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By D. A. Rice

As part of its mission, the U.S. Bureau of Mines continues to develop technologies that will enable cost-effective compliance with environmental requirements. To this end, investigations to improve the kinetics of chalcopyrite dissolution by simultaneous grinding-leaching in ferric sulfate solution were conducted using the Bureau-designed turbo mill. The development of such a hydrometallurgical process would provide a nonpolluting alternative to conventional smelter technology. The effects of mill rotational speed and volume percent solids on the leaching time and energy required for copper extraction from chalcopyrite were evaluated. The results of this laboratory study have shown that the simultaneous grinding-leaching of chalcopyrite concentrate using the turbomill is technically feasible with essentially 100 pet extraction of copper being possible at 90° C. An optimal energy consumption of 1,153 kW?h/st of copper leached was found in batch testing with the mill operating at 400 rpm with a slurry containing 35 vol pet chalcopyrite. This energy consumption, while higher than other proposed leaching processes (about 600 kW?h/st), is of the same order of magnitude. Further refinement of the energy requirements would require additional testing using a continuous circuit. Leaching times of less than 1 h, for 80 pct copper extraction, are achievable using the turbomill grind-leach process.

Jan 1, 2010

By Shirley F. Colby

Much interest has been shown recently in the possible utilization of dolomite as a source of magnesium metal, a large production of which is deemed essential for national defense. As a result, many inquiries have been received by the Bureau of Mines as to sources of dolomite. This report has been prepared primarily to augment the Bureau's present published information on the occurrence of high-grade dolomite deposits in the United States. To supplement such data, the report also defines dolomite and related rocks and describes their properties and uses. The uses are covered in some detail in Information Circular 6524 entitled "Utilization of Dolomite and High-Magnesium Limestone," published in 1931 but now out of print. All essential data on uses contained in that report have been incorporated herein, and. have: been supplemented by data developed during subsequent years. DEFINITION Dolomite is a mineral composed of calcium end magnesium carbonates combined in equal molecular proportions, expressed by the formula CaMg(C03)2. Dolomitic limestones contain considerable dolomite but also include either

Jan 1, 1941

By Chu E. Ho, Paul Napoli

This paper presents the performance of nineteen open-ended steel pipe piles driven through highly variable overburden soils into glacial till and schist bedrock. The piles were 16 inches in diameter and 0.656 inches thick, with yield strength of 50 ksi. The piles were designed for a service capacity of 250 kips and were driven to achieve an ultimate geotechnical capacity of at least 500 kips. Due to the large variation in the ground conditions, installed pile lengths ranged from 25 to 66 feet. Some piles were driven to refusal on the bedrock while others were terminated at final driving resistance of 2 to 7 blows/in. Two piles were suspected to be plugged during driving while others did not. Each pile was instrumented with strain gages and accelerometers near the pile top, and observed using a Pile Driving Analyzer (PDA) to provide preliminary guidance on pile capacity achieved at end of initial drive (EOID). The influence of plugged and unplugged pile toe conditions on the interpretation of pile capacity was investigated using Case Pile Wave Analysis Program (CAPWAP). Characteristics of driving energy, compressive and tensile stresses developed in the steel pipe piles, and the resulting pile deformation behavior are discussed. INTRODUCTION The Hunters Point South redevelopment in Long Island City, Queens is one of New York City’s major efforts to transform former manufacturing zones into mixed developments for the middle-income community. The site is located along the eastern shoreline of the East River and Newtown Creek. The development included low to high-rise residential buildings, a public school and retail structures. Open spaces were created along the East River and Newtown Creek waterfronts in the form of a continuous park providing for recreational and community related activities. Waterfront structures included small park buildings, walkways and viewing platforms with the shoreline protected by revetments as part of the City’s flood mitigation strategy. The project was implemented in two phases, with completion of construction for Phase 1 in 2013 and Phase 2 in 2019. Based on available historical information, extensive reclamation took place between 1855 and 1898. After 1951, changes to the shoreline were made along the East River, including the removal of reclaimed land along the northern portion of the project site to allow for docking facilities. By 1977, these facilities had been demolished and backfilled to form the current shoreline configuration. The present site was temporarily used as a parking lot with stockpiles of fill mixed with construction demolition rubble, rip-rap and boulders of varying heights across the site. The existing ground surface varied significantly up to approximately 25 feet difference in elevation. The stockpiles were removed and the site was re-graded during final development of the project. This paper discusses the foundation design challenges due to the loose overburden soils and potential obstructions within the fill material, in particular, the issues relating to installation of open-ended steel pipe piles through the ground conditions encountered on site.

Jan 1, 2019

By M. J. Ferrante

Enthalpy and entropy increments above 298.15° K were determined for cop-per sulfate between 298° and 1,000° K and for copper oxysulfate between 2980 and 1,146° K by the method of copper-block drop calorimetry. Enthalpies, entropies, and heat capacities are tabulated for both compounds. In addition, free-energy functions are tabulated for the sulfate. Equations representing the enthalpies are given for each compound.

Jan 1, 1972

By Caelli T, Robey M

Most research into planning of open pit mines has been based on evaluation of volume-element block models in terms of their net present value. The major issues revolve around two interdependent problems the optimum ultimate pit and time-based scheduling. Despite feedback between the two problems, they are usually treated as separate tasks.The ultimate open pit is defined by the removal of whole blocks so that their net present value is maximised. This gives planners an estimate of the total worth of the venture in present terms, and is crucial to obtaining funding. All cost and profit values are assumed to be static throughout the mine life, and the only physical constraint usually taken into account is that of safe, average, wall slopes, which must be approximated by the removal of whole blocks. Modelling of any further constraints (for example, access roads and true wall slopes) is usually achieved by adding them to the optimal pit by hand. Typically this degrades the model by between five and 20 per cent of its value - which then brings into question whether it is still the true optimum.This paper reviews the dominant methods in use for this first task the ultimate open-pit planning problem. Some new optimisations are given, and the algorithms are examined in terms of their efficiency and accuracy. Finally, suggestions are made for improvement of model accuracy and eventual expansion into solutions of the more complete dual problem - that of simultaneously finding the optimum ultimate pits and dynamic schedules for the venture.

Jan 1, 1996

ABSTRACT' Mainland Papua New Guinea is formed of a microcontinental / island arc system (?Eocene - latest Oligocene Sepic arc) which in Middle to Late Miocene times was obducted over the northward- moving Australian plate. The sedimentary and volcanic units of this system form part of the Wogamush Group (Aure beds, Mena beds, Omaura Formation, Movi beds, Wogamush beds, Wogamush Formation. Nansananka Conglomerate and other correlates in- eluding cale-alkaline volcanics and carbonate beds). This Sepic event was followed in Pliocene-Present times by the obduction of the Finisterre-Adelbert-Oenake fore-arc or possibly oceanic plateau. Obduction of the Sepic arc produced crustal thickening

Jan 1, 1997

By Miguel Reyes, Chenming Zhou, MATTHEW GIRMAN

Electromagnetic energy emitted from electronic devices has been known to interfere with other electronic systems, hindering their ability to function properly. Mines have many electronic devices critical to the health and safety of mine workers that could be negatively affected by electromagnetic interference (EMI). To ensure that devices are electromagnetically compatible, tests must first be conducted to measure emissions and check for immunity. There are many standards available across multiple industries that prescribe emission limits and test methods for electronic devices. Due to the unique environment of an underground mine, it may not be enough to simply adopt a standard from another industry to mining. A literature review has been conducted, and an overview of EMI standards in other industries will be provided in this paper. Also, an example of how a standard can be applied to mining equipment is presented. Finally, recommendations on standards which could potentially be applied to mining will also be included. This work will inform the mining industry of EMI standards in other industries so that mine workers and technology manufacturers have guidance of the steps that can be taken to investigate and reduce the impact of electromagnetic interference and potentially work toward electromagnetic compatibility. The findings and research involved in this effort can also be used to explore the need to develop mining-specific EMI recommendations and standards.

Nov 25, 2021

By D. B. Taliaferro

[Recovery of core specimens from subsurface formations and their subsequent analysis are important aids in efficient development and operation of oil and gas fields. Core specimens first were obtained mainly for the geologic information they revealed; now they are analyzed to determine many of the physical characteristics and conditions of tae subsurface formations as well. Cores recovered from the producing formations may be analyzed for porosity, permeability, oil content, "connate" water content, and other physical and chemical properties of the formation, all to the end of furnishing enough data for making reliable estimates of the quantity and availability of oil and gas within a reservoir and in devising, efficient means for their withdrawal.]

Jan 1, 1939

By Zhiwei Wang, Chunsheng Qiao

"Aiming at the problems of the existing calculation methods for the support pressures of shallow tunnels in layered jointed rock strata, by using OAT (orthogonal array testing strategy) and DEM (distinct element method), 12 influencing factors including the thickness of the weathered overburden, and the states of the rock joints were considered. Then, the classification of the loosening zone was analysized. On this basis, by using the DEA (data envelopment analysis) theory, quantitative analysis on the influencing factors was conducted. By analyzing the influence of the key factors, a prediction formula of the boundary of the ringent trumpet-shaped loosening zone was established. According to principles of stress transformation, the formula of support pressures of the loosening zone which could considering the key factors were deduced. Finally, a practical case was introduced and studied to verify the proposed method.INTRODUCTIONIn recent years, various urban subway tunnels are increasingly carried out through jointed rock strata in many cities. Rock masses are discontinuous mediums with fissures, fractures, joints, bedding planes, and faults. The frequency of joints, their orientation with respect to the engineering structures, and the roughness of the joint have a significant importance from the stability point of view. However, there is a lack of understanding about the influence of the joints on the stability of tunnels. Therefore, how to measure the degree of the joints’ influence is a problem that needs to be solved.For the calculation of the support pressures, until now, many research results were focused on soil ground (Bierbäumer 1913; Terzaghi, 1943; Peck, 1969; Sabatini et al., 1999). In terms of site tests and model indoor tests, by measuring strut loads and calculating earth pressure based on strut spacing, the results proposed by Peck (1969) and Tschebotarioff (1973) have been widely used in practice for designing excavation support systems under sand (drained) and clay (undrained) soil conditions. Note that, it is unclear whether these findings could be extended to rock strata. For numerical simulations, how to simulate the states of the rock joints is a key problem that needs to be solved."

Jan 1, 2015

By R. Leiby

Prior to March 1992, the only component of the lead acid battery that was not recycled by East Penn Manufacturing Company was the sulfuric acid electrolyte. This acid was unusable in new batteries because the iron level was found to exceed new product specifications. The development of a liquid ion exchange process to remove the iron from the acid allows East Penn to currently recover over three million gallons of sulfuric acid annually. The process is based upon the use of an iron selective liquid ion exchange material or solvent to extract iron from the sulfuric acid electrolyte followed by regeneration of the solvent. Equilibrium and kinetic data for the extraction and regeneration steps were collected in order to scale up the process to commercial scale. An electrochemical process for the treatment of the acid used in the regeneration step was, also developed which significantly reduces the volume of strip acid required in the process.

Jan 1, 1995

By L. Martins Demuner, D. Burzic, V. Cunha Aranda, F. L. Lourenço, G. Romeu Trindade dos Santos, F. Ramstorfer

For many years, Dynamic Soft Reduction has been regarded as a proper method in improving internal quality of slabs. Even though processes models improved significantly over the past years, the efficiency of Soft Reduction was always limited by the discretization error, which inherently exists if segment rollers cannot be positioned individually. The recently developed SRD segment type allows for an individual roller positioning within the mushy zone by avoiding any discretization deviation from the optimal gap. This paper provides a detailed technological overview of the SRD segments as well as operational results at their very first implementation at Ternium Brazil.

Oct 1, 2019

By P. L. Swanson

Over a recent 20-month observation period, the U.S. Bureau of Mines obtained seismogram records from a single vertical-component, short-period seismometer installed at the surface of a metal mine in northern Idaho. The seismic events were analyzed for local (Richter) magnitude (M), time of occurrence, location, and relation to rock bursting and production blasting. Approximately 150 seismic events with -0.5 = M = 2.9 were located within the mine, yielding a b value (slope of the logarithm of the number of events with magnitude greater than M versus M) of 0.5. Event locations were constrained using a dense underground array of high-frequency accelerometers. Twenty of the surface-recorded events, with 0.5 = M = 2.9, were associated with rock bursts that produced damage requiring at least 1/2 day of cleanup and/or repair. Other possibly hazardous rock bursts, with magnitudes as small as -1.1, were numerous but were not associated with significant structural damage. Approximately 60 pct of the seismic events with M > -0.5 and 75 pct of damaging rock bursts occurred within 45 min of blasting. Estimates of characteristic rupture dimensions for rock bursts with -1.1 = M = 2.9, based on a conventional dislocation shear-slip model of failure, range from 3 to 300 m.

Jan 1, 2010

The Great lady gold deposit presented the challenge of providing a new grade control system for an usual type of orebody in the Eastern Goldfields. Mineralisation occurs as secondary enrichment about a quartz sand - granite saprolite contact 30m below surface. The ore horizon, which averaged 2.5m thickness, was near-horizontally disposed in contrast to the typical steeply dipping, shear hosted deposits of the region. A trial mining operation was undertaken on the richest, most continuous portion of the deposit to test the economic viability of this type of orebody. Controlling and minimising vertical ore dilution was considered crucial to the profitability of the operation.An understanding of the grade distribution combined with the practicalities of mining produced a grade control system which allowed for the mining of 1/2rn composited grades on level lm benches. Ore mining was combined with strict monitoring of levels, truck destinations and ore boundaries. Ore reconciliation results showed this system to be effective.

Jan 1, 1990

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966

By B. W. Jong

The Bureau of Mines studied reinforcement of sulfur concretes using glass, polyester, and aramid fibers. The objective of this research was to determine the feasibility of fiber-reinforcing the sulfur concrete to enhance the flexural properties. Optimum fiber sulfur concrete compositions were formulated with a cement-to-fiber ratio of 9.0:1 for glass-fiber and polyester-fiber sulfur concretes and 12.1:1 for aramid-fiber sulfur concretes. Test samples were prepared using techniques developed by the Bureau of Mines. Flexural strength values of up to 50 pct of compressive strength values were achieved with fiber additions. With non-fiber-reinforced sulfur concrete, the values ranged up to 20 pct. The impact strength and fracture toughness of sulfur concretes were increased sig-nificantly by reinforcement with glass or with aramid fiber and were adversely affected by use of polyester fiber. Strain tolerance was doubled and failure mode was shifted from catastrophic to noncatastrophic type by adding glass fiber. The glass-fiber and aramid-fiber sulfur concretes are resistant to acid corrosion and have proved durable in freeze-thaw cycles. This laboratory and field evaluation has shown that fiber reinforcement of sulfur concrete is feasible and that it enhances the flexural properties.

Jan 1, 1985

By Armine F. Banfield

The Purpose of the Paper It is fitting that the first paper of a session on the Financial Aspects of Mining should be on the basic data upon which any financial discussion of a mining project must be based. The history of a mining project starts with exploration in an area considered geologically favorable for mineralization and culminates in the discovery of a body of valuable mineral material commonly known as a mineral deposit. Subsequently more detailed exploration establishes the approximate size, shape, tonnage and average grade of the deposit by surface and/or underground drilling, -surface trenching and/or underground workings. Some preliminary metallurgical testing and other studies, as required, are made at this time. Development work is then carried out to provide representative samples for determining flowsheet and metallurgical balances, preparing the deposit for production and establishing more firmly the grade and mining characteristics of the deposit. A feasibility study is then made of the engineering aspects of the project including the estimation of operating coats, the capital required to place the deposit into production, profit and return on investment. A valuation of the deposit

Jan 1, 1972

By E. M. Tignor

A research program to aid development of improved methods for increased production of petroleum from partly depleted reservoirs is a vital part of the Bureau of Mines effort to effect true conservation of that mineral resource. This report presents results of an investigation to identify the clay minerals within some Appalachian petroleum-reservoir sands, the effect of clay content on the fluid-flow behavior of those sands, and the use of brines in water-flooding operations. Permeability measurements using kerosine, calcium chloride brine, simulated oilfield brine, potassium chloride brine, sodium chloride brine, and distilled water were made on reservoir-rock cores. Clay fractions were separated from sand grains of disaggregated portions of each core sample, and the clay minerals were identified by the differential thermal analysis method. Relations of the permeability to various fluids were developed.

Jan 1, 1957

By Alim Ullah

The paper discusses the necessity of upgrading low-iron containing ores, giving as an example, NML-Tata Steel Project in the Quebec-Labrador region of Canada. As cooling of pellets is generally a bottle-neck in most pelletizing plants, examples are given of the methods used to improve cooling in the existing plants and a simple, low-cost alternative, tested on a pot-grate system, is presented. The procedure described is applicable to sinter plants also. The trends in iron and steel production worldwide are then given, as well as the reasons for the increase in steel production by the Electric Arc Furnace (EAF) route. The stoichiometric and thermodynamic requirements for producing iron, irrespective of the process, are explained. The different ironmaking processes, especially the Direct Reduction (DR) ones are briefly discussed, outlining recent improvements made to some of them. The pros and cons of producing cooled DRI and Hot-Briquetted Iron (HBI) are given with predictions made for their future growth. An alternative to cold-briquetting of DRI fines is also discussed. Highlights of an ironmaking processes which is at the laboratory/pilot plant stage are given.

Aug 1, 2018

By R. D. Dey, V. Castranova, J. M. Antonini, J. A. Blackford Jr.

Alveolar macrophages (AM) exposed to cytokines or bacterial lipopolysaccharide (LPS) produce the free radical nitric oxide (NO·) by an inducible nitric oxide synthase (iNOS). They also release reactive oxygen free radicals following exposure to silica dust. The purpose of the present study was to determine whether NO· is produced by rat AM and/or recruited leukocytes following the intratracheal (IT) instillation of silica. Male Sprague-Dawley rats (175 to 225 g) were IT instilled with either silica dust (10 mg/100 g body wt) or LPS (0.25 mg/100 g body wt). After 24 h, bronchoalveolar lavage cells (BALC) and lavaged lung tissue were assayed for iNOS mRNA. Cell counts of BALC and iNOS-dependent (Nw-nitro-Larginine methyl ester [L-NAME]-inhibitable) chemiluminescence generated by AM were also determined. Northern blot analysis demonstrated that the steady-state levels of BALC iNOS mRNA were significantly increased by 3-fold following IT silica and by 7-fold following IT LPS. Partially enriched fractions of either AM or leukocytes from silica-treated rats both exhibited significantly elevated iNOS mRNA in Northern analysis. iNOS-dependent chemiluminescence was significantly increased in AM by 36-fold following IT silica and by 89-fold following IT LPS. Differential counts of BALC showed that AM numbers did not change in any of the treatments; however, red blood cells increased by 30-fold following IT silica and by 23-fold following IT LPS. Total leukocytes (polymorphonuclear leukocytes plus lymphocytes) increased by 58-fold following IT silica and by 274-fold following IT LPS. The results demonstrate that AM and neutrophils iNOS steady-state mRNA levels, AM iNOS-dependent chemiluminescence, and lavagable red blood cells and leukocytes all increased following IT silica. These findings suggest that NO· production in rat AM and neutrophils is increased in response to silica. NO· has the ability to then combine with superoxide and form a highly reactive toxic species, peroxynitrite, which may be responsible in part for silica-induced lung damage.

Dec 1, 1995

By Omid Marzoughi

Chromium has a wide range of applications, including as an alloy addition in various steels and also as a corrosion resistance coating. Carbothermal reduction of chromite ore (FeCr2O4) in a submerged arc furnace is an important industrial process for extracting chromium, but the energy consumption is excessive. It is suggested that one area for future research is the low temperature carbothermic solid state reduction of chromite to produce an intermediate product, which can subsequently be upgraded to ferrochromium. In this regard, a thermodynamic model has been developed to investigate this process and the effects of temperature, carbon additions and ore composition on the recovery of chromium and the grade of the ferrochromium, have been studied. Further development of the model may allow it to be applied to the simulation of other processes for the recovery of chromium from chromite ores.