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By Yael Miron

Ammonium nitrate-fuel oil (AN-FO) mixtures are used as blasting agents in mining pyrite-bearing ores. The temperature of these ores can increase by the continuous, though at times slow, oxidation weathering of the pyrites. At elevated temperatures, AN-FO reacts exothermally with pyrite, and the reaction becomes self-sustained at 120° C ± 10° C. The Bureau of Mines has conducted an investigation to determine the reactivity of mixtures of AN-FO with pyrite containing ferrous sulfate. The results of tests in a heated vessel simulating a hot borehole demonstrate that small amounts of ferrous sulfate, a major product of pyrite weathering, initiate a self-sustained exothermic reaction with AN-FO at 80° C. Five pct by weight of urea was found sufficient to prevent a reaction among the three ingredients, at least within the limits of the test, which reached 180° C. Smaller amounts of urea and of potassium oxalate slowed down the reaction and delayed its onset to higher temperatures, but did not prevent it.

Jan 1, 1979

By John M. Gomes

Two methods for electrowinning tungsten from wolframite [(Fe,Mn)W04] were investigated. The first method, direct electrowinning from wolframite concentrate dissolved in molten salt mixtures composed essentially of various combinations of sodium phosphates, sodium borates, and sodium halides, yielded impure products. The second method was electrowinning from a halide-tungstate melt that was obtained from a high-temperature, two-phase extraction of tungstic oxide (W03) from wolframite. Electrolysis in electrolytes prepared from addition of sodium metaphosphate (NaPO3) and boric oxide (B2O3) to the halide-tungstate melt produced tungsten metal of 99.9 percent purity. Tungsten carbide (WC) was electrodeposited from the halide-tungstate melt when the melt was adjusted to contain 82 mole-percent NaCI and 6.0 mole-percent each of W03, sodium metaborate (Na2B204), and caustic soda (NaOH).

Jan 1, 1970

By Francis R. Redfern

Newton's method of solving a nonlinear equation is employed to develop a least-squares acoustic emission source location method in which the spatial residuals of the location equations are minimized. These residuals, related to the distances from the least-squares source location perpendicular to the surfaces described by the location equations, permit location error to be estimated to first order along the spatial axes. The solutions obtained by this method are the best spatial solutions to the location equations in the least-squares sense. Also presented is a procedure by which the geometrical control of a transducer array can be evaluated using the rate of change of source location with fractional velocity change.

Jan 1, 1982

By A. J. Rambosek

An evaluation of diamond-bit performance data accumulated from core drilling in quartzite shows that core recovery and physical characteristics of drill bits and diamonds have economic significance. Relatively inexpensive, low-quality, small Congo diamonds will perform as well as, or better than, other diamonds used as drill bart. M-type bits set with oriented Congo diamonds provide those engaged in core drilling with near optimum combination. Various factors that affect bit performance, including size of diamonds, size and type of bits, grade or quality of diamonds, and percentage of core recovered, are evaluated by means of tables, charts, and discussion.

Jan 1, 1958

By Fun-Den Wang

Finite-element structural analyses were performed to determine the stress distribution and displacements around a single rectangular coal mine opening in a multilayered rock system. The effects of changes in mechanical properties of roof and coal layers, roof layer and mine opening geometry, horizontal-to-vertical load ratio, and structural geologic features on the stress distribution about the opening were studied. Variability in the stiffness and relative thickness of the immediate roof layers can produce a considerable difference in the stress distribution about the opening as compared with that of a homogeneous material. Changes in opening width and horizontal-to-vertical load ratio have different effects on the stress distribution about the opening depending on the composition of the roof layers. In general, where a stiff layer exists in the roof at the surface of the opening, the stresses are higher in the roof and ribs around the opening. Horizontal changes in facies in the roof layers produced by structural geologic features can also greatly alter the stress distribution about the opening compared with the simple layered cases.

Jan 1, 1974

By W. S. Sanner

Grinding experiments were conducted to determine the finest anthracite particles that could be produced in a ball mill. Continuous and batch tests were run in a dry-grinding ball mill. Batch grinding produced the finest coal particles. They averaged 2.2 microns in diameter and were 99.0 percent smaller than 37 microns. Continuous grinding yielded a product 6.1 microns in diameter, with 96 percent smaller than 37 microns.

Jan 1, 1968

By Michael J. Gallagher

Diamond-bit performance data accumulated by the Bureau of Mines in core-drilling limestone and dolomite show that the physical characteristics of the diamonds and the sizes and types of bits used are economically significant. An analysis of the data establishes one trend of particular significance to those engaged in core drilling: Bits set with small, low-quality drill bort are the most economical. Detailed analysis of the factors that affect diamond-bit performance, such as size and quality of diamonds, sizes and types of bits, percentage of core recovered, and physical characteristics of bit matrices are assessed in the tables, bar charts, and discussion.

Jan 1, 1958

By Philip B. Lorenz

A Bureau of Mines feasibility study on the use of tracer pulses to assess the degree of fracturing in an underground formation consisted of three phases: 1. A laboratory study on sand packs and open tubes, which developed a correlation between dispersion of the pulse and size of the flow channels. 2. A test on a retort, 11 feet in diameter and 45 feet high, packed with shale rubble. Void volume was measured, but evaluation of channel size was not possible because of interference from the space unoccupied by the matrix. 3. A field test on an explosively fractured shale formation. Pressure, flow, and transit time led to qualitative estimates of fracture pattern, but quantitative detection of dispersion in the formation was overwhelmed by dispersion effects in the well.

Jan 1, 1973

By W. E. Robinson

Oil-shale samples selected from a core of the Green River Basin (Wyoming) were studied to ascertain differences in the composition and/or chemical structure of the organic material in the samples relative to stratigraphic position within the Green River Formation. This involved a systematic study of the soluble organic material and the insoluble kerogen present in the samples. Emphasis was placed upon the distribution of the alkanes (normal and isoprenoid compounds) in the soluble extract and upon the aromaticity of the kerogen. In general, it was concluded that significant differences exist in the chemical structure of the oil-shale organic material from various strata within the Green River Formation of Wyoming. Most of the compositional and structural changes were not related to burial depth but were related to source material variations, environmental differences, or other factors.

By M. G. Zabetakis

The method of moving averages was found useful in assessing the nature of methane emission in coal mines. Emission rates were influenced markedly by the presence of abandoned oil and gas wells in the vicinity of the mine. Such wells appeared to increase the flow rate of methane into the mine by a factor of 2 to 30 in an active mine in the Pittsburgh coal seam.

Jan 1, 1972

By Harold F. Unger

The Bureau of Mines conducted drilling experiments in the laboratory with a commercially available percussive drill that has an independent rotational system. Eight rock types with a wide range of physical properties were drilled under several combinations of rotational speed, drilling thrust, and operating pressure. Penetration rates and energy per unit volume correlated well with the coefficient of rock strength as shown graphically. Size-distribution analyses of some of the drill cuttings show how particle size varies with rotation speed and rock hardness. In general, changing the rotational speed has a greater influence on the penetration rate in softer rocks, with penetration rate increasing with increasing rotational speed.

Jan 1, 1972

By J. L. Konchesky

The Bureau of Mines investigated the main reactions of coal gasification by steam. Coal (minus 70 mesh)-water slurry was fed into a laboratory-scale tube-coil gasifier to show the effects of residence time (0.6 to 1.1 sec), steam-coal ratio (2 to 11 lb/lb), and temperature (1,600° to 1,900° F), at about 1-1/2 atm. Devolatilization was very rapid: about 70 pet of the coal's volatile matter evolved within 0.6 sec at about 1,600° F; temperature increase released more volatile matter until about 95 pct was driven off at 1,900° F. Devolatilization was not increased by raising steam concentrations and was only slightly increased by extending residence time. Below 1,600° F, there was no evidence of the steam-carbon reaction, but at 1,900° F more than 80 pct of the coal's fixed carbon was converted to gas; the conversion was increased Significantly by increased residence time and steam concentration. The water-gas shift reaction occurred simultaneously with devolatilization, and the steam-carbon reaction, approaching equilibrium with increased residence time and temperature and decreased steam concentration.

Jan 1, 1969

By M. J. Kovalik

The effects of the process variables on the production of chemical coke on a chain grate stoker, a type of traveling grate, were studied. Six bituminous coals, ranging in volatile matter from 16.7 to 43.8 percent, were successfully carbonized, yielding chemical coke with acceptable physical properties. The coke yields were dependent on the volatile-matter content of the coal. The air fuel ratio had the most marked effect on the yield and characteristics of the resultant coke, and the general furnace performance. Results can only be predicted; the actual yield and quality of coke obtained from any given coal can only be determined by actual tests using the optimum processing variables to obtain a coke with minimum volatile-matter content and to retain as much of the fixed carbon in the original coal as possible.

Jan 1, 1967

By Elizabeth A. Johnson

The effect of slag composition on lead losses to slags and on the behavior of associated accessory elements in lead blast furnace smelting has been studied by the Bureau of Mines. Equilibrations of 30 g of lead and synthetic slag doped with Cu, In, TI, and Sb at 1,200° C in CO-C02 atmospheres revealed the importance of the FeO:Si02 ratio and the basicity ratio, (CaO+MgO):SiO2, of the slag. Lead losses to slags increased with an increasing FeO:Si02 ratio and decreased with an in-creasing basicity ratio. Copper and indium distribution coefficients, [Lx =] increased from 15 at the lower basicity ratios to near 60 at higher basicity ratios. LTI values increased from 20 to 150 as slag basicity increased. Lcu, Lin, and LTI were relatively in-dependent of the FeO:Si02 ratio, but increased with greater amounts of accessory elements in the system. Antimony distribution alone was shown to be strongly affected by FeO:Si02 ratio, although data were scattered. LSb values ranged from 20 to 800 and decreased sharply with increasing FeO:Si02 ratios. The basicity ratio and the level of accessory element load did not have any noticeable effect on LSb.

Jan 1, 1983

By S. J. Page, J. A. Organiscak

Dust surveys were conducted around small truck-mounted rock drills operating at surface coal mines to assess their airborne respirable dust generation and in-service dust control methods. Of four out of seven drills sampled, respirable dust concentrations measured around the drill deck ranged from 8.68 to 95.15 mg/m with3concentrations ranging from 1.37 to 2.69 mg/m at distances 12.2 to 30.5 m downwind of these drills. The other3drills had noticeably lower respirable dust concentrations measured around the drill deck at or below 1.30 mg/m.3Rotoclone-type dry dust collectors were commonly used with dust being emitted from around the drill deck shroud, collector exhaust, and collector fines dumping. Wind speed and direction was also a factor in the dust concentrations measured on the bench. Dust control modifications were made to three rock drills to reduce their airborne dust emissions. Dust controls tested included water injection into the Rotoclone exhaust, Rotoclone exhaust extension, improved sealing of drilling deck shroud, shrouding the Rotoclone hopper dump process, and wet drilling. These control techniques showed noticeable improvement in dust concentrations measured around the drills. Finally, repositioning the drill operator showed that operator dust exposure can be improved by avoiding the dust cloud around the drill.

Jan 1, 1995

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 2 Program Use Instructions necessary to execute the program, after the card deck has been prepared, are summarized in the following. B 2. 1 Input Data Format Input data is supplied to the program in two ways a. By data cards that are read in after program compilation. b. By data specifications that are included within the program.

Jan 1, 1976

Enable mine personnel to determine the effectiveness of and to optimize the mine fire stench warning system without resorting to costly trial and error fire drills. Approach The mine fire stench warning system is used by underground metal/nonmetal mines to warn mine workers of a fire or other emergency. Stench is released directly into the mine ventilation and/or compressed air lines, and its repulsive odor warns miners to evacuate the mine or to follow other established emergency procedures. Unfortunately, since most deep metal mines have complex ventilation systems, some areas of the mine may receive nauseatingly high concentrations of stench while other areas, in more remote locations, may receive no warning or greatly delayed warring at best. The Bureau of Mines, through research, endeavored to solve this problem with a computer modeling system designed to calculate the distribution of odorant by the stench warning system.

Jan 1, 1986

By Aarne Visnapuu

Pneumatic chipping, scaling, and grinding can expose the tool operator to noise levels in the range 90 to 120 dbA. In most chipping and scaling operations, casting resonance is the primary source of noise, followed by air exhaust, and machine and chisel resonance. In grinding, the air-exhaust noise predominates. The Bureau of Mines has shown that noise from these operations can be reduced by up to 15 dbA. Workpiece resonance was reduced by sand or other damping methods; tool resonance, by internal damping; and chisel resonance, by constrained-layer treatment. Mufflers reduced air-exhaust noise, and an acoustically treated booth was effective in containing noise around the work area without increasing operator exposure.

Jan 1, 1977

By Powell. Alfred R.

"An investigation has been made of the applicability to a variety of coals, other than those from Illinois, of the Powell and Parr method of analysis for the forms of sulphur in coal.A complete study was made of the sulphur in the following coals:- Upper Freeport, Pa.; Pittsburgh seam, Pa.; Pocahontas No. 3, W, Va..; Letcher Co., Ky.; Morgan Co., Tenn.; and Cherokee Co., Kan.The method of analysis gave excellent results when applied to these coals. In the determination of pyrite, the iron-sulphur ratio checked in every case with the theoretical. After the extraction of the pyrite and sulphates, the remaining sulphur was proved to be organic in nature.This work indicated that sulphur exists in coal in three typical forms: - pyrite or marcasite, sulphates, and organic sulphur. A study of the changes which these forms undergo during coking has been made on a variety of coals, and the following five classes of reactions established.First. Complete decomposition of the pyrite and marcasite to ferrous sulphide, pyrrhotite, and hydrogen sulphide. This reaction begins at 300°C., is complete at 600 °C., and generally reaches its maximum between 400 and 500°C."

Mar 1, 1920

By Gregory P. Cole, Jeffrey Shawn Peterson

The Pittsburgh Research center3 conducted research to study and improve electrical fault detection on coal mine direct-current (dc) trolley systems. A suspended trolley line delivers power at voltages of 300 or 600 V dc to the haulage equipment and other loads. Roof falls or other accidents may force the trolley line down so that an electrical fault current may flow between the trolley line and rail. This fault current could result in localized heating, arcing, and perhaps fire. Such faults are not always preventable by the existing circuit protection because the current magnitude is well below typical operating levels of the trolley system. The research discussed in this report studies the applicability of computerized signal analysis techniques to solve this problem. Tests were conducted at cooperating coal mines. Measurements were taken during normal loading of the trolley system (light, intermediate, and heavy traffic), during induced fault conditions (arcing and bolted faults), and during transitions between the two. These data were then used to train and test a microprocessor-based fault detection algorithm. Later, field tests of the detection algorithm found that it correctly classified the state of the trolley system greater than 95% of the time.

Jan 1, 1997