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By W. Z. Yin

It is investigated systemically in this paper that the granularity of the precursor, ZnC2O4?2H2O, is influenced by synthetic conditions. Instantaneously adding of precipitation agent is able to control the mean size of precursor ZnC2O4?2H2O under 300nm, which has great function to obtain well-dispersed ZnO nanoparticles in the next step, pyrolysis. The pyrolysis kinetics model of ZnC2O4?2H2O powder is obtained. Two steps take place during the pyrolysis. The first is dehydration, which the pyrolysis kinetic model is 2(1-a)2/3(chemical reaction), A=8.3×108s-1, E=(75.82±3.00) KJ/mol. The second is formation of ZnO, which the pyrolysis kinetic model is (1-a) (random nucleation and latter growth), A=8.45×1028s-1, E=(360.54±12.00)KJ/mol. ZnO nanoparticles obtained by pyrolysis take on self-growth behavior. It is resulted that for precursor ZnC2O4?2H2O pyrolysis time takes obvious influence on the partilces size under 420?, 500? and 600?. Finally, a new flow sheet for synthesis of ZnO nanoparticles is investigated, in which blendes is used as raw material and hydrometallurgy is introduced into it. The whole flow sheet has no industrial wastes, that is all byproducts can be used in the flow sheet recycled, resulted in the de-crease of productive cost and industrial wastes.

Jan 1, 2014

By Doris M. Hyde

Limited geographically by size and geo-logically by origin, smaller countries and territories of the Caribbean are nonetheless engaging in efforts to encourage the initiation of mineral and mineral-related industries. Petroleum dominates the minerals sector, which otherwise consists principally of minor quantities of construction-oriented materials, usually for local consumption. The increased cost of petroleum has adversely affected most of the world, but these islands with their economies precariously balanced on the uncertainties of agriculture and tourism are especially vulnerable to petroleum's direct and indirect costs. In 1975, the Government of Antigua acquired the financially troubled West Indies Oil Company refinery at St. Johns. The refinery ceased operations in 1976. In 1979, negotiations were underway to sell Ashland Oil Co. an interest in the small, 20,000-barrel-per-day refinery for $6.6 million. In 1977, Antigua granted petroleum exploration rights to the Antigua Mineral Exploration Company, which planned to drill in an undefined offshore area, possibly between Antigua and Barbuda. The company expected to spend about $200,000 per year through 1982. There have been no reports on its activity.

Jan 1, 1981

By Walter Kawa

Bureau of Mines research on the hydrogenation of coal has been concerned with developing processes that could be used to supplement the Nation's petroleum and natural gas resources. Motor fuel was produced in a subsidized coal hydrogenation industry in Europe prior to 1945, but the process used is still not economical and other methods of producing liquid and gaseous fuels from coal are being investigated. As an aid to the planning of coal hydrogenation research, a literature survey was made of processes or methods of hydrogenating coal that differ from the subsidized or conventional process. This report contains a bibliography of unconventional methods of hydrogenating coal and a brief discussion of the economics of the conventional method. A general discussion of unconventional methods is included, and the advantages and disadvantages are pointed out where possible. The survey supplements a previous Bureau of Mines survey3 and a comprehensive review published in 1930.4

Jan 1, 1964

By R. J. Matetic, J. Noll, C. Zhou, J. DuCarme, M. Reyes, J. Srednicki

"In April 2016, the U.S. Mine Safety and Health Administration (MSHA) began requiring the use of continuous personal dust monitors to monitor and measure respirable mine dust exposures to underground coal miners. Mines are currently using the PDM3700 personal dust monitor to comply with this regulation. After the PDM3700’s implementation, mine operators discovered that it interfered with proximity detection systems, thus exposing miners to potential striking and pinning hazards from continuous mining machines. Besides the PDM3700, other electronic devices were also previously reported to interfere with proximity detection systems. MSHA sought the aid of the U.S. National Institute for Occupational Safety and Health (NIOSH) and mining industry stakeholders to determine how the PDM3700 and some other electronic devices and proximity detection systems interact with each other. Accordingly, NIOSH investigated existing standards, developed test protocols, designed experiments and conducted laboratory evaluations. Some interferences were observed to be caused by electromagnetic interference from some electronic devices, including the PDM3700. Results showed that there was no significant interference when the PDM3700, as well as other electronic devices, and the miner-wearable component of the proximity detection system were separated by distances of 15 cm (6 in.) or greater. In the present study, it was found that the PDM3700 and the personal alarm device needed to be at least 15 cm (6 in.) apart in order for them to be used simultaneously and reduce potential interference. IntroductionUnderground coal miners are exposed on a daily basis to a variety of hazards, such as coal dust exposures, high noise levels, roof and rib falls, potential for fires and explosions, and operating and working with heavy machinery. One of the hazardous jobs is that of operating or working near a continuous mining machine. According to U.S. Mine Safety and Health Administration (MSHA) statistics, 44 miners had been fatally struck or pinned by a continuous mining machine since 1984. In an effort to prevent future striking and pinning fatalities from occurring, proximity detection systems have been developed and are required on all operating continuous mining machines in underground coal mines, with the exception of full-face continuous mining machines, by 2018 (MSHA, 2015a)."

Jan 5, 2018

By W. Bendaikha, S. Larbi, A. Ramdane

An oolitic iron ore from Gara Djebilet, Algeria was characterized by X-ray diffraction, scanning electron microscopy, and energy dispersive spectrosopy and the phosphorus distribution between various phases studied. Two ore types were identified – a haematite-dominated, oolitic type and a more massive, magnetite-dominated type. The haematite-dominated ore had a higher phosphorus content, up to 0.6% in the iron oxide minerals, than the magnetite-dominated type (0.3% P). Owing to the very fine-grained texture of the gangue minerals, reducing the phosphorus content to levels suitable for steelmaking (below 0.05% P) by conventiobal means would entail an energyintensive process with a high carbon footprint. Preliminary leaching test work using a sulphurous geothermal water as lixiviant, assisted by solar thermal acceleration, gave very promising results, removing 0.13% of the residual P (or 21.7% removal of total P) from the high-phosphorus oolitic ore.

Mar 14, 2024

Lihir Gold Mine is situated in a dormant volcanic caldera on a small island off PNG. Not æextinctÆ but dormant. Current ground temperatures are up to 150 degrees Celsius with active geysers in the workings of the mine, pools of boiling ground water adjacent to low-grade dumps and hydrogen sulphide gas emissions. It is a unique mining environment by world standards. This paper will deal with the following issues encountered and managed by the operation:blasting in hot and reactive ground; management of sulphide gas emissions; disposal at sea of all mining waste rock; one dear to all Australian minerÆs hearts û dealing with landowner groups; and unusual human resource issues.

Jan 1, 1999

By The Staff

THE property of McKenzie Red Lake Gold Mines, Limited, consists of eleven claims located on McKenzie island in Red lake. The mine is about 4,Y:l miles by water from the Howey townsite on the same lake, and about 95 miles north of Kenora, Ont. (see Figure 4). Mail and express are flown-in daily, winter and summer, from Sioux Lookout, Hudson, Kenora, and Winnipeg. All heavy supplies are freighted-in during the summer over a water route, using four marine railway portages, from Hudson, Ont., a distance of about 180 miles. During the winter, freighting over the same route is clone by tractor if necessary, but costs are three to four rimes the summer rate. Due to these conditions, large inventories of supplies must be kept on hand, varying from a spring minimum of $45,000 to a peak of $110,000 early in November. The average cost of all freight brought in from steel during 1937 was $0.01 per pound.

Jan 1, 1938

By Charles D. Litton

This U.S. Bureau of Mines report describes the results of two large-scale tests conducted to evaluate a prototype nitric oxide (NO)-compensated carbon monoxide (CO) fire sensor, developed by Carnegie Mellon Research Institute (CMRI). In the tests, small coal fires were allowed to develop in the presence of diesel exhaust at relatively low ventilation airflows. These tests compared the response of the CMRI fire sensor with that of other fire sensors, including the Bureau's diesel-discriminating smoke detector. During the tests, CO, NO, and smoke levels were continuously monitored in order to determine the sensor alarm times and gas levels as the fire developed. The data indicated that the NO-compensated CO fire sensor was capable of suppressing the CO produced by a diesel engine and that the sensor responded reliably to the CO produced from the test fires. The tests also showed that the Bureau's diesel-discriminating smoke detector alarmed earlier than the prototype NO-compensated CO fire sensor.

Jan 1, 1993

By A. O. Drysdale

From a mining point of view the Portland Cement Industry falls logically into the Industrial Minerals Division. Portland Cement manufacture requires four principal materials, lime, silica, alumina and iron. The usual source of lime is limestone. Silica sources include clay, shale, quartz, sandstone and sand. Alumina is usually provided by selecting a silica source with a suitable alumina content such as clay and shale. "Cement Rock" is occasionally found in which all four ingredients are found in natural combination or sufficiently close that only minor adjustments are required. In the absence of iron oxides a white cement can be produced. All raw materials used in Canada contain some iron and in most plants further minor quantities of iron are added to promote fluxing, hence the typical grey colour of Portland cement. The modern period in cement manufacturing started in 1824 when Joseph Aspdin of England patented a process for the manufacture of a modified hydraulic cement which he called "Portland Cement". Hydraulic cements are cements that harden under water. Although natural cements, made by calcining and grinding natural argillaceous limestone were produced in Canada as early as the 1830's, Portland cement was not produced in Canada until 1890, about 18 years after it was first made in the United States.

Jan 1, 1964

By V Srinivasan, P Knights, C T. Farrelly

By 2025, with the widespread industry adoption of remote operation centres and advanced analytics, mining companies will find themselves making better, more informed decisions across the value chain. Process automation will drive significant business integration and reorganisation. Better collaboration between functions will make cross value chain optimisation a reality. Wherever possible decisions will be automated, based on analytical models and embedded in an enterprise decision management (EDM) architecture. This will take care of many of the minor day-to-day or the minute-to-minute decisions that consume operators and managers today. More flexible information technologies and architectures derived from the extensions to Web 2.0 and service oriented architecture (SOA) will solve many of the integration issues of today. The ongoing business imperatives for doing more with less people will make true collaboration with partners such as mining contractors, equipment vendors, transport providers, suppliers and maintenance contractors commonplace throughout the industry. All these organisations will be linked in and share common goals and objectives in real-time while providing visibility of internal constraints and available capability, allowing optimised decisions to be made across the extended enterprise. Humans will increasingly move to a more supervisory role and will use advanced collaboration to quickly solve complex abnormal issues that span the value chain out to the extended enterprise. The open collaboration and communication models instilled in the workforce through the widespread use of social networking technologies will drive thought leadership far beyond current æbest practiceÆ thinking. This will encourage the mining industry to extract the business value from rapidly converging fields of study such as environmental sciences, neuroscience, psychology, engineering, information technology and business finance. The future of mining will see a more uniform distribution of data savvy workers between the ages of 20 - 40, forcing a change in current operations. This group will drive the adoption of ubiquitous computing, augmented reality, presence and digital labelling. The enterprise will shift from a relatively static disparate set of functions to a digitally aware, integrated and interactive environment with information available, in context and just in time, to those who need it. The networked virtual enterprise will therefore be a reality.

Jan 1, 2008

Howard N. Eavenson, Gary, W. Va. (communication to the Secretary*):—For some time before the publication of Mr. Scholz's paper, I had been collecting data bearing upon its subject, and I now take pleasure in presenting to the Institute my results in the form of a discussion. It has long been a matter of common opinion among mining-men that mine-explosions are more frequent during the colder, or winter months, than during the warmer ones, and it is a matter of common knowledge among them that the air-ways and road-ways in most mines are much drier and are more inclined to be dusty during the winter than during the summer. In many mines, places which are wet and sloppy in the summer are dry and sometimes dusty during the winter. These changes, of course, can only be due to atmospheric conditions, and are caused by differences in temperature and humidity. Until recently, however, very little attention has been paid to the part that atmospheric conditions may play in mine-explosions, or, rather, to the effect they may have in rendering mine-conditions peculiarly dangerous, and in spreading and rendering more disastrous the effects of what otherwise probably would have been small explosions. To show the difference in mine-conditions during summer and winter months, I have tabulated in Table I. the results of 24 observations of hygrometric conditions in several different mines at different times of the year. Mines Nos. 1, 2, and 6 are located in the Pocahontas coal-region, in McDowell county,w.Va., the first one being a shaft-mine and the others drift. Mines 1A and 2A are drift-mines located in Logan county, W. Va. All of these are mines of fair size, but none of them has been in operation more than six years,

Jan 1, 1910

By A L. Randriamanjatosoa, G Small, C Greet

In flotation simulation models, the effects of pulp chemistry other than pH are often ignored and reduced to particles hydrophobicity or contact angle, neither of which can be measured readily in real time in an operating plant. The flotation response of a given sulphide mineral is known to be influenced and can be improved by changing the chemical characteristics of the pulp during grinding and flotation. The on-line measurement of pulp pH, potential, dissolved oxygen, temperature and oxygen demand of a process stream was completed with the PCM® (Pulp Chemistry Monitor) developed by Magotteaux in this study. The data generated together with relevant plant operating parameters were used to construct an empirical model and simulate the metallurgical performance of the ore. The same approach was also applied to laboratory flotation tests data using various grinding media types. The flotation models better fit the actual data when the chemistry of the pulp is taken into account.CITATION:Randriamanjatosoa, A L, Greet, C and Small, G, 2018. Effects of pulp chemistry on plant and laboratory flotation modelling, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 423–432 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By J. W. Butwell

Anaconda has been active In the Bingham mining district near Tooele, Utah since 1914 when the company acquired International Smelting & Refining Co. Over the years both custom ores and complex Pb-Zn-Cu ores from the district were milled and smelted at International. In 1948 Anaconda acquired the property that covers the present Carr Fork ore body. Since that time active exploration took place in the 50's followed by detailed geological evaluation in the 60's. Convinced that high grade Cu deposits would be found at depth, a deep drilling program commenced in the late 60?s, with intersection of the ore zone in 1969. Following extensive deep drilling in the early 70?s, a feasibility study was conducted in 73-74 with board approval given Sept. 6, 1974. The 9,000 t/d mine-mill complex was budgeted at $217 MM over a 5 year schedule with start-up in Sept., 1979. The following discussion includes the concentrator and surface facility portion of the budget or approximately $60 MM of the scope. Special emphasis will be made on equipment selection and layout.

Jan 1, 1980

By Andrea Pedroza da Rocha Santos

Neste trabalho, amostras de aço Lean Duplex UNS S32304 foram submetidas à temperatura de 800°C em um forno acoplado a um difratômetro de raios-x durante intervalos de tempo de 30, 60 e 90 minutos. Com o objetivo de analisar em tempo real a transformação das fases constituintes, foram realizadas várias varreduras insitu durante os diferentes tempos de permanência em 800°C deste material. Assim, observou-se a formação da fase sigma neste aço, tanto nos contornos de grão da ferrita como nas interfaces ferrita/austenita. Os valores de fase sigma obtidos para cada tempo de exposição foram calculados através do método de Rietveld sobre cada difratograma obtido e variaram de 11% a 17%. Notou-se que a fase sigma exibiu crescimento contínuo até 60 minutos e variação após este período. Todavia, observou-se que a formação de fase sigma a 800°C ocorre de forma significativa neste material após 30 minutos de aquecimento, o que pode comprometer as propriedades do mesmo.

Aug 16, 2017

By S Girard, L Rowland, V Lawson, Y Shields

Since 1948, ValeÆs Matte Separation Plant has been successfully using magnetic separation and froth flotation to separate the copper sulfide, nickel sulfide and Ni-Cu metallic alloy contained in Bessemer matte for downstream processing. Though some equipment upgrades have been performed over the years, the flow sheet has generally remained unchanged since the early 1970s. The need to improve metallurgical performance led to the trial of a scalping flotation column to produce a final copper concentrate ahead of the cleaner circuit feed to take advantage of a high degree of copper mineral liberation, reduce cleaner-recleaner circulating loads and decrease the associated loss of selectivity. Plant results indicated that 50 per cent of copper contained in the rougher concentrate could be recovered at final grade target. Results indicate that up to a 1.5 per cent increase in copper recovery to copper concentrate was achieved during the scalper trial due to a reduction in the generation of fine chalcocite which has historically been observed to report to flotation tailings due to surface contamination. Deficiencies are currently being addressed and a long-term trial is scheduled to confirm the benefits of copper scalping.CITATION:Girard, S, Rowland, L, Shields, Y and Lawson, V, 2012. Copper scalping at ValeÆs matte separation plant, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 299-308 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

The reliability of mining systems is generally low due to their harsh working conditions. Currently, efforts for improving mining system reliability are often made in isolation. This practice could substantially limit the effectiveness of the efforts on overall reliability improvement of the mining system. To enhance the overall reliability of mining systems, an integrated improvement approach is necessary. In this paper, we developed a framework for integrated mining system reliability improvement to address this issue. In this framework, there are five major components including data integration, business process integration, hardware integration, software integration, and analysis/decision integration, but we only focus on the integrated reliability analysis which is important to the analysis/decision integration. The reliability analysis considers the interactions between machines, and the impacts of design, operation, maintenance, automation and working environment on the overall system reliability. These multiple interactions present a big challenge to accurate reliability prediction. In this paper, we for the first time systematically investigated integrated reliability analysis approaches for dealing with this challenge using novel models and methods, including covariate hazard models, intelligent reliability prediction approach, and complex system modeling methods. While these models and methods have found some successful applications in other industries, they in general have not been effectively used for the reliability analysis of mining systems. Our study results show that the system integration approach is applicable to mining systems and can be used for developing a computer aided integration system for the implementation of the integrated reliability improvement approach.

Aug 1, 2013

By Duncan Chalmers, Rob Nowell, Miguel Araos

Australian underground mines produce in excess of 60 mtpa of coal. Most of these use the longwall method, and they require the use permitted explosives (which are called “permissible” in other countries) for challenges that appear during the day-to-day activities. To obtain the approval for these explosives, they should pass Testing Memorandum #2 (TM-2), which sets out the test required for each category of permitted explosive. These categories are P1, P3, and P5. With P5 being unrestricted use and P3 and P1 have conditional use in underground mines. The TM-2 test was originally set up for NG-based permitted products around 1900. With the closing of NG plants around the world, ammonium nitrate explosives were the natural replacement, and therefore these explosives need to pass the TM2. Australia does have a P1-emulsion based explosive available. For high-risk scenarios (like blasting coal), no P5 explosives are available. The lack of P5 explosives has been prolonged for more than 25 years, since the phasing out of nitroglycerine-based permitted explosive products around the world. The main problem has been that when emulsion based permitted products are tested in the deflagration cannon, the results obtained were not considered in the TM2 criteria and therefore the tests were invalid. A research work on permitted explosives began in 2005 funded by the Australian Coal Association Research Program (ACARP). The aim of the project was to address the lack of P5-type permitted explosive (and, potentially develop them further, i.e., develop safer explosives) and understand the behaviour of emulsion explosive and the results they presented in the tests. Both bureaucratic and technical barriers appeared along the way. On the bureaucracy side, the facility was shut down, reopened, and shut down again. In view of these difficulties, assistance was sought overseas. On the technical side, from the very start the results of the tests when using emulsion-based permitted explosives were not established in the criteria, ignitions occurred for trial samples that were expected to be P5-type, etc. The aim of this document is to present the painful journey in the Australian industry to have a P5-type emulsion-based permitted explosive, for use in UG coal. Also, the technical learning acquired about emulsion explosives and the ignition path of mixtures methane / air will be shown.

Jan 21, 2025

By G. Mei

"This study explores froth flotation and selective flocculation methods to recycle waste phosphors containing several rare earth elements, namely, yttrium (Y), europium (Eu), cerium (Ce) and terbium (Tb). The effects of the presence or absence of collector and of flocculant and their dosages, as well as the pH, were investigated. Reverse flotation resulted in concentrates with grade of 27.03 percent and recovery rate of 71.36 percent, while flocculation resulted in concentrates with grade of 31.43 percent and recovery rate of 91.28 percent. The flotation and flocculation behaviors were further analyzed by X-ray diffraction analysis, zeta potential measurements, particle size distribution and other methods. The successful separation of rare earth minerals by flotation was attributed to the selective adsorption of the collector onto quartz, making it particularly recoverable by reverse flotation so as to be separated from the valuable materials. The analysis of the particle aggregation process indicated that its better flocculation performance was due to the selective adsorption of flocculants onto the unwanted materials, enlarging the flocculant sizes by forming aggregations and facilitating the separation of rare earth minerals from waste materials based on different settling rates. IntroductionBecause waste phosphors pose the problems of heavy environmental burden and high risk to human health (Hu and Cheng, 2012) as a result of containing heavy metals such as mercury and manganese (He et al., 2006; Lucas and Emery, 2006), they have received added attention as urban mining resources for extracting rare earth elements (REEs) like yttrium (Y), europium (Eu), cerium (Ce) and terbium (Tb).At present, chemical processes such as acid leaching, alkali fusion, roasting and extraction are the primary methods for recovering REEs from waste phosphors (De Michelis et al., 2011; Li et al., 2012; Li, 2010). With these strategies, phosphors can be effectively decomposed and their REEs extracted. After the removal of impurities, the REEs can be efficiently precipitated by adding an H2C2O4 solution (Porob et al., 2012). Although relatively high recovery rates are achieved, those processes entail high energy consumption and can cause severe environmental pollution."

Jan 1, 2017

By Verônica Scarpini Candido

O alto consumo de energia e a elevada emissão de dióxido de carbono são os maiores problemas da indústria de cimento Portland relacionados à poluição do meio ambiente. Com o objetivo de reduzir estes problemas, os cimentos geopoliméricos despontam como uma nova classe de materiais de alto desempenho e não agressivos ao meio ambiente utilizados como aglomerante mineral capaz de substituir total ou parcialmente o cimento Portland. Estes cimentos são considerados quasi-frágeis devido ao seu comportamento elástico não-linear, provocado pela relaxação e redistribuição de tensões antes da ruptura. Todos os resultados obtidos no programa experimental para o concreto de cimento geopolimérico (CCG) foram comparados com aqueles obtidos para o concreto de cimento Portland (CCP), sob as mesmas condições de ensaio. Neste trabalho, são apresentados resultados de difração de raios-X (DRX), microscopia eletrônica de varredura (MEV) e análise térmica (DSC/TGA), a fim de reunir informações para um melhor entendimento da microestrutura do concreto geopolimérico.

Oct 30, 2017

By Mary Ellen Bruce Large

"INTRODUCTIONIn partnership with California Department of Transportation (Caltrans), Federal Highway Administration (FHWA), and with support from International Association of Foundation Drilling (ADSC), Deep Foundations Institute (DFI) organized a workshop on quality assurance (QA) practices for acceptance of post-grouted drilled shafts in conjunction with DFI’s 40th Annual Conference on Deep Foundations. The 1½-day workshop was held on October 15-16, 2015 at the Oakland Marriott City Center in Oakland, CA.Post-grouting, in the context of this workshop and report, refers to the alternative design and construction of base-grouted drilled shafts wherein a grout distribution system is installed during construction and used to grout the base under pressure after the drilled shaft concrete has gained adequate strength, resulting in a stiffer axial-compression load-displacement relationship and additional possible ground improvement effects. The primary goals of the workshop were to•?Identify and summarize the state of the practice for design, construction, inspection, verification, acceptance criteria, reliability and performance of post-grouting.•?Identify gaps and needs in quality assurance that should be addressed for successful use of post-grouting.This report is structured to follow the workshop program: workshop presentations outlined the state of practice and views from owners, engineers and contractors on acceptance of post grouting methods for drilled shafts; and subsequent workshop discussions attended by a small invited group of participants focused on identifying areas of agreement and disagreement on post-grouting best practices, acceptance criteria, design and verification procedures, and inspection requirements. A partial list of attendees of the open and closed sessions is provided as Appendix A, and copies of presentations are included as Appendix B.FHWA and Caltrans are the primary audiences for this report, and its content will be used to develop a roadmap for deploying the findings into policy and practice. The secondary audience is the broader industry group, and the report content will be disseminated in a variety of formats."

Jan 1, 2016