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By S. R. Rao, J. A. Finch, E. El-Ammouri, K. Ngoviky, P. A. Disten

Sludges produced by lime treatment of acid mine drainage (AMD) can contain significant quantities of base metals which represent both a potential hazard and a loss of values. A new technique for metal recovery from sludge is proposed by combining selective acid leaching and adsorption of metal ions by activated silica sol. The process is demonstrated on two AMD sludges, one containing primarily nickel and the second zinc. They were first treated with sulphuric acid (pH 3.5) to selectively leach the target metals and then activated silica sol was added to the leach solution to adsorb the nickel and zinc. Thickening and centrifuging gave about 90 percent rejection of the input volume to effluent. The adsorbed metals were redissolved by strong acid into a concentrated solution relative to the feed and the silica sol was recycled.

Jan 1, 2000

By Andrew B. Allen, Charles W. Robinson, Robert L. Schneider

In April, the US Synthetic Fuels Corp. broke a three-year silence and made its first financial award by approving a $820,750 loan for the First Colony peat-to-methanol project in North Carolina (ME, May, page 403). Peat Methanol Associates (PMA), a partnership between Koppers Co., ETCO Methanol Inc., Transco, Peat Methanol Co., and l. B. Sunderland, broke ground at First Colony last year and plans to begin production in Dec. 1985. Although the award is only a small part of Synthetic Fuels Corp.'s $15-billion budget, it does signal the corporation's intention to move aggressively ahead. It also is a positive indication that First Colony will be completed and operated successfully. This article describes the methods and equipment that will be used to harvest peat at First Colony, as well as how the peat will be converted to methanol. Introduction Peat deposits found along North Carolina's coastal plain contain high-quality fuel-grade peat with an average heating value of more than 23.3 MJ/kg (10,000 Btu/lb) (dry), with a low sulfur and ash content. The deposits differ from other US peats in that they contain large, sound Atlantic White Cedar and Cypress logs, stumps, and roots that may extend throughout the full depth of the deposit. A second difference is that these deposits are much more highly decomposed and, in the raw state, have the appearance and feel of a heavy, reddish-brown grease. These factors make it impractical to use standard production equipment so a new line was developed. Also, because of these conditions, techniques were modified to facilitate production. First Colony Farms, located near Creswell, NC, developed and evaluated a milled peat program. Equipment for this production method was designed and built, production rates were established from field operations, drying rates were established, weather data were analyzed, and total operating and capital costs were estimated. The method depends on the sun and wind for drying peat to the desired moisture content, in this case around 40%. Therefore, field preparation is actually the construction of a large solar collector to dry the peat so it can be harvested and stockpiled. It is essential that this collector be properly profiled initially and maintained during production to prevent precipitation from ponding. Initial Field Preparation Initial field preparation includes cleaning existing canals and constructing ditches and water control structures for proper drainage of rainwater run-off, building adequate roads for site access, removing surface vegetation, and profiling and sloping the fields. At First Colony, the 60.7-km2 (15,000-acre) harvesting area was divided into 129.5-hm2 (320-acre) blocks about 1.6 km (1 mile) long and 805 m (0.5 mile) wide. This was accomplished by cleaning main outfall canals with adjacent roads built from canal spoil at 1.6-km (1-mile) intervals. Existing intermediate canals that feed into main outfall canals at 805-m (0.5-mile) intervals also are cleaned. Headland roads are constructed from canal spoil along each side of each intermediate canal. This 129.5-hm2 (320-acre) block is then divided into 32 harvest strips by small V-ditches constructed at 50-m (165-ft) intervals. At the end of the field with the lowest elevation, corrugated steel pipe culverts are installed under the headland road in each V-ditch to control rainwater runoff into intermediate canals. Runoff water from the fields is diverted to a holding pond to prevent any increase in peak water runoff rates and to allow for more uniform drainage rate than experienced to date. After the drainage system is installed, harvest strips are ready for grinding and sloping operations. Surface vegetation, made up of small, waxy-leafed shrubs such as Gallberry, Bayberry, Magnolia, and scattered pond pine, can be effectively ground and incorporated into the upper surface of the peat layer. Here, it will rapidly decompose and have little effect on overall peat quality, thus eliminating the standard practice of pushing the vegetation and upper wood layer into long windrows with bulldozers and hauling this debris from the fields. Incorporating vegetation into the upper surface is known as the initial 102-mm (4-in.) surface vegetation grind and is accomplished by using a modified Bros Rota Mixer. Following this operation, and by using the same unit, a sec¬ond grind with a depth of 200-255 mm (8-10 in.) is made. This reduces the debris to a finer consistency, mixes it with the upper peat layer, and grinds any wood found in the upper 200-255 mm (8-10 in.). After initial grinding operations are completed, the augering or sloping operations can be accomplished with little or no hin-

Jan 7, 1983

By Roscoe W. Stensrud

The Marcona Corporation was established in 1965 to consolidate the ownership and management of the Marcona group operations. This company, with headquarters in San Francisco, has the following principal operating subsidiaries: Marcona Mining Company, formed in 1953, conducts iron ore mining, beneficiation and pelletizing operations in Peru. Cia. San Juan S.A., Panama, which contracts for sale and delivery of iron ore from the Marcona operation in Peru and from Mount Goldsworthy in Western Australia. Sari Juan Carriers, Ltd., a subsidiary of Cia. San Juan which owns and charters vessels for the bulk ocean transportation of iron ore, petroleum products, coking coal, slurry, salt and other commodities.

Jan 1, 1968

By J. W. Leonard

Gravity based coal/mineral preparation plants must be operated to yield products of a quality satisfactory to existing markets; but, because of historic control problems, recovery is frequently sacrificed to achieve quality resulting in losses of valuable product. Plant control has ranged from intuitive in-plant spot quality judgments made by various operators to gross methods involving such devices as density gauges, floats, grab-sample on-the-spot sink-float tests, etc. Millions of tons of quality coal/minerals are lost to refuse each year, because of the historic lack of a continuous and dependable control system. The result is both serious economic as well as environmental losses. While the economic losses are obvious, less obvious environmental losses, in the case of coal, result from the misplacement of more ignitable quality fuel to refuse banks. A control system capable of supplying a market-grade coal/mineral product, while continuously minimizing product losses to refuse, has until recently escaped technology.

Jan 1, 1991

By C. R. Zegarra

Extraction of manganese, gold, and silver from a low-grade manganiferous-silver ore was investigated by thiourea leaching followed by standard cyanidation. The levels of reagent concentrations in this investigation were 0.0 -1.0 M thiourea and 0.0 -1.0 M sulfuric acid. Temperature and agitation speed were maintained at Z5 °c and 300 rpm, respectively. The dissolution of gold, and silver was shown to be dependent mainly on sulfuric acid and thiourea concentrations. In general, 50.0 % Ag, 98.0 % Au, and 75 % Mn were recovered from a Mn-Ag ore by thiourea leaching. Overall silver extraction of 98.0 % was obtained by cyanidation after thiourea leaching. Thiourea leaching of sodium bisulfite leach residues was also studied, and the total extraction of gold and silver were 97 % and 40 %, respectively. Finally, a two-stage thiourea leach was also investigated.

Jan 1, 1988

"A cationic surfactant, tetradecyl tributyl phosphonium chloride (TTPC), was first used as a collector. Flotation characteristics of muscovite using TTPC have been investigated through flotation tests. And dodecyl trimethyl ammonium chloride (DTAC) was tested for comparison. Their adsorption mechanisms on muscovite surface were clarified using zeta potential measurement, DFT calculation and molecular dynamics (MD). The flotation results indicate that the recovery of muscovite decreases when the pH increases in the presence of surfactants. When a maximum of recovery was reached, the dosage of TTPC was 2×10-5mol/L which was half of that of DTAC. Zeta potential measurements confirm that the TTPC displays a stronger collecting power than DTAC and is a superior collector for the muscovite flotation. DFT calculation and MD simulations show that TTPC interacts with the muscovite mainly through electrostatic attraction and hydrogen-bonding. The conclusions drawn from purely theoretical computations matched remarkably well with the experimental results. Keywords: Quaternary phosphonium salts; Flotation collectors; Flotation INTRODUCTION Muscovite mica is widespread in igneous, sedimentary and metamorphic rocks. It has the general composition KAl2(AlSi3O10)(OH)2. Muscovite mica exhibits perfect cleavage along the (001) plane, which exposes interlayer potassium ions[1-3]. In aqueous suspensions, the potassium ions readily enter into solution, leading to the development of a net negative charge on the (001) plane[4-6]. The surface of the muscovite mica is negatively charged at all pH > 1[7]. Due to the negative charge surface over the whole pH range of 2–12, the muscovite mica would not be expected to respond to anionic collectors in the absence of an activator. Conversely, the mineral is readily recovered using cationic collectors. However, until now, various amines and their derivatives (with N atoms as the center) are still the only available cationic collectors which still had their shortcomings such as weak selectivity, low flotation speed. Since few types of cationic collectors could be used, in some sense, the limitations of collectors are increasing significantly and the cationic flotation is facing more and more challenges. Quaternary phosphonium salts, as novel cationic surfactants, are widely used in antimicrobial, catalysis and surface modification field due to their biological activities, hydrogen bonding capability, stability and superior group electrical property[8-10]. There are a number of processes where quaternary phosphonium salt surfactants have shown better properties than quaternary ammonium salts and amines. Although the adsorption of quaternary phosphonium salt surfactants at the bacterium–liquid interface has been studied thoroughly, the case of adsorption in mineral surface has not been investigated thus far."

Jan 1, 2016

By Palmer King

The increased emphasis on environmental protection, together with the exorbitant costs, or in many urban areas the complete unavailability of surface space, has resulted in a burgeoning demand for greater use of underground space. More and more, those considering new or expanded facilities are looking toward the possibility of utilizing underground space for communications installations, for transportation of people, industrial products, water, sewage and energy, and for industrial installations. Happily, this growing demand for use of underground space is accompanied by fast forward strides looking toward more efficient underground excavation techniques. The tunnel boring machine is already here and where ground conditions are suitable for its use it can greatly reduce the cost of underground excavations, savings of one-third or more often being realized. Research is underway involving excavation by use of laser beams, jetting, vibrations, improvement of tunnel boring machines to make possible the excavation of harder rock, and other advanced techniques. The Engineering Foundation estimated in 1973 that tunneling costs can be reduced as much as 30 percent by rapid excavation methods which are expected to be developed through ongoing research programs in the next few years. Your American Society of Civil Engineers reported in 1973 that $60 billion per year, or 15 percent of the gross national product, could be saved if facilities required to support life were located in the subsurface. Studies looking toward improved contracting practices are going on under the sponsorship of the National Academy of Sciences, and Mr. Al Mathews who is heading this program will address you during this session on the status of this project. I myself am a member of Mr. Mathews' study group and, considering the human element involved, it is too early to make predictions as to what can be accomplished in the way of savings in costs of

Jan 1, 1974

By R. V. Ramani, R. Bhaskar

Control of respirable dust in mines has been given paramount importance due to the health and safety implications associated with fine dust. Understanding the temporal and spatial behavior of dust has been recognized as essential for increasing the efficiencies of existing control techniques and for developing new control strategies. Mining-related studies in this area are, in general, limited. They are also mostly experimental. Some mathematical and computer analyses have been at-tempted. In this paper, first, a review of the mathematical studies performed in the last three decades in this area is presented. Second, a mathematical model for analyzing dust flow in mines is proposed. The model takes into account a number of factors affecting dust transport. It in¬corporates varying dust generation source strengths and dispersion, deposition, and coagulation of dust in mine airways. Finally, application areas for the model are discussed. A computer program based on the mathematical model has been developed. The program will output the dust concentration in the mine atmosphere as a function of time and distance from the source. The amount of dust deposited on the sides, roof, and floor of the airway is also determined.

Jan 1, 1987

By Ren Bryce

The ninth annual Mineral & Metallurgical Processing Division (MPD) student poster contest was held in February at the SME Annual Conference & Expo in Minneapolis, MN. A total of 33 students presented their work at the contest. The competition began in January when the students submitted a one-page abstract for judging. In February, they prepared and presented a poster that explained their research. A panel of judges went to each student and listened as the students explained their research in five minutes. The students worked hard at their research and then set aside time to complete all the necessary steps to enter the contest. The MPD recognizes the effort required to enter and, as a result, provides monetary rewards to all participants. As in past years, there are separate levels of competition for undergraduates and graduates, and the prizes are designated accordingly. At the graduate level, first place receives $1,000, second place $500, third through seventh $200 each, and all others $125 each. At the undergraduate level, first place receives $1,000, second place $500, third place $250, and all others $125 each.

By V. C. Kelessidis

Demand for multifunctional drilling fluids continuously increases. In the quest for more hydrocarbons, drilling has extended to deep water areas (now in excess of 2.000 m) and to very deep wells (now in excess of 6.000 m). In these extreme conditions, low temperatures, as low as 1-5°C on the sea bed, high temperatures, in excess of 200°C, and high pressures, more than 1.000 bars, in the bottom of the well, are frequently encountered. In these harsh environments, synthetic oil and oil based drilling fluids are used, but the former are expensive while strict environmental requirements have limited the use of the latter. Thus, drilling industry has turned back to water based drilling fluids which use bentonite as primary viscosifier and as a fluid loss control additive. However, in conditions of high temperatures, bentonite suspensions gel and loose their exceptional low temperatures properties, thus, additives are needed to overcome such problems. In this article we review these challenging drilling environments and establish the requirements for the multifunctional drilling fluids. Our research indicates that demand for continuing use of bentonite by drilling fluid industry is strong. Furthermore, we bring forward the opportunities for new additive development which can expand the operational ranges of bentonite suspensions.

Jan 1, 2007

By G. R. Coonan

A number of famous studies have shown that house damage relates better to peak particle velocity than to acceleration or displacement. The relationship is true but doesn't go far enough. Why, for example, can construction shots go well above 1.0 or 2.0 inches per second without reportable damage? Recent studies have shown that vie must look at frequency and duration of an event in addition to amplitude. The complexity of measuring frequency, duration, and amplitude makes the average blaster in the field shudder. An even more excruciating problem is the need to obtain such data inside the building or residence in order to accurately predict the damage potential or human response to nearby blasting. The author reviews current research programs and suggests new areas of research necessary to help maintain a balance between complicated research requirements and simple field measurements.

Jan 1, 1980

By T. L. Conley, J. J. Rozek

The $2 billion (A$) Melbourne City Link Project is one of the largest and most important metropolitan road developments ever undertaken in Australia. The project involves two three-lane vehicular tunnels totaling 5 km, constructed as deep as 65 m underground. The 3.4 km Burnley tunnel is one of the world's longest three-lane tunnels. The project is being delivered under a DBOOT [design-build-own-operate-transfer] process and all design and construction is performed to ISO 9000 standards. Tunnel excavation began in May 1996, and the tunnel will open to traffic in 1999. This paper focuses on the range of construction techniques utilized during construction.

Jan 1, 1999

By Howard L. Hartman

Pardon my audacity, but I feel that this is the solution, not just a solution. Further, I will be so bold as to maintain that this is the last-ditch, eleventh-hour chance for the mineral industry to solve its critical technical manpower shortage. I am not being facetious. I am convinced that there is only one solution--just as there is but one real cause of the problem. My conclusion 'is reinforced by countless talks of endless hours with people both in and out of the industry, with employers and employees, and with educators and students. While I claim no originality for the idea and have no pride of authorship, I am concerned that the industry hear and heed in time. It is quite unlikely that the mineral industry and the mineral engineering profession will willingly subscribe to my thesis or gladly buy my proposal. I am convinced, however, that it is the only course of action open to us, and the only course of action which will succeed.

Jan 1, 1967

By W. M. Ma, W. L. Zhong, Syd S. Peng

In a longwall section that consisted of 7 longwall panels, there were two high pressure gas transmission pipelines across the panels burying from 3 to 10 ft. below the surface. One pipeline was 20 in. in diameter while the other was 24 in. in diameter. In order to investigate the stress conditions sustained by the pipelines during underground longwall mining, strain gages were mounted on the pipelines above panel #3, #4, and #5. Survey monuments were also installed along but near the pipelines. This paper presents a subsidence prediction method and the preliminary results of the pipelines' stress conditions as affected by underground longwall mining.

Jan 1, 1986

By R. M. Barker

The historic Getchell property, near Golconda, NV, is being mined from the Getchell Main Under- ground workings, a footwall extension of the Getchell open-pit deposits along the Getchell fault. Drift-and-fill techniques are used to extract the ore through a ramp access. The adjacent Turquoise Ridge deposit is under development by two vertical shafts. These two mines will continue to provide feed to the Getchell's 2.9 ktld (3,200 stpd) mill/autoclave circuit. This will take Getchell Gold from its current production rate of 6.2 t/a (200,000 oz/year) to more than 12.4 t/a (400,000 oz/year) by 1999.

Jan 1, 1997

By K. A. Natarajan, M. K. Yelloji Rao

The electrochemistry of sphalerite and chalcopyrite was investigated under both open-circuit and applied potential conditions. Emphasis was placed on the selective dissolution of sphalerite from a mixture of sphalerite-chalcopyrite flotation concentrates as a function of applied potential, acid concentration, pulp density, and time. Morphological studies using a scanning electron microscope (SEM) were also carried out with chemically leached, galvanically leached, and unleached surfaces of sphalerite and chalcopyrite. Selective dissoulution of sphalerite could be achieved if the mixed chalcopyrite-sphalerite concentrate slurry was maintained at a negative applied potential of -0.4V (SCE). Probable mechanisms involved in the selective dissolution of zinc are disscussed.

Jan 1, 1990

By I. S. Parrish, D. W. Kappes, G. G. Austin

Micron-sized gold disseminated in lower Cambrian siltstone has been found at the Sterling mine near Beatty, NV. A shoestring-shaped body has been developed by central and fringe drifts and is being mined via a modified retreat room and pillar system. The siliceous ore crushed to 5.08 cm (2 in ) is stacked to 4.6 m (15 ft) over a layered sand, gravel, and impervious PVC base. Gold is leached using a 0.1% cyanide solution and deposited on activated coconut shell carbon. Stripping of the carbon by hot solutions of 1% NaOH and 20% Ethanol yields overall recovery of about 75% of the fire assay head.

Jan 1, 1983

By S. K. Sharma

The Bureau of Mines' rapid method of dewatering fine-particulate slurries uses extremely high molecular weight polymers. These polymers form large, strong flocs which can be dewatered by sieving or sedimentation. However, sometimes these flocs deteriorate rapidly if water is not removed immediately. During field tests, clay slurries have been encountered that could have been dewatered economically if it were not for the rapid floc deterioration. A kinetics study was conducted to determine the rate of kaolin-PED floc degradation in which polymer addition, to bring the flocs back to their original condition, was used to determine the extent of floc decay. Results showed that the amount of polymer added, to replace polymer lost by spreading, was less for the lower PEO concentrations. For this clay-polymer system, floc breakage as judged by polymer additions followed first order kinetics. It was also found that the addition of fluoride ion stabilized the kaolin flocs.

Jan 1, 1992

By A. M. Laird

Endako Mines' molybdenum operation is located near the geographic center of the province of British Columbia, Canada. The property is six miles south of the Northern Transprovincial Highway and the northern main line of the Canadian National Railway. The area is broken by high hills covered with dense stands of spruce and pine with vast areas of the valley floors covered with aspen and poplar. The climate is moderate with precipitation averaging 22 inches per year. Approximately four feet of snow accumulates in the winter, and temperatures range from 900 F. in summer to -40° F. in winter. The orebody, a lowgrade porphyry type deposit, occurs in a widespread granitic intrusive which has been locally weakened at the intersection of two regional faults. In this vicinity the quartz monzonite has been further shattered to permit the entry of mineralizing solutions and local dykes. Two types of mineralization occur within the orebody. The most prom¬inent is the six inch to four foot wide continuous quartz veins with characteristic ribbons of molybdenite and frequently finely-divided grains of molybdenite within the quartz. The second type occurs as fine fractures filled with quartz molybdenite in the form of a stockwork halo radiating out from 20 to 200 feet from the quartz veins. Minor hematite, magnetite and chalcopyrite are also present. Mineralization is roughly proportional to the extent of kaolinization in the quartz monzonite, kaolinization being one of three distinct forms of hydrothermal alteration. Pyrite is commonly associated with molybdenum mineralization within the orebody and a pyrite halo is recognized on the south side of the orebody.

Jan 1, 1968

By Tim O’Neil

Big and getting bigger. Barrick Gold Corp., the third-largest gold producer in the world, began production in September — ahead of schedule — at its Meikle Mine. At a scheduled full production rate of 12.4 t/a (400,000oz/year), it will be the largest producing underground gold mine in the United States. The $180-million Meikle Mine is located on Barrick’s Goldstrike property in Nevada and has 205 t(6.6 million oz) of gold reserves. The compact Meikle deposit has an average ore grade of 23 g/t (0.68 oz/st), making it one of the highest-grade mines in the country.

Jan 1, 1996