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By C. A. Herbert

In summer, when hot, moisture-laden air enters a coal mine in the region east of the Mississippi River, the moisture is likely to condense on the roof and ribs because the incoming air is cooled below its dew point upon contact with the roof, ribs, and floor of the mine passageways. When the roof and ribs become wet owing to this condensation they are said to "sweat." In many mines, as soon as this sweating begins, shale or slate roof that appears solid and strong in winter begins to cut and fall. For a long time most mining men believed (many still believe) that the roof trouble was due to this sweating. However, from observation of conditions in one mine the operators concluded that the trouble was caused by expansion and contraction of the roof due to changes of temperature. This opinion was confirmed by experiments at several mines in cooling the air as it entered the mines. Methods used in these mines for cooling the air are described in this circular. MINE A At mine A the roof gave considerable trouble in the summer, and it was observed that where a spray of water from a leaking dam kept the roof wet and at a uniform temperature no difficulty was experienced with the roof, although it had cut and fallen on either side of that point. From this fact the company officials concluded that changes of temperature in the air rather than moisture caused the trouble and that if the incoming air were cooled to approximately normal strata temperature much of the additional roof trouble experienced during the summer would be overcome.

Jan 1, 1940

By L. A. Haas

The U.S. Department of the Interior, Bureau of Mines, is conducting laboratory-scale research to determine the leaching conditions required with sulfuric acid for extracting base metal from a matte with a copper-to-nicke1 ratio of 6 to 1. The matte (61.2 pct Cu, 9.7 pct Ni, 3.3 pct Fe, 21 pct S, and about 5 oz of precious metals per ton) was prepared from Duluth Complex (Minnesota) ore by smelting a bulk sulfide flotation concentrate. The matte was pre leached at atmospheric pressure to selectively extract 20 pct of the nickel, and the undissolved solids were referred to as the matte residue. Autoclave leaching of the matte residue extracted over 95 pct of the nickel, copper, and iron. The remaining leach residue in the autoclave contained over 100 oz of precious metals per ton. The leaching conditions required were matte grind of greater than 98 pct minus 325 mesh, pulp concentration of 50 g/1, total pressure of 100 psig with oxygen at 150° C or 400 psig with air at 180° C, 50 g/1 H2S04, 700 rpm agitator speed, and 6 hours of leaching time. The leaching time was decreased to 2 hours by increasing the agitator speed to 1,300 rpm. Sulfuric acid concentration greater than 50 g/1 did not appreciably enhance the base metal extraction, but with less acid, residues with higher iron concentrations were obtained. Supersaturation of the liquor was prevented at 150° C by using a 1ixiviant that contained 30 g/l Ni and 20 g/1 Cu.

Jan 1, 1979

By H. G. Iverson

The effects of adding boron and boron plus carbon to electrorefined vanadium were evaluated with respect to mechanical properties at low temperatures and response to heat treatment. Grain size was significantly decreased with the addition of 0.05 percent boron, the decreases ranging from 30 percent at 800° C to 75 percent at 1,100° C. Increasing the boron content resulted in only a small increase in strength at room temperature, but at 77° K, boron contents of 0.005 to 0.076 percent increased the yield strength of vanadium over 50 percent, from 70,000 psi to 110,000 psi. When boron and carbon were present together, the individual grain-refining effects obtained with either element were retained. Approximately a twofold increase in strength was obtained by age-hardening the alloys containing both boron and carbon. Alloys with only boron additions did not age-harden.

Jan 1, 1968

By Joseph Cervik

Gas occurs in coalbeds in an adsorbed and a free gas state. Adsorbed gas is stored in the micropore structure and its transport is governed by Fick's law. The free gas occurs in the fracture system and flows according to Darcy's law. These two modes of mass transport are interdependent. Production decline curves of coal-gas wells are of the constant percentage decline type and, thus, show no indications of flow characteristics peculiar to coal-gas reservoirs. The effectiveness of surface boreholes as a degasification scheme depends upon both good fracture permeability and a high fracture density. Conventional methods of reservoir engineering analysis are not applicable to coalbeds

May 1, 1969

By H. D. Baylor

This is the first of a series of papers describing mining methods and costs at cement plant quarries throughout the United States and deals directly with those methods employed and costs obtained at the quarry of the Louisville Cement Co. located at Speed, Ind. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance of Mr. J. M. Buohheit, superintendent of quarries, and Mr. H. E. Schoonover, quarry engineer, in furnishing data and in compiling this report.

Jan 1, 1930

By Frank D. Lamb

Four samples of manganese-bearing material from the Aroostook County, Maine, deposits were tested at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., to determine their amenability to beneficiation by ore-dressing methods. The samples represented material from the Maple Mountain-Hovey Mountain deposit, the Dudley farm, and the Burnham farm and contained 11 to 14 percent manganese. None of the tests produced appreciably enriched concentrates suitable for further treatment for the production of ferromanganese. The intimate association of the manganese minerals with iron and siliceous minerals requires extremely fine grinding to liberate the manganese minerals in these ores and prevents efficient concentration by physical means.

Jan 1, 1953

By Arne Landsberg

Accessory metals, although valuable resources, present possible environmental concern in the smelting of base metals. The Bureau of Mines, U.S. Department of the Interior, has undertaken research to define the chemistry involving these metals. Arsenic in copper smelting is the first to be investigated. Roasting, the first step in many copper smelters, was chosen for initial investigation because of the potential for arsenic removal in this primary process. Simple, static-bed, vaporization experiments were devised to obtain the data in this study. Ancillary transpiration and mass spectrometry were also used to delineate conditions necessary for arsenic volatilization from a roaster feed. For nearly complete arsenic removal, a temperature of 650°-700° C, a reducing atmosphere including carbon monoxide, and a source of sulfur were found to be essential.

Jan 1, 1980

By N. S. Dalal, Xianglin Shi

"INTRODUCTIONEpidemiologic studies of workers in chromate-ore related industries, 1-3 and stainless steel welding and related occupations4 have shown that they have about 20-40 times higher risk of throat or respiratory track cancer than controls. Although the actual carcinogenic substances were not identified in these statistical studies, Cr(VI) compounds (for example, calcium chromate, zinc chromate, and lead chromate) were implicated as the causative agents, whereas Cr(III) compounds were not suspected as carcinogens. s These suggestions were supporte4 by laboratory studies wherein many Cr(VI) compounds produced sarcomas at the implant or injection sites.1,5 Squamous cell carcinomas and adenocarcinomas closely resembling human lung cancer were induced by intrabronchial implants of calcium chromate in rats, 6·7 whereas Cr(DI) oxide and Cr(lll) sulfate did not induce any tumor formation.6,7While the mechanism of the chromate-induced carcinogenicity is not fully understood, it is generally thought8 that it involves some damage to DNA. Specifically, it has been reported that: a) the chromate ion, henceforth referred to as chromate, can pass through the cell membrane and enter the cell while CR(DI) does not, 9 b) chromate does not interact with either native or denatured DNA 10 while Cr(III) does, 11 and c) the final Cr-DNA complex isolated from cellular reactions of chromate is Cr(III)-DNA, with Cr(III) binding to the phosphate groups.12,13 Thus the important question is: since Cr(DI) cannot pass through the membranes, how does Cr(III)-DNA complex form? For this to happen, Cr(VI) must be reduced to its lower oxidation states, 14 ultimately to Cr(III), by some reductants in the cellular environment. Unless this reduction occurs, the DNA would not be damaged and therefore no chromate carcinogenicity would ensue. Thus the reduction of chromate to its lower oxidation states seems to be a key step in the chromate carcinogenicity .1s One of the major reductants in cellular environments is thought to be glutathione (GSH), both outside and inside the cells.16-lB Some evidence for the role of GSH in the chromate toxicity was provided by recent studies showing that exposure of hamster cells to non-toxic levels of added selemite increases the levels of GSH as well as the Cr(VI)-induced DNA strand breaks,19 and that such DNA strand breaks in hepatocytes also change in direct proportion to the GSH content. 20,21 These observations were interpreted as implying that the reduction of chromate by GSH to some reactive intennediate is an important step in the chromate carcinogenicity. 20.21 In · the present undenaking22 we have used electron spin resonance (ESR) and spin-trap methodology to investigate the reduction of chromate by GSH and find evidence for the involvement of the glutathionyl radical (GS ·) as well as Cr(V)-intermediates."

Jan 1, 1990

By K. K. Kershner

To meet an increasing demand for high-purity cobalt, the Bureau of Mines has conducted investigations for producing this metal. Cobalt having a purity of 99.95 percent or higher is needed to determine heats of formation, corrosion resistances, phase diagrams, and other basic properties of the element and its compounds. This grade of cobalt may be used for preparing radioactive metal. As a result of its investigations a detailed procedure, which is of practical significance to the production of high-purity cobalt, has been developed by the Bureau for purifying cobalt solutions and for electrolytic deposition of the metal. Cobalt metal, which had a purity of 99.99 percent with reference to metallic contaminations, was deposited electrolytically. Qualitative spectrographic analysis showed only traces of calcium, copper, iron, magnesium, nickel, and zinc.

Jan 1, 1956

By L. R. Burdick, R. Wiggers, J. F. Berkley

"INTRODUCTION On February 23, 1944, Solid Fuels Administrator Harold L. Ickes stated that the existing fuel shortage made it necessary to utilize a great surplus of freshly mined anthracite ranging in size from Barley (No. 3 Buckwheat) downward through the smaller sizes. As a part of the program to increase the use of such coal, field trials of mixtures of bituminous slack coal and anthracite Barley were made on industrial-size stokers at many fuel-burning plants. The following covers the test information it was possible to accu-mulate during the work of initiating the use of these mixtures at the plants.SUMMARY AND CONCLUSIONSField tests of various mixtures of bituminous slack coal and anthracite Barley on industrial-type stokers show that the use of such mixtures is very practicable and that it is possible to change and usually to adjust to an improved condition the characteristics of a fuel bed of eastern bituminous slack coal by the addition of proper amounts of anthracite. The improved uniformity of the fuel bed of single-retort stokers makes possible less manual attention to the bed. Air flow through the fuel bed is affected.Smoke is decreased. In general, the fly ash and also the unburned combustible in the fly ash and refuse are increased. Clinkering in the fuel bed is generally lessened. The peak-load carrying capacity of the stoker is definitely affected, usually adversely for the higher percentages of anthracite."

May 1, 1946

By C. E. Armantrout, H. Kato, M. I. Copeland

The data collected during this investigation indicate that the chromiumgadolinium system has extensive liquid immiscibility and one eutectic point . Liquid immiscibility occurred at temperatures above the monotectic isotherm , 1,830 ° C , which extended from less than 0.25 to about 85 weight - percent gadolinium . The eutectic was at 96 percent gadolinium and 1,170 ° C. Gadolinium and chromium were the only phases in this system . There was a solid solubility of less than 0.25 percent gadolinium in chromium at 1,730 ° C and less than 0.10 percent chromium in gadolinium at 1,160 ° C. The alloys were prepared by nonconsumable - electrode arc - melting , and the alloy system was investigated by heat treatment , metallography , thermal analysis , and X- ray diffraction . All the melting , heat treatments , and thermal analyses were conducted in a vacuum or in helium because of the reactivity of chromium and gadolinium with the components present in the atmosphere at elevated temperatures .

Jan 1, 1964

By E. A. Magill

The Bureau of Mines has begun a study of the copper resources of the Cascade Mountains of Washington. The program includes reconnaissance of mineralized areas and examination and occasionally limited exploration of deposits that are considered characteristic of an area. The Bureau of Mines believes that published information may assist industry in searching for new sources of copper. The Miners Queen is one of a few Cascade Mountain deposits selected for prelim¬inary exploration. The investigation was not planned to delineate the ore body. A diamond-drilling program was carried out at the Miners Queen mine in the summer of 1955. Five diamond-drill holes were completed, totaling 628 feet. Two 35-foot shafts were dewatered, and all accessible underground and surface workings were examined.

Jan 1, 1957

By B. S. Covino

The Bureau of Mines, U.S. Department of the Interior, is conducting research to devise substitute corrosion-resistant materials by using ion implantation to form alloyed regions near the surfaces of metals. These alloys were prepared by implanting 25-kev Cr+ and/or Ni+ ions into iron. Their resistance to corrosive attack was evaluated by determining their anodic polarization behavior under potentiodynamic conditions in a solution containing sodium chloride, boric acid, and sodium borate. These electrochemical studies have shown that the general corrosion resistance of ion-implanted alloys was comparable to nominally equivalent bulk alloys. The pitting-corrosion resistance of the ion-implanted alloys was superior to that of iron, although not as good as that of most of the bulk alloys tested.

Jan 1, 1980

By R. G. Nelson

The mechanical properties of low-hafnium, arc-melted, Kroll-process zirconium are presented. The effect of temperature on the ultimate strength, yield strength, proportional limit, elongation, hardness, Young's modulus, electrical resistivity, and impact strength are shown, The effects of cold work and annealing on the tensile properties, bend radius, and formability, as determined by cupping tests, are also given, Tensile properties are compared, in part, to those obtained on earlier graphite-melted zirconium and on crystal-bar zirconium. INTRODUCTION The commercial production of high-purity, low-hafnium bearing zirconium has been achieved, and this metal is becoming available for industrial use. However, there is little published information regarding the physical and mechanical properties of this product; and, since there have been many improvements in the production and arc-melting techniques of zirconium in the past 3 years, it was considered advisable to present the properties of the vastly improved zirconium representative of current production.

Jan 1, 1954

By Geo. Adams Roalfe

THIS PAPER is one of a series being pre¬pared for and published by the United States Bureau of Mines describing, methods of mining and crushing and the costs of operation at commercial crushed-stone plants throughout the country. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators, as well as to the industry as a whole. On the other hand, operating, costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. Acknowledgments The author wishes to acknowledge the [ ]

Jan 1, 1932

By James H. Jolly

Although zinc in the environment is generally considered to be beneficial or benign, excessive amounts can cause deterioration of environmental quality and toxicity problems for some plants and animals. High amounts of zinc in the environment are often associated with anthropogenic activities, mainly those involving zinc production and consumption and those related to the use and disposal of zinc-containing products. To obtain some upper limit parameters on the historical quantities of zinc chat may have entered the U.S. environment from anthropogenic sources, the Bureau of Mines conducted a materials flow study of zinc from the earliest beginning of the domestic industry through 1990 and for the year 1989. For comparative purposes a generalized historical materials flow of zinc for the world was also prepared. The United States was the world's leading producer and consumer of zinc in the 1850-1990 period. In that period, U.S. mines and smelters produced 15% and 20%, respectively, of world output, and U.S. zinc consumption accounted for about one-fourth of the world total. Maximum zinc losses into the environment related to the above production, consumption, and disposal of end use products total about 63 million tons. Dissipative uses and landfill disposal have accounted for about 73% of the potential zinc losses to the environment, followed by mining and smelting 22%, and manufacturing, 5%. At the end of 1990, contained zinc in useful end-products in the United States was estimated to be about 23 million tons. In 1989 slightly more than 1 million metric tons of zinc in new zinc-containing products were added to the domestic pool of zinc in use but in the same year, an estimated 0.9 million tons was dissipated and discarded, indicating only small net gains to the zinc pool of use annually.

Jan 1, 1992

By Irving Hartmann

1. Under the conditions of the tests described herein, the proper use of an incombustible stemming plug of the type discussed prevented ignitions of gas in all tests during the firing of 21 single shots of permissible explosive in cool. In two tests with multiple blasting (four and five shots each) no ignitions resulted. 2. The results of a few tests in this investigation and of numerous tests made previously indicate that fire-clay stemming of the same weight as an incombustible plug provides about the same degree of protection as the plug against gas ignitions during blasting of coal by permissible explosives. 3. The hazard of gas ignition on firing charges of non-permissible 40-percent gelatin dynamite in coal was reduced but not eliminated when the shot holes were stemmed with one or two incombustible plugs or with an equivalent weight of fire clay. 4. On the basis of this investigation, the Bureau of Mines considers the proper use of incombustible stemming plugs of the design tested, under the conditions of the tests described in this paper, to be of equivalent safety as the same weight of fire-clay stemming. This report does not constitute approval or disapproval of the incombustible stemming plugs by the Bureau of Mines. 5. The test data indicate that misfired charges in shot holes stemmed with the incombustible stemming plug cannot be disposed of with certainty by the procedure recommended by the manufacturer. In this investigation the misfired charges failed to detonate in 30 percent of the trials.

Jan 1, 1950

By J. E. Tiffany, Z. C. Gaugler

"In presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 20 and 25 outlining the conditions in use under which, and only under which, the explosive or blasting device is permissible.In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 20 and condition 2 on page 25. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.PERMISSIBLE EXPLOSIVES TESTED UNDER SCHEDULE 17CAn active list of permissible explosives was published in October 1938 as part of Bureau of Mines Report of Investigations 3421, under the title ""Active List of Permissible Explosives and. Blasting Devices Approved Prior to June 30, 1938."" This list included 191 brand names.Changes in the list that have been authorized to June 30, 1939, placed 56 additional brands of permissible explosives on the active permissible list as a result of tests, changes in brand names, or transfer from the inactive list. Fifty-seven permissible explosives were transferred from the active to the inactive list. The brand names of four explosives were rescinded curing the year. The present list contains 18G brand names. The brand names of the Permissible explosives placed on the active list are as follows:"

Sep 1, 1939

By R. L. Soderberg

Large open stopes mined by vertical crater retreat or sublevel s are sometimes backfilled with uncemented sand to support the stope walls and alleviate rock bursts. The failure of bulkheads in two different mines prompted a research project at the Bureau of Mines to prevent a recurrence of these failures. A series of laboratory tests with drains and sand filters was conducted to measure the bulk-head pressures when adequate drainage was maintained. Results showed that bulkhead pressure was reduced to near zero while drains were in operation, as compared to full hydrostatic pressure when drains were blocked or drainage was restricted. A relatively simple, free-draining bulkhead was shown to be adequate.

Jan 1, 1985

By George S. Koch

Several methods of calculating ore grades by diamond-drill sampling in the Homestake mine, Lead, S. Dak., have been evaluated by statistical analyses of assay data. The natural distribution of gold particles, partly masked through sampling and assaying procedures, is probably lognormal. As a consequence of the gold particles being clustered rather than randomly distributed within the ore bodies, (1) more mine samples are needed to obtain a specified precision of mean grade than the number predicted by the standard-error-of-the-mean law; (2) the variance of gold values is not inversely proportional to sample volume, and, therefore, small-diameter drill core yields samples nearly as good as larger diameter core; and (3) sampling at 5-foot intervals provides nearly as good results as sampling at shorter intervals.

Jan 1, 1971