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"One of the functions of the United States Bureau of Mines is to investigate the ability of electrical mining equipment to operate in a gassy mine without danger of igniting explosive atmospheres. To accomplish this purpose, tests are made in which mixtures of gas and air are ignited in the equipment while it is surrounded by explosive atmospheres of the same composition. In such tests, records of pressures developed by the internal ex-plosions are obtained and observations are made of any flames, sparks, or smoke which may issue from bearings and joints. Occasionally the explosion pressures in a mining machine rheostat or a compartment of some other machine reach a value which is judged to be excessive or abnormal.A number of factors are known to influence the explosion pressures, and both German and. British investigators have irate extensive research on their effects. Much of this work had been done with artificial compartment which certain conditions could c held, constant while others were being varied. The U. S. Bureau of Mines has not made any research on a scale to compare with that of the British or German investigators; however, special studies have been necessary from time to time to determine the cause and remedy for high pressures obtained in the routine test of some piece of mining machinery. Thus it has been possible to verify some of tee theories established on a purely experimental oasis by practical tests of machines as actually built for mine use.Some of the factors determined the pressure that will result when an explosive mixture in a compartment or connected compartment is ignited are: (1) The volume of explosive mixture ignited, (2) the percentage of as in the mixture, (3) the amount of coal-dust in the compartment or compartments, (4) the degree of movement or turbulence of the mixture at the time of ignition, (6) tightness of the joints and bearings, (6) the size of opening between, compartments, (7) the distance between the point of ignition and openings, and (8) the cooling, effect of surfaces and of material inclosed in the compartments."

Dec 1, 1929

By H. C. Fuller, E. L. Anderson, F. S. Wartman, M. A. Cook

"This paper gives an account of the production of ductile-grade titanium powder in 100-pound batches by reduction of purified titanic chloride with magnesium, followed by grinding, leaching, and magnetic separation of the reaction product. Apparatus, technique, and methods of controlling product quality are described, and some data on operating costs are given.Although man has been aware of the existence of the element titanium for over 150 years, only recently has the metal itself been available in a form pure enough, particularly with reference to absorbed gases, to allow an estimate of its physical properties. In comparison with mild steel, the tensile strength of titanium is about the same, the resistance to atmospheric corrosion greater, and the specific gravity much less.These properties suggest the usefulness of titanium as a structural material for applications requiring resistance to atmospheric attack and a good strength-weight ratio. Although known reserves of titanium, high-grade enough to be useful at present are not sufficiently extensive to predicate that titanium might supplant iron, aluminum, and magnesium for structural purposes, the reserves are large enough to make its use as a structural material quite feasible in certain fields in which its unique properties are required.As a result of these considerations, the Bureau of Mines station at Tucson initiated an, investigation into the technology of titanium in 1938. First, a critical survey and small-scale trial of virtually all suggested methods7/ for producing the metal was made. The method devised by Kroll8/ seemed best adapted as a source of metallic titanium for, although the purity of the product was not as high as that of products from some other processes, it seemed that modifications in technique necessary for larger-scale production could be made more easily.Essentially, in applying the Kroll process, titanium tetrachloride was reduced to metallic titanium by adding the chloride slowly to molten magnesium contained in a molybdenum-lined iron reaction chamber filled with a protective atmosphere of argon. After reduction to the state of completion desired, the reduction mass and chamber were allowed to cool. Then the chamber was opened, and the reaction mass, consisting of titanium, magnesium chloride, and some unused magnesium, was removed by suitable means. Most of the magnesium chloride and metallic magnesium were removed by leaching in dilute hydrochloric acid. The leached sponge was then ground wet in a ball mill, releached in strong acid, and dried Removal of free iron by magnetic separation completed the production process.Development of the Kroll process by the Bureau was undertaken first at the station at Salt Lake City, in 1942 and the amount formed per run was increased in several steps from a few grams to pounds.9/ In addition to increasing the size of batch over that used by Kroll, the technique was simplified somewhat by the use of unlined reaction vessels."

Aug 1, 1949

By Gary M. Larwood

A study was conducted to determine the amount of transportation equipment required to move 1.2 billion tons of coal in 1985. The Federal Bureau of Mines has investigated a majority of the various practices associated with coal transportation and has gathered information on the regional origin-destination patterns, methods of movement, equipment stocks, rate structures, and operational capacities of the most important modes of coal haulage currently in use. Models employing this information were developed to establish the origin-destination pattern for 1985 coal shipments, estimate practical tonnage capacities for selected coal hauling rivers, develop modal shares for both unconstrained (by river capacity) and constrained cases, and present a range of coal transportation equipment requirements for given sets of constraints. Projected transportation shares for rail ranged from 63.7 to 72.3 percent, and for river, from 8.8 to 16.4 percent. Other coal transportation modes (truck, conveyor, Great Lakes, and tidewater) are expected to retain their historic shares of coal traffic. Equipment estimates were made for 1985 rail and water transportation based on 1973 average and best practice. Average practice estimates ranged from 675,000 to 710,000 hopper cars (100-ton) and 3,100 to 5,940 barges (1,400-ton equivalent). Best practice estimates ranged from 126,000 to 142,000 hopper cars and 1,750 to 3,450 barges. Full implementation of 1973 best practice by 1985 is unlikely.

Jan 1, 1976

By Robert M. Busche

[Recent developments in the gasification of coal, both by the Bureau of Mines and American industry, have intensified interest in the thermodynamic and kinetic principles necessary for understanding the reaction mechanism and rates and the physical changes that take place. In the course of a Bureau of Mines study of the kinetics of coal gasification at the Synthetic Liquid Fuels Demonstration Plant, Louisiana, Mo., a bibliography of approximately two references was compiled. They are listed n this publication and refer both to American and foreign sources.]

Jan 1, 1952

By Gilbert M. Farrior

Tests of resistance to molten metals , to oxidation at elevated temperatures , and to various chemical reagents were made for a series of compositions in the TiB₂ - CrB₂ subsystem . In reaction with molten metals , there was no noticeable difference in reaction of the various compositions in the ( Ti , Cr ) B₂ series . The oxidation tests were ( 1 ) a rising - temperature test in which the specimen temperature was increased 4° per minute to 1,200 ° C and ( 2 ) a constanttemperature test in which the specimen temperature was held constant at 1,000 ° C. Compositions near Tio.6 Cro.4 B2 had the best oxidation resistance . Ti。.6 The chromium- rich alloys showed marked superiority to the titanium- rich alloys in resistance to corrosion by the chemical agents investigated . The chemical reagents used were sulfuric , nitric , and hydrochloric acids and sodium hydroxide of different concentrations .

Jan 1, 1964

By W. E. Pittman

The Bureau of Mines, as part of its Health and Safety Technology Program, is conducting research on the use of ground penetrating radar (GPR) for mine hazard detection. GPR offers a possibility of mapping immediate below-surface geologic conditions, including faulting and other anomalies, thereby exposing potential safety hazards to miners. This report summarizes a literature review of the current status of GPR research in and outside the Bureau.

Jan 1, 1984

By W. K. Tolley

The Bureau of Mines is testing super critical fluids as solvents to selectively extract valuable components from complex matrices. Materials recovered during supercritical fluid extraction are often highly purified. Using laboratory apparatus designed specifically for supercritical fluid research, Bureau re-searchers have measured the solubility of titanium tetrachloride (TiCI4) in supercritical, liquid, and gaseous carbon dioxide (C02), CO2, a commonly used supercritical fluid, is inert, inexpensive, and nontoxic. Supercritical CO2 formed a single phase with TiCl4 at 45° C and 1,500 psig. When the solution was heated at constant pressure beyond 55° C, TiCl4 precipitated from the fluid. Results showed that TiCl4 solubility in supercritical CO2 is not controlled by the vapor pressure of the solute.

Jan 1, 1989

By E. R. Palowitch

This report is the result of a series of coal-cleaning tests using a dense-medium cone-type washer. Detailed results are given for 2 tests using a magnetite medium and 4 tests using a pulverized-refuse medium. Approximately 120 float-and-sink tests and over 500 separate chemical analyses were made in conjunction with these tests. In these tests higher recovery efficiencies and sharper separations were obtained when using a magnetite medium, especially on coal sizes below one-half inch. When sizes above 1 inch at low specific gravities of separation are cleaned, the pulverized refuse medium compared favorably with the magnetite medium.

Jan 1, 1956

By R. H. Schutz

TO ASSIST users in the selection of reliable and satisfactory respiratory protective devices, the Bureau of Mines bas established five schedules of minimum performance requirements for the approval of respirators. The current revisions of these schedules3 include 13D for self-contained breathing apparatus, 141F for gas masks, 19B and the amendments to 19B for supplied- air respirators, 21B for dust, fume, and mist respirators, and 23B for chemical cartridge respirators. Copies of these schedules may be obtained from the Bureau of Mines, Publications Distribution Section, 4800 Forbes Avenue, Pittsburgh, Pa., 15213. Approval tests on respirators are performed only at the request of the manufacturer4 of the respirator and at his expense. If the device meets the approval requirements, a certificate of approval is granted on the complete respirator. This certificate states that as long as the respirator is manufactured as originally approved, or in accordance with any changes covered by an extension of the original approval, the manufacturer may advertise and sell his respirator as being approved by the Bureau of Mines. Many industries and regulatory agencies require that respirators approved by the Bureau of Mines he used where respiratory protection is needed. The Bureau of Mines, however, has no regulatory power over the use of the respirators that it approves. It acts as an impartial testing agency to insure the availability of suitable and safe respirators.

Jan 1, 1966

By T. M. Garland

This report presents a more extensive perspective of the calculated profitability of developing and producing crude oil and associated natural gas by primary methods from selected onshore areas of the United States. Estimates were made for cost of drilling, completing, equipping, and producing oil wells at four depths in seven onshore producing areas. A computer program was developed for calculating the discounted cash flow rate of return for the 64 different models in each area resulting from varying the oil-producing rate and production decline rate. The results of these calculations provide data that vividly illustrate the change in rate of return to changes in well depth, initial producing rate, and production decline rate, as well as to variations in development cost and operating expense. Cost per barrel of oil produced in terms of annual cost and total cost is also discussed. Included in the report are explanations of the method of determining costs and the procedure used for profitability analysis. Summaries of all cost estimates and results of profitability analyses are presented in the appendix in tabular form for each of the seven producing areas.

Jan 1, 1972

By Lloyd H. Banning

With the ever-increasing demand for energy in all forms, electrical energy generated from geothermal resources could become an important energy source in the next few decades. Geothermal fluids, which contain appreciable quantities of dissolved salts and gases, are generally corrosive to materials of construction. Since data on corrosion of materials in geothermal brines is limited, the literature was surveyed through February 1972 to obtain a compilation of information on corrosion resistance of aluminum and its alloys, copper and copper-base alloys, carbon steel and cast iron, stainless steels, chromium-iron alloys, nickel-and cobalt-base alloys, and titanium in heated brines including sea water.

Jan 1, 1973

By Curt D. Edgerton

This study was made to determine trends in fresh water usage by California petroleum refineries, to forecast fresh water requirements to 1975, and to evaluate water conservation practices. Statistical data used in the study were obtained largely from published sources and from records of selected companies. An adequate sampling of the State's refining capacity was obtained, and the data were extrapolated to the total California refining capacity. A breakdown of the data was then made on the basis of the following refining regions: (1) the Los Angeles Basin and Southern Coastal region, (2) the Southern San Joaquin Valley, and (3) the San Francisco Bay area. An unpublished forecast of crude oil input to refineries by a major oil company operating on the West Coast was used as a basis for predicting fresh-water usage. The 1963 fresh water intake by California petroleum refineries was 84 million gallons per day. This is expected to increase to 128 million gallons per day by 1975. The fresh-water to crude-oil ratio is increasing in all regions except the Southern San Joaquin Valley. At present, the supply of fresh water available to almost all of the State's petroleum refineries, mostly from surface sources and company-owned wells, is adequate, although shortages may develop within the foreseeable future. Present conservation methods are centered around the following four objectives: (1) minimum intake of fresh water of the lowest possible quality commensurate with sound technologic practice; (2) optimum recirculation; (3) proper treatment before discharge; and (4) substitution of air cooling for water cooling.

Jan 1, 1965

By J. L. Wiley

[NOTE. - P before the number indicates that the ab tract appears in patent section. Abstract numbers without. P appear in literature section. A Abietic acid, hydrogenolysis - 404 Acetone, recovery - P-4024 Acetylacetonate catalyst - P-3352, P-3664, P-6067 Acetylene, production - P-2556, P-3169, P-4064, P-4221, P-4222, P-5002 Acid catalyst - P-4584 Salts - P-4555 See also Specific acid. Acid treatment. See Procedure. Adsorption. See Hydrogen, adsorption. Agitation. See Equipment, agitators; Procedure. Alcohols: Decomposition -1128 Hydrogenation - P-3288, P-4743 In motor fuel - 1486]

Jan 1, 1952

By Horace C. Porter, F. K. OVITZ

The various fuel investigations that were being carried on by the technologic branch of the United States Geological Survey were transferred by law on July 1, 1910, to a new federal bureau, the Bureau of Mines, that was authorized to continue the investigations and make public reports of the results. In consequence of this transfer, the following report is published as a bulletin of the new bureau. The United States Geological Survey had been engaged in analyzing and testing coals, lignites, and other mineral fuel substances under authority given by act of Congress. This work, now centered at the experiment station at Pittsburg, Pa., had its beginning in the operations of the coal-testing plant erected at the Louisiana Purchase Exposition in St. Louis, Mo., in 1904. The results obtained at that plant showed that the work of determining the fuel value of the coals and lignites in the United States with a view to increasing efficiency in their utilization would be incomplete if it did not include systematic physical and chemical researches into the processes of combustion. Hence in its later investigations the Survey carried on such re- searches, concentrating attention on those lines of inquiry which promised results of greatest economic importance. This bulletin is a report on an investigation of the volatile matter in several typical coals-its composition and amount at different tem- peratures of volatilization. As the investigation is still in progress and will doubtless include other coals than those already examined, the bulletin may be considered a preliminary report, stating the prob- lems studied, the methods used, and the results thus far obtained.

Jan 1, 1910

By Wilbert J. Huff

The work of the Explosives Division, Bureau of Mines, United States Department of the Interior, for the fiscal year ended June 30, 1939, is described in the following pages. This paper is the fourth of a series of annual reports covering the activities of the division since July l, 1936.

Jan 1, 1940

By G. W. Elger

The Bureau of Mines investigated the conversion, at both laboratory and pilot plant scale, of a low-grade ilmenite to chlorination-grade feedstock that could substitute for imported rutile used to produce titanium tetrachloride. The concentrate was derived from the Tahawus, NY, lode deposit of ilmenite-magnetite in rock that contains anorthosite and gabbro. Charges of the ilmenite concentrate, containing 46.6 wt pct Ti02 blended with soda ash, were carbothermically reduced in an electric arc furnace, which separated most of the iron and left a high-titanium slag. However, the slag contained Ca, Mg, and Mn constituents that rendered the material unsuitable for continuous chlorination by causing plugging problems. After being ground and pelletized, the slag was reacted with S02 and air at 7000 to 9000 C, which selectively converted the harmful impurities to soluble compounds that were removed in a subsequent water or dilute HCI leach. In laboratory tests, the combined levels of harmful impurities were decreased from 5 to as low as 0.5 wt pct in leached slags. In pilot plant tests, leached slags sulfated at a rate of 10 lb/h averaged 85.5 wt pct Ti02 with pertinent impurity levels averaging 1.86 wt pct. The leached slag was successfully chlorinated in a laboratory fluidized-bed reactor at 9500 C to extract titanium as TiCI4.

Jan 1, 1986

By J. F. Neill, O&apos

[The Cartersville mining district is in Bartow County, Ga., about 40 miles northwest of Atlanta. Barite, limonite, ocher, amber, hematite, and, manganese oxide ores have been produced from the strict since about 1840. In the search for a possible source of manganese ore, Bureau of Mines engineers made a preliminary study of the district from September 1950 to January 1951. During this study 139 deposits were examined, and many mineral exposures were sampled. Manganese mineralization occurs as fine oxide and concretionary pellets in residual clays, as fine oxides in umberous clay, in brown-iron deposits, and in a limited quantity in mud ponds and Jig-tailing piles. The future supply of ferrograde manganese ore from the district, using current mining and benefication methods, appears limited to the recovery of the hard manganese ores deposits. Rough estimates indicate a reserve of manganese-bearing clays of about 8,000,000 long tons. This type of deposit has been extensively exploited and the larger deposits mined out to depths of from 50 to 200 feet. The remainder of these deposits are low grade, are covered with deep layers of colluvium, or lie below the ground-water table. Any future production from this source will require systematic prospecting, improved concentration, and an increase in the price of concentrate.]

Jan 1, 1954

By T. A. Henrie

The Federal Bureau of Mines has investigated methods of sodium reduction of titanium chlorides to produce high purity titanium metal (14).4/ This investigation was made to obtain a better understanding of the reactions involved in sodium reduction of titanium chlorides and was part of the Bureau's activities toward improving the technology of titanium. Theoretical and experimental evidence show that sodium reduction of titanium tetrachloride occurs by stepwise reactions. The first stage reduction between sodium vapor and vapors of titanium chlorides produces titanium di-and trichlorides which subsequently condense with sodium chloride to form a salt mixture. The second stage reduction takes place in the condensed salt mixture between sodium and titanium subchlorides. Final reduction is a heterogeneous reaction between two separate phases, the a phase which consisted of sodium dissolved in sodium chloride and the ß phase titanium subchlorides dissolved in sodium chloride. The mechanism of the heterogeneous reaction between these phases is electrochemical in nature. The model proposed is a galvanic reaction at the interfacial region.

Jan 1, 1960

By R. A. Hatch

The United States depends mainly on foreign imports, principally India, for an adequate supply of sheet mica suitable for its many uses in the electrical and electronics industries. Sheet mica has, in fact, played an indispensable role in developing these industries,4/ and, in turn, the products of these industries (radio, radar, electric motors, and many others) have become indispensable to the military forces. Because or these conditions, sheet mica in its better qualities long has been classified as a strategic and critical material, and from this stems the wide-spread interest in substitute materials of which synthetic mica is one potential type. The United States Departments of the Navy and the Army entered into a cooperative agreement with the Bureau of Mines in 1947 to study ways and means of synthe-sizing and growing mica crystals. This is one of a series of reports5/ that describe the results of this program.

Jan 1, 1956

By Harry V. Makar

As part of a continuing research program for conserving domestic mineral resources, the Bureau of Mines is investigating new and improved scrap identification techniques to improve sorted mixed scrap purity. This report focuses on various classes of wrought and cast copper alloys produced with recycled scrap. Based on a survey of the literature, principal alloys, such as the brasses and bronzes, are examined with respect to impurity elements and their effects on metallurgical behavior. Effects of elements such as lead, antimony, iron, chromium, and aluminum are discussed. The metallurgical effects described include hot shortness, fire cracking, and undesirable phase transformations.

Jan 1, 1985