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By H. E. Powell

The selective recovery of nickel and zinc from a waste phosphate solution by solvent extraction was investigated by the Bureau of Mines as part of a broad program to recover valuable metals and compounds from industrial wastes, and to reduce the associated land and water pollution caused by dumping these wastes. The waste, which resulted from the phosphation of automboile bodies, yielded 99 percent of both the nickel and the zinc by extraction with dinonyl naphthalene sulfonic acid (DNSA) and di-2-ethylhexyl phosphoric acid (EHPA), respectively. Dilute sulfuric acid was used to recover the metals and regenerate the solvents.

Jan 1, 1970

By John A. Organiscak

The Bureau of Mines has recently completed a program to identify and evaluate various methods that address control of dust generated outby the longwall mining face. Dust generated by the stageloader-crusher, the panel belt, and the intake roadway can be long-term throughout the shift, contributing significantly to the dust exposure of all face workers. Dust control techniques were identified and tested at a number of longwall mining sections located in diverse geological conditions across the United States, Dust controls investigated include (1) methods that eliminate the sources of intake dust contamination--homotropal ventilation; (2) methods to limit the amount of respirable dust released into the intake airstream--improved water application and the use of curtains and enclosures; and (3) methods to clean the contaminated air prior to delivery to the mining face--scrubber systems. Usually they can be implemented at a low cost and can be very effective. This report describes each technique and its application and presents the resulting conclusions.

Jan 1, 1986

By William K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/ AgC1 reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrodes to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 2010

By R. D. Leitch

The pollution of streams by acid mine drainage has become of great importance in the past few years in certain regions of the United States. Large quantities of acids are used in a discharged from other industries than mining, notably in tube, sheet, tin-plate and era hell inn works. These are usually less important then coal mines as a source of acid drainage, because of their more limited distribution throughout the States most affected by acid waters and their relatively smaller numbers. Streams are naturally alkaline and are, therefore, able to take care of rather large quantities of acid wastes, but when such enormous quantities as are often found in mining districts enter the streams, the natural alkalinity is quickly overcome. When a neutral or almost neutral condition has been reached, the further addition of a relatively slight quantity of acids will cause a great difference in the quality of the water.

Jan 1, 1926

By F. Garcia, J. Cervik

The cross-measure borehole technique has been shown by the Bureau of Mines to be an effective method of controlling methane liberated by fracturing the roof strata in longwall gobs where overburden is less than 750 ft (229 m). Boreholes are drilled into roof strata before mining operations affect the roof strata. Longwall mining fractures the roof strata and releases methane from source beds. Surface exhausters or vacuum pumps are used to draw the gas to the surface through an underground pipeline and vertical exhaust hole. The captured methane is thus prevented from entering the mine's ventilation system. About 71 pct of the methane produced by longwall mining in the Lower Kittanning Coalbed was captured by the cross-measure boreholes. Borehole spacing is an important factor affecting the performance of the technique. Interference tests and measurements of methane flows in return air indicate borehole spacing in the Lower Kittanning Coalbed should be limited to about 200 ft (61 m) except on the first 600 ft (183 m) of the longwall, where spacing should be reduced to about 100 ft (30 m) to capture the large quantities of methane released when the first large roof fall occurs. Comparisons between measured and calculated gas pressure differentials on boreholes indicate borehole length can be reduced from 280 to 140 ft (85 to 43 m), which reduces drilling costs significantly. Additional experimentation is necessary to verify the calculations.

Jan 1, 1985

By Kelly C. Strebig

Laboratory tests were conducted by the Bureau of Mines to determine the effect of depth of cut and bit type on respirable coal dust generation. Apparatuses were constructed to contain the coal samples, measure the linear cutting forces, and analyze the dust generated. Single-bit tests were conducted in Illinois No. 5 and Pittsburgh seam coals with five bit types at four depths of cut. The results showed that bit type did not significantly influence dust production. On the other hand, deep-cutting bits were more efficient and generated substantially less respirable dust per pound of coal broke than shallow-cutting bits.

Jan 1, 1975

By B. H. Eccleston

Experimental work is reported showing the effects of gasoline characteristics on auto emissions. Fuel volatility is shown to influence evaporative losses, with the higher losses associated with higher volatility. Fuel front-end olefin is shown to contribute significantly to reactivity of emissions. Large vehicle-to-vehicle differences were found. The study was conducted by the Bureau of Mines at its Bartlesville Energy Research Center in cooperation with the Coordinating Research Council Air Pollution Research Advisory Committee. The work was done using 15 1968-70 model autos and eight fuels were tested at ambients ranging from 20° to 95° F. Data on emissions from each vehicle-fuel-temperature combination are presented. Also included are calculated photochemical reactivity data and the distribution of hydrocarbon and nitrogen oxides during the test cycle.

Jan 1, 1972

By B. H. Eccleston

The Bureau of Mines, in cooperation with the American Petroleum Institute, studied the effect of fuel volatility and front-end fuel composition on the amount and photochemical reactivity of automobile exhaust and fuel-system evaporative emissions. The study involved six gasolines--the base fuel, three fuels of varied volatility, and two fuels differing from the base and from each other in front-end olefin content. Data were obtained from 16 vehicles operated on a chassis dynamometer using a speed-load-time cycle that approximated a typical urban trip. Tests were made at ambient temperatures of 20°; 45°, 70°, and 95° F, using a climate-controlled dynamometer room. The amount of hydrocarbon emission and its probable photochemical effect, a potential contribution to pollution, is expressed as weight (reactivity equivalent) of a moderately reactive material, ethylene. Emissions of oxides of nitrogen, car-bon monoxide, and aldehydes were also observed. Results showed that reduction of volatility from currently typical levels serves to reduce both the amount and the reactivity equivalent of evaporative losses with a slight penalty by way of higher exhaust emissions. Alternatively, reducing the amount of light (low boiling) olefin in the fuel had no effect on the amount of hydrocarbon pollutant but did significantly reduce the reactivity equivalent of the emissions. Neither volatility change nor chemical changes to the fuel significantly affected the nonhydrocarbon emissions.

Jan 1, 1970

By Joseph N. Harstead

This Bureau of Mines report provides information on the first 49 water-flood projects (or units) in Nebraska. All injection was in the ?D? or "J" Cretaceous sands of western Nebraska. Specific data presented include location, map, discovery and development, water supply and injection, oil and water production, estimates of oil in place, primary and secondary recoveries. The 49 projects studied) including four dual-zone projects, should recover about 126.5 million barrels of oil. Eighty-six percent of the estimated oil had been recovered by the end of 1966. Abundant water was found near most projects.

Jan 1, 1967

By Arthur M. Hartstein

The Bureau of Mines, through contract with Ultrasystems, Inc., obtained data on the oxidative degradative behavior of a number of materials used in coal mines. Tests were performed using a stagnation burner arrangement. Materials examined included those used in typical coal mining operations such as (1) polyvinyl chloride-containing materials. (2) neoprene compositions, (3) rigid foams (urethanes/isocyanates), (4) miscellaneous materials (including jute, fiber glass, and polyethylene), (5) coal, (6) fluids (phosphate esters, organic esters, oil-water emulsions), and (7) composites. The composite comprised a mixture of a phosphate ester fluid with (1) coal, (2) a representative polyvinyl chloride sample, or (3) a neoprene-type composition. A number of decomposition products are identified that could represent a potential health hazard to miners including HC1, CO, SO2 and H2S, if they were generated to exceed toxic levels.

Jan 1, 1974

By D. D. Dornenburg

The effect of changes of atmospheric pressure on methane emissions from extensive worked-out areas of coal mines in several Midwestern States has lone caused concern to State and Federal mining departments, as well as to the operating companies involved. Common mining and ventilation methods employed in mines in these States have resulted in large sealed and unsealed worked-out areas in which considerable quantities of methane are emitted alone both intake-and return-air courses. The common practice is to watch barometric changes very closely and take special precautionary measurer during periods of low barometric pressure. Although the hazard is recognized, mining officials have different opinions concerning the effect of barometric pressure variations on the emission of mine gases. These opinions are based upon scattered personal observations, as no records exist of actual studies to establish such effects.

Jan 1, 1955

By J. C. Nigro

Hematite-to-magnetite reduction kinetics were investigated mainly in CO-CO2 atmospheres at temperatures ranging from 500° to 1,000° C. Reduction rates were measured with a thermobalance, which recorded the weight loss as the specimen was reduced. Reduction data on both synthetic and natural hematite spheres showed good linearity of ro [1-(1-R)1/3] with time, t, up to over 85 pct conversion to magnetite; the rate coefficient (k[L], cm/min) obtained from the linear portion of the plot was used to characterize the penetration rate of the hematite-magnetite interface. Gas composition, porosity, and silica content were major factors affecting the rate. Temperature dependency of the reaction rate was small, yielding a mean activation energy of about 3 kcal/mole. Silica additions increased the reaction rate, probably through an increase in the effective surface area and diffusion; however, above 900° C, silica can react to form fayalite. Experimental data showed that the linear thickening rate of the magnetite layer, normally evidence of a chemically controlled reaction, can also be indicative of a reaction controlled by both mass transfer and diffusion. Evidence from this study indicates that the dominant rate-controlling factor in the reduction of hematite to magnetite at high temperatures is transport in the gas phase.

Jan 1, 1973

By Manuel Gomez

The purpose of this study was to evaluate the feasibility of using statistical response surface regression analysis to predict the sulfur and ash distributions and the washability characteristics of coal along a seam in advance of mining. Prediction equations were developed with experimental data from channel, bench, and core samples from the Pittsburgh coal seam in Greene County, Pa. It was not possible, with the available experimental data, to construct mathematical models to predict ash and sulfur concentrations between sample points. In the authors' opinion, however, the good agreement between experimentally determined and predicted values at given sample points demonstrates the usefulness of the method. More input data, such as geologic information, seam characteristics (rock-to-coal ratio), petrographic analysis, and chemical data, would perhaps make it possible to predict sulfur and ash concentrations and washability characteristics between sample points.

Jan 1, 1970

By F. D. Osgood, H. M. Cooper, A. C. Fieldner

The analyses in the tables are arranged geographically with respect to county and towns, and are grouped as follows: l The proximate analysis--moisture, volatile matter, fixed car bon, and ash; 2 The ultimate analysis-carbon, hydrogen, nitrogen, oxygen, sulphur, and ash; 3 The calorific value of heat of combustion; 4 The softening temperature of ash, when such determinations were made. Ultimate analyses are given in three conditions-namely, (1) as received, (2) moisture free, and (3) moisture and ash free Proximate analyses and heating values are given generally in one condition -namely, as received, some are in two conditions, as received and moisture free.

Jan 1, 1928

By S. A. Gustavson, H. E. Olund

This report has been prepared to review the history of the Premium Price Plan for copper, lead, and zinc, which was in operation from February 1, 1942, to June 30, 1947. It includes various charts and tables comparing costs and production data, and data on exploration premiums that were included in the Plan during the last year of its operation.

Jan 1, 1950

1. In 2003, 14,391 mining operations reported employment statistics to the Mine Safety and Health Administration (MSHA). Almost half (49%) were sand and gravel mines, followed by stone mines (30%), coal mines (14%), nonmetal mines (5%), and metal mines (2%).

Feb 1, 2005

1. In 2003, a total of 1,972 coal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Coal mines comprised 13.7% of all mining operations. • Bituminous mines comprised 92.5% (n = 1,825) and anthracite mines 7.5% (n = 147) of coal mining operations. • More than 70% of all coal mines were located in three states: Kentucky (29.0%), West Virginia (20.9%), and Pennsylvania (20.2%). • Bituminous coal mines reported the production of over 1 billion coal tons.

Feb 1, 2005

By F. M. Goodwin, John Campbell, G. W. Jones

"INTRODUCTION In previous reports 5 results were given of a manhole investigation carried out over a period from June 1929 to July 193C in cooperation with the Edison Electric Illuminating Co. of Boston. Mass., and during 1931 in cooperation with the Edison Electric Illuminating Co. of Boston and the Boston Consolidated Gas Co., to determine the general hazards of combustible gases and vapors in manholes and other underground openings owned by the Edison Electric Illuminating Co. and to develop methods of eliminating these hazards. These investigations have demonstrated that the detection, control, and elimination of combustible hazards in manholes can best be obtained by a close cooperation of the interested parties through a systematic and continuous inspection of manholes, under proper supervision.The investigation carried out during 1932 has been along lines similar to those conducted during 1929, 1930, and 1931 test crew consisting of two men, one an employee of the Consolidated Gas Co. and the other an employee of the Edison Electric Illuminating Co., was continuously employed during the year in the testing of gases in manholes served by the Edison system. The test crew was under the direct supervision of John Campbell, superintendent of the special service department of the Edison Electric Illuminating Co., and F. M. Goodwin, vice president of the Consolidated Gas Co.As in the previous investigations, all tests were numbered. The test-data sheets, on which the information regarding the tests was recorded, were prepared in triplicate, ono copy going to the Edison Co., one to the gas company, and the third to the Bureau of Mines at Pittsburgh, Pa. These test-data sheets were then filed (1) according to the town, (2) the street location, and (3) the manhole number; in this way a complete record of each manhole tested was immediately available. A typical test-data sheet was given in the 1931 report. These data sheets were found to entirely satisfactory and no changes were made during the 1932 investigation. The procedure of sampling manhole atmospheres, shipment of the samples to Pittsburgh, and method of analysis has been the same as that described in the 1931 report and need not be repeated here. Likewise, there has been no change in the method of calculation of explosibility of the samples analyzed or the use of charcoal filter tests given in appendix A."

Jun 1, 1933

By John D. Sullivan, Edward P. Barrett

The experimental work on the utilization of tin-plate scrap at the North- west experiment station of the U. S. Pireau of Mines in cooperation with College of Mines, University of Washington, necessitated the selection of a simple method for the determination of tin in the iron produced. Some of the standard methods for the determination of tin which were tried are given below: 1. Dissolving in acids and precipitating the tin as sulphide, igniting and weighing as Sn02. 2. Dissolving in aciis, reducing with nickel, cooling in an atmosphere of carbon dioxide, end titrating with standari iodine solution. 3. Dissolving in acids, precipitating the tin as sulphide, dissolving this sulphide in H3 and H2S04, heating until fumes of 503 are evolved, reducing with nickel or sheet lead, cooling in an atmosphere of carbon dioxide, ani titrating with a standard iodine solution.

Mar 1, 1923

By Charles L. Kimbell

This study is intended to serve three roles. First, it is the second annual edition of this study in a separate volume that represents a global overview and summary to supplement and complement the five regional volumes that now constitute the U.S. Bureau of Mines international, geographically arranged studies. In this regard, it also extends previous works under this title that appeared in the inter-national volume of the Minerals Year-book from the inception of that volume (the 1963 edition) until it was subdivided into six separate volumes in 1989. Following the traditional format of past chapters under this title, the basic statistical presentations herein deal chiefly with 1990, and in a few instances with 1988 or 1989; these latter two only because more recent, comprehensive global statistics simply are not yet available owing to delays in data collection and processing in some countries and continued governmental suppression of data in others. The second role of this study is to provide an update to the coverage of events impacting on the world's mineral industry that have occurred between the end of 1990 and the preparation of this study. Inclusion of this update is almost essential because of the potential effect of some of these events on global mineral industry activities.

Jan 1, 1993