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By H. Asgari, A. G. Odeshi, J. A. Szpunar

In the present study, the dynamic response of AZ and AE cast magnesium alloys to shock loading, are compared for strain rates ranging between 900 and 1200 s-1. Texture measurements showed that after shock loading, the (00.2) basal texture component of both alloys was strengthened. However, the strengthening magnitude was higher for AE samples. Also, it was observed that the twinning fraction decreased in both alloys with increase in the amount of alloying elements. In addition, cracks are formed at the interface between matrix and second phase particles in the AZ alloys. However, crack nucleation and fracture in AE alloys occurred at the sites where twins accumulated. Furthermore, analysis of the dynamic mechanical behaviors showed that the ductility of AE grade is higher than that of AZ alloy for all strain rates used in this research. This difference was explained by differences in deformation mechanisms of these alloys.

Jan 1, 2014

By M. A. Golozar

Partially stabilized zirconia (PSZ) has been proven to be an excellent candidate as a thermal barrier coating (TBC) for hot sections in, for instance, heat or internal engines and gas turbine parts. The main functions of these coatings are reduction of heat losses, reduction of fuel consumption, increasing efficiency, and extending durability and life. One of the main problems involved is wear behavior in the development of such coatings for these applications. Using air plasma spraying (APS) technique, conventional and nanostructured 8 wt % yttria partially stabilized zirconia (Y-PSZ) coatings were deposited on austenitic stainless steel (AISI 304) disc-shaped substrates. The coated substrates were subjected to pin-on-disc wear tests, using 10 mm silicon nitride and zirconia balls as the pin. The coefficient of friction was recorded in real time. The weight loss of coated substrates was measured. Coatings were characterized before and after being subjected to wear testing by various techniques including optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and X-ray diffraction (XRD). Effects of various experimental parameters such as wear distance, test temperature, and counterface material were also investigated. Results obtained revealed that, regardless of experimental conditions applied, the nanostructured zirconia coating shows better wear and tribological properties than those of the conventional one.

Jan 1, 2005

By C. M. Acuna, M. Sherrington

In high temperature processes thermodynamic equilibrium is assumed and therefore chemical potential of elements, among the condensed phases, have to be the same. In such situation impurities distribute accordingly and their fractional distributions are affected by the masses of the coexisting phases. It has been claimed Teniente Converters perform quite well for smelting high impurity concentrates, especially in respect to volatilization and/or slagging. Production of high matte grade near white metal composition, requiring moderate oxygen enrichment in the process air, results in a huge mass of gas and therefore a high fraction of impurities report to it. Similarly, by recycling different sources of slag, flue dust or other materials, the mass of the final slag is increased and so do the masses of impurities reporting to the slag. Nevertheless, above a certain level the recycling of smelter byproducts is no longer feasible and the cycle has to be halted, unless higher impurity mattes are accepted. Although the process might be continued during converting and refining, lengthy and expensive measures have to be taken if suitable anode copper for electrolytic refining is to be achieved. In the present study samples of high arsenic matte grade and slag were obtained on a pilot scale. The matte samples, on the order 75%Cu, were equilibrated with slag at varying ratios in magnesia crucibles under CO/C02 atmospheres at 1523 K. After 24 hours equilibrium matte and slag were rapidly solidified and analyzed by copper, sulfur, iron and arsenic. Furthermore, industrial samples of matte and slag, in the order 75%Cu at 1523 K, were obtained via a special quenching sampling device to determine the association of copper and suspension of matte and copper in slag. Based on the results, the distribution coefficient of arsenic between slag and matte was evaluated along with copper species in slag and the fractional distribution of arsenic, in the coexisting phases, was determined as a function of the ratio mass of slag to mass of matte.

Jan 1, 2007

By J. H. Reiss, D. F. Bruhn, Idaho National Laboratory, Y. Jiao, D. W. Reed, Y. Fujita, D. L. Daubaras

"Bioleaching offers a potential approach for recovery of rare earth elements (REE) from recyclable materials, such as fluorescent lamp phosphors or degraded industrial catalysts. Microorganisms were enriched from REE-containing ores and recyclable materials with the goal of identifying strains capable of extracting REE from solid materials. Over 100 heterotrophic microorganisms were isolated and screened for their ability to produce organic acids capable of leaching REE. The ten most promising isolates were most closely related to Pseudomonas, Acinetobacter and Talaromyces. Of the acids produced, gluconic acid appeared to be the most effective at leaching REE (yttrium, lanthanum, cerium, europium, and terbium) from retorted phosphor powders (RPP), fluidized cracking catalyst (FCC), and europium-doped yttrium oxide (YOEu). The Acinetobacter isolate, BH1, was the most capable strain and able to leach 33% of the total REE content from the FCC material. These results support the continuing evaluation of gluconic acid-producing microbes for large-scale REE recovery from recyclable materials.INTRODUCTIONAn enhanced recovery, substitute, reuse or recycle paradigm is important for balancing the supply and demand of critical materials (DOE, 2011). The recovery of rare earth elements (REE) from recyclable materials is an important component in this model. REE are used in a variety of modern products. For example, neodymium, europium, terbium, dysprosium, and yttrium are important for applications such as permanent magnets, lamp phosphors, rechargeable batteries, etc. (Binnemans, Jones, Blanpain, Van Gerven, Yang, Walton, & Buchert, 2013; DOE, 2011; Graedel, Harper, Nassar, & Reck, 2013). Cerium and lanthanum are used in glass polishers and additives in fluidized cracking catalysts (FCC)."

Jan 1, 2016

By J. E. Zajic, E. A. Sullivan, T. R. Jack

"The release of vanadium, iron, nickel and titanium from the cokes produced in the upgrading of Alberta oil sands bitumen has been assessed for simple chemical leaching processes. Flexicoker coke (Exxon Engineering and Research) has been found to be quite amenable to the recovery of vanadium as well as nickel, iron and some titanium by these techniques, whereas fluid coker coke (Syncrude) and delayed coker coke (Great Canadian Oil Sands) are relatively intractable under the mild conditions employed. The factors affecting the extent of vanadium release are discussed in terms of the surface area accessible, the wettability of the material, and the chemical and physical composition of the coke particles in each case.A novel biologically assisted heap leaching procedure for f1exicoker coke is also described, based on the growth of the chemolithotrophic bacteria, Thiobacillus thiooxidans A TCC 8085, on elemental sulphur added to the coke."

Jan 1, 1980

By David Rahal, Saul Ortiz, Maria Escobedo

The general trend in the minerals industry is towards the processing of fine grained, disseminated mineral deposits. This has led to an increase in the number of fine/ultra-fine grinding installations using stirred media mills. The challenge is that both the equipment type and the mineralogy of the deposit have an effect on specific energy consumption. Fresnillo PLC recognized this issue and addressed it by providing samples for testing in a laboratory regrind system. The objective of the test program was to determine the specific energy required to achieve a product size of 10 µm (P80). A specific energy plot was generated for both a lead and zinc flotation concentrate. It indicated that 34 kWh/t and 51 kWh/t were required for the two samples (Pb and Zn respectively). This difference highlights the effect of mineralogy on the energy required for fine grinding. The regrind feed and products were submitted to a range of basic mineralogy tests to quantify the mineral differences that could have changed the specific energy requirements. These tests provided general mineralogy, documented optical textures, and provided particle size microscopy. The lead concentrate was found to contain significant amounts of silicates in addition to the dominant sulphide, pyrite. The zinc concentrate was determined to be mostly sphalerite with minor amounts of quartz, chalcopyrite, pyrite and galena. The material testing results illustrate the importance of basic mineralogy studies in conjunction with comminution testing to determine specific energy consumption.

Jan 1, 2016

By R. Thierbach, W. Kahnt, Oberthür. T., D. Eisenburger, V. Gundelach

ABSTRACT: The ground penetrating radar (GPR) method was used in a platinum mine in Zimbabwe by members of the Federal Institute for Geosciences and Mineral Resources (BGR). The measurements were carried out in boreholes and drifts. Electromagnetic re?ections from a fault that consistently trends parallel to the mineralization zone permitted the mapping of the economically minable parts of the deposit. An introduction is given to the geology of the studied area and the application of the GPR method. The electrical parametres of the rocks are measured in situ, the GPR measurements are displayed with radargrams, and the visible structures are explained in illustrations.

Jan 1, 2010

By M. C. Villeneuve, P. A. Siratovich

We present an integrated analysis of laboratory-based thermally induced fracturing and results of numerical models to give insight to the role of thermal shock fracture on geothermal reservoir rocks. Thermal stimulation is a reservoir permeability enhancement technique applied to commercial geothermal reservoir rocks to enhance fluid injection capabilities for spent power plant working fluids. The process is well known to enhance permeability but the thermodynamic and physical constraints of the process are less certain. In an attempt to constrain the interaction and the ideal conditions that lead to permeability enhancement, experimental procedures were carried out to mimic the conditions that a reservoir rock would experience during a thermal stimulation using temperature differentials ranging from 50-300°C. Samples underwent such thermal gradients under controlled laboratory conditions and were characterized for the changes to permeability, porosity, ultrasonic velocities, dynamic elastic moduli and petrological changes. The thermal stimulation was simulated in a FLAC2D thermal numerical model to investigate the nature of the thermally induced changes in the sample. The development of this model also allows us to investigate the relationship between geological characteristics and the ability to thermally stimulate any type of rock. The results indicate that numerical thermal shocking experiments are corroborated by laboratory-based results. The implication of this study is that the refined numerical models present an insight to the conditions and constraints under which thermal stimulation can prove to enhance permeability that could not be gained through purely laboratory-based studies.

Jan 1, 2015

By M. Leijd, K. S. Forrester, M. Saxon, M. Oczlon

This paper provides an introduction to wet high intensity magnetic separation (WHIMS) and its successful application to the beneficiation of rare earth element (REE) enriched eudialyte. The analysis includes an in-depth reporting of the deportment of key elements as well as a statistical interpretation of the relative importance of operational parameters including magnetic field intensity, flow velocity, and matrix loading density. Conclusions are drawn on the relative success of the technology, potential areas for process improvement, and the research direction that continues to be investigated. Three original equipment manufacturer (OEM) technologies were subjected to a series of screening and characterization tests to identify the optimal operating parameter set to magnetically beneficiate eudialyte from Norra Kärr, Sweden. Upon the completion of the characterization test it was apparent that the Metso HGMS technology was superior with respect to REE recovery and gangue rejection for the Norra Kärr composite. The Metso HGMS was then subjected to a series of verification tests to confirm the repeatability and reproducibility of the system.

Jan 1, 2014

By A. B. Luz, A. Middea

Kaolin clay is heavily used in the paper industry as a coating and a filler, however to attend the specifications required by the industry it has to be processed. Kaolin is also used as a filler and pigment in various materials, such as paint, plastic, rubber etc. Some crude kaolins as mined in Northern Brazil, contain colored impurities such as iron oxide and rutile/anatase. These minerals normally are stained by iron and as a result vary from yellow to dark brown in color. The kaolin beneficiation process used in that region consists mainly of degritting, fractionation by centrifuge, high gradient magnetic separation, bleaching with sodium dithionite, filtering and drying. In some kaolin clays from that region, titanium oxide mineral occurs in fine fraction, lower than 2 µm, and so making the industrial process more difficult. The conventional method of classification and bleaching with sodium dithionite, markedly improves kaolin brightness, but has little effect on anatase removal. In fact, the fine fractions resulting from centrifugation, in many cases contain more TiO2 minerals than the original whole clay or the coarse fraction. The present work is related to purification of Brasilian kaolin clay using selective flocculation for removing its colored impurities such as rutile and anatase. This study was conducted in bench scale and it consisted of: blunging, screening, conditioning and decantation. Overflow and underflow resulting from settling of the flocculated material were then dried and submitted to TiO2 and brightness analyses. Sodium polyacrylate and sodium silicate were added to kaolin clay suspension as dispersant and ammonium hydroxide was also added to adjust pH. After degritting, the minus 44 µm fraction was conditioned with hydroxamate surfactant and then polymers of different anionic charge were added. The influence of pH and type of polymer on efficiency of TiO2 removal, as well as kaolin mass recovery were studied. The results obtained in the present study are quite promising. It was possible to diminish TiO2 content and increase kaolin brightness (ISO) from 82 to 88%.

Jan 1, 2004

By S. Malkin, Z. Shi, H. Attia, D. Chellan

An experimental investigation is reported on creep-feed grinding of a nickelbased alloy (IN718) using conventional aluminum oxide grinding wheels. Straight surface grinding expe.riments were conducted on nickel-based alloy blocks over a wide range of grinding conditions with straight oil as- grinding fluid applied at high pressure. Grinding power, forces, workpiece surface roughness, and radial wheel wear were measured. Specific material removal rate as high as 64 mm2/s was Used without burning the workpiece, which can be attributed to the extremely low specific energy of 12.6 J/mm3. It was found that the grinding wheel under the present test conditions had a strong capability of self-sharpening as indicated by the stabilized power, forces, and surface roughness after an initial short transient.

Jan 1, 2006

By Nick Vagenas

"Loading and transportation are important activities of the mining process. Automation of these activities in underground hard rock mining has been discussed for a long time. This paper deals with the performance evaluation of a prototype automatic Load-Haul-Dump (LHD) vehicle (a 7-ton GHH LF LHD model) operating in Zinkgruvan mine, Sweden. The purpose of the data analysis is to evaluate the operational and maintenance characteristics of the automatic LHD system in the mine. Graphical and numerical methods have been used for the statistical analysis of the data. IntroductionDuring the past years, the idea of integrated automation and tele-operation on Load-Haul-Dump (LHD) machines (Fig. 1) has attracted considerable interest in the Swedish mining industry. This is mainly due to the demand for improvement in the working environment and due to the rapid development of economic and reliable microprocessors for mining vehicles. Several advantages can be foreseen with the application of a Remote-controlled/Automatic LHD (RAL) system in underground mining. Some of them are (1)':• better utilization of working hours;• less interruption in production at shift changes;• better operational control of a fleet of vehicles;• improved safety; and• one operator may be able to operate more than one vehicle simultaneously."

Jan 1, 1993

By S. S. Rahman, A. Gholami, M. A. Aghighi

"This paper provides a foundation for studying the growth of fractures in presence of other discontinuities and different anisotropies of low permeable hydrocarbon formations and helps to improve the design strategies for multistage fracturing.The multistage fracturing technology has recently been used to exploit low permeable hydrocarbon reservoirs. However, the mechanism of hydraulic fractures interaction and the impact of local heterogeneities on ultimate trajectory of the growing hydraulic fractures are not yet understood in depth. A fully coupled poroelastic Finite Element based model is developed to investigate the mixed mode propagation behaviour of growing hydraulic fractures. This model takes advantage of an explicit representation of the fracture which enables us to take the effects of rock and fluid related parameters into account. Moreover, impact of fracture geometry and leak-off phenomenon is investigated. The refined mesh around the crack provides the added advantage of more detailed stress distribution, pore pressure change and back stress in the vicinity of the fracture and in particular at the fracture tip. The potential deviation propensity of the fractures is evaluated based on the fundamental rule that fractures propagate perpendicular to the direction of the minimum horizontal stress.This study shows that pressurization of transverse hydraulic fractures results in the reorientation of local principal stresses, particularly in vicinity of fracture tips. Variation of flow patterns clearly influences the evolution of shear stress around the fracture tips which will potentially lead to mixed-mode I and II fracturing and consequently, fracture deviation. The presence of local heterogeneities such as preexisting fissures and/or fractures is a main source of such pore pressure induced stress redistribution and reorientation and potential deviation of hydraulic fractures.Most existing models ignore or simplify the effect of pore pressure/stress coupling as well as the fracture geometry and fluid flow within the fracture. Also, the fluid leak-off from the hydraulic fracture into the formation, which is a controlling factor in fracture growth, is often considered using analytical models. Taking advantage of a fully coupled porelastic model along with an explicitly discretized fracture, this study provides a more realistic insight into the complex fracture propagation processes of multistage fracturing operations particularly in presence of reservoir geo-mechanical complexities."

Jan 1, 2015

By G. Heinrich

Size by size recoveries and pentlandite liberation data from image analysis were used to evaluate plant tests of pentlandite flotation and pentlandite/pyrrhotite middlings flotation from pyrrhotite in a circuit treating low grade magnetic intermediates at the Strathcona Mill. Raising the pH with lime gave improved selectivity for liberated pentlandite but there were major losses of middlings unless the circuit was pulled hard indicating the need for finer regrinding. However, size by size recoveries at the normal regrind showed that, while the pentlandite recovery improved in the finer ranges, the pyrrhotite recovery also increased leading to little selectivity in any size range. A much finer regrind gave greatly improved selectivity in all size classes suggesting that 'surface polishing' as well as liberation effects were being seen. Using liberation data from image analysis of the products, surface polishing accounted for over 99 % of the improvement in selectivity. Unreasonable recoveries of more highly liberated particles were observed for liberation analysis by volume fraction but showed the expected trend in recovery when the analysis was based on surface liberation. The surface liberation data showed that the improved pentlandite recoveries after finer regrinding were to more than 90 % caused by improved liberation with the remainder contributed by surface polishing effects. The practical implications of this work are that i) the comparison of particle grades with product grades allows to estimate the effect of regrinding on co-flotation/entrainment, ii) surface liberation models should be used for evaluating recoverabilities by flotation and iii) regrind circuits may be set up to ensure that all particles go through the mill or that only the coarse fraction is reground depending on the surface scrubbing found to be required.

Jan 1, 1993

By D. G. Cerigo, D. M. Bryce, P. H. Jennings

This paper summarizes the results of an experimental and economic study undertaken to evaluate the feasibility of treating an oxidized orebody of about 10 million tons, grading about 0.75 per cent copper, by agitation leaching and by percolation leaching.

Jan 1, 1968

By W. A. MacWilliams, R. G. Reynolds

"This paper describes, for the first time, a patented method of extracting sodium sulphate from a natural deposit in Western Canada. The method resembles, but is not, strictly speaking, solution mining. The fact that a plant based on this method has been in successful operation since late 1969 will be of added interest. The deposit in question is located near Metiskow, Alberta, and conventional surface recovery methods could not be applied because of heavy concentrations of mud. Considerable pilot work went into the separation and recovery process on which the plant operation is based. The history of the industry is covered briefly as background to this development. Today it is clear that the method has broader application within the industry and, in concept, may generate interest in many other applications."

Jan 1, 1973

By A. L. Holloway, N. M. Soonawala, L. S. Collett

"Since the late 1970s, a major R&D program has been under way in Canada to assess the concept of disposing of nuclear fuel wastes in deep plutonic rock. Atomic Energy of Canada Ltd . (AECL), a federally-owned corporation, has been given the responsibility of directing this research (Rummery et al., 1983).The Underground Research Laboratory (URL), constructed in a granite pluton 15 km east of Lac du Bonnet, Manitoba (Fig. 1) is a major component of the Canadian Nuclear Fuel Waste Management Program. A diverse geotechnical experimental program is being carried out during both the construction and operating phases of the URL. This program involves detailed geological mapping, rock mechanics and hydrogeology studies, and geophysical surveying, to characterize the rock mass surrounding the shaft, and it has been described by Simmons et al. (1983). As part of the construction-phase program, ground-penetrating radar (GPR) surveys are being carried out during excavation, in an attempt to delineate fractures both ahead of the excavation and behind the walls of the excavation. This paper presents the results of surveys performed during shaft excavation and describes a procedure for plotting the data.Ulricksen (1982) cites examples of radar surveys to evaluate surficial deposits, such as peat, sands and gravels, and cavity detection in subsurface hard rock. Fowler (1981) used radar for fracture and clay vein detection in coal seams.In Canada, pioneering work in GPR has been done by Annan and Davis since the mid-seventies (Annan and Davies, 1976). Their work concentrated on problems relating to permafrost in the Arctic ."

Jan 1, 1986

By S. Pietruszczak, G. Su, T. S. Nguyen, E. Haghighat

"In this paper, the mechanical properties of Tournemire argillite are modeled using a mathematical framework which employs the microstructure tensor approach (Pietruszczak & Mroz, 2000). The experimental data incorporates the results of a series of triaxial tests (Abdi & Evgin, 2013) conducted at different orientation of bedding planes relative to the direction of loading. First, a plasticity framework is presented which involves the specification of the conditions at failure as well as the description of the irreversible deformation process. Later, a systematic procedure is outlined for identification of material functions/parameters involved. The paper is concluded by presenting the results of numerical simulations of the triaxial tests. It is demonstrated that the model can adequately reproduce the primary effects of anisotropy in the stable deformation regime as well as the onset of fracture.INTRODUCTIONThe understanding of the mechanical behaviour of argillaceous rocks is important in many types of geotechnical projects, including petroleum extraction, carbon dioxide sequestration as well as deep geological disposal of radioactive waste. In all these cases, the primary concern is the onset and propagation of damage due to excavation, transport of pore fluids and/or elevated temperature. The Canadian Nuclear Safety Commission (CNSC), Canada’s nuclear regulator, will be responsible for the licensing of future deep geological repositories. In order to evaluate the safety of deep geological repositories, CNSC staff keep abreast of scientific developments by collaborating with national and international partners on experimental and theoretical research on the long-term performance of those engineered and natural barriers. Through that collaboration, the CNSC has access to data resulting from experiments performed at different Underground Research Laboratories (URL). Such an URL is situated in Tournemire, France, in an argillaceous rock formation, the Tournemire argillite. The Tournemire argillite is characterized by the presence of closely spaced bedding planes and exhibits a strong anisotropic behaviour, so that its strength as well as deformation properties are directionally dependent."

Jan 1, 2015

By B. J. Cunliffe

"Filter cloth in the mining industry is an ambiguous title asthis suggests filter cloth use from underground ventilation to the refining processes. The time allowed for this paper would be better served in con-centrating on vacuum filters common to all mine mills and to offer some simple guide lines to the mill metallurgists in the choice of filter cloth for this type of filter.The requirement of the filter cloth is to separate solids from liquids under a vacuum head by forming a permeable layer of solids or cake, through which liquids can flow until the panel or disc sector leave the slurry tank and to continue to pass residual moisture from the cake formed during the cake drying cycle, and to discharge the cake on air-blow so that the cycle can be repeated.Whilst the mill metallurgist should not be expected to under¬stand all aspects of filter cloth manufacturer, it is however, advantageous for him to understand a little of the textile language associated with filter cloth for his own protection against ""trial-and-error"" methods, which are both time consuming and costly.If improvements are to be made over existing filter cloth in use an examination of the limiting factors of the cloth used should be made and the major causes for removal determined, e.g. cloth blinding, high moisture in cake, poor cake discharge on air blow, mechanical damage to cloth.As each of the limiting factors mentioned has a bearing on the choice of fibre used, the yarn type and weave of a suitable cloth, an under-standing of these points will assist the mill metallurgist in avoiding repetitive trials offering little degree of success."

Jan 1, 1971

By J. G. Speight

Laboratory studies indicate that autogenous heating of low-rank coal can be prevented by a prior treatment which involves immersing the coal for short (5-15 min.) periods in an inert liquid at temperatures between ~ 350° and 400°C. Such "carbonization" effectively reduces the accessible pore volume of the coal to levels at which heat generation through subsequent sorption of moisture and oxygen is too slow to cause significant temperature rises in a stockpile. In addition, this treatment also irreversibly removes most of the moisture held in the raw coal and raises its calorific value by as much as 10-12%.

Jan 1, 1973