbon contents, it is desirable to know the expansion in the limiting case of the binary, carbon-free, iron-chromium alloys. We have, therefore, determined the thermal expansion of a series of five special alloys, ranging in chromium content from 3 to 10.5 per cent, with not more than 0.03 per cent carbon, over a temperature range extending beyond the transformation region; this low carbon content enables us to draw reasonably reliable conclusions as to the behavior of the carbon-free system. Moreover, the measurements serve to determine the beginning and the end of the alpha-gamma transformation; and they emphasize once more the fact that a transformation temperature determined by any method in which the specimen is cooled at an appreciable rate is apt to be seriously in error, particularly if the metal contains a transformation-retarding element such as chromium or managanese. The lag, or undercooling, observed at the ? — a transformation is explained in terms of the influence of temperature on transformation velocity; the rather unusual shape of the ? loop is attributed to a change with temperature and with composition of the distribution of chromium between the alpha-iron and gamma-iron solid solutions. The exact composition of the alloys, which were obtained through the courtesy of Dr. W. Rohn, of the Heraeus Vakuumschmelze A-G., is given in Table 1. Determinations of the linear thermal expansion and of transformation temperature were carried out in the vacuum dila-tometer previously described,' using a rate of heating and of cooling of 3.0" to 3.5" per minute unless otherwise stated. Magnetic susceptibility, which was measured in studying the rate of transformation, was determined with a magnetic balance, which also has been described.2 Results and Discussion Thermal Expansion Coeficients.—Numerical values for the linear expansion coefficient, derived from a smoothed curve based on at least

Jan 1, 1935

By H. H. Pierce, J. B. Austin

In developing a consistent picture of the thermal expansion of the commercial chromium steels, which cover a range of carbon contents, it is desirable to know the expansion in the limiting case of the binary, carbon-free, iron-chromium alloys. We have, therefore, determined the thermal expansion of a series of five special alloys, ranging in chromium content from 3 to 10.5 per cent, with not more than 0.03 per cent carbon, over a temperature range extending beyond the transformation region; this low carbon content enables us to draw reasonably reliable conclusions as to the behavior of the carbon-free system. Moreover, the measurements serve to determine the beginning and the end of the alpha-gamma transformation; and they emphasize once more the fact that a transformation temperature determined by any method in which the specimen is cooled at an appreciable rate is apt to be seriously in error, particularly if the metal contains a transformation-retarding element such as chromium or managanese. The lag, or undercooling, observed at the ? — a transformation is explained in terms of the influence of temperature on transformation velocity; the rather unusual shape of the ? loop is attributed to a change with temperature and with composition of the distribution of chromium between the alpha-iron and gamma-iron solid solutions. The exact composition of the alloys, which were obtained through the courtesy of Dr. W. Rohn, of the Heraeus Vakuumschmelze A-G., is given in Table 1. Determinations of the linear thermal expansion and of transformation temperature were carried out in the vacuum dila-tometer previously described,' using a rate of heating and of cooling of 3.0" to 3.5" per minute unless otherwise stated. Magnetic susceptibility, which was measured in studying the rate of transformation, was determined with a magnetic balance, which also has been described.2 Results and Discussion Thermal Expansion Coeficients.—Numerical values for the linear expansion coefficient, derived from a smoothed curve based on at least

Jan 1, 1935

By Yang Hong-ying, Yu Juan

Electrochemical behavior of natural chalcopyrite in electrolyte solution at pH value of 6.97 was studied by cyclic voltammetry, X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy. The results showed that the electrochemical processes occurred on electrode surface were controlled mainly by the growth of sulfur species at lower applied potentials (<0.35Vvs.SHE), and the oxidative dissolution of sulfur species and the hydroxylation of iron at higher applied potential (>0.45V). The EIS spectra of oxide product layers could be illustrated by the equivalent circuit of Re(QdlRct(QfRf)), and the degree of hydrophilicity for chalcopyrite was higher when the value of charge transfer resistance Rct. was greater. The optimum potential range for the floatation of chalcopyrite in collectorless solution at pH value of 6.97 was between OCP (0.165V) and 0.35V.`

Jan 1, 2015

By X. Gumede

A model is being developed to quantify the benefits for mining houses resulting from the reduction in greenhouse gas and energy consumption by the application of innovative blast designs in addition to direct financial benefits throughout the mine to mill value chain. The conversion from shock tube initiation systems to electronics and some changes to powder factor measured on an open pit mine had previously been used to show significant improvement on blast outputs. Benefits were realised on drilling, blasting, loading, hauling and beneficiation. Quantification of the relationship between powder factor and reduced greenhouse gasses is investigated in this study. The study has highlighted new data that must be recorded and hence some assumptions were made as to fuel consumption and the energy in crushing was obtained from the Bond work equation. The mine to mill projects in an open pit platinum mine and a quarry produced energy savings and reduced greenhouse gas emissions associated with the careful application of explosives and blast innovations. The less fines project showed an increased carbon footprint. The model provides a new insight into how project feasibility should be decided based on economic and environmental viability.

Jan 1, 2012

By Chamila Jinendra Nanayakkara, Nimila Dushyantha, Amila Sandaruwan Ratnayake, Gayithri Niluka Kuruppu

Rare earth elements (REEs) are key ingredients in many advanced materials used in energy, military, transportation, and communication applications. However, the prevailing geopolitical dynamics and the rising demand for REEs have rendered the reliance on primary REE resources susceptible to future supply disruptions, posing a substantial risk to the availability of these elements for numerous applications. Therefore, it is imperative to undertake substantial initiatives in the extraction of REEs from secondary sources on a large scale to ensure the resilience of the supply chain. Permanent magnets, lighting phosphors, and nickel-metal hydride (NiMH) batteries are among the secondary sources with high potential for sustainable REE extraction. This review assesses the extraction potential of REEs from the aforementioned three secondary sources and their leaching kinetics and thermodynamics aspects. More importantly, state-of-the-art different existing kinetic models employed in rare earth (RE) leaching were well discussed for a better understanding of the REE leaching reactions. Furthermore, the optimized leaching parameters related to this kinetics were described, and various RE recovery methods were comprehensively summarized. These processes facilitate to managing one of the fastest-growing solid waste streams by minimizing environmental impacts and producing critical metals, including REEs via circular economy approaches. The recovery of REEs from secondary sources aligns with numerous United Nations Sustainable Development Goals (SDGs), particularly in the renewable energy sector for climate change mitigation. Consequently, this trash-to-treasure urban mining concept to transforming e-waste into a valuable resource for REE recovery emerges as a pivotal element within the REE industry.

Dec 28, 2023

By Hsing Kuang Lin

Ferric chloride leaching w.as applied to a complex sulfide ore from Tok, Alaska to dissolve zinc, lead, silver and copper. Gold in the leaching residue, as well as in the ore, is found to be refractory to the conventional cyanidation process. Roasting, pressure oxidation and elemental sulfur removal followed by cyanidation were tested to improve gold dissolution. Also tested were thiourea leaching and high-pressure cyanidation. The readsorption of dissolved gold by carbonaceous matter in the chloride leaching residue was analyzed. Based on the experimental results, factors causing difficulty of gold dissolution from the leaching residue are discussed.

Jan 1, 1989

By Xie Zhang, Jiang Diao, Xiaojun Li, Bing Xie

"Vanadium is widely utilized as an important element to improve the quality of alloyed steels in iron and steel industry. Moreover, the crystallization process of V-containing spinels plays a significant role due to the aim of achieving a fairly larger size of spinel crystals in vanadium extraction. Thus, a comprehensive exploration and discussion on the competitive precipitation and growth of vanadium, chromium and titanium spinel crystals in vanadium slag during a cooling process were carried out in the present study on the basis of a crystallization kinetic model. To be more specific, the abilities of forming crystal, precipitation order and suitable temperature range for crystallization of the three kinds of spinels were discussed with both theoretical and experimental methods.IntroductionVanadium is an important element which is used almost exclusively in ferrous and non-ferrous alloys due to its excellent physical properties such as high tensile strength, hardness, and fatigue resistance [1]. Various kinds of processes of vanadium extraction from V-containing hot metal are available at present. However, only four processes which are the Highveld process (South Africa), the Pan-steel process (China), the NTMK duplex process (Russia) and the New Zealand steel process (New Zealand) take the dominant positions [2, 3]. Although the type of reactor and the initial vanadium content in hot metal are different in these techniques, they share the same principle that vanadium is oxidized by oxygen into vanadium slag."

Jan 1, 2012

By A. Deepatana

This study compares the use of an aminophosphonate chelating resin Purolite S950 and a sulphonic acid strong cation exchange resin Purolite C160H to recover nickel and cobalt from the synthetic bioleach solutions. Batch adsorption of metal citrate is performed as a function of metal citrate concentration (15~2000 mg/L) and solution pH (0.01M and 0.1M citric acid). The adsorption mechanism as inferred from the fit to Langmuir (LM), Freundlich (FM) and Redlich-Peterson (RP) models demonstrates that nickel citrate adsorbed onto C160H appears monolayer in comparison to that adsorbed onto S950 exists multilayer. In contrast, cobalt citrate adsorption onto both C160H and S950 agrees with the LM model. The results have shown that loading capacities of nickel and cobalt citrate onto C160H are 60 and 65 mg/g whereas those observed onto S950 are 16mg/g and 6 mg/g respectively. These are achieved in metal citrate prepared in 0.1 M citric acid. Resin regeneration is conducted in using 2 M nitric acid solution. The results show high efficiency of nickel and cobalt citrate elution from Purolite C160H. Findings from this study suggest Purolite C160H is a suitable adsorbent for recovering nickel and cobalt from bioleaching solutions.

Jan 1, 2014

By S. Vongpaisal, T. R. Yu

"A set of new blast damage criteria has been developed, with special reference to blasthole mining operations, for assessing damage by incorporating the vibration level, rock properties, site characteristics and the effects of ground support systems. The main objective of this work was to provide a database with reasonable accuracy for use in optimizing blast design, numerical analysis and ground control expert system module development.The new damage criteria allow one to estimate the degree of damage to rock structures in terms of a dimensionless parameter defined as Blast Damage Index (BDI). This allows for the description of blast damage in a unified form, and facilitates the development of codes for numerical modelling to express the degree of blast damage universally. A number of field investigations from several stope production and slot opening blasts at a large underground base metal mine were carried out to verify the developed index. The results show a good correlation between the observed damage and the type of damage predicted from the BDI values.Practical measures are also provided for minimizing blast damage in large underground blasthole mining operations"

Jan 1, 1996

Jan 1, 1933

By Richard D. Smith

The Bureau of Mines evaluated the emission control methods, including the capital investments and operating cost, necessary for further reducing lead levels in ambient air at the Glover, Herculaneum, and Buick smelter-refineries in Missouri and the East Helena, MT, smelter. The U.S. Environmental Protection Agency (EPA) has proposed more stringent lead in ambient air standards than those currently in effect. This report presents theoretically achievable lead emission reductions and estimated capital and operating costs. Lead emission inventories theoretically can be reduced from 1985 levels by 2,421 lb/d at the three Missouri operations by containing and filtering fugitive emissions within structural enclosures and baghouses. The aggregated capital and operating costs in 1986 dollars using conventional environmental and workplace technologies are estimated to be $250,014,100 and $18,507,800, respectively. Estimated total incremental cost is $0.063/lb as refined lead. Additional regulatory costs attributable to Occupational Safety and Health Administration (OSKA), U.S. Department of Labor, workplace standards are included since proposed environmental controls may otherwise degrade workplace conditions. Continuous drossing is evaluated as an alternative to conventional OSHA controls. Substituting continuous drossing for conventional work- place technology results in an estimated aggregated capital and operating costs of $258,344,800 and $15,719,600, respectively. Estimated total incremental cost is $0.062/1b as refined lead. For comparison, the average open market price of refined lead during the first quarter of 1986 was $0.184/lb.

Jan 1, 1987

By Kenneth K. Humphreys

INTRODUCTION What is automation? Why automate? Webster&apos;s New Collegiate Dictionary defines automation as "the automatically controlled operation of an apparatus, process, or system by mechanical or electronic devices that take the place of human organs of observation, effort, and decision." This definition gives an implied answer to the second question, "Why automate?" Automation, automatic control devices, and process control equipment receive their justification in supplementing or replacing manpower, which results in decreased operating costs. In the past, processes were operated with the minimum amount of instruments needed merely to guide operators. Processes were manually con- trolled by the operator on the basis of simple temperature, pressure, flow, and level indications on a panel. Today the tendency is to design a new plant to operate in a fully automatic manner according to a preset pro- gram utilizing a minimum of manpower. In addition to this direct cost reduction in manual labor, increased equipment capacity results from uniformity of flow and uniform control of process variables. This control eliminates or minimizes surges and permits equipment to be operated at or near its ultimate capacity and, for a given material throughput, permits the use of smaller process equipment. Automatic control, therefore, be it in the field of coal processing or in any industrial field, is simply a problem of economics. Control equipment is justified in terms of its contribution toward increasing productivity, increasing profit margins, or producing a new and salable product at a profit. Instruments and control devices can be divided into two general groups: (1) units which measure and (2) units which both measure and control a process variable.

Jan 1, 1979

By R. L. Grant

The principal official test performed by the Bureau of Mines to determine the permissibility of coal-mine explosives, commonly referred to as the gallery test, has been in use at the Bruceton station for many years (2, 16).4/ In this test the explosive under study is loaded into the borehole of a steel cannon and fired into a flammable mixture of natural gas and air or natural gas, air, and coal dust. To meet the requirements for permissibility, the explosive must not ignite the gas mixture under the conditions of the test. There is little doubt that these tests have succeeded in the main objective, namely, to screen the relatively safe from the relatively hazardous explosives. It has been generally conceded that adoption of permissible explosives by the coal-mining industry in the United States has substantially reduced the frequency of disastrous underground explosions caused by blasting. In recent years, however, research workers planning programs for improving the safety of coal-mine explosives have felt the growing need of a more quantitative method for measuring the incendivity of explosives based on a better understanding of the role of the important variables in the gallery tests, Accordingly, it was decided to apply certain statistical methods and techniques to the gallery test to develop it into a more precise tool for evaluating permissible explosives. One of the first and more important methods applied for this purpose was the up-and-down technique (6,7,17), It was demonstrated (14,15) that the weight of the explosive charge directly affects the ignition probability of the natural gas-air atmosphere and that the curve of ignition probability versus charge weight is a cumulative normal curve. Following these experiments, a program, still in progress, was set up to study how the addition of sodium chloride to various permissible-type ex-plosives affects their incendivity. This program resulted in 3,294 shots,

Jan 1, 1961

By Dmitrievskaya TY, Cheremnykh PA, Kuftinova IV, Yaremenko VN

The comprehensive processing of raw materials and the tendency to waste-free production require the combination of various methods of concentrating mineral resources. Magnetic separation, an ecologically clean method of concentration, is one step in the technological cycle of ore processing, and cleaning and classifying of raw materials. Separators with superconducting magnetic systems cooled by liquid helium are the novel equipment for practical concentration. Recently, high-gradient (HGMS) and open-gradient (OGMS) magnetic separators using the effect of superconductivity have appeared. The separators of the first type are expedient in the head-end of the technological cycle, as they are most efficient for processing of particles 100 ¦m and greater in size. In this case the main task is to obtain pure tailings with a minimum amount of the useful component. This method allows the essential reduction in the cost of the subsequent crushing and grinding, because only the magnetic concentrate is directed to further processing. The separators of the VGMS type are used more efficiently in the final stages of the concentration cycle to condition the end product. The present work is devoted to the theoretical and experimental investigation of the motion of weakly magnetic particles in the working chamber of superconducting separators of the open-gradient magnetic separator (OGMS) and HGMS types. The flat OGMS is equipped by a magnetic system with NbTi racetracks cooled by liquid helium. The chamber is divided into zones by partitions parallel to the plane of the magnetic system. It is shown how, depending on the number of the zones and their depths, the extraction function of the OGMS varies and the transition from the OGMS to the HGMS occurs. The particles 2 mm and less in size are considered. The extraction parameter distribution of the particles was measured for a multicomponent weakly magnetic ore. It was experimentally shown that xD2 is the extraction parameter for the particles in the OGMS on condition that (p-po)D /l8/tl/g

Jan 1, 1993

By M. Elbert Nigri

Radioactive wastewaters from nuclear source of electrical energy production need to be treated and disposed of properly. Sr, Ca, Mg and Ba are common elements in this effluent, which can cause incrustation in process equipments and being unsafe to human health (90Sr). Fixation of CO2 can be applied to remove the ions mentioned before and to provide a solution where CO2 is sequestered and the deleterious elements precipitated, becoming one of the possible steps to reuse the water into the process. Moreover, removal of several metals from distinct wastewater has been evaluated using bone char through adsorption. The chemical similarity between calcium and strontium makes the exchange of these two metals favorable in the hydroxyapatite structure contained in bone char. This paper evaluated the combined action of precipitation and adsorption process with injection of CO2 and bone char addition in simulated nuclear wastewater. Removal levels of 89.0% (Sr) and 83.3% (Ca) were obtained in the combined process. The presence of bone char as seed increased the precipitation kinetics, allowing a Sr removal of 85.2% in five minutes, higher than 75.3% obtained in absence of seeds. However, removal of 91.6% (Sr) and 89.8% (Ca) were obtained in absence of seeds at 24 h. Analysis of solids have evidenced that CO2 was consumed to precipitate the metals as carbonates, since the hydroxides are formed at higher pH’s.

A comprehensive analysisof rock structures in non-oriented (axially oriented) drillcore is now available (Laing, in press). The system embodies new concepts which better equip the geologist and engineer to deal from the outset with optimising the acquisition of structural information in drillcore, logging, interpreting, and graphically presenting the results. The few existing techniques for determining orientations of structures are augmented by a wide range of new techniques, and all are brought together into two solution types by considering the underlying Euclidean geometries. Analysis of these solution types in terms of what data are required to implement each solution and what assumptions need to be made, leads to strategies which facilitate intelligent design of different drilling programs for blind and outcropping situations. Drillcorc is variably structurally fertile, depending on the number of different structures present. This concept fosters the selective logging only of the more fertile core. Drillholes are also variably fertile, depending on their orientational relationship to the structures in the host rocks. Structural parameters are either vectorial or non-vectorial. Vectorial structures parameters comprise normal structural orientations plus polar vectors like vergence, younging, shear sense and so on. They can be determined by one of two solution types: external solutions, which use an external reference structure to fix the drillcore and thus permit orientation of all structures within that core, and internal solutions, which use orientational data from a selected structure at three or more different drillhole orientation to determine the unique orientation of that structure, without reference to any external structure.

Jan 1, 1990

By H. Lawrence

In 1977, the Bureau of Mines awarded a grant to the State of South Carolina to explore the possibility of using Landsat multispectral scanner (MSS) data as an aid in monitoring surface mining activities in selected counties of the State. Work had been done in Aiken County prior to the grant by Bureau of Mines and State personnel at the EROS Data Center using both the GE Image 100 and ESL IDIMS systems. The initial work on the 1-100 consisted of locating and measuring the areas of various kaolin mines. The results were excellent on location, identification, and accurate area measurements of several mines as compared with aerial photos of each mine. The effort also included locating and measuring the size of all mines (including sand and gravel) within two U.S. Geological Survey (USGS) 7 ½ min quadrangle maps. Line printer overlays using the IDIMS equipment and software resulted in the location of all known mines within an estimated error less than ±91.4m (5300 feet). Mine acreage was calculated by counting each symbol (which represented one pixel) and multiplying by 1.1 (the number of acres per pixel). Figure 1 shows a portion of one quadrangle overlay. Table I gives a comparison of acreage measured for sever- al mines from the 1-100 and IDIMS systems vs. aerial photo measurements.

Jan 1, 1979

By Pamela J. Watson

A novel technique has been employed by the U.S. Bureau of Mines to determine the zeta potential of particles for a far-reaching series of material types in a wide variety of baseline waters, both alone and with many different chemical additives. The materials tested ranged from naturally occurring Sioux Quartzite and Tennessee marble to commercially produced magnesium oxide bricks. The waters tested ranged from ultrapure distilled, deionized water to municipal tap water and mine-site water. The chemical solutions tested included inorganic additives, such as aluminum chloride (AICI3) and sodium chloride (NaCl); organic additives, such as dodecyltrimethyl ammonium bromide (DTAB); and nonionic polymers, such as polyethylene oxide (PEO). The results of precise zeta potential determinations have application in a large number of laboratory studies as well as in various mining and processing operations.

Jan 1, 1989