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By Pierre Filiatreault, Brian Straight, Stephanie Thibeault, Devin Castendyk, Londie Cameron

"Working on or near water at active, closed or abandoned mine sites is inherently dangerous. Between 1996 and 1999, the U.S. Mine Safety and Health Administration (MSHA) reported 17 fatalities involving drowning at U.S. metal, non metal and coal mines (MSHA, 2000). Openpit mines which fill with water following mine closure, called pit lakes, present numerous risks to environmental monitoring teams including: a) drowning, b) hypothermia, c) falls to the ground from the top of high walls, d) collapse of unstable access roads, e) rock falls and avalanches from pit walls, f) avalanchegenerated tsunamis traveling across the lake surface and g) rapid degassing events.Some pit lakes are simply not safely or easily accessible for ongoing monitoring. However, the routine collection of water samples from the entire water column on a regular basis is needed to monitor the evolution of water quality over time, verify the accuracy of numerical predictions and, ultimately, manage lake water chemistry and ecological risks. For pit lakes with surface water discharge, regular monitoring is used to appropriately design and adjust water treatment plants in order to produce acceptable site discharge water quality.As a product of these risks and the need for water samples, mining companies spend considerable expense on pit lake safety as part of monitoring programs. This includes training personnel for on water duties and hazards, purchasing or hiring specialized equipment and personnel (such as boats, boat operators, personal floatation devices and cold-water clothing called mustang suits), stabilizing pit walls and maintaining safe access roads to the lake surface and employing spotters who can directly communicate with emergency medical services to watch sampling activities because cell phones and radio signals can be blocked by pit walls. Some sites utilize redundancy to prepare for unexpected incidents and accidents. For example, one Canadian mining company requires two boats on the water during pit lake sampling events, with a third boat on the shoreline, gassed and ready to go. In addition, water samplers are required to hold Marine Emergency Duties training to ensure the entire boat crew is sufficient and competent for the safe operation of the vessel in the event of an accident."

Jan 7, 2017

By D. C. Lindley, D. H. Gaucher

The displacement of oil by water in a waterflood project is accomplished by the action of transient viscous, gravitational and capillary forces which drive fluid through interconnecting pore spaces toward production wells. The relative importance of each of these forces to the effectiveness of the displacement and the production history depends on properties of the reservoir itself and the manner in which it is operated. There has been considerable discussion'-3 concerning the importance of these factors and the extent to which they control the performance of individual waterflood projects. No data have been presented, however, to demonstrate the effect on waterflood behavior of variations in rock permeability, water-injection rates and mobility ratios in three-dimensional reservoir systems in which viscous, gravitational and capillary forces are allowed to assume the proper relative influence on fluid flow. Much information relevant to water flooding has been gained from the study of field case histories. But, the complexity of the systems involved, the difficulty of defining geometry and obtaining sufficient data, and the fact that the same reservoir is never flooded twice with the same initial conditions, all obscure the role of process variables such as rate. Further, mathematical calculations of waterflood behavior are restricted at this time by available mathematical techniques to highly simplified situations. Scaled models, however, do offer an approach at the present time to evaluation of the effects of the pertinent variables. Several investigators have predicted prototype reservoir behavior from observations of model waterflood performance under a variety of conditions. Two-dimensional aspects of waterflood pattern efficiency have been investigated by Muskat, Aronofsky, Dyes, et al, raig, et al,' and Rapoport, et al. he effects of gravity segregation, viscous fingering and permeability stratification have also been studied in two-dimensional models. Craig, et al," studied the importance of gravitational forces on frontal displacement in three-dimensional models with wells on a five-spot pattern. This work in- vestigates the tendency for water to segregate in homogeneous reservoirs because of gravity and to under-run the oil for a range of water-inject ion rates. The effects of permeability stratifications were investigated by these authors using miscible fluids to simulate water-channeling through permeable strata in systems of negligible capillary force. In this investigation, a three-dimensional model of a five-spot pattern flood was designed to represent typical prototype conditions, and the sand and liquid properties were selected so that capillary, gravitational and viscous pressure gradients were scaled. It was not, however, possible to achieve exact similitude regarding viscous fingering when the more viscous oil was used. The effects of rock stratification on waterflood behavior were studied by changing both the permeability ratio and the position of the more permeable sand stratum in a two-layered, horizontal model. For each type of stratification, constant-rate floods were performed and the rates were varied, in separate experiments, over a tenfold range. To observe the effect of mobility ratio on flood performance, two series of constant-injection-rate floods were performed on the most highly stratified reservoir at a water-oil viscosity ratio of one.

By I. Mikov

Established in the 60-ies, the Zlatna Panega quarry is a cement raw materials quarry supplying 95% of the needs of the Zlatna Panega Cement Plant with limestone, marl and other silica-aluminates. The two major types of raw materials are formed by accordingly dipping strata of Upper Jurassic limestones and lower Cretaceous marls. Between them there is a ?transition-zone? or ?contact-zone? of a high-silica content layer, about 5-m thick, defined as ?flint? by investigations including spot sampling throughout the quarry. For many years this ?contact-zone? layer was neglected due its negligible thickness. Further, with the increasing demand on the quality of the raw materials feed to the Plant and the focus on variability of the chemical and mineralogical components, it was decided not to mine any of the parts of the quarry contaminated by this material, for about three years. The latter had an impact on the availability of operating benches that could result in a substantial decrease in the total recoverable re-serves of Zlatna Panega, particularly with respect to marls. There were considerations for resorting to a partial, selective excavation of the quarry pit with a reduced lifetime for the lime-stones and re-opening of an other (currently in-active) marl quarry at a distance of 6 Km from the Plant. The Quarry Team of the Zlatna Panega quarry was assigned to study the problem. The ?contact? layer was duly confirmed with systematic geological (including mineralogy) studies, statistical analysis of available data, surface sampling and shallow exploration drills, resulted into distinguishing a third type of reserves and their credible subsurface delineation by means of geological 3-D modeling and quarry design. A new quarry design was finally elaborated with a view of providing flexibility in mining, utilization of the total volume of all available reserves and maximizing the mine life of Zlatna Panega quarry. An industrial test took place in December 2005, by using the contaminated parts of the quarry (co-mining of the ?contact-zone? materials) at a contribution of 15-20% in the raw materials mix, as dictated by their contribution in the total recoverable resources of the quarry. The purpose was to investigate the viability of this solution ? in line with improved quarry planning ? without compromising the quality of cement production and the efficiency of Plant Operations. Results were overall successful.

Jan 1, 2006

By P. Altinkaya, O. Celep, H. Deveci, E. Y. Yazici

"Copper-bearing gold ores have proved difficult to treat in conventional cyanide leaching process owing to prohibitively high consumption of cyanide by readily soluble copper minerals interfering with gold extraction. Cyanide leaching of gold from copper-rich ores can be improved by intensive cyanidation or application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting and leaching). In this study, nitric acid leaching of a copper-bearing pyritic concentrate (0.3% Cu, 62 g/t Au and 110 g/t Ag) as pre-treatment prior to cyanidation was investigated. The mineralogical analysis of the concentrate has revealed that it is composed of mainly quartz (25%), pyrite (32.7%), sphalerite (5.37 %), galena (2.12 wt %) and anglesite (1.13 %). Arsenopyrite, chalcopyrite, covellite and bournonite were also detected as minor phases present. Previous studies carried out by the authors showed that direct cyanidation (1.5 g/L NaCN) of the as-received concentrate (d80: 80 µm) produced low gold (45% Au) and silver (46% Ag) extractions. Nitric acid pretreatment of the as-received concentrate was performed for 5 hours at 1-5 M HNO3 and 80oC. In these tests, 65% Cu/Pb and 94% Zn were leached. The nitric acid pre-treatment improved the extraction of gold and silver in subsequent cyanide leaching (1.5 g/L NaCN) to 82% Au and 87.5% Ag with a concomitant decrease (up to 54%) in cyanide consumption. It can be inferred from these findings that the removal of copper from the concentrate and the liberation of the occluded gold by nitric acid leaching as pretreatments can be appropriately employed for the treatment of the copper-bearing pyritic concentrate with high gold/silver content. INTRODUCTION Refractory ores are often characterized by their low amenability to cyanide leaching resulting low (often <80%) Au/Ag extractions (Bhappu, 1990; Celep et al., 2009; Marsden and House, 2006). One of the most common causes of refractoriness is the physical or chemical encapsulation of submicroscopic or fine-grained gold in sulphide minerals such as arsenopyrite and pyrite (La Brooy et al., 1994; Vaughan, 2004). To render refractory gold ores/concentrates amenable to cyanide leaching, the decomposition of sulphide minerals within a pre-treatment process to expose the encapsulated gold grains to the action of cyanide is required. In this regard, roasting, pressure oxidation and biooxidation are commercially used processes for pretreatment of arsenopyrite/pyrite gold ores/concentrates ahead of cyanide leaching (La Brooy et al., 1994). Presence of cyanide-soluble copper minerals in the ore leads to low gold recoveries and high cyanide consumptions under conventional cyanide leaching conditions. High cyanide concentrations (CN:Cu>4) should be employed to achieve high gold recoveries from copper-rich gold ores/concentrates. This may require recovery of cyanide from effluents. In this regard, SART Process (sulphidisation-acidification-recycling-thickening) employed industrially for recovery of cyanide and copper as a by-product. This process simply relies on the addition of sulphide (as Na2S, NaSH or H2S) to the leach solution prior to the acidification to pH 4-5. This results in the precipitation of copper as Cu2S and occurrence of free cyanide which is recycled to the leaching circuit after S/L separation (Dai et al., 2012)."

Jan 1, 2018

By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

By D. W. Fuerstenau

On page 1243, column 1, the first line of the author&apos;s reply should read "D. W. Fuerstenau (author&apos;s reply)---," rather than D. E., as printed. In the sentence immediately preceding the first equation (page 1243, column 2)&apos; the word "none" was omitted. The sentence should read: "However, if enough ore is put into the mill [so] that none of the energy put into the mill is wasted on metal-to-metal impact, then the product should have size modulus determined by the relation: ..."

Jan 1, 1961

Paper presented at the Mining Institute of Scotland's annual general meeting held in Glasgow, 8th April 1916. Although there is nothing novel or difficult about the sinking described, circular shafts are not numerous in Scotland so the details connected with such a sinking may be of interest. The shaft was sunk at Dykehead Colliery, Larkhall, which has been worked for over 50 years from the upper seams. It became necessary to sink another shaft to serve as a replacement downcast, by which the output might be maintained and some of the lower seams won. As the sandy clays regularly caused bulging into the rectangular shaft and sinking of the surrounding ground it was decided to make the new shaft circular and to enclose its mouth in a foundation-block of concrete resting on the solid clay. Details are given of the sinking, brick seating and lining, kettle strike, water-rings and doorhead lintels as well as the permanent fittings, winding gear and the cages themselves

Dec 1, 1916

By A. P. Mehta

The role of microorganisms in the leaching of metal sulfides is well established (Torma, 1977; Murr, 1980). However, this established knowledge applies mostly to chemolithotropic microorganisms such as Thiobacillus ferrooxidans which function optimally in leaching catalysis between 25-35° C, and in a pH range of 2-2.5. Although leaching with thermophilic microorganisms capable of extending the range of catalytic viability beyond 35° C is also documented, there are few if any attempts to optimize or extend sulfide concentrate leaching with thermophilic microorganisms. When mixed metal sulfides or other materials having different rest potentials (referenced to the standard hydrogen electrode, SHE, in the electromotive series) make contact in a conducting, aqueous medium, the contacting members will act as an electrochemical cell, with the member having the higher rest potential assuming the role of an electrical cathode. In leaching reactions involving such galvanic couples, the cathode becomes passivated, while the anodic member reacts vigorously due to the electro- chemical reaction which occurs (Hiskey and Wads- worth, 1975). Serry, eta1 (1978) observed that when chalcopyrite and pyrite were in intimate contact in natural ores, the chalcopyrite reacted vigorously by galvanic conversion as a result of the higher rest potential (~ 0.63 V) as compared to the chalcopyrite (~ 0.53 V). In addition, it was postulated that because of the elemental sulfur which can form on the anodic chalcopyrite in this galvanic conversion process, reactions in acid-bacterial medium would be expected to have accelerated copper extraction because of the conversion of any sulfur product layer on the chalcopyrite anode to sulfuric acid according to the following general reactions: [MS?M2+ + S° + 2e- (1) and 2S° + 302 + 2H20 bacteria?-2H2SO 4 (2)] where M in reaction (1) designates the metal (or metals in the specific case of chalcopyrite) to be released to solution by galvanic conversion.

Jan 1, 1982

By E. C. Lane

This paper is the first part of a report giving the results of the Bureau of Mines&apos; twenty-third semiannual survey of motor gasoline marketed in the United States. A companion report, Part II, is in preparation and will give a more detailed discussion of the whole survey. Results of the determination of copper-strip corrosion, color, sulphur content, copper-dish evaporation residue, and gum content as given by the Bureau of Mines steam-oven method will be presented in the second paper, which will also include the prevailing retail price and the tax at the time the sample was taken. This paper deals specifically with data relative to gravity, Reid vapor pressure,5 and distillation (method 100.13).6 The samples tested were divided into "competitive-price gasolines" and "premium-price motor fuels," a method of presentation that was begun with the twenty-second semiannual survey.7 A total of 312 samples were collected from service station pumps in 20 cities throughout the United States. Of this number of samples, 207 were "competitive-price gasolines" and 105 were "premium-price motor fuels." All of the samples were collected in March, 1931, and analyzed at the Petroleum Experiment Station of the United States Bureau of Miner at Bartlesville, Okla.

Jan 1, 1931

By Arthur V. Petty

The Bureau of Mines has researched the utilization of mining and pro-cessing wastes as raw materials for the production of glass-ceramic pipe. Characterization of various wastes as to occurrence and chemical composition is reported. A computer program was developed and used to identify waste materials and mixes that would result in glass melts from which glass-ceramics could be produced after cooling and subsequent heat treatments. The production of abrasion-resistant pipe from inexpensive and readily available domestic resources could offer an economical substitute for high-alloy steels containing the critical and strategic materials cobalt and chromium.

Jan 1, 1984

By Norman TE

The design of composite materials for wear resistant service aims at com- bining two or more materials in such a way as to achieve unique and useful properties not generally available in any single homogeneous material. Properties and applications are presented of what might be described as a new generation of wear resistant materials, namely, metallic and part- metallic composites suitable for use in the high abrasion/moderate impact environment encountered in the crushing and screening of ore. Significant cost performance benefit can result from the use of such materials and several specific case histories are discussed. Some promising new developments, utilis- inn white iron and rubber, as yet in the field testing stage, are reviewed. Further comments are offered foreshadow- ing new composite developments, as yet untried but which appear to h,uve merit.

Jan 1, 1978

By Viktor Lishchuk, Olof Martinsson, Tobias E. Bauer, Elena Haller

Freely accessible and non-confidential real-life geological data sets from mineral deposits are desirable for the wide range of applications in research and education. However, publicly available statistical data are limited in their number and quality—they contain reduced information about geological, geophysical, geotechnical, chemical, mineralogical, and other relevant properties of deposits. This makes such data insufficient for scientific purposes. However, the amount of geological knowledge obtained for a variety of deposits in the past allows the construction of an idealized synthetic ore body model using analytical approach. Such a model could be used for education purposes and testing basic scientific theories, e.g., visualization of deposit structure; teaching sampling strategies; testing new algorithms for mine planning; or comparing geostatistical modeling methods. This paper presents an analytical approach to simulate volcanic massive sulfide (VMS) deposits and shows how synthetic deposit model can be constructed and further used for studying sampling with drilling and simulating folding and faulting.

Jan 14, 2021

Jan 1, 2004

By Josef Arnold, Norbert Fuegenschuh

The “Eggequerung” is an important part of the German Railway’s (Deutsche BahnAG) modernized Dortmund—Kassel line. The heart of this 13-km-long (8 miles)construction lot is the double-track Egge Tunnel with a total length of 2,880 m(9,450 ft.). The tunnel was driven using the New Austrian Tunnelling Method (NATM).The construction contract also called for a reinforced concrete secondary lining, guaranteed for a full water pressure of 30 m (100 ft.) water column. Preliminary geological study already showed that very problematic geological-hydrological conditions would have to be expected. This talk describes the chosen NATM driving concept that was adapted to the prevailing geological and hydrological conditions, the special driving method applied in geologically difficult zones as well as the water control concept used during driving. The flexibility and the limits of the NATM under exceptional hydrological conditions are illustrated. Also described are reinforced concrete lining works for the watertight secondary vault (reinforced concrete secondary lining without water-proofing membrane).

Jan 1, 2003

By Mostafa Maazouz, Jeff Blackwood, Mauricio Gordillo, Sang Hoon Lee, Micah Ledoux, Liang Zhang

To meet rising requirements for the low-damage ultra-fine process with the focused ion beam (FIB) in the materials science and semiconductor industry, the advanced ion column and corresponding advanced applications as a solution are developed and demonstrated. Novel high-speed high kV milling, low kV cleaning and imaging capabilities have enabled the creation of impeccable ultra-thin structures such as TEM samples and nanometer scale structures. Minimizing Ga+ induced sample damage is achieved through the optimized final cleaning at 500 eV ion landing energy with the new ion optics, which utilizes close control of the ion dose, beam incidence angle, spot size, pattern algorithm and imaging performance. Newly introduced process solutions achieve the improved process throughput. Initial demonstration is performed on the latest 14 and 10 nm scale FinFET device. Validation of the thinnest <0.8 nm thick ion damage layer on the <7 nm thick lamella structure was confirmed through TEM analysis.

Mar 1, 2017

By Ernest L. Corp

First in a projected series on the use of flexible liners for support of underground mine openings, this report presents information obtained from an extensive review of the literature on this subject. It also includes results of some preliminary test work by the Bureau of Mines. Investigations thus far indicate that flexible liners offer numerous advantages over rigid-type sup-ports, By deforming in the direction of the applied stress, the stresses are redistributed from the liner to the surrounding material. The corresponding buildup of passive resistance in the direction of diametric extension causes an equalization of stresses around the liner, thereby enabling the liner to carry loads in a more efficient manner. However, additional experimental data are needed to establish design criteria that will permit maximum utilization of the flexible liner concept in mining. Testing of small-scale models, accompanied by measurement of free-field stresses in material surrounding the model, is recommended as the most suit-able approach to the problem. The experimental procedures necessary to such an approach are outlined in detail and a statistical design for the experiments is proposed. The report also describes a device developed by the Bureau for measuring free-field soil pressures to 1,000 psi and a technique for evaluating the response of the device.

Jan 1, 1967

By James P. Cooney

What is required for the mining industry to grow and prosper in a politically challenging world? The answer to this can be summarized as “the industry’s three priorities.” The first priority is gaining access to the world’s mineralized jurisdictions. The second is establishing a measure of security and predictability in government treatment of mining. Confidence in the stability of the fiscal and legal framework within which mining operates is necessary to encourage the investment of large amounts of capital in mine development. The third priority is sustaining the industry’s welcome during the long term in those jurisdictions worthy of investment.

Jan 1, 1996

In this paper is given a description of the flotation plant recently erected by Broken Hill South Limited at the South Mine, Broken Hill, N.S.W. It has been built on the site of the old flotation plant, which was described in a previous paper published by the author. The present paper is supplementary to the former paper in that it replaced the following sections thereof, namely, those from end of the second paragraph, page 269, to the end of the first paragraph page 282, and from the end of the second paragraph, page 284, to the end of the third paragraph, page 302.The roll crushing, fine grinding, gravity concentration, filtration, disposal of products and sampling in the new plant are the same as described in the above mentioned paper.The reconstruction of the flotation section, described herein, completes the reconstruction and modernisation of the treatment plant which was begun in 1928. A description of these earlier alterations has already been published in the Proceedings of this Institute.

Jan 1, 1935

By G. Lucas

"Material substitution occurs continuously in response to competitive and economic pressures. Technical development can accelerate or slow substitution by improving the performance of the invading or defending material. The choices are seldom simple and have to be made in the context of continuous commercial change.The development and commercialization of a new aluminum material is examined. The material has been introduced into· several different markets, so it is possible to compare and contrast the degree of success obtained in each.IntroductionAluminum-based materials have been in use for over one hundred years and , therefore, the development of a new family of alloys is rare. In the early 1970s, Dr. L.R. Morris and his coworkers at Alcan&apos; s Kingston Research Centre started work on what was, at the time, something of a scientific curiosity-a family of alloys strengthened by an unusual mechanism.This paper deals with the development and commercialization of what became known as the Alcan 255 alloys"". These alloys have found uses in several markets, usually as improved substitutes for existing materials. Forecasting the usefulness of a substitute material in an existing marketplace is difficult, in part, because even material users are seldom able to specify precisely their requirements. This uncertainty can cause the failure of some substitutions but can also lead to opportunities which were not initially obvious.Technical BackgroundPure aluminum is a soft, weak material. It can be strengthened by the addition of various alloying elements and by work hardening. Alloying elements usually act by forming solid solutions which are stronger than the pure metal or by precipitating during heat treating or aging and so preventing the easy movement of dislocations during deformation. Elements which can perform either role had been investigated for decades and were thought to offer little chance of technical breakthrough in 1970. An outgrowth of the then new and exciting research on directional solidification seemed, however, to offer such promise.Some aluminum-iran-manganese alloys will solidify under certain conditions as &apos;coupled growth&apos; eutectics (Figs. I and 2). The microstructure shows one phase growing as long rods through the other. This is an uncommon structure and it was investigated to see if it had equally unusual properties. On deformation by rolling the rods were broken up into small equiaxed , evenly-spaced particles (Fig. 3). Materials with this structure were found to be stronger than other alloys with similar amounts of alloying addition, and to resist thermal softening remarkably well. This combination of properties was thought initially to be due directly to the particles by a dispersion strengthening mechanism, but later this was found not to be strictly true."

Jan 1, 1987

By S. P. Sandoval

In 2002 the Freeport-McMoRan Technology Center undertook research to develop a lower-cost alternative to guar for cathode smoothing in copper electrowinning. The work was conducted at the Technology Center?s SXEW Test Facility located in Morenci, Arizona. Bench-scale copper electrowinning cells were designed and implemented to screen a number of potential polymers for cathode smoothing. These included modified polysaccharide polymers that were nonionic, cationic, and anionic in nature.

Jan 1, 2010