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By Peter Forschner

Classical Mixing Theory is based on applying many fundamental correlations to standard baffled dished bottomed vertical cylindrical vessels with high degrees of symmetry. Horizontal autoclaves operating at elevated temperatures and pressures have been used for more than two decades. All compartments and especially the first and last compartments are asymmetrical. To date no comparison of the effects of the asymmetric geometry on mixing system design and scale-up has been published. The results of investigating solids suspension, mixing time, momentum transfer from the impeller to feed slurry and feed inlet location in the first autoclave compartment are presented as influences on residence time distribution. CFD modeling was developed and verified with the test apparatus.

Jan 1, 2003

By J. E. Dutrizac

Fracture-exposed surfaces of sphalerite samples having five different solid solution iron contents ranging from 0.0 wt% to 14.8 wt% Fe were leached for 15 to 120 s at 100°C in 0.3 M Fe(S04)1.5 -0.3 M H2S04 media. The reacted samples were examined using X-ray photoelectron spectroscopy (XPS) which provides chemical state information on the first few nanometers of the solid surface. Surface compositions show that the leaching rate increases with increasing solid solution iron content of the sphalerite. Detailed evaluation of high resolution S2p spectra show that the leaching progresses via the formation of polysulphide species. Disulphide species were not detected in any of the experiments. Examination of the Zn2p and Fe2p spectra indicate little change in the chemical states of these elements over the duration of the experiments. Longer leaching times resulted in the generation of elemental sulphur. The ratios of elemental sulphur to dissolved ferrous ions and zinc suggest that less than 5% of the sulphide is oxidized to sulphate. Morphological studies showed that the elemental sulphur commonly formed at a few isolated sites, such as the grain boundaries. Furthermore, euhedral sulphur crystals were often identified. These observations suggest that at least part of the elemental sulphur forms via dissolved sulphide species which are oxidized in solution by ferric sulphate.

Jan 1, 2003

By J Lane, D J. Barker, B Pei

Queensland Alumina Limited (QAL) is the worldÆs largest producer of smelter grade alumina, located in Gladstone, Queensland, Australia. The plant employs evaporative cooling towers for waste heat rejection. Process water requirements include red mud residue disposal, steam venting to the atmosphere and Calcination feed moisture. Raw (untreated) water consumption in 2001 was 37 700 m3/d or 3.8 m3 per tonne of production. The Gladstone region experienced a water shortage in the period 2001 to 2003, resulting in progressive water restrictions. Industry operated under a ten per cent restriction from April 2002 and in November 2002 a 25 per cent restriction came in force. The maximum restriction level of 50 per cent was anticipated for the middle of 2003. Water restrictions of these magnitudes have the potential to result in significant production limitations, which would have major economic consequences for QALÆs owners, customers, suppliers and employees. Therefore it was imperative that measures be found to mitigate the impact of these restrictions. Furthermore, as one of the largest water users in the Gladstone region, QAL had an obligation to the community to minimise water usage as much as possible. A thorough analysis of water usage on site was conducted, focussing on all water streams leaving the plant. The philosophy used was that by minimising water outputs, the inputs would follow suit. Where possible, preference was given to solutions that provided lasting water savings. This occurs when the value of the water saving justifies the project cost, irrespective of water restrictions. By June 2002 an average water saving of 19 per cent was achieved, almost double the required saving. By end November 2002 further projects had increased the total water saving to 29 per cent, mainly through the re-use of GladstoneÆs municipal treated effluent as wash water. Further measures to reach the target of 50 per cent reduction were investigated. The evaporative cooling system was to be replaced with seawater cooling, using cooling towers to minimise the seawater pumping cost. Another benefit of this concept was the ability to dispose of the cooling tower bleed stream with the existing system for neutralised red mud disposal. This would avoid the need for an additional environmental outfall from the plant. In February 2003 the Gladstone region received over 500 mm of rain, which boosted water reserves to five years supply at forecast usage rates. This led to the lifting of all water restriction. As most of the implemented water savings measures are economically viable in the absence of water restrictions, raw water usage at QAL is still less than 75 per cent of pre-2002 levels.

Jan 1, 2003

By C. Schwandt

Recent research work has led to the development of a new electrochemical hydrogen sensor, which is based on a proton conducting solid electrolyte in conjunction with a self-contained solid hydrogen reference standard and is operated at elevated temperatures. The incorporation of the internal hydrogen reference renders the sensor versatile and user-friendly and makes it attractive for practical exploitation. The present article focuses on the utilisation of the sensor as the integral part of a probe for the quantitative determination of hydrogen in molten aluminium and aluminium alloys. The main features of the sensor and the probe as well as the measuring technique are discussed. Experimental results obtained with the novel analyser in trials under industrial conditions are presented and highlight the good performance of the device.

Jan 1, 2003

By K. H. McDaniel, D. M. Loring

The underground ventilation system at the Waste Isolation Pilot Plant (WIPP) provides for the unparalleled ability to ensure the safety of the workers, the public and the environment. Although small spatially, the system can vary the airflow from 31.2 to 217.1 m3/s (66,000 to 460,000 cfm). The system can automatically incorporate HEPA filtration in the event of radioactive contamination. Remote-capable regulators individually control the four main splits, and they can be adjusted from the surface if necessary. A ventilation remote-monitoring and control system provides real-time information. Future areas of concern include DPM compliance, system psychrometry, logic-based real-time mine-ventilation simulation and automation using PLC technology. This paper discusses the evolution of this system.

Jan 1, 2003

By M. Sagisaka

The purpose of this study is to obtain carbon dioxide emissions by copper production systems and quantitative merit to use copper scraps in Japan. Electrolytic copper and sulphuric acid originating from the refining gas are produced in the system. In this study, the inventories such as the fuel consumption of the unit processes and the in-house electricity generation were obtained from published papers and public statistical data. The following observations were made based on the Life Cycle Assessment (LCA) method: (1) Carbon dioxide emissions from the production of electrolytic copper and sulphuric acid in the system are about 1.0 kg and 0.4 kg/kg-product respectively. The carbon dioxide emissions attributable to the transportation of copper concentrate correspond to 20% of the total emission. This emission is higher than that of zinc because the metal content in the concentrate is lower than zinc. (2) The carbon dioxide emissions from the system decrease with the recycling of copper scrap to the converting process because the consumption of copper concentrate is reduced. The reduction is estimated to be 0.18 kg-CO2/kg-Cu at the point of 0.1 kg-scrap/kg-blister Cu. This corresponds to 9% reduction for the present system. However, this recycling leads to the decrease of sulphuric acid by 450x103 tonne at the point. The recycling of scrap should be evaluated not only from the reduction of carbon dioxide emissions, but also in terms of sulphuric acid demands as well as advantage of waste management.

Jan 1, 2003

By L. Burdukova

"In flotation, depressants are used to reduce the amount of gangue that reports to the concentrate and hence increase the selectivity of the flotation process. At the University of Cape Town extensive batch flotation tests are carried out to evaluate industrial depressants and standard procedures have been developed over the years.This study was conducted in order to develop an improved method for comparing depressants using machine vision as an aid. The modified method of batch flotation involved a test with prolonged intervals between scraping to allow more time for the froth to build up and mature.This method of testing showed increased differences between the flotation performance obtained as represented by grade recovery curves for carboxymethyl cellulose and guar depressants when compared to the standard method of testing with shorter scraping intervals. The improvement was attributed to reduced entrainment resulting from longer drainage time in the froth and therefore yielded a better test for comparing depressants on the basis of true gangue flotation with minimized entrainment. As expected, the sulphide recoveries were unaffected by the change in method. The machine vision system also added to the information obtained during these tests by recording bubble size trends throughout the tests which were later analyzed and related to the amount of flotable gangue in the froth. Modifications are recommended to improve the usefulness of machine vision in batch flotation."

Jan 1, 2003

By Jochen Petersen, David G. Dixon

"Although heap leaching may be perceived as a somewhat low-tech route for the extraction of low-grade minerals, the underlying physical, chemical and biological processes are in fact extremely complex. There has been increased interest in heap leaching of sulphide minerals in recent years with the advent of controlled bio-heap leaching, and the need to mine more marginal ore deposits.A detailed investigation into the dynamics of heap leach processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool. Some of the features include mineral kinetics, particle level effects, bacterial growth, oxidation and adsorption, gas adsorption, pore diffusion, bulk advection, gas balance and heat conservation.Two case studies are presented which illustrate specific features of the model for different applications and how these have helped to identify key areas of concern. In each case the model has proved as an invaluable tool either for the improvement of existing heap leach practice or for the development and assessment of novel applications."

Jan 1, 2003

By George M. Filz

Restrained basement walls and unrestrained but massive concrete walls on rock foundations experience very small movements in response to lateral earth pressures. Such walls are often designed using at-rest earth pressures without consideration of either compaction-induced lateral pressures or vertical shear forces resulting from compression of the backfill in response to self-weight. Compaction-induced lateral earth pressures can be detrimental to the integrity and stability of retaining walls. For example, the lock walls at Eisenhower and Snell Locks on the Saint Lawrence Seaway near Massena, New York, were damaged by compaction-induced lateral earth pressures, and an extensive rehabilitation program was necessary to ensure safety of the locks. Vertical shear forces, on the other hand, can be beneficial to stability because the downwards-directed vertical force tends to counteract the overturning moment from lateral earth pressures. The contribution of vertical shear forces is not included in most modern analyses of non-moving walls, but Terzaghi used this effect in his design of a high concrete retaining wall at Fifteen Mile Falls Dam. The lock walls at Eibach Lock on the Main-Donau Canal in Germany were instrumented for both lateral and vertical stresses applied by the backfill to the wall, and the resulting measurements show that vertical shear forces from the backfill were significant and persistent over the multi-year period that the wall was monitored. Other data from pilot-scale retaining walls confirm the existence of both compaction-induced lateral earth pressures and vertical shear forces. These forces should be considered in design of non-moving walls.

Jan 1, 2003

By Genrich A. Denisov

Principles of ecologically friendly geo-technologies construction are formulated on the basis of the works of the leading scientists in the field of rational processing of mineral resources of the Russian Academy of Sciences. One of these concepts is a new direction in rotational disintegration of mineral and technogenic raw material with the purpose of effective subsequent enrichment. A large amount of practical experience has been accumulated in the industry on selective destruction by application of vibrational method on initial material with consideration of its physical-mechanical properties and mineral structure. This method is successfully realised in a conic inertial pulverisation devices constructed by Mekhanobr Institute (St. Petersburg). A new construction of conical-inertial pulverisation with a modification of disintegration force has been developed recently at Mekhanobr Institute. It allows, in some cases, to increase selectivity of subdivision and to avoid over-disintegration. Advantages of “wet” subdivision methods in conic inertial disintegration devices are proved. The efficiency of such subdivision can be increased due to rational use of the phenomenon of a dislocation-dynamic diffusion. Its advantage is proved by the effect on disintegrated material by frequency-modulated variable electrical fields of low power. It was shown in industrial conditions, that the productivity of the spherical mill can be increased by 10 %, and that it also prevents ecologically harmful surface active substances (SAS) in milling zone and it reduces the dust content in the air. The techniques of tentative estimation of efficiency of various proceedings technogenic materials and their classification are created. The scientific fundaments of rational, ecologically friendly technology of processing and regeneration of various kinds of technogenic raw material are developed. A number of effective technologies on processing of wastes is developed and inculcated in concentration factories and metallurgical factories.

Jan 1, 2003

Due to the reduction in frictional resistance, the characteristics of joint infill have a major role to play on rock mass instability. This paper elucidates the laboratory behaviour of graphite infilled joints based on a large-scale shear apparatus under constant normal stiffness (CNS). Discontinuities in a graphite mine have been simulated using high strength gypsum plaster, with the joints infilled with compressed graphite layers. The Fourier series was employed to characterize the joint surface, and the method of using the Fourier coefficients for the prediction of dilation and normal stress with displacement is explained. Die Charateristik von Verbindungsfüllungen hat einen wichtigen Einfluss auf Felsmassenstabilität aufgrund der Verringerung des Reibwiderstandes. Diese Veröffentlichung untersucht das Verhalten von Graphit gefüllten Verbindungen im Labormaßstab mit einer Methode die auf einem gross-umfang Apparateprinzip unter konstanter Normal-Steifheit beruht. Unregelmässigkeiten in einer Graphit Mine wurden mit Gypsum Gips von hoher Festigkeit simuliert, die Verbindungen wurden mit kompressierten Graphitschichten gefüllt. Fourier Reihen wurden angewandt um die Verbindungs Fläche zu Characterisieren. Die Methode die verwendet wurde um die Ausdehnung und Normalkraft mit der Verschiebung mit Hilfe von Fourierkoeffizienten zu bestimmen wird beschrieben. Due à diminution des résistances par frottements, les caractéristiques des joints de remplissage joue un rôle majeur sur les instabilités de la roche. Cet article étudie le comportement en laboratoire des joints de remplissage en graphite à partir d’un dispositif de friction à grande échelle sous rigidité normale constante. Les discontinuités dans une mine de graphite ont été simulées grâce à un plâtre à haute teneur en gypse, dont les joints ont été remplis de couches de graphite compressées. La caractérisation de la surface des joints a été réalisée avec les séries de Fourier. La méthode utilisant le coefficient de Fourrier pour la prédiction de la dilatation et de la compression en fonction du déplacement est également expliquée.

Jan 1, 2003

By Daniel Roy

This paper introduces a new, safer bulk emulsion loading system for underground mining operations. The features and benefits of the equipment, along with the use of Dyno Nobel Inc. patented gassed emulsion technology, is summarized in the application of a stope blast with very difficult and complex ground conditions. The paper describes methods used to optimize the amount of energy required to break the ore while protecting the integrity of the surrounding backfilled pillar.

Jan 1, 2003

By C. Pelley, S. Kelebek, G. Kunzel, P. Katsabanis

Small blocks of granodiorite have been subjected to blast loads from a single borehole and from a series of boreholes detonating at various timing intervals. The damage of the blocks was assessed through P-wave velocity monitoring, measuring the change of the point load strength index of the rock after dividing the large blocks into smaller ones and measuring the work index of the material at different distances away from the blasthole. Numerical modelling with the AutodynTM code enabled visualization of damage. It was shown that damage is optimum at a small delay time between successive holes while it drops rather drastically after this point.

Jan 1, 2003

At the present time, cyanide is the most widely used reagent to extract gold from its ores and concentrates. However, its use in mining has become the focus of intense attack by various groups throughout the world; as a consequence, a renewed effort has been launched to find suitable alternative lixiviants to recover gold. Chlorination was the most popular process to extract gold, before it was rendered obsolete with the advent of the cyanidation process at the turn of the last century, not least because it required the use of potentially hazardous and costly chlorine to oxidize/complex the gold. The PLASTOL® process, originally designed to recover the platinum group metals (PGM?s) from their ores and concentrates, provides an alternative to cyanide for gold ores. The process generates oxidizing conditions in the autoclave capable of forming the AuIII ion, and gold chloro-complexes result from the addition of small quantities (~5-10 g/L) of sodium chloride to the autoclave. The principles of the PLASTOL® process are briefly described, and several applications of the process to gold concentrates are presented. Various options available to recover gold from PLASTOL® leach solutions are also discussed.

Jan 1, 2003

By C J. Corbett

Many underground mining methods rely on blasted rock moving under gravity to report to extraction points. Mining of orebodies dipping between 20 - 45 degrees poses a unique challenge for mining engineers in that a dip angle in this range will not allow the movement of broken ore down the footwall to the mucking horizon utilising gravity. This is more so in cases where the natural angle of repose of the rock is less than the dip of the orebody. Hence, innovative mining systems are necessary to mine this type of orebodies. In Australia, the method of uphole retreat panel stoping is commonly used to extract orebodies in the dip range of 20 - 45 degrees and thickness range of 5 - 15 m. In the Zambian Copperbelt a method called continuous retreat updip stoping is used for orebodies with similar dips and thicknesses. The mechanised form of this mining method has potential for application in the metalliferous mining industry in Australia. In this study a comparison is made between mechanised updip (MUDS) and transverse retreat stoping (TRS) methods. A hypothetical nickel sulphide orebody located in Western Australia is used as case study. The net present value for mechanised updip stoping is seven per cent higher than that of transverse retreat stoping based on the assumptions applied. Initial results of this study indicate that mechanised updip stoping can be adopted for Australian mining conditions. However, lack of significant local experience with the method is often cited as a reason for not adopting it even in situations where it is clearly the best option.

Jan 1, 2003

By D. Boldini, R. Lackner, H. A. Mang

ABSTRACT: In this paper, the strong interaction between the hardening shotcrete lining and the surrounding ground in NATM tunneling is investigated by means of axisymmetric analyses, accounting for the three-dimensional nature of the excavation process. The effect of the hydration of shotcrete on strength, stiffness, chemical shrinkage as well as microcracking and creep are accounted for. For the description of the mechanical behavior of the ground, a multi-surface plasticity model is employed. The performed analyses of the excavation process provide insight into the influence of each phenomenon accounted for in the material model for shotcrete on the response of the ground-shotcrete compound structure. ZUSAMMENFASSUNG: In diesem Beitrag soll die Interaktion zwischen dem erhärtenden Spritzbeton und dem Boden auf der Basis axisymmetrischer Berechnungen untersucht werden. Derartige Berechnungen ermöglichen die Berücksichtigung des drei-dimensionalen Charakters des Vortriebprozesses. Die Auswirkung der Hydratation auf die Entwicklung der Festigkeit, Steifigkeit und der chemischen Schwindverzerrungen, sowie das Reißen und das Kriechen des Spritzbetons wurde berücksichtigt. Das mechanische Verhalten des Bodens wurde mittels eines Mehrflächenplastizitätsmodells simuliert. Die durchgeführten Berechnungen des Vortriebprozesses geben Einblicke in die Auswirkungen der Spritzbetoneigenschaften auf das Tragverhalten des Boden-Spritzbeton-Komposits. RÉSUMÉ: La stricte interaction entre le soutènement en béton projeté durcissant et le terrain dans un tunnel creusé avec la NATM est étudiée par des analyses axisymétriques, compte tenu de la nature tridimensionnelle des processus de creusement. Les effets de l’hydratation du béton sur la résistance, la rigidité et la contraction chimique, ainsi que sur la micro-fissuration et le fluage, sont mis en compte. Pour la description du comportement mécanique du terrain on emploie un modèle de plasticité multi-surface. Les analyses conduites mettent en évidence l’influence de chaque phénomène considéré dans le modèle constitutif du béton projeté sur la réponse de la structure composite terrain-béton projeté.

Jan 1, 2003

By W. Wittke, J. Gattermann

ABSTRACT: One alternative to close a radioactive waste repository in rock salt is the construction of a “Cross Section Closure (CSC)“ sealing barrier. The proposed material for the CSC is highly compacted bentonite. To investigate the swelling behaviour of a highly compacted bentonite a large number of laboratory tests were performed. In addition, large scale model test were carried out to demonstrate the development of a nearly homogeneous and isotropic swelling pressure. The results of the large scale model tests were interpreted numerically based on the models for stress-strain behaviour and water uptake which are implemented in the finite element codes FEST03 and HYDOPO. The investigations show a good agreement of the results of the model tests and the corresponding analyses and show, that the theoretical models are capable of describing the behaviour of sealing structures based on highly compacted bentonite. ZUSAMMENFASSUNG: Eine Möglichkeit für den Verschluß eines Endlagers für radioaktive Abfälle im Steinsalz ist die Konstruktion einer Querschnittsabdichtung aus hochverdichtetem Bentonit. Zur Untersuchung des Quellverhaltens von hochverdichtetem Bentonit wurden eine große Anzahl von Laborversuchen durchgeführt. Um die Entwicklung eines nahezu homogenen und isotropen Quelldrucks nachzuweisen, wurden darüber hinaus auch Modellversuche in größerem Maßstab durchgeführt. Die Ergebnisse dieser Modellversuche wurden im Hinblick auf die Wasseraufnahme und das Spannungs-Verformungsverhalten mit Hilfe numerischer Berechnungen mit den finite Element Programmen FEST 03 und HYDOPO interpretiert. Die Untersuchungen zeigen gute Übereinstimmungen zwischen Versuchs- und Berechnungsergebnissen. Die numerischen Modelle sind somit geeignet, das Verhalten von Abdichtungsbauwerken aus hochverdichtetem Bentonit zutreffend zu beschreiben. RÉSUMÉ: Une possibilité pour fermer un dépôt final de déchets radioactifs dans sel gemme est la construction d'un étanchement de coupe transversale, fabriqué de bentonite fortement compacté. Pour étudier le comportement de gonflement de bentonite fortement compacté, de nombreux essais en laboratoire ont été exécutés. En outre, des essais sur modèle sur une plus grande échelle ont aussi été exécutes afin de prouver le développement d'une pression de gonflement à peu près homogène et isotrope. Les résultats de ces essais sur modèle étaient interprétés en vue de l'absorption d'eau et du comportement contraintes-déformations par le moyen de calculs numériques avec les programmes d'éléments finis FEST03 et HYDOPO. Les études montrent de bonnes conformités entre des résultats d'essai et de calcul. Les modèles numériques sont ainsi capables de décrire justement le comportement d'ouvrages d'étanchement fabriqués de bentonite fortement compacté.

Jan 1, 2003

By A. C. Maffei, M. V. Lins Gonçalves

Ore concentration processes are a function of the respective particle size distribution; however, most of them do not use an efficient operational method to determine it. From a practical point of view, the surface area can be calculated for any size analysis. The physical principles for determining the size distribution in each method are different, for the results will not be compared directly. During the development of the research project of the sulfide ore flotation method using inert gas, different methods for calculating the specific surface area have been used, such as sieving, sedimentation/X-ray, laser diffraction and BET, i.e. specific techniques to determine the specific surface area of copper and gold ore concentrates. The statistical method of minimum squares was used to achieve practical correlation equations among them. Regarding these two ores, if one knows a specific surface area value using one of the methods above, one can predict the result of the others. Diminution of the reagent consumption was so controlled and it could be even decreased by using inert gas.

Jan 1, 2003

By A. R. Leach

Anomalous mining conditions can be described where the level of hazard is increased relative to normal conditions within a mining area. Normal conditions would be those defined as a Ground Control District in a mine’s code of practice, and for which mine standard support layouts are generally developed. It has been found that up to 80% of fall of ground accidents occur where anomalous mining conditions exists, typically in the vicinity of geological weaknesses. These areas require specific attention to ensure they are readily anticipated and identified and that appropriate strategies are used to reduce the hazards associated with them. As part of SIMRAC project GAP 607 checklists to aid identification and best practice mining methods were identified for a range of geotechnically anomalous conditions.

Jan 1, 2003

By Roger L. Baer

Introduction Brief Review -SEC mission & history -Development of SEC mining disclosure guidelines -Principles of good public company ‘disclosure’ SEC staff views of alternative approaches to mining company disclosure -SME Resource & Reserve Committee – April 2003 Food for thought

Jan 1, 2003