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By Robert Semrad, J. Colin Anderson

INTRODUCTION Sulphur is a mineral which accounts for 0.05% of the earth's crust and may be found either in its elemental state or as a compound. References to sulphur production and consumption are found in early antiquity and international trade of sulphur from volcanic deposits in Sicily began in the 1880's. The supply of sulphur consists of two components: the first is production, and the second is inventory. HISTORICAL SUPPLY Production World sulphur production in 1984 was approximately 53.5 million metric tons, compared to the 1970 level of 42 million metric tons. Of this 11.5 million metric tons production increase, brimstone accounted for close to 90%. Production distribution in 1984 was 62% brimstone, 21% pyrites and 17% other forms, while in 1970 it was 55%, 28% and 17%, respectively. Brimstone Production is derived either from mining operations (Frasch, underground melting and native refined) or as a by-product from hydrocarbons. World production in 1984 exceeded 33 million metric tons, up approximately 10 million metric tons from the 1970 level. This increase was uniformly distributed throughout the world as shown in Table A.

Jan 1, 1986

By Eli Curiel, Ingar F. Walder, Patrizia P. Schuster, Walt Keyes

Mansfield Canyon, of the Wrightson Mining District, Santa Cruz County, Coronado National Forest, Arizona, was actively mined in the late 1800's and early 19001s, with minor activity until 1953. The main products were lead, silver, copper, zinc, and gold occurring in polymetallic quartz veins. The canyon contains numerous adits and waste dumps, some of which generate metal-loaded acid. Samples of seeps, waste dumps and bedrock have been collected for various analyses: metal concentrations, acid base accounting (ABA), and water quality to evaluate the extent of oxidation and metal release from the start of mining until present, the potential impact, and reclamation options. Although the waste-rock piles within the canyon are small (2,000-10,000 tons), they have a high sulfide content with little or no neutralizing capacity. It is planned, therefore, to move the waste piles either to a constructed repository site within the canyon or to a copper leach facility to be used as an acid generator.

Jan 1, 2000

By V. K. Paruchuri, J. D. Miller, J. Nalaskowski

An understanding of forces responsible for the stability of dispersions of colloidal particles when interacting with each other in aqueous solutions is of great interest academically and industrially. When water-soluble polymers are adsorbed onto colloidal particles, various effects on the stability of their suspensions can be expected ranging from steric stabilization to bridging flocculation. The possibility of detailed characterization of such systems using direct measurements of interaction forces between particles can help in further improvement of existing technologies of solid-liquid separation. An atomic force microscope (AFM) colloidal probe was used to measure the interaction forces between a silica sphere and a silica substrate in the presence of water-soluble polymers. Poly(ethlene oxide) (PEO) with three different molecular weights (7,000, 43,000, and 63,000), each with a very narrow molecular weight distribution, were used in this study. The interaction forces measured with the AFM over an extended time scale are discussed in terms of the adsorption kinetics measured through in-situ FTIR/IRS measurements.

Jan 1, 2003

By W. F. Hahnert, T. L. Ward, K. E. Stoll, P. A. S. Ralston

Fuzzy logic is well suited to the control of non-linear, time-varying, and/or any system for which it is difficult to obtain an exact mathematical model. To design a good fuzzy controller, a thorough understanding of the desired process behavior is required. Many papers have suggested that fuzzy controllers are robust. If they are, it is reasonable to explore whether or not they respond better than conventional controllers to errors in the feedback signal due to imperfect measurement or sensor degradation. It may be the case that simpler or less expensive sensors could be used in some processes. The research presented here relies on an integrated array of computer programs that model and simulate (1) the process to be controlled, (2) common feedback instrumentation, and (3) both fuzzy logic controllers (FLC's) and conventional controllers. Various types of feedback sensor imperfections are imposed upon the system, and the performance of the two controllers is compared. Each controller is tuned to its optimal performance in response to a setpoint change using perfect feedback measurement.

Jan 1, 1993

By Nick J. Miles, Gareth J. Brown

The degree of fragmentation of dispersed systems of brittle materials such as pulverised rock has been described by a fractal dimension i.e. the fragmentation fractal. This fractal dimension represents a power law size-frequency distribution, where, in this case, the size is defined as the square root of the projected area. The existence of a fractal dimension for the number-size distribution, of the progeny of failure event, is direct evidence for scale invariance of the fragmentation process. Since a fractal dimension infers that failure mechanisms operate on all scales it has been suggested that the fractal dimension is a measure of the fracture resistance properties of materials during fragmentation. In order to investigate this a range of rocks of varying fracture toughness were broken under similar levels of impact velocity in the dynamic tensile failure of single particles. The fragmentation fractals determined from the resultant particle populations, of the breakage experiments, were monitored and are discussed.

Jan 1, 1995

In conjunction with steady increases in production levels, longwall operators have applied greater quantities of ventilating air and spray water in an effort to control respirable dust and/or methane. Air velocities greater than 7.6 m/s (1,500 )fpm) have been measured on longwall faces. Operators have expressed concern over the potential entrainment of respirable dust at these high velocities. The greatest likelihood for entraining dust into the high-velocity airstream may occur as shields are advanced, allowing relatively dry particles to fall from the shield canopy directly into the airstream. Laboratory tests to simulate dust liberation during shield movement were conducted at the Pittsburgh Research Laboratory of NIOSH at velocities ranging from 2.0 to 8.2 m/s (400 to 1,600 fpm). Airborne dust samples were obtained with personal impactors to quantify the size distribution and concentration of the dust entrained at the various air velocities. Statistically significant increases in both total and respirable dust concentrations were measured as test air velocities were increased.

Jan 1, 2002

By Satya Harpalani, Xue Zhao

This paper discusses the results of an experimental investigation to study the release of methane in coalbeds. Absolute porosity of coal samples was first determined experimentally. Following the porosity measurement, adsorption/ desorption tests were carried out to determine the gas content of coal and the rate at which it is released. Finally, micrographs were obtained using electron microscopy and the use of a physical model, developed to explain the gas flow behavior of coal, was justified. The results of this study indicated that the measured absolute porosity of the coal sample was between 5 an 6%. This was significantly lower than the porosity estimated by comparing the micrograph area occupied by the pores and the area of observation for several micrographs, suggesting that coal has a large number of pores with a very small volume. The micrographs also clearly indicated that coal has a large interconnected network of cleats and microfractures. The adsorption/desorption experiments showed a hysteresis between the adsorption and desorption isotherms. Also, the rate of desorption was found to be strongly dependent on the particle size of the specimen.

Jan 1, 1989

By R. M. Damodaran

The flotation performance of Florida phosphate rock was evaluated in terms of the mixing behavior of reagents and particulates during anionic conditioning of phosphate slurries. The various conditioning variables that influence mixing, namely, solids loading, agitation speed and conditioning time, were investigated to determine their effect on reagent coating of the particles. The phosphate recovery was used to monitor the conditioning efficiency. The mixing characteristics of the phosphate feed were evaluated in terms of the ratio of the mixing power (P) to the minimum power (Pm) required to keep the slurry in suspension. It was found that mixing conditions govern the conditioning time required to obtain a high recovery. Reagentization was slower at lower P/Pm ratios. At higher P/Pm ratios, the flotation recovery was optimized, and the agitation speed was found to have no significant effect. Optimum mixing conditions were obtained for a74 wt% slurry at an agitation speed of 450 rpm (47 radians/sec). Under these optimum mixing conditions, the collector dosage required for an improved recovery was lower and the conditioning time was shorter.

Jan 1, 1997

By S. E. Phillipson, P. L. Tyrna

Lineament analysis, a remote sensing application, for geological structures, has been criticized, for its reliance on subjective interpretations. The Mine Safety & Health Administration's Roof Control Division performs lineament analyses with a technique that removes much subjectivity. Study areas are viewed on satellite images with software that allows examination under artificial sun azimuths and elevations. Extraneous lineaments are removed through successive steps of superposition, resulting in selection of the most robust linear features. Field investigations revealed a strong coincidence of joint and. fault zones that were parallel with projected lineaments. The Roof Control Division's successful identification o f lineaments associated with roof falls and high wall failures has prompted some mine managers to incorporate lineament analysis as a mine-planning tool. The identification of potentially hazardous ground conditions would allow mine operators to obviate safety concerns that might otherwise adversely affect the health and safety of miners.

Jan 1, 2003

By A. Foscolos

Land reclamation and rehabilitation of depleted coal mines in the wider area of Ptolemais-Amynteon is practiced by the Division of Mines of the Public Power Corporation of Greece in order to conform to the concept of environmentally sustainable economic development of its operations. Detailed chemical and mineralogical studies were performed on reclaimed soils and their crops in order to evaluate the results of land reclamation and rehabilitation while similar studies were undertaken in adjacent, regularly cultivated, soils. Results indicate that trace element concentrations as well as concentrations of elements of environmental concern to be higher in regularly cultivated soils than the reclaimed ones. However, the concentration of the elements in wheat grains harvested from both, regular and reclaimed, group of soils is the same. The reason for this behavior is the very low water solubility, of the elements in the soils, due to their high pH values and the nature of their occurrence. As a result, wheat crops produced from reclaimed-rehabilitated soils developed on depleted lignite mines in the wider area of Ptolemais-Amynteon do not pose any health problem on either humans or animals when consumed.

Jan 1, 2003

By N. B. Aughenbaugh

Compacted, fine-grained soils, often referred to collectively as clays, are used as permeability barriers in many mineral engineering projects such as heap leaching, containment ponds, tailings disposal and earth dams. Source materials for these liners include a variety of sand, silt and clay admixtures. These exhibit dramatically different engineering properties when densified. Therefore, it is imperative to adequately assess and characterize any soils being considered for compacted liners. The permeability and plastic properties of fine-grained soils are reviewed with respect to the state of compaction as the water content varies. Because they are weak in tension, compacted clays are susceptible to cracking when subjected to differential flexural movements. Designs of compacted clay liners also must include an evaluation of their flexibility. That is the ability of a fine-grain soil to bend plastically without cracking. This paper will also discuss the importance of flexibility with respect to soil types, compaction effort, failure mechanism and testing evaluation to the performance of clay liners in preventing seepage of pollutants from a containment site.

Jan 1, 1991

By I. Nishkov, L. Alexandrova

The kinetics of froth flotation and the three-phase contact (TPC) parameters are studied at temperatures varying from 20°C to 40°C. The material floated consists of glass spheres and a quartz particles with various diameters. Dodecylamine hydrocloride (DDAHCI) is used as a collector. The equilibrium three-phase contact angle is measured with a microscope technique using the modified Mingins-Scheludko method. Using a Wilhelmy method, the temperature effect on the surface tension of the DDAHCI solution is determined. The formation of the thin film on a polished plate of vitreous silica and the expansion of TPC is monitored by means of a metallographic microscope and recorded on a attached camera at different temperatures. The experimental data show an intensification of the flotation kinetics at 30 and 40°C in the case of small particles. Such an intensification is not observed with the larger particles. The cause for intensification of the flotation kinetics is sought for in the dependence of the TPC rate of expansion and induction time on temperature.

Jan 1, 1995

By R. M. Cox

Pneumatic coal loading and conveying systems provide alternative methods for the safe and efficient mining of the thin, high-grade coal seams found in the Southern Appalachians. Pneumatic systems eliminate most of the health and safety hazards associated with the operation of conventional mining and haulage equipment in small low-coal mines by removing powered mobile equipment from the mine. Ventilation is also improved by the coincidental removal of gas and respirable dust from the mine by the operation of the pneumatic loading and conveying system. Other significant advantages of pneumatic coal recovery systems are relative simplicity, operating flexibility, low capital cost, quiet operations, environmental benefits and ease of automation. The design considerations and field evaluations of experimental prototype pneumatic coal loading and conveying systems installed and operated in small thin-seam mines are presented in this paper. In addition, fundamental design criteria and recommendations for the installation and operation of a variety of pneumatic coal loading and conveying systems that offer alternative coal-recovery systems that alleviate the serious health and safety concerns of current small mine operations are proposed.

Jan 1, 2000

By Keith G. Wallace, Robert Wise, Ian J. Duckworth

This paper describes a case study for the ventilation planning at Utah Fuel Company's Skyline Mines which are located outside Price. Utah. The Skyline Mines are currently comprised of two longwall coal mining blocks located in two different mines. A third replacement longwall block is currently being developed. Future ventilation systems for the mines were determined by establishing ventilation models developed from data collected during a detailed ventilation survey. The paper discusses the challenge to coordinate immediate ventilation requirements with long-term demands. The continuous movement of the longwall, which frequently represented the only open split in the ventilation network, resulted in cyclic ventilation demands dependent upon the length of the tailgate. A series of system configuration changes were recommended based on the results of the network modeling exercise and an economic evaluation of the various options. The scope and cost of the configuration changes, and the mead improvement resulting from these changes is discussed.

Jan 1, 1995

By E. Kokinou

The main scope of the present study is to investigate the suitability and sensitivity of the magnetic susceptibility as a pollution monitoring tool in urban areas. For this purpose, a municipal park located in the centre of Chania city, which may be affected by traffic and domestic heating pollution, was selected as the study area. In the context of the present work, magnetic susceptibility measurements were conducted in two phases. Surface soil samples were collected in 2006 from the area under investigation and they were analyzed in order to estimate the spatial distribution of the magnetic susceptibility. One year later, mapping of the magnetic susceptibility has been contacted in situ using Bartington MS2D and MS2F sensors. Additionally, soil samples were collected from selected positions in order to compare the values of the magnetic susceptibility with that estimated in 2006 research. Both investigations indicate high values of the magnetic susceptibility around the park near the roads and in a small area inside the park where a café is located.

Jan 1, 2008

By Gordon M. Elliott

Health risk underlies all of today's environmental regulations. Mine Manager's are no strangers to risk, but risk in the context of mine management is not the same as risk in the context of environmental regulation. One of the risks facing the mine manager is whether the mining operations meet environmental compliance standards. These standards are defined in terms of the frequency of occurrence of adverse health effects in an exposed population (i.e., health risk). Demonstration of compliance necessarily involves mathematical modelling and selection of values for input variables. What is not immediately apparent is that the method of estimating the human health risk has a significant influence on remedy selection and the amount of money spent at suspected contaminated sites. Using a hypothetical, mining-related example, this paper illustrates the disassociation between the current deterministic approach to health risk assessment and cost-effective decision making. This paper also illustrates how the probabilistic approach to health risk assessment provides a more realistic characterization of health risk and enables mine managers to identify cost-effective remedial strategies for the site.

Jan 1, 1992

By I. Longson

Maintaining control over underground environmental conditions in the United Kingdom is increasingly dependent on the contribution of underground booster fans. Given the recent trends of higher rates of production from a fewer number of coal faces with higher levels of mechanization and higher power consumption, the effect has been to place a greater load on the mine ventilation system. This has increased the scale of potential problems that may arise should any of the main ventilation control devices not perform at the required full duty. This is particularly true for underground booster fans. Major changes occur in the main ventilation parameters on the stoppage or restart of a booster fan which results in a temporary loss of environmental control. This paper analyzes the impact of such events and details a mathematical model thar has been developed for a single-mesh circuit containing a main and a booster fan. Predictions based on this simple model are presented and discussed with particular reference to the energy changes occurring within the ventilation system immediately following a booster fan stop or restart

Jan 1, 1995

By Peter Kowalczyk

The acquisition of submarine gravity data using airborne gravity technology is a practical reality. Ocean Floor Geophysics plans to deploy a free-swimming ROV based submarine gravimeter on a commercial basis in early 2009. The submarine instrument is a variant of the well-used GT-1A airborne gravimeter. Airborne gravity surveys are now routine. The primary factor controlling the accuracy of airborne gravimeters is the precision of the GPS measurement of vertical movement of the sensor platform. The gravity measurements along a flight line are the differences between the output of the gravimeter vertical accelerometer and the estimate of the aircraft vertical acceleration using the differential GPS system. The principle difficulty of moving an airborne gravimeter to a free-swimming submarine platform is the necessity to have an accurate real time estimate of the changing elevation and hence changing vertical acceleration of the platform; GPS doesn't work underwater and an accurate estimate of depth fluctuations to the necessary precision is difficult to acquire. It is interesting that the airborne gravity gradiometer technology, which competes with the airborne gravity technology, was first developed as a classified military application for use by missile submarines during the cold war. Gradiometers were developed for this application specifically to avoid this problem. A gradiometer does not require as accurate an estimate of its vertical position to make a useful reading- it measures gravity gradients, not the gravity field itself.

Jan 1, 2008

By Jakub Nalaskowski, Vamsi K. Paruchuri, Marcin Niewiadomski, Jan D. Miller

Spherical oxide particles can be used as mineral fillers, paint pigments, polishing materials and catalysts. They can be prepared using various techniques involving precipitation and spray drying. Melting of particles in a high-temperature flame is a simple technique which produces particles with a high degree of sphericity and high smoothness from non-spherical feed material. In current research the preparation of alumina particles by melting the feed material in a hydrogen- oxygen flame is described. The spherical particles obtained were characterized using scanning electron microscopy, atomic force microscopy, energy dispersive spectroscopy, X-ray difiaction, Fourier transform infrared spectroscopy and electrokinetic measurements. The particles pre- pared exhibit a high degree of sphericity and a low level of roughness. The chemical composition of the material after preparation is unchanged, however the crystallographic structure is different. It is suggested that alumina changes from pure a-alumina to a mixture of different transitional forms. Changes in the electrokinetic behavior were also observed for alumina which can be attributed to the strong dehydration of the oxide surface and/or change in the crystallographic structure. Also, the possible accommodation of trace amount of impurities in the surface zone during melting cannot be ignored.

Jan 1, 2003

By Vincent Castronova, Jane Y. C. Ma, Joseph K. H. Ma, Chang-geng Mo, Carl J. Malanga

A group of bisbenzylisoquinoline (BBIQ) alkaloids has been shown to exhibit various degrees of effectiveness in preventing silicainduced fibrosis in animal models (1, 2). The capability of these drugs to interact with phosphatidycholine vesicles and rat alveolar macrophages was studied using fluorometric and equilibrium dialysis methods. The lipid binding affinity of these alkaloids was found to depend upon several structural factors including hydrophobic substitutions, the chiral configurations, and the double oxygen bridge-restricted conformation of the benzylisoquinoline moieties. Tetrandrine, which is highly effective in preventing fibrosis, showed strong binding to both lipid vesicles and alveolar macrophages. In contrast, curine and tubocurine, which have little or no effect on silicosis, exhibited only weak binding to lipid vesicles and almost no binding to cells. The moderate binding affinity of fangchinoline to vesicles and cells corresponded to a moderate effectiveness of the compound as an antifibrogenic agent. Methoxyadiantifoline, an alkaloid of unknown antifibrogenic potential, also exhibited high binding affinities for lipid and cells. In summary, this study indicates that alveolar macrophages exhibit large binding capacities for certain members of the BBIQ alkaloids. A positive correlation was observed between binding affinity to alveolar macrophages and the reported antifibrotic potency of these compounds, suggesting that the ability of these drugs to interact with alveolar macrophages may be a key step in inhibition of the progression of silica-induced pulmonary disease.

Jan 1, 1991