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By D. C. Goldring

Many high-grade iron ores are considered to result from the supergene enrichment of banded iron formations. The secondary processes may be related to either present-day or ancient erosion cycles and may reach a considerable depth. Other high-grade ores hosted by banded iron formations are regarded as either sedimentary or metamorphic in origin although often also subjected to the secondary processes. The evidence for this multiplicity of origins is reviewed with descriptions of selected deposits: Kedia d'Idjil and M'Haoudat in Mauritania, Bomi Hills and the Nimba Range in Liberia, the Itabira district in Minas Gerais, Brazil, and El Pao in eastern Venezuela. Emphasis is placed on the recognition of textures that show that some ores are tectonites, the precursor materials having undergone pervasive deformation accompanied by metamorphism. The question whether such ores are pre- or syntectonic is difficult to resolve, the evidence being inconclusive, but a diagenetic/early deformation origin is preferred. The possible range of origins has to be taken into account in exploration, particularly as regards the depth of drilling, and in the characterisation of ores for metallurgical use

Jul 1, 1991

By Scott Chesman

Increased TBM performance is leading the way for resurgence in tunneling activity in NYC. Tunnels will be excavated in the same geologic formations as previously excavated D&B tunnels whose construction records are providing valuable insight into the prediction of rock mass behavior. This report compares an eight mile stretch of NYC Water Tunnel #2 with the recently excavated eleven mile stretch of the TBM driven Water Tunnel #3. Comparisons of the type and amount of rock support installed as well as water inflows and grout quantities are made. Rock mass characteristics specific to TBM performance are also evaluated.

Jan 1, 2005

By J. A. Morgan

IN the art of roasting sulfides it is well known that the lower the temperature and the higher the pressure of SO, the larger will be the amount of sulfate present in the product. However, the mechanism of sulfate formation is not generally understood. The following experiment" demonstrates in a direct way that, in the roasting of Cu2S, the sulfate forms from the reaction of Cu2O, formed by the oxidation of Cu2s, with gaseous SO, (or SO3) and 0,. Thus, the sulfate does not form at the sulfide surface. The reaction at the sulfide surface is the same whether or not sulfate is formed. Using an indirect method, Ong, Fassell, and Wadsworth' infer that sulfate forms after oxidation, during the roasting of sphalerite, agreeing with the observations of this paper. The method presented here of demonstrating that sulfate forms after formation of Cu2O is to roast a sample of Cu2S and then to locate and identify the phases formed.' A solid cube of cuprous sulfide, made by melting Fisher reagent grade Cu2S powder and measuring about 1.5 cm on edge, was placed on a Nichrome wire grid suspended over the top of an Alundum combustion boat. The assembly was placed in a tube furnace at 600°C and oxygen gas, flowing at 0.60 liters per min, was passed around the specimen for 24 hr. The furnace tube diameter was 1.5 in. The partially roasted sample was removed from the furnace and impregnated with resin No. BR 0014, obtained from the Palmer Products Co., and the impregnated sample was then mounted in Lucite. A cross section was obtained by grinding and the surface was prepared by the following steps: 1) grinding—60 grit, 3M disk, dry; 2) preliminary polishing —60 through 600 grit, 3M disk, dry; 3) polishing— 8 µ diamond putty, silk cloth; and 4) final polishing —1evigated magnesia in isopropyl alcohol, Selvyt cloth. The color micrograph of the polished surface is shown in Fig. 1. The layers present in the micrograph are given along the side. The comwositions of the various layers were established by Debye-Scherrer patterns. From this evidence the following sequence of reactions which occur in the roasting of Cu2S is inferred: 1) The oxidation of Cu2S occurs with oxygen which has been transported through the oxide-sulfate layer by either gaseous or solid state diffu- sion. The products of this reaction at the Cu2S surface are Cu2O and SO,. 2) The SO, diffuses out through the pores in the Cu2O and finally reaches a position in the Cu2O where the oxygen pressure and the SO, pressure have values such that the thermodynamic conditions for the formation of CuSO4 are fulfilled. Then, the mixture of SO2, SO3, and oxygen reacts with the Cu2O to form CuSO1. 3) The CuSO, decomposes by the evolution of SO,, or SO, and O2, to form the basic sulfate. This is reasonable, since the SO, gradient will decrease toward the oxygen gas phase from the CuSO4 layer. 4) For this same reason the basic sulfate will decompose to form CuO. The above sequence of events is based on the assumption that diffusion through the oxide and sulfate layers, rather than the reaction at the sulfide-oxide interface, is rate-determining. This assumption is supported by the observation that these oxide and sulfate layers combined are almost nonperme-able to the flow of gases through them. Acknowledgments This research was supported by the U. S. Air Force, through the Office of Scientific Research of the Air Research and Development Command. The authors wish to acknowledge the helpful suggestions of Ralph Wells of the Applied Research and Developmeit Laboratory, U. S. Steel Corp. References E. A. Peretti: A New Method for Studying the Mechanism of Roasting Reactions. Discussions Faraday Soc. (1948) 4, p. 174. - J. N. Ong, Jr., M. E. Wadsworth, and W. M. Fassell. Jr.: Kinetic Study of the Oxidation of Sphalerite. Trans. AIME (1956) '206, pp. 257-263; Journal OF Metals (February 1956).

Jan 1, 1957

By Rainer Kahrger

During the last decade, advances were made in solvent extraction/electrowinning (SX/EW) technologies. Combined with heap leaching, these technologies made it viable to exploit large, low-grade oxide copper deposits. The El Abra Mine is a good example for such a deposit. The deposit is situated in northern Chile at an elevation of about 4,000 m (14,000ft), 70 km (45 miles) north of Calama. Codelco sold 51% of the El Abra to Cyprus Minerals in June 1994, with Codelco retaining the balance. In 1993, Cyprus and the engineer on the project began discussions withinternational companies regarding the materials-handling system requiredfor the project. These early discussions were considered critical for this fast-track project.

Jan 1, 1996

Application of Gy?s formula is appropriate for calculation of the Fundamental Error (FE) prior to samples being collected at any stage of the minerals process, provided that sampling parameters K and a (alpha) have been determined by calibration of the ores. Two types of calibration procedure are well established in the industry, the Hetrogeneity test and the 32-piece sampling tree experiment. The sampling tree experiment uses the variance and average grade of metal analyses from four series of samples at different nominal fragment size, as the basic input data. Pierre Gy suggested the cube as an appropriate exponent of the nominal fragment size for use in his equation. More recent work suggests that this exponent is variable and characteristic of specific ores and therefore requires calibration. The method described here explains the experimental procedure of the calibration. It is then possible to calculate a sampling nomogram using the sampling parameters K and a. This allows the sampler to determine a suitable protocol for the sampling event that will ensure that the FE does not exceed a predetermined precision at any point in the sampling procedure.

Jan 1, 2007

By Q. Lui, J. Oxenford

The occurrence of heavy minerals in the oil sands of Alberta has long been known and has been well documented in the literature. Unfortunately most of the researchers working on this resource have been unable to produce products that meet acceptable market specifications. This has resulted in many misconceptions about this resource. Recent efforts have shown that with some innovative approaches, marketable material can be produced and as a result it might finally be possible to realize the potential of this immense resource that, some have estimated, could contain in excess of 20% of the world demand by 2010. This paper highlights the uniqueness of this mineral assemblage and the mineral processing challenges it presents. It shows the most recent work that has resulted in the production of marketable titanium and zircon products. This paper also focuses on some of the special problems resulting from the variability in the heavy mineral suite. Of special interest is the occurrence and removal of bitumen and pyrite without adding to the sulphur dioxide loading in the regional airshed. The trend by the mining industry to develop various positions on ‘sustainable mining’ has some significance for the heavy mineral industry. Although the industry generally has an excellent track record of eventually rehabilitating disturbed ground in an acceptable manner, heavy mineral mining operations tend to have a relatively large footprint of disturbance and the industry is under considerable pressure to develop options that are more environmentally acceptable. In addition, as operators move to exploit deposits that are lower grade and/or are further from a port site, the emissions per unit of sold product will also rise and the industry will be under pressure to address this issue as well. Because heavy minerals from oil sands are by-products of existing operations, there are virtually no incremental disturbances or emissions that would be associated with heavy mineral production. All mining and tailings remediation issues are accounted for by the oil sand operation. The only incremental emissions would be those associated with the mineral processing operations and transport of finished products to a port site. This paper discusses the environmental and cost implications of this situation.

Jan 1, 2003

By V. Svalbonas

The process of grinding mill quality assurance brings with it associated truths and myths. When the mill quality assurance process took its first great steps forward in the late 1970s and early 1980s, they were in response to the conditions existing, in our industry, at those times. In the late 1990s, we are faced with different conditions, and problems, and need fresh solutions. Yet the system developed for the early 1980s has produced no new approaches for the late 1990s, becoming instead more hardened and entrenched. This lack of development and actual resistance to research is now costing the industry significant amounts of money in late start-ups and useless scrap loss.

Jan 1, 1999

By John P. Borovsky

A 3-year study was conducted to evaluate the problems and benefits of using vegetation to stabilize tailing from a potential Minnesota copper-nickel milling operation. The project consisted of three separate investigations: a waste characterization study, a greenhouse study and a field study. With few exceptions, the physical and chemical characteristics of the tai ling were found to lie within the range of properties of Minnesota soils. The tailing lacks organic matter; is deficient in nitrogen, phosphorus and potassium; and may contain elevated levels of soluble salts and heavy metals, particularly copper and nickel. Numerous grasses, forbs and woody plants will tolerate the tailing as a rooting medium. Peat incorporation and topsoil dressing provided few benefits to the revegetation process which were not provided by a fertilizer application. With fertilization, grass/legume production in the tailing was comparable to local agricultural yields. Concentration of heavy metals in grasses grown in the tailing were generally below suggested tolerance limits for plants and animal forage. Legumes tended to accumulate higher concentrations of copper and nickel, and metal uptake of most plants was positively correlated with rate of fertilization. Tailing drainage water contained elevated levels of heavy metals, and establishment of vegetation had little effect on the quantity and quality of tailing drainage water. However, topsoil dressing significantly increased drainage water volume when compared to unvegetated control plots. Copper-nickel tailing revegetation recommendations were developed.

Jan 1, 1983

By Paul J. Axtell

Two new railroad bridges in Kansas City, Missouri are founded on drilled shafts embedded into the soil and underlying shale. The uncertainty arising from the non-homogeneous, anisotropic nature of most shales, and the variability of shales across the U.S., makes it a difficult material to assign appropriate design properties. As was the case on this project, the uncertainty of foundation performance in shale can lead to overly conservative designs, particularly with drilled shaft foundations. An extensive Statnamic axial testing program was performed to verify that the load-settlement behavior of the drilled shafts would be acceptable for the intended railroad traffic. Axial Statnamic testing was applied in three increasing cycles of 927 kips, 1007 kips, and 3177 kips, respectively. The maximum movements recorded at the shaft head during each of the loadings were 0.052 inches, 0.062 inches, and 0.257 inches, respectively. The loads applied in each of the respective Statnamic tests were not sufficient to reach the capacity of the shaft; so direct comparison of measured and calculated capacities is not possible. However, evaluation of the estimated design capacity can be accomplished based on results from the Statnamic testing program by utilizing normalized load transfer relations presented by O?Neill and Reese (1999). Such comparisons necessarily require extrapolation of the data measured in the Statnamic tests following typical load-displacement response. Results indicate the Kulhawy and Phoon (1993) method for estimating side resistance in Pleasanton shale rock sockets, assuming a smooth socket, appears to agree well with observed behavior during Statnamic testing. Accordingly, the O?Neill and Reese (1999) method for estimating the toe resistance in intermediate geomaterials, assuming cohesive rock with Rock Quality Designation (RQD) between 70 and 100, appears to agree well with observed behavior during Statnamic testing. Finally, based on Statnamic testing at varying load magnitudes and normalized curves developed by O?Neill and Reese (1999), the contribution of side resistance to the capacity of a deep foundation can be determined assuming no load is transferred to the base of the foundation during lower magnitude testing. Furthermore, higher magnitude testing can provide a means to evaluate the accuracy of design end bearing calculations.

Jan 1, 2006

Study on Treatment of Wastewater Containing Heavy Metal Ions Using Modified Oceanic Cobalt-Rich Crusts

Sep 13, 2010

By M. E. Rossi

All large-scale applications of conditional simulations intend to benefit from the ‘correct’ (or’ accurate’) characterization of uncertainty, adequately describing the variability observed from the data and its impact on the final objective. This paper discusses a number of relevant issues that highlight the extent to which, in reality, a model of uncertainty is dependent on the random function model chosen. Often in the presence of large number of conditioning data most available random function models will provide similar models of uncertainty. When conditioning is scarce, the resulting models of uncertainty will vary more widely, since the final output will depend mostly on the underlying assumptions of the model chosen. The application described in this paper is taken from a large porphyry Cu operation in northern Chile, and it demonstrates the impact of several variables on the resulting models of uncertainty. In particular, some of the decisions involved include the number of conditioning data and the underlying Random Function model used (Gaussian or indicator-based). Also, implementation-specific parameters must be decided upon, such as grid size used, random number generator, simple or ordinary kriging, multiple-grid simulation, and simulation of irregular three-dimensional bodies (as opposed to regular grids). Some practical guidelines are proposed to deal with these decisions.

Jan 1, 2003

By Pengfu Tan

A thermodynamic model of KIVCET lead smelting process has been developed. The model has the capability to predict the distribution behaviors of Pb, Zn, Fe, S, O, As, and heat balance in KIVCET direct lead smelting furnace. The compositions of lead bullion, matte, slag and gaseous phases, and heat balance are calculated. The effect of the ratio between oxygen and feed on the chemistry of the smelt and heat balance of the coke checker has been simulated and discussed. The thermodynamic model also helps to understand the tapping issue of the lead bullion. In this paper, some applications of this model in the industry have been presented.

Jan 1, 2006

By Paul C. Hyndman

No minerals have been produced from the McGraw Creek RARE II area. During the 1982 U.S. Bureau of Mines study, there were no active mines in the area. Limestone occurrences (fig. 1, no. 2), four copper prospects (fig. 1, no. 1, 4, 5, 6), and a prospect with no significant mineral values (fig. 1, no. 3) were examined. A moderate potential for high-calcium limestone resources was estimated between ocurrences within the study area near McGraw and Spring Creeks (fig. 1, no. 2). There is low potential for copper resources at the Argenta Prospect (fig. 1., no. 1) in the study area, and the McDougall Prospect adjacent to the area.

Jan 1, 1983

By Michael J. Jorgensen, Anoop Polsani, Khurram S. Khan

Riveting operations in aircraft manufacturing involves the use of power tools for manually drilling holes for the rivets, power drills for the setting of the holes for the rivets, as well as rivet guns to drive and set the rivets. To close the rivet, the rivet is driven against a metallic bar commonly called a “bucking bar”. The bucking bars are typically held firmly to increase the quality of the riveting, as well as keep the bucking bar from “dancing” against the metal piece being riveted. Thus, employees in aircraft manufacturing involved in riveting are exposed to hand-arm vibration from several sources, and epidemiological evidence suggests that vibration-related musculoskeletal disorders are associated with long term exposure to riveting tasks in the aircraft manufacturing of aircraft.1,2 Recently, tungsten technology has been introduced into aircraft manufacturing for bucking bars, which are heavier than traditional steel bucking bars of the same size. Rivet guns with tungsten pistons instead of steel pistons have also recently been introduced with the objective of reducing vibration exposure to the riveter. The objective of this study was to assess vibration characteristics of steel and tungsten bucking bars and rivet guns to identify the combination that simultaneously reduced the combined exposure to both the “riveter” and “bucker”. Methods Vibration (10g tri-axial accelerometer, Biometrics S2-10G-MF Series 2) was measured from eight experienced employees using seven different rivet guns on size 6 rivets, with the same person bucking for all subjects. Vibration was also measured on two different bucking bars for these same eight subjects, with the same person driving the rivets using the various rivet guns. The rivet guns consisted of three E4 steel piston guns with different RPMs (Guns A-E4, B-E4, C-E4), an E4 vibration dampened rivet gun (Gun D-E4D), an E3 steel piston rivet gun (Gun E-E3) and an E3 and E4 tungsten piston rivet guns (Guns F-E3T and G-E4T). The bucking bars were made of 90% tungsten (1694g) and cold-rolled steel (843g), and were the same shape and size. A two-way repeated measures analysis of variance was performed on the vibration (mean frequency weighted resultant acceleration) on both the rivet gun side and the bucking bar side, and mean rankings were used to assess the vibration simultaneously for the rivet gun and bucking bars to investigate which combinations provided the lowest vibration exposure. Results Frequency weighted resultant acceleration was significantly lower on the E3 tungsten (F-E3T) rivet gun than the E4 steel piston (B-E4) and the E4 tungsten piston (G-E4T) rivet guns (Figure 1). When measuring vibration on the bucking bar, the E4 (A-E4) steel piston rivet gun resulted in lower vibration on the bucking bars than the E4 tungsten piston (G-E4T) and E4 vibration dampened (D-E4D) rivet guns (Figure 2). Additionally, use of tungsten bucking bars resulted in a 35% decrease in resultant frequency weighted acceleration than when using steel bucking bars.

Jan 6, 2006

By Emmanuel N. Zevgolis

Energy required for roasting and smelting of a nickeliferous laterite ore by the rotary kiln - electric furnace process is investigated. From this work it comes that thermal energy is about 65% of the total energy needed and the rest is electrical. Also, 61.3% of thermal energy input in the roasting step (of all combustibles fed into the rotary kilns) is used for pre - heating, 11.6% for pre - reduction and the rest (27.1%) corresponds to the energy of the remaining carbon in the rotary kiln products (i.e., calcine, dust and coatings). Carbon entering the system is used as follows: 57.9% for combustion, 37.1% for reduction and the rest (5.0%) remains unburnt. Exploitation of energy from gases of both furnaces, as well as the higher possible reduction degree, the optimum temperature of the calcine and also elimination of the excess air in the rotary kilns, improve significantly energy balance and economics of the process.

Jan 1, 2006

I was lucky to land a job in the powder business. I was looking for some way to support my wife and first child to be when I saw an ad in the Hercules magazine, “Explosives Engineer” for technical representatives. I answered the ad in hopes that a geologist might find something else to do besides sit oil wells or “doodlebug” for oil. Both of these occupations I had tried and while the money was good the life was a bit erratic. The Army also wasn’t made for a guy who asked too many questions although my two plus years in uniform were interesting and in a few cases fun.

Jan 1, 2004

The Minerals Data Source Directory is a compilation of descriptive information on the availability, content, and location of minerals data in the Federal Government. It is intended to assist Government personnel and the general public in locating and acquiring minerals information. Included in the Directory are descriptions of data bases, publications, information systems, and information offices containing data pertaining to all aspects of mineral production, consumption, trade, and related information. These mineral data sources include the Federal agencies such as the Department of the Interior's Bureau of Mines and Geological Survey whose major mission is the collection and dissemination of mineral information. Also included are agencies such as the Departments of Agriculture, Commerce, Labor, State, and Treasury, and the Central Intelligence Agency, whose primary mission is the collection of data in non mineral subject areas, but in which the mineral industry is a component.

Jan 1, 1982

By R. Dekkers, J. Plessers

The feasibility of using hydrogen to obtain clean steels is investigated. High hydrogen contents are generally considered as detrimental due to the risk of flakes, bubbles and breakouts during casting. Hydrogen can nonetheless be removed by degassing of the steel. The results of industrial campaigns, where total oxygen content and hydrogen content were monitored, are presented. High resolution microscopy of inclusions and laboratory experiments on the rate of inclusion removal by CaO-Al2O3 slags at different partial hydrogen have been carried out. So far, evidence that hydrogen may influence inclusions or the steel cleanliness is not clear. Keywords: hydrogen, cleanliness, inclusions.

Jan 1, 2004

By Juan Carlos Salas

In this paper, a collaborative R&D model which has been successfully applied by a global mining companies association is presented and analysed both from the conceptual and practical point of view and an example of these collaborative initiatives, the Copper Technology Roadmap recently generated by a group of the most relevant copper mining companies, is presented, including an analysis of strategic opportunities and challenges in the Latin American region.

Sep 9, 2007

By Alan Jorgansen, Dave Hummer, Scott Scovira

Kennecott Energy's Colowyo Coal Mine is the largest open pit coal mine in Colorado and produces 5.5 MM tons per year. Colowyo uses the terrace mining method to recover up to seven seams of rolling coal ranging in thickness from 5 to 20 feet. Draglines are used to strip overburden ranging from 60 to 120 feet thick off two coal seams. These two seams are characterized by soft and fold fractured coal and in past practice cast blasting caused excessive coal damage. As a result, to ensure minimal coal damage and high coal recoveries, the overburden was excavated in two passes. The first pass removed the upper overburden to within 10 to 20 feet of the coal seam. The second pass removed the remaining overburden above the coal. Two-pass mining was effective in controlling coal damage, but also carried significant additional costs.

Jan 1, 2003