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By Ren G. Dong, Kristine M. Krajnak, Dan Welcome

Continual occupational exposure to vibrating hand tools can damage the neural, vascular and other soft tissues of the fingers. Rat tail models have been developed to investigate the biological responses of the tissues to vibration.1-2 However, the biodynamic response of the tail relative to that of the human fingers has not been characterized. The objective of this pilot study was to compare the transmissibilities of rat tails measured via a scanning laser vibrometer to those of human fingers gripping a handle. Methods In Part I of this experiment, four male Sprague Dawley rats (6 weeks old) were exposed to discrete 5g-rms sinusoids of 32, 63, 125, 160, 250, and 500 Hz. The rats were restrained in Broome-style restrainers with their tails constrained without compression to an exposure platform via elastic straps as shown in Figure 1. The platform was attached to a vertically vibrating shaker. The vibration was measured for the array of points shown in Figure 1 using a scanning laser vibrometer (Polytec) and the transmissibility calculated for each point on the tail relative to the reference points on the platform. In Part II, three male human subjects were exposed at the frequencies specified in Part I - with the addition of 1000 Hz - at a magnitude at the ANSI <0.5-hr limit up to 63 Hz, after which the acceleration was held constant at 5g-rms. The subjects gripped an instrumented handle at 20 N as shown in Figure 2. The transmissibility was calculated relative to the reference points on the handle. [ ]

Jan 6, 2006

By Carnevale Francesco, Bracci Laudiero Alberto, Pampanin Piero

"SummaryIn the Port of Naples a slurry wall has been realized through a sandy layer up to a deep tuff layer using the Cutting Soil Mixing technique.The executed panels have dimensions of 2.8 m x0.65 m in plan and a total length of 25 m. Primary and secondary panels have been executed using the wet to wet technique. During the panels execution the following parameters had been measured: injection pressure, injected volume, verticality. At the end of the works an exploratory campaign has been carried out through boreholes collecting samples for laboratory tests in order to verify the diaphragm thickness and its physical and mechanical properties (i.e. unit weight, unconfined compressive strength).The interpretation of the collected data allowed to verify the efficiency of the method, the volume of slurry loss due to permeation during the panels execution, the quantity of the obtained spoil compared to the volume balance equation, both for the sand and the tuff layer.Eventually, the measured physical and mechanical characteristics of the panels have been correlated to the execution method performed.IntroductionIn the Naples Port area there is a polluted site which has to be hydraulically isolated in order to prevent the pollution of the groundwater that flows from land to the sea through the Port area. A hydraulic cut-off wall has to be realized and particularly a slurry-wall realized using the CSM method had been executed.To date, two stretches have been executed, 140 an 110 m in length respectively, as shown in Figure 1 and Figure 2.After execution, the slurry-walls have been investigated with boreholes. In-situ and laboratory tests on the recovered samples of grout have been carried out; furthermore, the geotechnical parameters of the mix composing the wall have been measured."

Jan 1, 2014

By D. N. Madge

The use and development of industrial process control computers in the mineral industry during the 1970&apos;s has been sluggish. This cautious approach is due to lack of commitment by senior management. The lack of commitment is due to several reasons: variable mineral processes and technologies, market fluctuations, and excessive costs and inadequacies of applicable products supplied by computer vendors.

Jan 1, 1979

Founded in 1994 through a joint effort between Underwriters Laboratories Inc. (UL), the U.S. Consumer Product Safety Commission (CPSC) and the National Electrical Manufacturers Association (NEMA), the Electrical Safety Foundation International (ESFI) is North America?s only non-profit organization dedicated exclusively to promoting electrical safety in the home, school and workplace. ESFI is a 501(c)(3) organization funded by electrical manufacturers and distributors, independent testing laboratories, utilities, safety and consumer groups, and trade and labor associations. ESFI sponsors National Electrical Safety Month each May, and engages in public education campaigns and proactive media relations to help reduce property damage, personal injury and death due to electrical accidents. The Foundation does not engage in code or standard writing or lobbying and does not solicit individuals.

Jan 1, 2004

By V. F. Swanson

At the AIME meeting in Tampa in Oct. 1966, an empirically developed equation was presented which allowed the calculation of free settling velocity for any sized particle: 1 [ ] This equation requires the use of two parameters a and p which are coefficients derived from boundary layer theory.2 It was possible to develop values of a and p for several minerals by back calculation of published data. The original equation had one major flaw. When the fluid density exceeds the density of the solids, the solution to the equation becomes imaginary. A flaw was indicated also by the fact that galena and sylvite both having cubic cleavage, did not have similar values for a and b. Galena gave calculated values of a = 1.082 and g = 3.11, while sylvite gave values of a = 1.870 and p = 2.56. These flaws prompted further study of the equation, resulting in the following empirical modification: [ ] It is obvious a real solution of the equation is possible for all values of ps and p. When PL > PS, V is negative, indicating that the particles will rise against the attraction of gravity. The validity of the modification is borne out by the fact that when values of a and p were back calculated for galena and sylvite using the modified equation, both minerals gave values of a = 1.038 and p = 3.01. With the modification shown in Eq. 2, Newton&apos;s friction factor becomes [ ]

Jan 1, 1976

By Y. Luo

"It is generally known that spontaneous combustion potential is a function of coal rank, with low-rank coals having high susceptibility to self-ignition and high-rank coals having low potential. To establish this functional relationship and use it as an engineering tool to identify the propensity of coal to self-heat, both rank and spontaneous combustion potential should be quantified. ASTM D388 is normally used to classify coals by rank, but this classification system can only serve a qualitative analysis. To classify coals by their potential for spontaneous combustion, the self-heating temperature (SHT) method originally developed by the U.S. Bureau of Mines (USBM) was used by Litton and Page (1994) to correlate coal rank with spontaneous combustion potential. In that method, the SHTs of coal determined by an adiabatic experiment are linked with proximate analysis results through a proposed concept known as the “moist fuel ratio.” This ratio is a function of moisture, volatile matter and fixed carbon, all of which have widely different content percentages in different ranks of coal and have strong relationships with coal rank. However, the method is highly empirical, and there is large standard deviation between experimental data and calculated results. The equation correlating the coal quality parameters to determine SHT should be improved with more experimental data.This paper reports on the development of a new system for predicting the spontaneous combustion potential of U.S. coals, based on coal composition data from the U.S. Geological Survey’s coal quality database. First, the user is provided with a quantified classification of coal rank. Second, based on experimental SHT data covering a wide range of ranks from lignite to low-volatile bituminous coal, the original USBM correlation for predicting SHT is improved for the respective rank of coal. The relationship between the rank and SHT of U.S. coals was developed and plotted. The plot diagram can be used for a quick estimate of the SHT of a U.S. coal and as a cost-effective tool for the initial risk assessment of a new mine development."

Jan 1, 2015

By G. Danha, D. Glasser, D. Hildebrandt, N. Hlabangana

"In this work, we apply a method known as the attainable region (AR) technique in order to optimize the milling and leaching process of a low grade gold ore. No work on the application of the AR optimization technique has been done yet on a joint milling and leaching process. The advantage of the AR approach lies in its ability to simplify the optimization problem, as searching over a defined set for the maximum of an objective function is a fairly standard procedure. The objective function we selected was that of optimizing a linear function of the value of the recovered material minus the cost of both milling and leaching. Using the three variables (milling time, leaching time and recovery), we constructed a 3D plot and used it to obtain all the possible recoveries from the different milling and leaching times. The optimum for our chosen objective was then found by overlaying a contour plot of the objective function on the 3D plot. Our results show that the optimum was obtained at 90 % recovery with a profit value of 600, milling time of 30 minutes and leaching time of 1750 minutes.INTRODUCTIONAfrican countries are facing a general increase in demand for electrical power. In South Africa, the demand is now surpassing the supply from ESKOM, the main electric power provider of the country. This has resulted in load shedding strategies being implemented in many local communities in an attempt by ESKOM to cope with the high demand. A potentially better approach is to propose use of energy efficient technologies in the country’s largest power consuming industry; the mineral processing sector.In mineral processing, milling is the highest consumer of energy. The objective of carrying out milling is not merely to reduce the particle size of the feed material, but also to liberate the constituent minerals that make up an ore. This is done so that valuable minerals can be separated from the gangue, in downstream processes, such as leaching. However, the milling process is generally performed relatively poorly, and at a considerable expense in terms of electrical power utilization. Tomanec and Milovanovic (1994) estimated that milling accounts for more than 50 % of the total power used in the concentration process, but this can rise to as high as 70 % for hard or finely dispersed and inter-grown ores. Apart from being relatively wasteful of energy, the milling process is also inefficient with regard to mineral liberation because of the indiscriminate nature of the grinding force."

Jan 1, 2016

By Greg Wyartt

In the Pilbara region of Western Australia, an iron ore mine is undertaking a high wall cut-back to improve stability and allow access to deeper ore deposits. Several sections of the wall have been classified geologically sensitive due to unstable localised geology, and therefore an engineered approach to vibration critical blasting was required. The use of electronic detonators allowed multiple signature (seed) holes to be incorporated into a production blast adjacent to the geologically sensitive area, therefore providing baseline vibration data to be used for future modelling with the added advantage of eliminating unnecessary pit closure downtime typically associated with a signature hole program. All subsequent blast patterns also incorporated multiple signature holes to provide additional data and allow continual updating – and therefore improved accuracy - of the blast prediction model.

Jan 1, 2018

By Fred Witt, Milton Schwartz

ESTABLISHED methods for obtaining quantitative pole figures for flat sheets1"5 can be extended to apply to thin films on a substrate. The mode of scanning the sample is exactly the same as described in the references? but consideration is given to the fact that the scattered X-ray intensities are due to both the thin film and its substrate with appropriate attenuation factors. The purpose of this paper is to describe a method to obtain the scattered intensities from the film alone for subsequent pole-figure determinations. Fig. 1 shows the four possible general positions of the film (f) and its substrate (s) with respect to the incident X-ray beam (I,). In this paper it will be assumed that the plane of the sample is normal to the plane of the diffractometer. In the diagrams the line jV is the normal to the flat sample and the line P is the trace of the diffracting crystallographic planes in the plane of the diffractometer. The angle of tilt, a, is the positive acute angle measured from the line N to the line P; if this angle is measured clockwise then a is said to be in the positive a region; if this angle is measured counterclockwise then a is said to be in the negative a region. For the reflection cases, the total scattered intensity, at the proper Bragg angle for a particular set of planes, is due to that scattered by the film Vf) and that scattered by the substrate. The beam incident on

Jan 1, 1967

By W. J. Mitchell

During the months of April and May 1992, the Phelps Dodge Hidalgo smelter underwent a major turnaround. This was the third such turnaround in the life of the facility which was commissioned in 1976. During the third furnace campaign, the smelter processed 5.2 million tons of concentrate producing 2.6 billion pounds of anode copper over a 7.5 year period. The critical path on the fifty-nine (59) day turnaround schedule was the reconstruction of the Outokumpo flash furnace which integrated some modifications with standard rebuild practices. Modifications included incorporation of horizontal cooling jackets throughout the furnace settler as well as the installation of castable refractory in the reaction and uptake shafts.

Jan 1, 1993

Abbott, Argyle Campbell 1209 Sherwin Ave, Chicago, ILL. &apos;29 Almstrom, Adne A., Student, Met. Engrg, Washington State College Pullman, Wash. &apos;29 Ankedinoff, N., School of Mines, Univ. of Utah Salt Lake City, Utah. &apos;30 Apter, Robert F., Student, McGill Univ Montreal, Que., Canada. &apos;30 Bailey, Donald G 798 1/2 Kensington Rd., Los Angeles, Cal. &apos;29 Baker, Kenneth B., Met, Aluminum Co. of America Pittsburgh, Pa. &apos;29 Barger, Thomas, Student, Univ of North Dakota Grand Forks, N D &apos;23 Bartholomees, Geo. C Box 304, Bonne Terre, Mo. &apos;29 Bates, Walter, Student, Univ. of Utah, School of Mines . Salt Lake City, Utah &apos;30 Bobb. Russell V. . 16 College Ave., Houghton, Mich. &apos;29 Boswell, John C., Stripping Asst, Fairbanks Exploration Co Fairbanks, Alaska &apos;29 Brandenburg, E. C., Student, Univ of Kentucky 112 Church St, Lexington, Ky &apos;29 Brannen, John, Chemist, Assay Office, Consolidated Min & Smelt Co. of Canada, Ltd , Tadanac, B. C , Canada &apos;29

Jan 1, 1923

By Fábio Luiz dos Santos

As ligas de alumínio, em particular, apresentam certas restrições quando submetidas ao processo de união por soldagem. Isto se deve, principalmente, por apresentarem elevada condutividade térmica, elevada contração na solidificação e elevada solubilidade de hidrogênio. Levando em conta estes aspectos, o processo de soldagem FSW apresenta grande potencial para esta aplicação, visto que, é autógena, realizada sem fusão do material e sem utilização de escórias ou gases de proteção. A partir deste conceito, o objetivo do presente trabalho é avaliar a união de chapas finas de alumínio da liga 3105 H26, com espessura de 0,7mm. Para realização dos testes, foram analisados fatores como: penetração da ferramenta nas chapas processadas, ângulo de ataque, tipo de ferramenta e modo de controle de penetração (posição ou força). Os resultados indicaram que o modo de controle por força se mostrou o mais indicado para chapas finas, e que o regime transiente no início de soldagem foi a parte mais crítica para controle da qualidade da junta soldada.

Aug 16, 2017

By A. Nhasengo

Paper written on project work carried out in partial fulfilment of B. sc. Eng (Mining Engineering) The purpose of this investigation was to assess the mining strategy for steep reefs at Mine A mine in 2005 and 2006. Reefs steeper than 35° were discovered when production commenced at the mine. At that time reefs steeper than 35° were not popular in South African tabular gold mines, therefore new techniques of mining them had to be developed. The underhand mining method was chosen for this purpose. The project was about assessing ventilation, support costs, local support cycles, adherence to the mine?s support standards, mine planning and efficiencies of the underhand mining method. The project work was covered by doing a literature research for underhand mining methods and performing a literature review of the mining methods, support methods, ventilation standards at Mine A. Underground visits were conducted at Mine A mine for data collection, and Mine B was visited to obtain information on support costs and efficiencies. During the investigation it was realized that the underhand mining method was an appropriate method for mining steep reefs; however, there were some challenges related to ventilation and support installation. Efficiencies could be realized with the underhand mining method and planning and scheduling were not different from breast mining.

Jan 1, 2007

By K. L. Marshall

A facetious title was purposely given this talk, so that a formal paper would not be expected. TWO or three days ago, while discussing with Mr. Dickinson some of the details of the dust explosion demonstrations we are planning for this coming Saturday, I remarked that we would like to have as many people as possible see some samples of 20 and 200 mesh dust, so they would more fully understand just what was causing the explosions. Mr. Dickinson requested that I bring samples and screens and in this informal manner, give you all a ".close-up" of coal dust which is considered in Explosion Hazard reports. While sampling mines, for road, rib, and roof dust, in connection with safety service and hazard reports which the Bureau of Mines Engineers make at the request of coal operators, I have often been assisted by under- ground mine officials or other men of many years experience and on almost every occasion, while we were carefully brushing the very fine dust from timbers or coal surfaces, they would make some remark such as: "never had noticed this kind of dust, didn&apos;t know it was here", or "well, that&apos;s the first time I really understood what all &apos;this dust talk was about." Such experience makes me believe that the much published terms, 20 mesh and 200 mesh are just numbers to the great majority of both miners and operators. We are now going to have lesson one in the primer of coal dust explosions and I want to say, in all sincerity that a complete course in the hazards of mining is deserving of a place in the curriculum of the best mining schools of this country. Sample No. 1 is fine coal and dust and is a fair sample of what can be found every where in rooms and entries of a mine, as it is too small to be gathered up with a shovel and is left in the ordinary mining at the faces and is spilled along the entries in haulage. In this you will see some quarter inch coal, much eighth and sixteenth inch coal, in fact those are the sizes I find many people have in mind when they are asked about the dust made in mining. Although the sizes mentioned are the ones which seem to almost entirely make up this sample, such is not the case, for from 10 to 20% of such a sample will usually pass this 20 mesh screen and in Sample No. 2 we have 20 mesh dust. Result of many tests, supports .the statement of the coal mining division of the Bureau, that it is quite probable that coal over 20 mesh does not take part in any but the most violent of explosions and that all dust under 20 mesh may take part in any explosion. The largest particles in this sample will not be over .03 inches in their largest dimension and a pound of dust to a foot of average heading is very easily found in most every mine I have visited and usually a great deal more can be readily gathered up. It was .found early that the finer the dust the more dangerous it was for a given coal. So for the early explosion tests conducted by the Bureau a commercial pulverizer was used and it turned out a 20 mesh dust of which about 75% would pass 200 mesh. Some men question whether the ordinary mining methods made such a dust and so doubted the explosibility of the dust in their own mines. The question was well taken, and hundreds of dust samples were taken by the field men of the Bureau to determine the kind of dust being made in all methods of mining and all classes of coal. The result of such sampling showed some coals. resisted breakage more than others and that actual mine road dust, through 20 mesh, would show from 10 to 20% through 200 mesh, and for actual rib and roof dust through 20 mesh, they would get from 20 to 40% of 200 mesh dust. In testing the

Jan 1, 1924

By R. Alford

In the modern world of demolition safety is paramount and unnecessary or unquantifiable risks are not accepted (FasterCapital, 2024) and all risks must be kept As Low As Reasonably Practicable (ALARP) (BSI, 2017). This principle has led to a huge reduction in deaths in the last 50 years and the statistics continue to improve although this is starting to plateau (Beal, 2007). Under normal circumstances, this is now simply part of the normal way work is done and systems are in place to ensure both safety and economic profits are assured. What happens when the environment is less controlled and risks are unknown, such as after a natural disaster, war, an accident or a stand-up from a failed demolition attempt? A dangerous structure cannot responsibly be left alone with a fence around it so some action must be taken, but how can this be done safely and responsibly? An incident in Didcot, England in which half of a power station’s boiler house being prepared for an explosive demolition collapsed suddenly, killing four men in 2016 provides a useful case study of how technology, creativity and planning can be used to conduct complex demolition fully remotely to avoid any further risk to life.

Jan 21, 2025

By Tom Snyder, John Brulia

Part 4 is the final article by the authors on hazardous materials (HM)transportation safety and compliance for U.S. shippers and carriers who offer and transport commercial explosives in commerce on public highways. This article covers hazardous materials (HM) cargo segregation and securement of non-bulk packaged explosives.

Jan 1, 2015

By George Weaton

Two years ago the general features of the St. Joseph Lead Company&apos;s zinc-smelting process were described.1 At that time the discussion was limited to a description of the production of high-purity electrothermic zinc oxide. The present paper will describe the commercial production of electrothermic zinc metal. Since a fairly complete description of the plant of the Josephtown smelter was given in the earlier paper, the brief recapitulation given here will be limited to mention of additional equip-ment recently installed and a bare outline of the preparatory process. The raw material is zinc sulphide concentrate received from the com-pany&apos;s mines in St. Lawrence County, New York. An average dry-weight analysis of this material is: Zn, 58.28 per cent; Pb, 0.56; insoluble, 1.6; Si02, 1.12; Fe, 6.4; CaO, 0.47; MgO, 0.27; S, 31.9; Cd, 0.1; Cu, 0.06; Mn, 0.24. Moisture content is usually about 3 per cent. Three 21-ft. 6-in. diameter, 12-hearth Nichols-Herreshoff furnaces roast the concen-trate to a calcine of average composition (first 10 months of 1938) : Zn, 67.69 per cent; Pb, 0.06; insoluble, 1.75; Si02, 1.26; Fe, 7.24; CaO, 0.47; MgO, 0.36; S, 1.88; Cd, 0.1; Cu, 0.07; Mn, 0.27. The sulphur dioxide gas, after passing through a waste-heat boiler, proceeds through a recently redesigned low-resistance gas-purification assembly to the contact sul-phuric acid plant, of which the capacity is 200 tons of concentrates per day. The calcine is mixed with a portion of returned furnace residues and sintered on 42-in. by 44-ft. Dwight-Lloyd sintering machines, gas-fired. Wind-box gases pass through air coolers before filtering in a 1440-bag Dracco unit, and thence to stack. The Dracco fume is mixed with Cottrell dust, from roaster gas cleaning, and sent to the leach plant, where it is roasted (SO2 to acid plant) and leached with sulphuric acid to recover, as end products, lead sulphate, zinc sulphate and cadmium.

Jan 1, 1939

1. New books Specialty steels and hard materials, edited by N. R. Comins and J. B. Clark. Oxford, Pergamon, 1983.482 pp. Hardcover £55.50. Papers presented at an international conference on advances in flow measurement techniques, edited by H. S. Stephens and B. Jarvis. BHRA Fluid Engineering (Cranfield, Bedford, MK43 OAJ, England), 1982. £36. Papers presented at Fourth European Conference on Mixing, edited by H. S. Stephens and D. Goodes. BHRA Fluid Engineering (Cranfield, Bedford, MK43 OAJ, England), 1982. £36. Papers presented at an international conference on hydrocyclones, edited by H. S. Stephens and G. Priestley. BHRA Fluid Engineering (Cranfield, Bedford, MK43, OAJ, England), 1982. 248 pp. £27. Controlled atmospheres for heat treatment, by R. Nemenyi. Oxford, Pergamon, 1983. 225 pp. Hardcover 20, flexicover £7.50. Electrochemical techniques in corrosion testing and research, edited by J. S. Scully. Oxford, Pergamon, 1983. 150 pp. Flexicover £9.45 2. Book reviews Off highway truck haulage, by the Newman Combined Group. Parkvine (Victoria), Australasian Institute of Mining and Metanurgy, 1982. Reviewer: B. J. Vorster Elsevier&apos;s mineral and rock table, compiled by P. Lof. Reviewer: A. Wedepohl Field geologists&apos; manual, by B. A. Berkman. Monograph Series No. 9, Australasian Institute of Mining and Metanurgy, 1982.295 pp. Reviewer: R. A. G. Cuipers 3. Mintek reports Report M56 A computer programme for the evaluation of process routes in the production of ferrochromium. Report M61 An atomic-absorption programme for the Apple 11 Plus computer. Report M63 A general-purpose data logger. Report M65 A preliminary survey of the corrosivity of water in gold mines. Report M66 A review of corrosion inhibitors: theory and practice. Report M67 The determination of total cyanide in solutions containing uranium and gold. Report M68 The suitability of Doppler flowmeters for use in the minerals-processing industry. Report M70 The preparation and certification of two reference materials of South African manganese ore. Report M78 A n evaluation of the Leeds laboratory-scale flotation cell. Report M79 The determination, by X-ray-fluorescence spectrometry, of gold and uranium on resin. Report M80 The installation and commissioning of a Siemens SRS200 sequential X-ray-fluorescence spectrometer. Report M81 The application of the inductively coupled plasma system to the simultaneous determination of precious metals. Open-pit and strip mines The South African Institute of Mining and Metallurgy and the Mining Alumni Society of the University of Pretoria are organizing an International Conference on The Planning and Operation of Open Pit and Strip Mines in Pretoria from 9th to 13th April, 1984. Other Institutes co-sponsoring the Conference are The Canadian Institute of Mining and Metallurgy, The Institution of Mining and Metallurgy, and The Society of Mining Engineers of AIME.

Jan 1, 1983

By X Zhang, B McFadzean, C T. O’Connor, S Pikinini

The Platreef in South Africa contains one of the world’s largest reserves of platinum group elements. One of the major platinum group minerals (PGM) components in this ore is sperrylite (PtAs₂), which has been found to be slow floating compared to the other PGMs. In a study aimed at determining the reasons for the poor floatability of sperrylite and to improve its recovery, tests were carried out to determine the interactions of the mineral with a range of standard and novel collectors. Microflotation tests were carried out to determine the hydrophobicity of the minerals before and after adsorption of collectors. In addition, experiments were carried out to determine the enthalpy and extent of collector adsorption on the minerals and to investigate electrochemical interactions between sperrylite and selected standard collectors. The results indicated that poor collector adsorption was the major cause for the poor floatability of sperrylite. Sperrylite had both poor natural (14.5 per cent) floatability and collector-induced flotation recoveries, the highest recovery of 26 per cent being observed using PNBX collector at pH 9. Moreover, the rest potential tests showed that the interaction of sperrylite with standard collectors such as xanthates was poor. The decrease in potential after the addition of the standard collectors ranged from 7.9 mV to 24.9 mV under alkaline conditions. Furthermore, sperrylite rest potentials remained unchanged with a change in pH from basic to acidic, indicating its resistance to surface alteration. Surface alteration of the minerals is key for the chemisorption of collectors to take place on the mineral surface. This was further emphasised by flotation recoveries at low pH, where only certain collectors responded positively to a decrease in pH and these were shown to have undergone a structural change. This work has highlighted the difficulties associated with sperrylite flotation and provides some direction for future research.

Aug 24, 2022

By John Chipman, Minu N. Dastur

This paper presents equilibrium data on the reaction of water vapor with vanadium dissolved in liquid iron at 1600°C. The thermo-dynamic behavior of vanadium and oxygen when present together in the melt is discussed. A deoxidation diagram is presented which shows the concentrations and activities of vanadium and oxygen in equilibrium with V209 or FeV2O4. STUDIES of the chemical behavior of oxygen dissolved in pure liquid iron1-3 have served to determine with a fair degree of accuracy the thermody-namic properties of this binary solution. The practical problems of steelmaking, however, involve not the simple binary but ternary and more complex solutions. Only a beginning has been made toward understanding the behavior of such systems. The silicon-manganese-oxygen relationship was studied long ago by Korber and Oelsen4 and more recently by Hilty and Crafts." The carbon-oxygen reaction was investigated by Vacher and Hamilton6 and by Marshall and Chipman.7 A number of deoxidizing reactions have been studied empirica1lys&apos;10 with the object of determining the appropriate "deoxidation constants." The work of Chen and Chipman" afforded a clear-cut view of the effect of the alloy element, chromium, on the thermodynamic activity of oxygen in liquid ternary solutions. These investigators determined the oxygen content of experimental melts which had been brought into equilibrium with a controlled atmosphere of hydrogen and water vapor and were able to show that the presence of chromium decreases the activity coefficient of oxygen. They determined also the conditions under which the two deoxidation products, Cr2O3 and FeCr2O4, were formed and showed that the activity of residual oxygen is considerably less than its percentage. It was the object of this investigation to apply a similar method to the study of molten alloys of iron, vanadium, and oxygen. Vanadium was once considered a moderately potent deoxidizer, but this is now known to be erroneous, in the light of its behavior in steelmaking practice. Its reaction with oxygen retains a certain amount of practical interest in that a high percentage of one element places a limit on the amount of the other that can be retained. As a deoxidizer it will be shown that vanadium lies between chromium and silicon. Experimental Method The apparatus was that used by the authors3 in their study of the equilibrium in the reaction: H2(g) +O = H2O(g);K,= [1] PII., ao Crucibles of Norton alundum or of pure alumina were used. The latter were made in this laboratory and were of high strength and low porosity. Under conditions of use they imparted no significant amount of aluminum (less than 0.01 pct) to the bath. Temperature measurements were made with the optical equipment and calibration chart of Dastur and Gokcen.= The charge was made up of calculated amounts of ferrovanadium (20 pct V) and clean electrolytic iron totaling approximately 70 g. The first few heats were made in alumina crucibles with an insufficient amount of vanadium so that no oxide of vanadium would be precipitated under the particular gas composition. All the heats were made at 1600 °C under a high preheat and with four parts of argon to one part of hydrogen in the gas mixture to prevent thermal diffusion. The rate of gas flow was maintained constant at 250 to 300 ml per min of hydrogen. The time for each heat was three quarters of an hour after the melt had melted and attained the required temperature (1600°C). The water-vapor content of the entrant gas mixture was gradually raised in succeeding heats, keeping the vanadium content of the melt constant. This was controlled by manipulation of saturator temperature. A point was reached when for a given H2O:H2 ratio some of the dissolved vanadium was oxidized and appeared as a thin, bright oxide film on top of the melt. By raising the temperature of the melt it was possible to dissolve the oxide film which reappeared as soon as it was cooled down to 1600°C. The temperature readings taken on the oxide film were consistently higher by 80" to 85 °C as observed by the optical pyrometer. The heat was allowed to come to equilibrium under a partial covering of this oxide film. At the end of the run the power and preheater were shut off and the crucible containing the melt was lowered down into the cooler region in the furnace. This method of quenching proved quite

Jan 1, 1952