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By John M. Devine

The severe corrosion of equipment that is caused by the presence of hydrogen sulphide in oil and gas has been described in detail by several authors. Such corrosion, termed "low-temperature hydrogen sulphide corrosion", presents a somewhat different problem from the "high-temperature hydrogen sulphide corrosion" that is encountered in refinery operation and which has been described by various-investigators of refinery corrosion.

Jan 1, 1932

By Antoine Allanore, Guillaume Lambotte, Bradley R. Nakanishi

Current industrial methods used for rare earth element (REE) extraction involve: 1) ore enrichment, 2) separation of rare earth oxides (REOs), 3) chlorination or hydrofluorination, and 4) individual electrowinning of REEs from a molten halide electrolyte. The complexity of REE extraction is inherited from their electronic configuration. Recently, molten oxide electrolysis (MOE) has been used to produce reactive metals directly from their oxides, e.g. titanium. As a single-step alternative to processes 3) and 4), or laboratory has investigated rare earth extraction by MOE. A key challenge is to find a molten electrolyte more stable than REOs. One possibility is to use binaries of REOs directly as a solvent. We have, therefore, developed two experimental approaches for studying molten REOs at temperatures exceeding 2200oC. The present work reports the most recent experimental results obtained with La2O3-Y2O3. Those promising results demonstrate potential for operating with molten REOs and refine the underlying materials challenge for electrodes to enable metal recovery.

Jan 1, 2015

By H. B. Zhou

The process of bioleaching marmatite using moderately thermophilic bacteria has been studied in this research by comparing marmatite leaching performance of mesophilic bacteria and moderately thermophilic bacteria and valuating the effect of venting capacity on marmatite leaching performance of moderately thermophilic bacteria and the effect of pulp densities on marmatite leaching performance of moderately thermophilic bacteria. The results show that moderately thermophilic bacteria have more advantages over mesophilic bacteria in bioleaching marmatite. Aeration agitation can improve the transfer of O2 and CO2 in solution and promote the growth of bacteria and therefore, enhance the leaching efficiency. With the increase of pulp density, the total leaching amount of valuable metals increased, however, the extraction efficiency decreased due to many rea-sons, like increasing shear force that results in poorly growth condition for bacteria, etc.

Jan 1, 2014

By Duk-Wom Park

INTRODUCTION he most important information required for the engineering design of structures in rock is its inherent rock properties. Without providing adequate parameters on the rock property, high quality of the engineering design cannot be expected. Many laboratory rock testing methods have been developed, but they are mostly for testing intact homogeneous rock without appreciable discontinuities. In reality, the intact rock properties do not represent the behavior of rock masses because rock masses include irregularities such as joints, cracks, interlayers, variations in mineral compositjon, etc. In general the type and intensity of the rock defects may be much more important than the type of rock which will be encountered (Terzaghi, 1977; Bieniawski, 1984). In-situ rock testing can provide better information on rock parameters, but it takes a tremendous amount of effort, time and cost. In recent years, numerical modeling techniques are gaining popularity as a design tool for structures in rock bodies due to the enormous progress in computer technology (Wang, 1985; Kripakov and Melvin, 1983; Park and Ash, 1985), but it is quite dangerous to use numerical techniques without having proper input data. Bieniawski (1984) states as follows: Some design methods such as numerical techniques have outpaced our ability to provide the input data necessary for the application of these methods. In order to provide an adequate amount of input data, an extensive testing program may be required, thus major efforts in time and expenses are commonly spent, In this paper, a new rock testing method, which utilizes the principles of laser holographic interferometry, is introduced. This method requires only a few minutes to measure the modulus of elasticity and quality of a rock core sample, which does not have to be cut or ground. The Poisson's ratio can also be measured in a few minutes from a sliced rock specimen. HOLOGRAPHIC INTERFEROMETRY Principles of Holographic Interferometry In 1948, Gabor invented holography, which is the technique of reviving three dimensional images using a monochromatic light source. A full demonstration was not made then because a clean monochromatic light source was not available. Later, in the early 19601s, the laser was adopted as a monochromatic and coherent light source (Leith and Upatnieks, 1963). Since then, applications have been made in many different fields ranging from crime prevention to three dimensional television. In this technique, an image is usually recorded by means of constructing a hologram which is a record of the interference pattern formed on a high resolution photographic system as shown in Figure I. A beam splitter divides the laser beam into two beams: (1) an object beam which is expanded while passing through a beam expander and illuminates the object, and (2) a reference beam which is expanded and illuminates the holographic plate. Subsequent to an exposure, the holographic plate is developed and illuminated by the expanded reference beam. The original scene of the object is revived in a three-dimensional image. The entire instrument should be placed on a vibration free environment. The wave fields reflected by the object in two slightly different configurations can be superimposed to form an interference fringe pattern. Thus, it is possible to measure the displacement that took place between the two configurations. This method is called holographic interferometrv. There are two methods of achieving this phenomena. The first is the double exposure method, wherein two exposures of the object are made prior to developing the film. The first exposure represents the original condition and the second, the disturbed condition. The second method is the real time holographic method. In

Jan 1, 1986

By Chu E. Ho, Alfredas Daugiala, Nicola Ebanks

"The construction of an ancillary structure for the new Second Avenue Subway Line in Manhattan, New York City involved a deep excavation in highly variable rock conditions adjacent to a fragile masonry building. The maximum difference between the lowest and highest rock elevations was about 30 feet, which posed a problem for the installation of secant piles that formed the supporting retaining wall for the excavation. At certain areas, the rock levels were higher than the top of the invert slab of the ancillary structure. To avoid disturbance to the adjacent fragile building, the secant piles were fully cased for drilling through the overburden soils and the rock sockets were formed using non-vibratory technique. This paper discusses the design and installation details of the secant pile wall and the contingency measures that were considered to mitigate the highly variable rock conditions. Monitoring of the adjacent fragile building showed that impact of pile installation were controlled within tolerable limits and safety of the building was not compromised.INTRODUCTIONThe 96th Street Station forms part of the newly constructed Second Avenue Subway Line on the East side of Manhattan Island, New York City (Figure 1). During construction of this station, several deep excavations were carried out adjacent to existing fragile buildings (Arksman et al. 2012, Grigson et al. 2016). These fragile buildings were typically four to five stories high, with a single rubble wall basement supported on timber piles or seated directly on the fill. The timber piles were often found to be in a poor condition and connections to the footings were compromised due to rotting of the timber within the zone of water table fluctuation. Several of these fragile buildings had to be strengthened and underpinned to improve the stability of the structures prior to commencement of excavation for the new subway station box (Trabold et al. 2012, Ho and Pena-Iguaran, 2013). The situation was most challenging at Ancillary Buildings 1 and 2 located at 93rd and 97th Street respectively, where secant pile walls were located merely 2 feet away from the adjacent property line, due to architectural space constraints. While mitigation of excavation induced ground movements can be controlled by the adoption of a stiff excavation support system, a more concerning factor was the uncertainty associated with the impact of the secant pile wall installation on the stability of the existing fragile buildings. This was particularly difficult at Ancillary 1 where the secant piles encountered highly variable rock levels that intruded into the excavation space. The following sections discuss the design and installation of the secant pile wall and contingency measures that were considered at Ancillary 1."

Jan 1, 2016

By J. A. Marts, R. C. Gilmore, Jr. Bogin, S. A. Saki, J. F. Brune, J. W. Grubb

"Colorado School of MinesResearchers at Colorado School of Mines (CSM) have developed computational fluid dynamic (CFD) models to study gas distributions and explosion and fire hazards in longwall gobs. In underground coal mines, methane continuously emitted from surrounding strata mixes with air from active mine workings and may form explosive gas zones (EGZs). Some western United States coal mines are also prone to spontaneous combustion (spon com). Insight into oxygen concentrations within the gob is crucial for assessing spon com hazards and mitigation strategies. Nitrogen injection used in conjunction with progressive gob sealing can reduce EGZs and spon com hazards by forming a dynamic seal that separates the methane in the gob from the air that ingresses from the face. This paper describes CFD modeling simulations studying the formation of such dynamic seals by optimizing the nitrogen injection locations. The impact of nitrogen on oxygen ingress and formation of EGZs is discussed. Optimum nitrogen injection quantities and injection locations were determined. Dynamic seal formation is most effective if the headgate nitrogen injection locations are split between the first crosscut inby the face and a second location about 300 m (1,000 ft) further inby. INTRODUCTION Underground longwall coal mine ventilation systems are designed to dilute hazardous gases and to provide breathable air to miners working in the area. Methane gas is liberated as the mining process extracts the coal and disturbs the surrounding strata. Methane mixes with the ventilation air and often produces explosive gas zones (EGZs) within longwall gobs (Brune 2013). Past CFD modeling research of underground coal mine ventilation systems has shown the effects of face air quantity on EGZs (Worrall 2012) and nitrogen injection to control spon com (Balusu et al. 2005; Ren et al. 2012; Ren et al. 2011; Smith and Yuan, 2008; Yuan and Smith, 2014). Other modeling approaches include network ventilation models of oxygen ingress (Dziurzynski and Wasilewski, 2012), and coupled Linear Network CFD algorithms (Wedding 2014). In a project sponsored by the National Institute for Occupational Safety and Health (NIOSH), CSM researchers are using Fluent®, a CFD software package by ANSYS, Inc., to model gas compositions and flows in underground longwall gobs. Figure 1 shows a progressively sealed gob with a U-type ventilation system in a three entry development. As the longwall advances, seals are constructed along the headgate in the crosscuts between the center entry and the gob. Additional gob isolation seals are built to block off the headgate entries inby the face. Nitrogen is injected through the seals in the first two crosscuts on the headgate side and at the first crosscut inby the face on the tailgate side, as shown in Figure 1."

Jan 1, 2015

By Anna Paula Littig Berger

O objetivo do presente trabalho foi estudar a influência da adição de argônio à atmosfera de redução a plasma sobre a redução de pós de hematita. Os experimentos de redução foram realizados em reator a plasma pulsado DC, sob pressão de 533 Pa, temperatura de 380ºC, tempo de 60 min, fluxo total de hidrogênio e de argônio de 400 cm3/min e variando os teores de argônio e hidrogênio. Os resultados mostram que os aglomerados de partículas após redução possuem um aspecto esponjoso. Verificou-se que o uso de uma mistura gasosa contendo 2% de Ar e 98% de H2 permite um aumento de aproximadamente 7,76% na fração de redução.

Aug 8, 2018

By Luiz Gustavo Franco Amaral

The recent tragedies that occurred in Brazilian territory had a greater impact than that presented in the major newspapers and led an entire industry to question the technology and techniques that were previously practiced in the mining industry. With this, there is the prospect of new projects and innovations in the most varied branches of engineering. This publication presents computational technologies to support the decision making of engineering projects aimed at the mining sector and explores the benefits obtained from the use of current technologies in the mining sector. Recent works are referenced in order to propagate not only the methodology employed in these researches, but also to provide the reader with an overview of the industry and companies that invest in technology to support their decision making in the most diverse projects gains on products and processes obtained through this practice.

Oct 3, 2019

By A. J. Rigby

The wear mechanisms of the tuyere lines of Peirce-Smith and Hoboken converters are a subject of endless debate and speculation. However, there has been an indication that one of the primary factors in the deterioration of tuyere lines is due to the batch operation of the converting process. The cooling of the brick in the tuyere line during out-of-stack times leads to shrinkage of the brick and resultant opening of the joints. Subsequently, on re-entry of the tuyere line into the bath, the joints become penetrated with matte and re- expansion of the brick is prevented. It is thought that this regular cycle of exiting the batch for slag skimming and replenishment of matte and re-entering for further blowing leads to a gradual “ratcheting” of the tuyere brick lining. If no expansion allowance is furnished between the endplate and the endwall of the lining, then the generation of damaging compressive stress is unavoidable. INTRODUCTION It is generally accepted industry-wide that the integrity of a refractory lined vessel is determined by an inextricable combination of refractory brick quality, the caliber of the lining design and installation, and the severity of the process inflicted upon the high wear areas of the vessel lining. Rigby has summarized the concentrated attempt, over the past several years, to optimize the microstructural, chemical, and fracture properties of the refractories used in non-ferrous pyrometallurgical vessels. Furthermore, lining design concepts involving larger and longer brick and the extent and positioning of expansion allowance in the joints have been extensively trialed. All these efforts have provided some, but not startling, improvements. The simple fact is that a vessel lining composed of bricks with an optimized microstructure and chemical inertness must installed with a well-conceived design to decompress the lining stresses that are generated by the batch operation of copper converters. REFRACTORY QUALITY Converting is conducted by injecting air into the molten matte and white metal for the very purpose of generating iron and copper oxide slags. These slags must be contained by a refractory which, by its mineralogical formulation, is optimized for chemical inertness.

Jan 1, 2019

By V. E. Christensen

AT most smelting plants, forced draft, induced by high stacks or fans, is used to carry the gases away from the furnaces, roasters, or sintering plants. Gases moving under forced draft carry varying amounts of solids in the form of dust and fume. Where the weight of the solids is material, and the metal content high, it is usually profitable to treat the gases to recover these solids. Baghouses, Cottrell treaters, and settling chambers are the common forms of plants used to recover solids from gases. To check on the efficiency of these plants it is necessary to know the volume of gas leaving the plant and the amount of solids carried by the gas. As the volume of gas is equal to the product of the velocity of that gas and the cross-sectional area of the flue, the determination of the volume includes the measurement of the area of the cross section and the determination of the velocity. The velocity is generally measured by means of the Pitot tube and Ellison differential pressure gage, although low velocities are best determined by means of an anemometer. The dust concentration is determined by passing a measured volume of sample through a filter and weighing the dust caught. From this the dust concentration per unit of volume may be calculated. It is necessary to assume that the gas is homogeneous or that each cubic foot of the gas contains the same weight of dust as every other cubic foot. Having the volume of gas passing through a flue per unit of time, and the dust concentration of the gas per unit of volume, the amount of solids may easily be calculated.

Jan 1, 1935

By T. Takamori

This paper reviews the present status of coal preparation in Japan concentrating on the process in coal cleaning and waste water treatment. This paper also discusses recent topics on maintenance, automatic control, raw coal management, etc.

Jan 1, 1982

By Neal Retzer, Adam Bedell, Nick Cioffredi

The first wagon trail across Loveland Pass was built in 1869 thus starting the struggle between the Colorado Rockies and interstate travel. The 1st Pioneer Bore underneath Loveland Pass at the Continental Divide in Colorado was attempted between 1941 and 1943 and was abandoned due to ground conditions at the Loveland Fault. Construction on the nearby Eisenhower Tunnel began in 1967 and was completed in 1973. Numerous challenges associated with tunneling, including at 11,000 ft were overcome. The purpose of this paper is to summarize the history of investigation and construction challenges associated with the Eisenhower Tunnel to celebrate its 50th anniversary.

Jun 13, 2023

By M. E. Tyrrell, C. W. Houck

Mixtures of zirconium diboride and refractory metals of group VI were resistance sintered to high - density compacts using modified electric welding equipment . To evaluate the use of chromium , molybdenum , or tungsten as binders for zirconium diboride the sintered compacts were examined in polished sections and tested for crushing strength , hardness , microhardness , oxidation rate , and resistance to mechanical shock . Chromium yielded the highest compressive strength , the greatest resistance to mechanical shock and oxidation , and a satisfactory Rockwell hardness . Molybdenum did not yield a satisfactory cermet . Tungsten yielded compacts having high microhardness but very low mechanical strength .

Jan 1, 1964

By A. A. Tytko, T. S. Golosinski

"The paper discusses the accuracy of magnetic inspections of corroded hoist ropes. It quantifies the error of measured LMA (loss of metallic area) caused by presence in the rope of ferromagnetic products of corrosion. The paper concludes that in mining practice this error is not significant. Hoist Rope Corrosion and its AssessmentCorrosion is one of the most common forms of wire rope wear. For ropes working in wet mine shafts, ropes used by the fishing industry and, in general, ropes working in humid and chemically active environments, corrosion wear is usually the prime reason for rope discard. In most mining applications, rope corrosion is accompanied by fatigue cracking of wires, abrasion of external wires, internal nicking and other forms of wear.Quantification of corrosion damage in ropes using standard inspection procedures and examination methods is very difficult. Qualitative comparisons are sometimes used to describe the degree of rope corrosion to compensate for the lack of quantitative measures (SABS 0293, 1996). If available, the results of magnetic examinations of ropes may be of help in assessing their corrosion weakening.Magnetic rope examination requires that the rope first be magnetized. After that, the rope magnetic flux and the leakage flux along the rope are measured. The first is assumed to be directly proportional to rope metallic area (LMA) and its changes are indicative of the rope’s loss of breaking strength (LBS). Existence of the second indicates existence of local faults (LF) in the inspected rope. As the corrosion of rope results in development of corrosion cracks and in loss of rope metallic area, both the LF and the LMA should be used to quantify the level of rope corrosion. More specifically, the changes to the amplitude of the LF signal are considered to provide qualitative information on rope corrosion (Hansel et al., 1990), while those of the LMA signal are believed to provide quantitative information (Geller and Rousseau, 1990; Golosinski, 1996)."

Jan 1, 1999

By R. Matusewicz, A. Kaye

Ausmelt Top Submerged Lancing (TSL) Technology has gained widespread commercial acceptance in non-ferrous applications, including the processing of lead and zinc primary concentrates and secondary (post-consumer) materials. TSL is highly flexible and efficient, and is one of the few technologies which can process primary and secondary feeds, and use varying fuels, to deliver high recoveries and excellent environmental performance. With the recent high value of both lead and zinc, and an escalating awareness of the sustainable use of resources, focus on the processing of secondary feed material sources has surged. Ausmelt Technology has proven to be well suited to the economic recovery of values, with twenty-two (22) Ausmelt furnaces processing lead and zinc bearing feed sources now in operation, under design or construction. This paper describes Ausmelt's progress in the fields of lead and zinc processing, and developments in new processing areas such as EAF dust processing and linking to innovative hydrometallurgical technology. Ausmelt has recently committed to the Whyalla Zinc project as the owner/operator of a facility for the treatment of zinc bearing secondary feeds. This project is due for start up in the first quarter of 2008.

Jan 1, 2008

By Arash Habibi, Anna Cable, David Loring, Aleksandar D. Bugarski, Logan Ingalls, Calvin Rutter

The results of diesel particulate matter (DPM) monitoring were used by the underground mining industry to mitigate adverse effects of exposure to DPM. NIOSH Method 5040, currently used for ambient and personal exposure monitoring, does not provide needed real-time information. The objective of this study is to develop a methodology for continuous monitoring of DPM concentrations in an underground environment, founded on the application of the Dekati electrical particle sensor (DePS). The DePS, which measures concentrations of submicron aerosol in real time using a diffusion-charging sensor, was evaluated by comparing the results of the concurrent measurements with reference methods at several locations downstream of the diesel-powered equipment. The DePS results were found to correlate well to those obtained by reference methods. However, it was found that dependence of the response on the physical and chemical properties of aerosols necessitates sitespecific correlation factors for the targeted matrices. The site-specific factors for number and mass of diesel aerosols were derived using the results of concurrent measurements with TSI NanoScan, FLIR Airtec, and carbon analyses performed on the concurrently collected filter samples. The results showed that methodology based on compensated DePS measurements would be suitable for continuous monitoring of DPM in underground mining operations.

Dec 1, 2022

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from the University of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

By A. Angelov, U. Peukerd, S. Gaydardzhieve, A. Stefanov, K. Grossman, V. Stoilov

Flotation concentrate originating from the Asarel-Medet porphyry copper mining and processing complex in Bulgaria has been subjected to regrinding using a Ro-Star mill; the effects of which on the downstream metallurgical behaviour are discussed. Particularly the effect on the liberation degree was studied through an optical microscopy and MLA-SEM automated mineralogy. On the other hand, copper selective flotation of the reground bulk concentrate was realised to evaluate the anticipated metallurgical improvement. Process parameters such as involvement of prior hydrocycloning and variation of collector dosage have been evaluated. Within a two-minute residence time inside the Ro-Star mill, an improved liberation degree of the copper bearing minerals has been observed. As a consequence, enhanced copper recovery and selectivity against pyrite was noted. It has been found that in order to guarantee efficient flotation of the resulting ultrafine particles, a modified flotation regime (i.e. changing collector suite and dosages) should be followed. Keywords: RoStar Mill, liberation, flotation recovery, ultrafine particles

Jan 1, 2020

By M. E. Charles

The use of water flowing as a lower layer to reduce pressure gradients in petroleum pipelines was investigated using 17.5 deg. A.P.I. Lloydminster crude oil in a 1-inch laboratory pipe-line and a 21h-inch field pipeline. The method was found to be very effective in reducing the pressure gradient below that for the oil flowing alone. The factor by which the pres-sure gradient was reduced varied with the percentage of water added, and in general exceeded 10 for water contents ranging from 40 to 60 per cent. Within this range of water content the pressure gradient reduction factor was independent of the oil flow rate.

Jan 1, 1960

By Charles J. Stehlik

This report deals with the changing behavior of mine roof bolt and roof rock as a result of repetitious production blasting . Observations were made in the upper shale production headings at the White Pine Copper Co. room and pillar mine , White Pine , Mich . Roof bolt compression pads and a stratascope were used in the investigations , which were carried out in three separate test sites in which nearly identical procedure produced comparative , repetitive , and anomalous observations . Results indicate roof bolt tension change and roof quality deterioration anomalies were coincident with blasting . The hypothesized cause of the anomalies is a seismic shock generated by the blasts .

Jan 1, 1964