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By A. L. Irwin

THE disposal of tailing or waste material, which is generally a very large proportion of the ore treated, is a major problem in the location and operation of any concentrating enterprise and especially so where the life of the operation is expected to continue for many years. Many factors need to be taken into consideration in the selection of a tailing site, chief among which are economical handling of the material, subsequent re-treatment of the tailing, and precaution against stream pollution by waste water. The final location of many mill sites bas been governed largely by the selection of a sui table area for tailing storage. The Sullivan concentrator of the Consolidated Mining and Smelting Company is situated about three miles from the Sullivan mine at Kimberley, B.C., and one of the deciding factors in its location at this distance from the mine was the availability of a suitable area in which tailing could be deposited. In view of the indicated long life of the property, a far-sighted policy bad to be adopted in the matter of tailing storage, for not only would it be necessary to accumulate a huge tonnage of finely ground material, but also reclamation for iron recovery at some future date bad to be considered. Some idea of the extent of the problem may be grasped when it is noted that, by the end of 1938, over 18,000,000 tons of tailing bad been impounded in an area of some 200 acres.

Jan 1, 1939

By J. C. Li, Y. Zou, L. He

"The effect of rock joints is significant in characterizing dynamic behaviors of discontinuous rock masses. To reveal the relation between the transmission coefficient and the contact situation of the joint surface, an experimental study on stress wave propagation across an artificial rock joint was carried out using a modified Split Hopkinson Pressure Bar (SHPB) apparatus. All the bars and specimens were norite cored from the same site, and one surface of the specimen which contacted to the transmitted bar was sawn with a number of notches to simulate the artificial rough joint. According to a wave separation method, two strain gauges were mounted on each pressure bar at a specific spacing, then the incident, reflected and transmitted waves across the joints were obtained from the test data. It was found that the contact situation of the rock joint surface makes a different on the wave propagation. Finally comparisons of the transmission coefficients with different contact area ratios and different joint thicknesses were made respectively. The results show the effects of contact area ratio and thickness of joints on wave transmission.INTRODUCTIONJoints affect the dynamic mechanical behaviors of the rock masses significantly. When propagates across the rock masses, wave usually attenuates in amplitude and frequency due to the presence of the joint as a discontinuous interface in the rock masses. Rock joints are the main factor that affects the behaviors and properties of rock masses. Many researchers have focused on the mechanical properties of rock joints under quasi-static conditions. Nowadays, the effect of joint dynamic properties on wave propagation across rock masses is gradually taken into account in theoretical and numerical studies.The effective contact area, joint roughness, and properties of the asperities and filling materials have been found to influence the normal stiffness of joints (Bandis et al. 1983). As suggested by the International Society for Rock Mechanics (ISRM), the roughness of the discontinuities can be generally characterized by large-scale “waviness” and small-scale “unevenness” (Brown 1981). Many researchers focused on the roughness of rock joints that affects the mechanical properties of rock masses and wave propagation. For example, Brown and Scholz (1985, 1986) presented theoretically and verified experimentally a closure model of contact between two random nominally flat elastic surfaces, which showed that the joint closure property depended both on the surface topography and material properties. Pyrak-Nolte et al. (1997) presented the quantitative aperture data for three-dimensional interconnected fracture networks, which were imbedded in intact opaque rock samples several centimeters in length, using x-ray computerized tomographic (CT) imaging. Fardin et al. (2001) systematically investigated the effect of scale on the surface roughness of rock joints and concluded that samples should be equal to or larger than the stationary limit for surface roughness to be accurately characterized on a laboratory scale or in the field. Zhao et al. (2006) conducted excellent ultrasonic tests across intact cement mortar specimens, singlefracture specimens, and two-fracture specimens."

Jan 1, 2015

The dissolution of chalcopyrite has received a significant amount of attention. The predominant paradigm of investigation is that its rate of dissolution is limited or passivated by a surface coating or film of material. The common candidates for such a passivating coating are numerous: polysulfide coating, metal deficient layers, copper sulfide coating, bornite layers, jarosite precipitates, and elemental sulfur films. While this line of explanation, that is, the explanation based on passivation, seems to have won some form of consensus with researchers, there is another explanation for the results that can account for all the results observed. Crundwell (1988) proposed that the solid state properties of chalcopyrite, in particular, the semiconducting properties, are responsible for the observed behaviour of chalcopyrite. The purpose of this paper is to outline the semiconductor mechanism of dissolution, and to show how this mechanism accounts for all the observed phenomena recently reported in the literature. The paper outlines the semiconductor mechanism of dissolution, shows how this mechanism accounts for the dissolution

Jan 1, 2014

By A. Singh

Deformation structures after tensile and compression tests on Mg926Zn64Y alloy extruded at 250°C and 400°C are studied, in as-extruded and heat treated conditions. The icosahedral phase particles stimulate recrystallization during extrusion, resulting in fine grain size. Tensile and compression tests at room temperature show comparable yield strength, with a yield asymmetry ratio up to 0.98. c-type dislocations are observed in the grains near the submicron size icosahedral phase particles. The source of these dislocations is believed to be dissociation of <c+a> type non-basal dislocations. No dislocation pile-ups on icosahedral phase particles are found. {10 1 2} type twinning occurs in compression.

Jan 1, 2006

By D. Y. Li, C. D. Ma, T. Zhou, T. J. Cheng

In this paper, a number of experimental tests are carried out to study the strength difference on rectangular prismatic marble specimens with different height-to-width (H/W) rations. The specimens have a nominal size of 45×15 mm in the compressive cross-section (W×T) and different heights (H = 22.5 mm, 45 mm, 60 mm and 90 mm). It is to say that the height-to-width ratios are equal to 0.5, 1.0, 1.33 and 2.0, respectively. The quasi-static uniaxial compressive tests are finished by a servo-controlled INSTRON machine (the strain rate at about 10-5/s), and the dynamic compressive tests are finished by a diameter of 50 mm cylindrical SHPB apparatus (the strain rate reaching about 101/s). The rock failure process of marble specimens is captured by a high speed camera in order to distinguish the fracture propagation behaviour. It is found that the compressive strengths increase when the H/W ratio of marble specimen changes from 2.0 to 1.0 due to the end clamping effect both for quasi-static and dynamic loads. However, when the H/W ratio changes from 1.0 to 0.5, the apparent compressive strengths decrease both for the two loading conditions. The strength decrease of short marble specimens may be attributed to the change of failure mode from shear to slabbing, which can be identified by the fracture patterns of the specimens. Based on the uniaxial compressive tests, the slabbing strength of the marble was found to be about 40% of its UCS for the specimens with a nominal height-to-width ratio of 2.0. In addition, it is found that the dynamic increase factors (DIF) are affected by the specimen’s aspect ratios. It implies that the same aspect ratios should be used to compare the dynamic and static compressive strength of rocks. Meanwhile, both the static and dynamic tensile strengths of the marble are obtained by the Brazilian disc tests. The ratio of the dynamic tensile strength to the static tensile strength of the marble is about 2.68.

Jan 1, 2015

By A. J. Russell

"This paper investigates why it is critical for a mine to accurately determine thermal rock properties and virgin rock temperatures. Theoretical simulations of deep mining production zones have demonstrated that thermal conductivity (k), virgin rock temperatures and specific heat (cp) significantly impact rock heat predictions which can be the dominant component of a mine’s heat load. Natural variability in these factors showed that realistic errors can have a significant effect on mine heat loads. This can ultimately affect miner safety and introduces risk to the viability and sustainability of a project. INTRODUCTION Accurate heat load determinations are critical to ensure that underground working conditions are maintained within legislated and mine specific parameters to safeguard the safety and productivity of employees. Underpredicting mine heat loads will result in hot underground conditions, which risk the health and safety of employees, reduce the productivity of employees or stop production if legislated temperatures in working areas are exceeded. Overestimating mine heat loads will result in increased capital and operating costs reducing the viability of the project. Over- or under- predicting the heat load for a project will increase the project risk. Heat sources in a mine can broadly be broken into two categories. These two categories are defined by Hemp and Rawlins (2014) as natural and artificial heat sources. Those sources which depend on the size, location and depth of the mining areas are defined as natural heat sources, whereas those heat sources which are a result of the actual mining activities are defined as artificial heat sources. Autocompression, or the conversion of potential energy, to enthalpy is an important consideration when determining the air temperature in the mine and its interaction with natural and artificial heat sources. It is documented by Jones (1985) and Hemp and Rawlins (2014), that the heat flow from rock in deep mines can dominate other heat sources; information from BBE’s archives show that this is between 40% and 60% of the total heat load. They also point out the importance of accurately measuring both the thermal rock properties and virgin rock temperatures (VRTs) for determining and planning the ventilation and refrigeration requirements for a mine. Both of these texts cite multiple methods for calculating the heat-flux and ultimately the heat load for the different working areas in a mine. All of these methods demonstrate that the heat flux and heat load will increase proportionally with increased thermal conductivity (k), specific heat (cp) of the rock or mineral, and VRT depending the area of the mine or mining method."

Jan 1, 2019

By Joseph B. de Hart

Two papers recently published on the subject of mine ventilation: "The Theory of Ventilation," by Douglas Hay. and "The True Effect of Natural Ventilation in Deep Mines," by Robert Clive, form the first and second reports respectively of the committee on the Ventilation of Mines appointed by the Midland Institute of Mining Engineers. The purpose of the present paper is to draw attention to these two papers and the discussion thereon. The theory of ventilation as taught in our schools is based on Atkinson&apos;s formula, which is a variation of Chezy&apos;s formula for the flow of water in pipes. The formula depends on two assumptions : 1. That air is an incompressible fluid within the limits ordinarily encountered, and; 2. That the pressure required to produce ventilation varies as the square of the rate of flow. The Atkinson formula has been assumed to hold good over the entire range of conditions met with in mines.

Jan 1, 1924

By H. Clare Horwood

"In the Little Long Lac-Sturgeon River area of Thunder Bay district, Ontario, most of the known ore deposits occur in fractures, shear zones, and zones of brecciation, in folded sedimentary rocks . In two or three instances, however, deposits occur in Keewatin greenstones and in later granitic rocks of probable Algoman age.The principal regional features in the area are the long narrow bands of Keewatin volcanic rocks and Timiskaming sedimentary formations that extend east from lake Nipigon to Long Lac, a distance of about 65 miles. The belts continue to the east for many miles beyond Long Lac and probably for some distance to the west under the waters of lake Nipigon. They are intruded in places, particularly in the north, by large masses of diorite, granodiorite, and granite. Small intrusive masses of diorite and porphyry also occur in many localities throughout the area.The Little Long Lac-Sturgeon River mining area is the youngest camp in Ontario and has been in production only since 1934.The district is readily accessible from the branch line of the Canadian National railway between Longlac station on the main line and Port Arthur, and from the Trans-Canada highway No. 17. Both these means of communication traverse the area in a general east-west direction parallel with the principal structural trend of the rocks of the region.In the Little Long Lac section discoveries were made by W. W. Smith in 1931 (Hard Rock property) , by T. A. Johnson in 1932 ( Bankfield property) , by T. A. Johnson and T. Oklend in 1932 (Little Long Lac property) , by F. MacLeod and A. Cockshutt in 1933 (MacLeod-Cockshutt property) , and by George and Frank Papineau in 1935 (Hutchison Lake property).In the Sturgeon River section discoveries were made by Powers and Silam in 1925 (Northern Empire property), T. A. Johnson in 1931 (Dik-Dik property) , and by Russell and James Cryderman in 1935 and 1936 (Sand River and Leitch properties)."

Jan 1, 1954

By d&apos, F. Elia

Hot cracking of magnesium (Mg) alloys during welding creates a barrier to enhancing the use of these alloys in automotive applications. As a result, it is imperative to understand the mechanisms responsible for hot cracking of Mg alloy welds in order to develop means of eliminating this problem. In this study, the hot cracking susceptibility of AZ91E and AE42 magnesium alloys were assessed using the moving torch Varestraint test method. Plates of 3 mm thickness were extracted from AZ91E and AE42 ingots and subsequently tested. Quantitative cracking data in terms of maximum crack length (MCL) was used for evaluating the cracking susceptibility. Scanning electron microscopy was carried out. The results suggest that AE42 showed a higher resistance to hot cracking in comparison to the AZ91E alloy. This was attributed to the difference in microstructure between the two alloys. In the fusion zone and HAZ of AE42, the brittle needle-like A1IIRE3 phase was seen to decompose to the more ductile particle-like Al2RE phase, thereby increasing the alloy&apos;s resistance to hot cracking. In contrast, SEM fractography revealed that brittle A16Mn and Mg17A112 intermetallic particles segregated to grain boundaries and triggered hot cracking in AZ91E.

Jan 1, 2011

By Sudarshan Martins

The measurement of acoustic signals produced by a tumbling mill has been previously used to determine the operating state of the mill and correlate the variations of the sound intensity with the operating conditions of the mill. Separately, the discrete element model (DEM), a software simulation of the mill, was developed to provide insight into the operation of the mill. Presently, there has not been much work reconciling the DEM simulation of the mill with the acoustic signal. Working from basic principles of linear, time-invariant systems, agreement between an acoustic DEM simulation and the measured signal is sought. First, the impulse response function of the mill is measured. The DEM provides the forces applied to the mill shell as a function of time. A convolution of these simulated shell forces and the transfer function gives the simulated acoustic signal. This signal is compared to the measured acoustic signal, both in the time domain and the frequency domain. Finally, a discussion of the results is given.

Jan 1, 2012

By David Stone

The Beal Mountain Mine near Anaconda, MT is an interesting case history of a mine that has continued operations despite several large pit wall failures over a period of about 10 years. The largest event involved some 3.9 million tons of rock that has moved steadily at a rate of about 0.05 ft/day since 1992. This paper documents the geotechnical instrumentation and monitoring programs implemented at Beal to provide the company with a comfortable baseline that supported ongoing operations. The success and failure of a variety of stabilization measures will be discussed, along with typical instrumentation responses for several significant events. The success of Beal Mountain serves as a good model for mines faced with serious geotechnical challenges.

May 1, 2001

By J. W. Coetzee, H. E. Deist

Carbon-in-pulp (CIP) and Carbon-in-leach (CIL) processes are used extensively in the gold mining sector to recover aurocyanide from solution. This paper discusses the modelling of these operations, using various simplifying assumptions, in order to simulate the effect of changing operating conditions on the dynamics of the system. It is assumed that the adsorption and leaching rates are a function of concentration difference between the source phase and recipient phase. The simulation was set up using Matlab&apos;s Simulink interface. Plant variables are solved using a medium scale Newtonian search algorithm in Matlab, where the differences between the actual and predicted plant outputs are minimized on a continuous time-line.

Jan 1, 2005

By M. Hozayen, Q. Ni, E. S. Radwan, P. Nawrocki, A. Jebbouri

"A major geomechanical study was conducted for one of the UAE onshore oil fields with the purpose of studying reservoir rock properties and stress distribution, based on which a 3D coupled reservoir geomechanical model was built. This model was later used for wellbore stability analysis and for analyzing the effect of fractures on future reservoir production performance, including fracture deformation and permeability evolution occurring due to reservoir depletion and resulting changes in local stress field. The subject of this study was a complex fractured Upper Cretaceous carbonate reservoir characterized by high degree of heterogeneity, both vertically and laterally. Wellbore instability related drilling problems were encountered while drilling the wells in this field. The problems were mainly in drilling the horizontal wells, including breakouts and mud losses. Experimental results of laboratory tests used in this study are summarized in Part I of this paper whereas wellbore stability analysis and formulation of a3D geomechanical model that was built for that purpose is summarized herein.A 3D geomechanical reservoir model was developed, which included natural fractures. The mechanical properties of the reservoir rock, such as Young’s modulus, Poisson’s ratio, UCS, friction angle and tensile strength were populated based on the correlations established in Part I of this paper and the developed model was then used to simulate the 3D mechanical-property distribution and the evolution of the in situ stresses in the field due to depletion from 1983 to present-day. Based on the full field model, mud weight cubes were developed to predict the safe mud weight windows in different drilling directions. In addition, well stability prediction for two planned wells was performed using a 3D near-borehole model. Firstly, the computed stress state and mechanical properties simulated in the full field model were extracted along the well trajectory of an existing horizontal well which was drilled recently and then, a3D near-borehole model was constructed along the well trajectory. The wellbore stability analysis along the well trajectory, including stress state, strain distribution and displacements, was performed to identify the instability events along the well trajectory. It has been seen that the presence of natural fractures is closely related to the recorded borehole instability incidents. The computed plastic strains which indicate the wellbore failure were consistent with the recorded wellbore instability events in the FMI image logs, what provide further verification of the developed model. Then, this 3D near-borehole model was applied to two planned horizontal wells and the wellbore stability analysis for the two wells was carried out.The results showed that drilling vertically in the reservoir is safer than drilling horizontally. However, the drilling mud weight window in the vertical direction is narrow, being as narrow as 18.7 pcf or 0.299 sg locally. Drilling horizontally is less stable towards the maximum far field stress direction than towards the minimum far field stress direction. The mud weight cubes were used to identify the optimal well placement and well trajectory. For planned well trajectories, this technology can also be used to determine the optimal mud weight."

Jan 1, 2015

By Craig Haase

A. Introduction

Jan 1, 2003

By J. Kouam

Al-Si-Cu and Al-Si-Mg alloys are widely used in several applications. Although they can be produced near-net-shapes, products made of these alloys very often require some machining. The purpose of this study is to evaluate the machinability of A319 and A356 under TO and T6 conditions. The machinability was assessed using during dry drilling machining process and the machinability indexes used are the chip form, the chip breakability and the cutting forces. It is found that 319 and 356 exhibit different machinability behaviors, especially in the T6-condition in terms of forces requirements, chip breakability and chip segmentation. It is also found that both the microstructure of the workpiece materials and the machining conditions significantly affect the chip formation mechanism, and therefore, the machining parameters could be selected to promote a chip form that is easily manageable in production.

Jan 1, 2011

By P. Turcotte, E. Karampinos

"Construction of underground excavations in squeezing ground conditions faces several technical challenges that can result in delays in production and high costs due to rehabilitation. A review of the behaviour of drifts under squeezing ground conditions was undertaken at the LaRonde mine. In particular it focused on implemented strategies to control the observed large deformations. The mine experiences a large range of squeezing ground conditions, mostly driven by the presence of foliation and high stresses. This results in large deformations over one meter in radius. A comprehensive ground control strategy has been implemented with the aim to manage, rather than arresting drift closure. The evolution and effectiveness of the employed support strategy are discussed based on documented field observations. In complement to the field implementation numerical models are used to provide further insight on the observed squeezing conditions.INTRODUCTIONThe development of underground excavations under squeezing ground conditions is usually associated with excessive rehabilitation and significant failure of ground support due to large deformations. Cost research case studies have concentrated on squeezing ground conditions in tunnelling. An overview of the methods used for the identification and quantification of squeezing and the numerical methods for the simulation of these conditions in tunnelling has been provided by Barla (2002). Numerous support systems that can manage ground deformation are available for civil engineering tunnelling. Nevertheless, the use of these systems in mining would result in high support cost and production delays. Mining operations have higher development rates and shorter service life. This study focuses on the behaviour of underground excavations under squeezing ground conditions in hard rock mining.In a mining context, the magnitude of deformation is usually higher than in civil engineering tunnelling as there is a higher tolerance for operation purposes. Potvin and Hadjigeorgiou (2008) noted that in mining, squeezing is encountered when the total displacement of an excavation reaches at least tens of centimeters over the life expectancy of a supported drive and is associated with considerable damage to the ground support."

Jan 1, 2015

By S. Yadav, T. G. Murthy, C. Saldana

"An experimental study has been carried out in order to study the deformation of porous brittle materials under plane strain indentation. Gypsum, which is well known model system for understanding the behaviour of soft rocks, is used in this study. The effect of wedge angle is investigated in this research through this series of experiments, using wedges of 3 different apical angles. High-speed, high-resolution images are captured using a CMOS camera during the experiment. The images obtained are analyzed using a Particle Image Velocimetry (PIV) algorithm in order to obtain the evolving velocity, strain-rate and strain fields.INTRODUCTIONThe problem of indentation, which is usually referred to in the context of hardness testing is ubiquitous as a material characterization technique for a large class of solids. Mechanical properties of materials such as yield stress, flow stress, fracture toughness, elastic moduli etc. can be related to the hardness of a given solid. The indentation problem involves a given material or solid (whose properties are to be determined) indented by a relatively harder material (indenter) allowing the solid to undergo plastic deformation, which is then related to the yield stress of the material. The problem of indentation and its variants see many applications ranging from mining and petroleum industry, infrastructure industry, manufacturing, and biomedical sectors. Indentation has been extensively studied in metals, with accurate measurement of deformation parameters, stresses and comparison with analytical solutions. On the other hand, understanding of indentation in other class of solids such as cellular solids, porous solids, rocks, and soft solids is still nascent. In case of rocks, a comprehensive understanding of the indentation problem is very crucial because of the obvious applications in mining, petroleum and infrastructure sectors. The inherent porosity, the brittle nature of the rocks, adds to the complexity of indentation in these porous brittle solids. Various theoretical models with degrees of simplifying assumptions have been proposed to study the indentation in rocks. The most common model used in the study of indentation in rocks is a cavity expansion model, wherein a blunt indenter indenting into a rock is approximated with the expansion of cylindrical or spherical cavity in an elastic-plastic material. Complementary studies in understanding fracture initiation and propagation due to indentation has been largely based on the studies of traditional brittle materials such as glass."

Jan 1, 2015

By H. C. Cooke

"The Part of the Eastern Townships dealt with in this paper is shown in the accompanying figure. Each rectangle represents one of the topographic maps published by the Department of National Defence on a scale of one mile to one inch. Each sheet covers an area approximately 24 miles long and 17 miles wide, or slightly more than 400 square miles. The north-western part of the area figured, comprising the Upton, Aston, Becancour, and the two unnamed sheets, (Three Rivers and Yamaska), together with most of the Lyster, Drummondville, and St. Hyacinthe sheets, is largely covered by clays and sands deposited in interglacial and post-glacial time in the Champlain estuary, so that outcrops are widely scattered and in-formation is correspondingly sketchy. In the remainder of the area figured, comprising more than 4,000 square miles, outcrops are reasonably numerous and have been mapped on a scale of one mile to one inch, and the structure is moderately well understood.The Eastern Townships was an area of intense orogenic disturbance, apparently beginning late in the Cambrian or early in the Ordovician, and continuing till well on in the Devonian period. During this long period, which may have lasted for a hundred million years or more, the area was subjected from time to time to intense thrusts from the east and southeast. Each of these caused folding of the rocks, accompanied by faulting, raised parts of the area above sea-level, and presumably created ranges of mountains. Long periods of erosion cut away the mountains and reduced the area nearly to sea-level after which subsidence carried it below sea-level, and permitted further sediments to accumulate before the next thrust initiated the next cycle.The first of these movements, as stated, appears to have been in late Cambrian or early Ordovician time. The group of rocks known as Caldwell was folded and, south and east of the town of Asbestos, was thrown into great drag-folds before deposition of the next overlying series, termed the Beauceville, began. Unfortunately, the date of this orogeny is very imperfectly known, because both series of rocks have been so crushed and sheared that almost all fossil remains have been destroyed. Graptolites, found in one place in slates generally considered Beauceville, give that series a tentative Middle Ordovician age. In the Caldwell rocks, which underlie the Beauceville with great unconformity, no fossils whatever have yet been found. Thus, if the Beauceville rocks are correctly dated as mid-Ordovician, the best that can be said of the movement folding the Caldwell is that it took place at some time before Middle Ordovician."

Jan 1, 1949

By H. Fujiwara, T. Ito, T. Mizuguchi, K. Kawasaki

"In this study, we characterize the high-temperature deformation of typical “Class I” solid solution Al-Mg alloys as a superplastic elongation attributable to the solute drag creep of dislocations. The second-phase particles formed by adding Fe or Si as impurity atoms to the Al-Mg alloys impeded the gliding motion of dislocations, thereby decreasing their hot ductility and resulting in cavity formation. High-temperature tensile tests were performed with initial strain rates in the range of 1×10–3 to 1×10–1 s–1 at air temperatures 673–723 K. The dominant high-temperature deformation mechanism in these alloys was the solute drag creep controlled by the interdiffusion of Mg in Al. In this study, the calculation of critical length, defined by the diffusion-based relaxation of the stress concentration region around second-phase particles, is reported using the Needleman–Rice parameter. An analysis of the impact of cavity formation based on a comparison of the Needleman–Rice parameter and second-phase particle size is also reported.INTRODUCTION Aluminum alloys with high specific strengths are utilized as structural materials for transportation machines to minimize their weight, which consequently maximizes fuel efficiency, environment preservation, and so on (Miller et al., 2000; Heinz et al., 2000; Starke & Staley, 1996; Polmear, 1996; Immarigeon et al., 1995; Burger, Gupta, Jeffrey, & Lloyd, 1995; Ye, 2003). Microstructure refinement by severe plastic deformation (SPD) has been performed on a laboratory scale to achieve a higher strength of crystalline materials (Valiev et al., 2006; Song, Ponge, Raabe, Speer, & Matlock, 2006; Beyerlein & Toth, 2009; Sabirov, Murashkin, & Valiev, 2013; Sauvage, Wilde, Divinski, Horita, & Valiev, 2012). At room temperature, grain refinement strengthens the material, as given by the Hall-Petch relationship (Hall, 1951; Petch, 1953); at higher temperatures, superplasticity can be expected (Sherby & Wadsworth, 1989; Edington, Melton, & Cutler, 1979; Furukawa, Horita, Nemoto, & Langdon, 2001; Langdon, 2006). However, the synthesis of large-size materials by SPD processes is not yet feasible."

Jan 1, 2018

By Georges Houlachi, Akram Alfantazi, Maysam Mohammadi

Manganese ions in zinc electrowinning electrolytes form a protective MnO2 layer that ultimately decreases Pb contamination in the zinc product. In this study, the effect of dissolved Mn2+ on the electrochemical performance of Pb, Pb-Ca and composite Pb-MnO2 anodes was investigated. The properties of the MnO2 layer formed on these anodes were studied and compared. Potentiodynamic polarization and cyclic voltammetry experiments were performed in 180 g L-1 sulphuric acid to study the electrochemical reactions occurring on the anodes. The anodes were subjected to galvanostatic polarization at 50 mA cm-2. The morphology and uniformity of the MnO2 layer on the anodes were examined using scanning electron microscopy (SEM). Experimental results revealed that the MnO2 layer formed on the composite anode was more compact and uniform compared to that formed on the Pb and Pb-Ca anode. It was also observed that the cell mud formation rate, and consequently manganese ions consumption, depended on the anode type. Although initial formation of the MnO2 layer decreased the oxygen evolution overpotential, its growth might negatively affect electrocatalytic activity of the anodes.

Jan 1, 2014