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By Joey R. Kish, Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton

The kinetics of the Cr2O3-based scale oxidation and volatilization were studied in the presence of water vapour (H2O). A commercial Cr2O3-based scale forming Type 310S stainless steel was examined at the ambient pressure (0.1 MPa) and 550ºC in relatively low and high H2O containing environments of air- 10% H2O and air- 70% H2O, respectively. The increase in the partial pressure of H2O (pH2O) from 10% to 70% resulted in transition of the oxidation and volatilization kinetics from the parabolic rate law for air-10% H2O to the paralinear rate law for air-70% H2O. The kinetics transition was attributed to the increase in the Cr loss rate from the base scale after coupons exposure in air- 70% H2O. The significant role of the Mn alloying element in the base scale protectiveness was also discussed in the context of the Cr2O3-based scale stability.

Jan 1, 2017

By J. D. Zhu

A numerical model for predicting microporosity formation in aluminum castings has been developed, which describes the redistribution of hydrogen between solid and liquid phases, the transport of hydrogen in liquid by diffusion and Darcy flow in the mushy zone, One of the key features of the model is that it uses a two-stage approach for porosity prediction, In the first stage, the volume fraction of porosity is calculated based on the reduced pressure, whereas, in the second stage, at fractions solid greater than the liquid encapsulation point, the fraction porosity is calculated based on the volume of liquid trapped within the continuous solid network, which is estimated using a correlation based on the Niyama parameter, The porosity model uses thermal data calculated using the commercial finite element package ABAQUSTM. The model has been applied to examine the evolution of porosity in a series of experimental samples cast using unmodified A356 in which the initial hydrogen content was varied from 0,048 to 0.137 [cc/100g], A comparison between the model predictions and the experimental measurements indicates good agreement in terms of the variation in porosity with distance from the chill and the variation resulting from initial hydrogen content.

Jan 1, 2005

By Yuki Koshino, Kenji Kaneko, Yasuhiro Aruga, Takuya Maeda

"In general, there is a strong correlation between dislocation characteristics and mechanical properties of aluminum alloys. In this study, dislocation characteristics of tensile deformed Al-Mg alloys were examined by transmission electron microscopy. An Increase in the solute concentration, ranging between 0.3 and 1.1%, Mg leads to increase in strength and decrease in uniform elongation. The accumulation of dislocations during the tensile deformation is observed in lower strain as the concentration of solute Mg in the alloy is higher. It is believed that the solute Mg in Al-Mg alloy promotes the accumulation of dislocation during the tensile deformation resulting in the decrease in elongation.INTRODUCTION The influences of the amount of Mg concentration on the tensile properties of Al-Mg alloys has been investigated by many researchers. It has been understood that the tensile ductility of Al-Mg alloy is higher for the Al-Mg alloys with higher Mg concentration beyond 2 mass% (Mukai, Higashi, Hirano & Tanimura, 1993). Uchida and Yoshida (1995) reported the formation of microbands during the tensile deformation due to the localization of dislocations, and the amount of microbands were reduced when the Mg concentration of the Al-Mg alloy was increased from 3 to 9 mass%. Their study suggested that the dynamic recovery of dislocation was retarded due to the increase of the Mg concentration during the tensile deformation, which resulted the increase in ductility. On the other hand, in the case of Al-Mg alloys with the Mg concentration less than 3 mass%, the reason why the ductility of Al-Mg alloys decreases with increasing Mg concentration has not been sufficiently investigated. In general, the Mg concentration used for automotive usage is less than 1 mass%, in the case of Al-Mg-Si alloys (Aoki, 2013). Therefore, to clarify the roles of Mg in the low concentration range on ductility of aluminum alloys and to elucidate its mechanism contribute to alloy design of Al-Mg-Si alloys having good formability."

Jan 1, 2018

"INTRODUCTIONThe Department of Energy, Mines and Resources has recently developed two automatic controls for use in the cyanidation circuits of Canadian gold mills. These controls are the alkalinity probe and the Continuous Cyanide Titrator both of which are discussed in the paper ""Instrumentation in the Cyanide Process"".(1)In May 1966 these process controls and associated recording equipment were installed in the Bralorne mill by two Scientific Officers from the Department. The object was to determine if the equipment was amenable and applicable to this particular circuit. The purpose of this paper is to discuss the performance of the equipment over a test period of 4 months.CONCLUSIONSThe results of test work to date indicates that both the Conductivity Probe and the Continuous Cyanide Titrator would be an as set to the operation of the Bralorne mill.The conclusions are generalized as follows:-(1) At a milling rate of 100, 000 tons per year the expected reductionin reagent consumption would give a direct saving of 37, 660 lbs of lime@$0.030 per lb and 15, 790 lbs of sodium cyanide@ $0.175 per lb. Such cost savings would pay for the equipment and installation costs within a 30 month period"

Jan 1, 1967

By W. Lodge, G. Rasmussen

"The carbon-in-pulp (CIP) process has been the dominant gold recovery technology since the 1980s. During all this time carbon measurement, and control of the carbon transfer pumps has been largely manual in nature. Such manual operation inevitably limits process efficiency, potentially resulting in higher gold solution losses, and higher cost of circuit operation. Based on the authors’ experience, average plant solution loss is in the range of 0.02-0.03 ppm Au, as opposed to the general industry target of 0.01 ppm Au or less. Gekko Systems, in conjunction with Curtin University’s Gold Technology Group, has developed a carbon concentration meter, the ‘Carbon Scout’ meter. The meter automatically measures carbon concentration in all tanks, providing more frequent and more precise data. Combined with SIMCIL, a CIP circuit process model which is used to determine the optimum set points for the circuit, the meter should ensure lower gold solution losses, and more efficient operation of the carbon circuit. This paper will review they critical factors for good carbon management, the development of the meter and results from the first plant installation. Additional benefits of the Carbon Scout, including improved health and safety and the opportunity to measure other key variables in the leach/adsorption circuit from one central location will also be described.INTRODUCTION The carbon-in-pulp (CIP) process was first introduced to the gold industry in the early 1950s at the Carlton Mill in the USA (Fast, 1988), with the modern version of CIP becoming fully developed with large scale installations in South Africa in the late 1970s (Laxen, 1982). CIP quickly became the technology of choice for new operations, and for the retrofitting or upgrading of existing operations. In the 1980s the carbon-in-leach (CIL) circuit configuration became the process design of choice due mainly to its lower capital costs. With 40 years of operational experience, CIP/CIL for gold recovery is now mature a technology, whose operations and limitations are well understood. To extract further efficiencies from such technologies, by improving recoveries and/or reducing operating costs, is challenging and may require new approaches to circuit management. Gekko Systems, in association with the Gold Technology Group at Curtin University, has developed the Carbon Scout, an automated carbon measurement device. This device replaces manual measurement of carbon concentration in carbon adsorption tanks, providing more frequent and more accurate data for control of the CIP process. Data from the Carbon Scout can be used to automatically control the carbon forwarding pumps."

Jan 1, 2018

By I. M. Gordon

"INTRODUCTIONThe Hollinger tailing disposal plant is situated about 1 1/4 miles south of the mill. The area available for tailing covers 620 acres and is roughly 1 ¼ miles long by ¾ mile wide.Tailing was first deposited on the northeast section of the present site. This section, 1 mile long by ~ mile wide, sloped from northeast to southwest, the slope amounting to 106 feet between the northeast corner and the low land to the south west. The low land was wet and a considerable area was covered with muskeg up to 17 feet deep. It was drained by a creek running across the property in a southwesterly direction. Later, when more ground was needed, the low lying mining claims adjacent to the south and west boundaries were acquired to allow for expansion of the plant. This entailed some extra difficulties and expense that would not have been necessary had the whole of the present site been acquired with the original purchase.At the conclusion of milling, May 7, 1968, the site contains nearly 56 million tons of tailing. The top of the deposit is from 70 to 90 feet above the original low lying ground along the northwest, west and south boundaries."

Jan 1, 1969

By George Kellock

In presenting this paper for discussion at the Western Annual Meeting to be held in Edmonton, it is with the idea of creating a full and general discussion by the mining men in the Province as to the best way to eliminate, or at least hold down to a minimum, the dangerous coal-dust which is made in mining pitching seams in our Alberta mines by the chute method. Also, an alternative method is outlined, whereby the percentage of lump-coal mined can be increased, and the mining costs reduced-although the paper does not go into any detailed consideration of costs. The general trend of mining practice and lay-outs is at present towards mechanization, and the results being accomplished by the substitution of machines for manual labour are fully justifying the changes. In the technical mining journals, there are published from time to time papers dealing with a variety of methods of mining, which are descriptions of actual operations, and a great deal of interesting and valuable data is given as to the comparative values of the different methods, insofar as the percentage of grades of coal produced, the cost of production, etc., are concerned; but the mechanical methods described in these papers are nearly always suitable only for flat seams, or seams with a very low inclination.

Jan 1, 1929

By LeRoy A. Thorssen

The use of lightweight aggregate as a constituent of concrete is not a recent development. Pumice was used by the early Romans, in pozzolana cement concretes, in the construction of many of their works. However, the recent development of manufactured lightweight aggregates, such as the expanded shales, vermiculite and perlite, has created a possible use for a whole new group of Portland cement concretes. Concrete can now be produced with unit weights ranging from 30 to 150 pounds per cubic foot and with various insulating, fireproofing, acoustical and structural properties. The tonnage of such materials being used has increased considerably in each of the past ten years, and can be expected to increase for the next several years as availability of the aggregates becomes more widespread and the properties of such concretes become more thoroughly investigated and more generally known. LIGHTWEIGHT aggregates of many types have become avail-able to the construction industry in most localities on this continent

Jan 1, 1963

By J. W. Cox, W S. Jones, A E. Chase

For a long time the Oil Industry has been looking for a logging tool which can determine the quality of the cement job behind casing. Older methods such as Temperature Surveys and Radioactivity Surveys might detect the presence of cement behind the casing, but short of production tests, it was impossible to tell that the producing zones were adequately sealed off from adjacent zones. A new logging method, which is called the •Cement Bond Log, operates on the principle that a sonic pulse transmitted by the casing is greatly attenuated when the casing is strongly bonded to an outer annulus such as cement. The down-hole tool consists of a source of sonic energy which is detected by a receiver situated a few feet away from the source. The amplitude of the detected energy is measured and the resulting signal transmitted to the surface where it is recorded versus depth. Amplitude is a function of attenuation and thus the log is readily interpreted.

Jan 1, 1961

By O. Hyvärinen

Outokumpu has developed a new chloride leaching process called HydroCopper®. In this process copper sulfide concentrates are leached at atmospheric pressure in concentrated sodium chloride solution using cupric ions as the oxidant. Copper is recovered from the purified leach solution by precipitating cuprous oxide, which is then reduced to pure copper and further melted and cast directly into copper products. The key reactants: sodium hydroxide, hydrogen and chlorine are generated from the spent sodium chloride using chlor-alkali technology. An important feature in the HydroCopperTM process is that the gold contained in copper concentrates is leached as chloride complexes and recovered from solution by activated carbon. Conditions for the leaching of gold-bearing pyrite can also be achieved in the chloride system by optimizing the redox conditions. This paper deals with the basic factors affecting gold leaching from copper sulfide concentrates. Opportunities for the recovery of refractory gold associated with arsenopyrite and pyrite will also be discussed.

Jan 1, 2005

By P. M. Chapman

Risks to aquatic receiving environments from uranium mining and milling fall into three categories: physical (habitat change), chemical (e.g., uranium, selenium, total dissolved solids [TDS], metals including vanadium), and radiological. Although all categories of risk need to be managed, chemical risks are the most significant and are typically chronic rather than acute. For instance, selenium toxicity is primarily manifested as reproductive impairment due to maternal transfer, resulting in embryotoxicity and teratogenicity in egg-laying vertebrates. Risk is best assessed using a weight of evidence approach focused on ecosystem services. Risk management should be based on both risk assessment and adaptive monitoring.

Aug 1, 2010

By T Nakamura, M. Itoh

Most of the used cathode ray tube (CRT) glass in Japan, which contains lead oxide, was exported and recycled in overseas factories of new CRTs. However, domestic treatment and recycling of waste CRT glass has become necessary because overseas CRT factories have shut down and exports of CRT glass have stopped. Some of the waste CRT glass recycled domestically is charged in lead blast furnaces instead of silica flux, because there is no local reproduction route for glass that contains lead. However, the mass of CRT glass that can be treated in this manner is limited because of its high silica content. Consequently, additional treatment methods for waste CRT glass are required so that more can be used as a lead smelting material. In this study, waste CRT glass was treated with hydrofluoric acid to dissolve the silica contained in the glass, and the dissolved lead was recovered by precipitation. Lead metal was recovered by electrodeposition from the prepared hexafluorosilicic acid solution.

Jan 1, 2011

By Y. Chunhua, L. Chunsheng, W. Sheng

"Countercurrent solvent extraction is the dominant industrial rare earth separation method. For the rare earth separation, with low separation factors and multiple components, designing and optimization plays an important role in reaching product quality and reducing separation plant costs. Based on the theory of countercurrent extraction, cost-efficient methods, such as third-outlet separation and hyperlinked extraction processing, have been introduced following computer simulation. The consumption and fixed investment of industrial practice are compared, by which advantages of the optimized rare earth separation process are indicated. INTRODUCTIONThe rare earths (RE) have outstanding optical, magnetic and electric properties in advanced material applications and have therefore received much international attention in recent years. Liquid-liquid extraction is the major industrial RE separation method and is widely used in the industry. Supported by the government and with collaboration from the institutions and enterprises, China has made great progress in RE separation, and has become the dominant supplier of separated RE products. Complicated by multiple elements and low separation factors, careful design of RE separation processes is vital for the quality and cost of production. The theory of separation is the key to basic of flowsheet design and industrial applications.BASIC SEPARATION PROCESS AND THEORYGeneral ProcessAcidic extractants such as P507, P204 and naphthenic acid, are the most popular extractants in modern RE separation industry. In the general separating process, the extractant is saponified with a base, then ion-exchanged with RE solutions, thereby to provide stable and high RE loading in the extractant to fulfill the requirement of production quantity and quality. The RE-loaded extractant is then countercurrently extracted and scrubbed with RE solutions and the RE element thereby is purified. After the countercurrent extraction process, the RE-loaded extractant is stripped with acid to obtain an aqueous RE product, and prepare the extractant for recycling (Xu, 1995)."

Jan 1, 2012

By Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

A thermodynamic description of the equilibrium in liquid and gas phases under specific conditions of refractory gold pressure oxidation was generated using the HKF theory. The gold behavior was considered at 190-225°C in the presence of 1-100 mg/L of chloride ion, and under oxidationreduction potential (ORP) of +700 to +1030 mV. The calculations show that the predominant form of gold(I) occurrence is [AuOH]° compared to [AuCl2]?. High ORP favors the formation of [AuCl4]? as a predominant form of gold(III). It is noted that this complex is responsible for the gold losses buildup during POX. Laboratory test results for double refractory concentrate POX are shown. The combined negative effect of (i) organic carbon of the concentrate and (ii) dissolved chlorides in POX slurry on gold recovery is demonstrated. The effects of carbonate blending to the POX feed concentrate and incomplete oxidation of sulfides on POX performance were studied. The pilot tests results of continuous pressure oxidation are also shown and generally confirm the laboratory results and theoretic dependencies. A comparison of the experimental data with the results of thermodynamic calculations is made. As a result of current research, an effective process for POX treatment of carbonaceous sulfide concentrates in the presence of chlorides was developed.

Jan 1, 2014

By Nelson C. White

This paper summarizes the present state and future prospects of the potash industry, with special reference to its impact on production in Saskatchewan.

Jan 1, 1968

By Gabriel G. Walton

Conventional numerical modelling tools for analyses of underground excavations are well suited for modelling elastic behaviour and yield response of geomaterials with very simple constitutive behaviour. Non-dilatant elastic and perfectly plastic behaviour is most commonly used for preliminary analyses in the absence of the data required to consider more complex behaviours such as strainweakening and dilation. For truly brittle models, this deficiency is more acute. Current state of practice allows only for reliable estimation of the volume of failure, but not for any prediction of displacement. In fact, there is no consensus in rock engineering regarding the most accurate approach or most suitable tool to model the magnitude of the plastic deformation that strain-weakening or brittle rocks experience at tunnel boundaries, particularly when support is incorporated into these models. This problem is largely a function of a poor understanding of how inelastic dilation occurs in different types of rockmasses, the rate controls on strength loss and volume change during yield, and the complexities of rock-support interaction in yielding conditions.

Jun 1, 2012

By R. R. Potter

"IntroductionAlthough iron formations were recognized in western New Brunswick about 1820, commercial production was not achieved until 1848. The Jacksonville deposits near Wood stock were developed first, and ore was treated at a blast furnace constructed 5 km to the southeast on the Saint John River. Several charcoal burners were also constructed. Pig iron was produced sporadically until 1884, when operations were finally suspended. There was little further interest in the area until 1953, when Stratmat Ltd. initiated an ambitious exploration program. At the same time, the company carried out research on an electric-reduction process to produce metallic iron and ferromanganese. The technical feasibility of this process (Udy process) was confirmed, however the high energy costs were prohibitive and work ceased in 1957. Some metallurgical research was carried out by Mandate Refining Ltd. about 1970 and more recently by the New Brunswick Research and Productivity Council.The Years Prior to 1848New Brunswick became a separate province in 1784, shortly after the influx of a large number of Loyalists from the United States. Man y of these people sett led along the Saint John River, including the area of excellent farmland near the present town of Woodstock.There were indication s that some of these earl y settlers recognized iron formations in the vicinity of Woodstock about 1820, however the nature of the deposits was not known until 836 when Dr. C.T. Jackson, a geologist commissioned by the Stat e of Maine, investigated the mineral potential of the area. Jackson (1836) described the ""ore"" as compact red hematite yielding 44 per cent pure metallic iron, and suggested that sizable tonnages may be present. It was about this time that an extensive limonite deposit was found in north-central Maine, near Mt. Katahdin. Other iron deposits were found in the Nictaux area of Nova Scotia, and a few years later at Londonderry."

Jan 1, 1983

By A. Fischersworring-Bunk

The new inline six spark-ignition engine is the realization of BMW's concept of efficient dynamics at high technological level to achieve the attributes of low weight and high efficiency, The paper presents different aspects of the development and manufacturing of BMW's inline six-cylinder engine magnesium-aluminium composite crankcase, Reference will be made on the AJ magnesium alloy optimization approach to balance between mechanical properties and the high pressure die cast ability requirements, Next to this aspect some mechanical design issues will be covered, with CAE methods playing an instrumental role in the early project stage for the assessment of the compound concept, Due to the compound design chosen, the interface posed challenges to both design and productions, A set of novel techniques has been used to cope with these tasks.

Jan 1, 2006

By G. H. Hope, D. Green

"Recent process advances at Lac Minerals Est Malartic Division are discussed. The Est Malartic mill treats massive sulphide, copper/gold ore from the Bousquet 2 mine, to produce a gravity gold product, a copper flotation concentrate and a gold precipitate. The mill operation has been improved by the application of Knelson concentrators to replace jigs, the application of Outukumpu high grade tank cells and optimizing the cyanide leach to minimize cyanide consumption.IntroductionThe Est Malartic mill is located near the town of Malartic in the Abitibi Region of north western Quebec. The mill has been in production since the mid- J 930's processing mainly clean, free milling gold ore. Active mining from the Est Malartic mine ceased in 1980 and the mill was switched to custom processing of ore from La Mine Doyon located some 45 km to the west. This custom processing arrangement continued until 1987 when the expanded mill at Doyon became available to process all of the Doyon production. In 1987, Lac Minerals commenced development of a second mine at the Bousquet site located 40 km west of Malartic. This mine, Bousquet 2, is the down dip extension of the La Ronde mine developed by Agnico Eagle. During pre-feasibility evaluations, it was determined that modification of the Est Malartic mill to handle this new ore source was economically more attractive than building a new facility on site. Modifications to the mill to process the high copper/gold ore from the Bousquet 2 mine began in late 1989 and the new circuits were commissioned in mid-1990. Modifications included the addition of both gravity and flotation concentration circuits to recover coarse, free gold and the copper. The existing leach circuit continued operating on the copper flotation tailings with some minor modifications to the solution handling systems. An SO,/air cyanide destruction circuit was also added at this time."

Jan 1, 1993

By Larry M. Southwick

There have recently been executives at major metals companies who have recommended that Greenfield Projects not be pursued. Greenfield includes not only new geographical locations, but also new technologies and new types of feed materials. In the middle part of the 20th Century, two such projects were successfully commercialized to recover nickel from Cuban lateritic ores. One project (at Nicaro) used the Caron ammonia-ammonium carbonate leach and the other (at Moa Bay) a high pressure acid leach. How both of these projects dealt with these Greenfield issues will be reviewed, based on the original reports that described the research and development of the plants. This study will include a review of the critical ore characterization and sorting issues, as well as the extractive metallurgical, product recovery and equipment selection and sizing problems and how they were solved at each stage of project development, from laboratory through one or more pilot scale plants to start up and operation. In one case, a major revision of the plant was made after several years of operation to correct operating, equipment selection and materials of construction problems that hindered economical operation. These descriptions will provide a guide through the complicated and critical issues that in recent times have caused many companies to give up on similar development. Even with the more advanced analytical and computational tools available to today’s mineralogists, engineers and metallurgists, the basic concepts with which these projects successfully addressed their sets of problems are still required. In addition, upper management, now perhaps further removed from hands-on experience than was common then, will see how complicated problems require intense and detailed effort to avoid failure in the field and capital blowouts. Build it and we will make it run, kicking the can down the road and borrowing operating and design concepts incorrectly on technological issues, or nine year olds on a sugar high making financial decisions are not philosophies by which to succeed with Greenfield Projects.

Jan 1, 2014