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By R. P. Hackl, P. G. West-Sells

Carbonaceous gold ores are particularly attractive for leaching by ammonium thiosulfate as the gold thiosulfate complex is not significantly adsorbed by the organic carbon present in the ore. A technically and economically feasible process for treating these ores with ammonium thiosulfate has been developed. In this process, gold is extracted by leaching the ore with ammonium thiosulfate, the solution is separated from the ore by counter - current decantation, the gold is recovered by precipitation with ammonium sulfide, and finally the gold containing product is upgraded by reacting the elemental sulfur present in the precipitate with ammonium sulfite. The precipitation filtrate is recycled back to the grinding step to close the solution balance. Reagent consumption is not excessive. Besides precipitating gold, the precipitation step removes most deleterious solution impurities and converts a portion of the polythionates back to thiosulfate. This paper discusses the optimization of the leaching, precipitation, and upgrading steps. The results of a 10 kg/h pilot plant campaign are also discussed.

Jan 1, 2005

By Emmanuel John M. Carranza, Martin Hale

Abstract- An application of logistic regression to mapping of gold potential in the Baguio district of the Philippines is described. Categorical map data such as lithologic units and proximity classes of curvi-linear features, based on spatial association analyses, are quantified systematically and used as independent variables in logistic regression to predict the probability for presence or absence of gold mineralization. Regression experiments to compare between using all independent variables that are associated spatially with the response variable and using only statistically significant independent variables are performed. The results of the regression experiments are similar; however, the use of all independent variables produces slightly optimistic results but better prediction rates for the known gold deposits in the test district. At least 68% of the ‘model’ large-scale gold deposits and at least 76% of the ‘validation’ small-scale gold deposits were predicted correctly. The predicted geologically favorable zones are also similar to delineated geochemically anomalous zones. The technique presented using logistic regression as a data integration tool is effective for geologically constrained technique of mapping mineral potential.

Jan 1, 2001

By C. Poon

For slope stability, knowledge of major and minor discontinuity sets that form the rock mass fabric is paramount for pit slope designs. Due to the increased awareness of health and safety in mining projects, efforts have been made to limit structural mapping in order to minimize the risk to personnel associated with approaching potentially unstable areas. Recognizing the importance of such safety precautions, Golder Associates Ltd. is applying a combination of techniques including 3D photogrammetry, conventional mapping and drilling with core orientation to enhance structural data collection. Photogrammetry uses digital photographs to produce a virtual model of a rock mass surface. The application of these techniques will be exemplified through an expansion design of an existing open pit. A comparison of stereonets obtained using these techniques showed some agreements, but also highlighted limitations of each method. The application of photogrammetry was found to be very useful in complementing the other existing techniques.

May 1, 2009

By G. A. Gamble

"The inlet air velocity profile of any surface mine ventilation fan is an important factor when designing the connecting ductwork from the mine shaft collar to the fan. Deficient fan performance can be the result of ductwork that adds unnecessary pressure loss and/or adversely influences the fan inlet air conditions (velocity profile). The need for optimized inlet air conditions begins with discussing the process of performance testing during the development of the fan performance curve. Additional discussions include design of the shaft collar connection and the connecting ductwork. A preferred design of ductwork for parallel fan installations will be illustrated.INTRODUCTIONThe inlet air velocity profile of any surface installed mine ventilation fan is one of the most important factors to consider when designing the connecting ductwork from the mine shaft collar to the fan. Oftentimes deficient fan performance can be traced to poorly designed ductwork that adds unnecessary pressure loss and/or adversely influences the fan inlet air conditions (velocity profile). Such designs may lead to added power requirement, excessive vibration and noise, and reduced fan performance.Understanding the need for optimized inlet air conditions begins with discussing the process utilized when factory testing takes place during the development of the fan performance curve.Additional discussions include design considerations for the shaft collar connection, the connecting ductwork, and fan inlet. Illustrations of cost savings and pressure losses will be included for audience consideration. The design of ductwork for parallel fan installations on the surface is another issue that requires consideration. A preferred method will be illustrated.The selection of accessory components, such as self-closing doors, can also add to the potential for reduced fan performance. Several components will be discussed.An elementary presentation of the Air Movement and Control Association (AMCA) Standard 201 “Fans and Systems” will be included to provide background for those audience members that want additional technical explanations of the need for a uniform inlet air velocity profile at the fan inlet."

Jan 1, 2019

By K. Sawada

Along with the expanding demand of copper concentrate in Asian countries, custom-smelters have confronted with difficulties of low TC/RC. Now, Japanese Copper Industry have 2 options; investment in mine development and/or recycling of copper scraps. The strategy of global mining companies is analyzed, and implications for Japanese Copper Industry will be discussed from the viewpoint of sustainability of smelters in Japan.

Jan 1, 2014

By Christoph Mueller

?Globalization and the impact on mine operations? is one of the themes of the 2003 annual CIM meeting. Global mining business in practice always means to act with local base material resources in order to reach the mining company?s global business goals. On the other hand these operations are characterized by cost pressure and cycling product prices. Driven by actual prices, local product markets and local production cost, one time one mine can be most efficient while under different circumstances another mine will be the most efficient producer for the same customer [PENSWICK, 2001]. Therefor in the future the most profitable mining companies will be those who have permanent ?real-time? control on their actual production cost level. Certain approaches are under way to provide reliable modeling tools for aiding mining companies in highly complex decision finding procedures. A high potential for enhancing efficiency is the integration of all single steps of the mining working chain into a production process structure to make advantage of an optimized flow of material and information through the ?moving ore factory? [WIGDÉN, 2001]. Crucial to all these activities is the ability of getting reliable, just-in-time information from the entire mining production chain. As modern mining machinery today is controlled electronically and even already operated autonomously, the theoretical preconditions for the data acquisition is already fulfilled. But up to now, there was no way of cost effectively exchanging the process information with databases, simulation tools and other enterprise level software. Any data exchange problem had to be solved by individual and expensive software development projects. To solve these problems, the International Rock Excavation Data Exchange Standard (IREDES) was launched in 2000 by major players in the industry. The task of this initiative is to define a ?common electronic language? for easy and standardized data exchange between mining machines and central computer systems. As in other industries, this standard is expected to have significant impact on the use of automated equipment. It shall provide easy ways of using multi vendor machine installations in data controlled mining processes. At the same time it reduces cost for individual development of interfaces for all parties involved. The standard?s technical architecture is flexible and open - also for future applications. It uses modern technology enabling easy data exchange with commercial databases as well as open on line networking.

May 1, 2003

By Asfahani. Jamal, Randa Mohamad

"Abstract - Electrical and structural characteristics of formations favorable for sulfur occurrences in northeast Syria are described using geo-electrical prospecting methods. Simple (VES) and combined (CVES) Schlumberger vertical electrical soundings and geo-electrical profiling using a Wenner configuration were applied to the Teshreen structure. Six profiles (A, B, C, D, E, and F) at the borders of anticlines, where positive and negative structures are joined and salt formations have a tendency to disappear, were studied.Secondary structures, characterized by high apparent resistivity exceeding 3000 Ohm.m were located on each profile using a Wenner profiling configuration. These secondary structures are demonstrated to be favorable for sulfur prospecting by both drilled wells and vertical electrical soundings. Traditional interpretation of the 84 VES measurments is supported by data from 14 CVES measurments. The CVES technique is a powerful tool, due to its improved resolution of the electrical boundaries.Thicknesses and resistivities of the Lower Al-Fares, Al-Garibeh, and Al-Dibbaneh formations were determined through the interpretation of VES measurments. The same VES measurments were then interpreted using the Pichgin method, whereby all the subsurface tectonic features were determined for depth penetration corresponding to AB/2 = 1000 m. The integration of the first and second VES phases creates a clear picture of the subsurface, including tectonic, geometric, and geoelectrical information. In summary, the sulfur occurrences in the research area are controlled by tectonic paths that are well defined by geo-electrical methods. These diverse geo-electrical methods could be used successfully for sulfur prospecting in similar environments."

Jan 1, 2002

By Bian Xue, Wu Wenyuan

High quality, mono-dispersed, hollow CeO2 microspheres with high surface area were produced by a spray pyrolysis method at 700oC. CeCl3 was used as the raw material of the process rather than Ce(NO3)3 because the latter is relatively difficult to obtain in industrial quantities. X-ray diffraction and electron microscopy results confirm the high quality synthesis of hollow CeO2 microspheres with narrow size distribution, good mono-disperse, and good reproducibility. The process of the formation of mono-dispersive CeO2 microspheres was investigated by chemical dynamics and a possible mechanism is proposed. This simple method for synthesis of CeO2 microspheres is easily scaled up to fabricate other metal oxide nanostructured materials at industrial scale.

Jan 1, 2014

By P. J. Poirier, J. A. Meech, H. Raabe

"An Expert System has been implemented to assist operators in applying knowledge about froth conditions in the control of the flotation circuit at Highland Valley Copper. For some time, the personnel at Highland Valley Copper have recognized that froth type is a useful indicator of good operating conditions. However, the operating strategy based on froth type recognition is an ad-hoc skill in which different operators use a variety of terms, features and procedures to identify and solve problems. The first phase of this project developed an on-line consultative system to advise and tutor so that the diffuse expertise could be rationalized and consolidated into a standardized format.The second phase has brought this knowledge into a real-time environment to advise the operators on the floor in identifying froth types and troubleshooting corrective action. This paper describes the steps taken to acquire the knowledge, to design the required system features and to implement the real-time version of this system.INTRODUCTIONThe use of expert systems in the mineral industry has been gaining popularity in recent years. Minnova Inc, Les Mines Selbaie, Wabush Mines, Potash Corporation of Saskatchewan are just a few examples of Canadian mining companies that use expert systems to monitor or control their plants. Applications in the field of flotation include Brenda Mines (Edwards, 1992), Mt Isa Mines Ltd (Lacouture et al, 1991), Outokumpu (Karhu, 1989) and Kidd Creek (Burrows et al., 1989).Expert systems are defined as ""computer systems that apply reasoning methodologies on knowledge in a specific domain in order to render advice or recommendations much like a human expert"" (Turban, 1988). The main areas of application are diagnosis, training, process monitoring and control, and design. There are basically two main types of expert systems: Consultative systems, which are off-line applications in diagnosis and design, and on-line realtime systems, used for supervisory process control and real-time advising."

Jan 1, 1993

By David C. Cook

The milling complex, situated just east of the Cassiar townsite, receives raw ore from the tramline and processes it into 105,000 tons per year of milled asbestos fibre. The ore is passed through a concentrator, where a barren rock fraction is removed. The concentrated ore, representing 70% of the feed, is dried, stored and then milled into nine separate fibre classifications. The finished product is packaged into 100-lb bags and loaded into trucks in one-ton units. New air-handling facilities were added in 1977to provide additional air for environmental control.

Jan 1, 1978

By J. Koponen, K. S. Stadler, A. Fuerst, S. Gaulocher, Th. von Hoff, R. Veldsman

"Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO).A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components:1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user.2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer.3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD.In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples."

Jan 1, 2012

By G. R. Baiden

This paper discusses the application of Load-Haul-Dump (LHD) machine teleoperation in combination with a guidance system for single operator control of multiple IJIDs. A system accomplishing these goals has been tested at Copper Cliff North Mine of Inco Limited. This development uses a high-speed, high-capacity production network to teleoperate an LHD during loading and dumping by using 3D video and radio remote control. Following loading, the operator dispatches the LHD using an automatic guidance system to traverse the drifts to the orepass. Remote dumping is done at the ore pass and then the machine returns to repeat the procedure. This has significant productivity gains and improvements in safety. Productivity is improved because operators are involved only in the loading and dumping part of the process. This frees the operators to utilize their time more effectively, loading or dumping a particular machine, while other machines with guidance systems continue to work travelling and/or automatically dumping ore in the ore passes. Safety is improved as the operator is located on a remote control station. Automatic dumping will be incorporated as a future development.

Jan 1, 1994

By John Keay, Douglas R. Shaw, Gregory J. Olson

"The results are presented herein of on-going laboratory investigations of heap bacterial oxidation as a pretreatment method for the recovery of sulfide-encapsulated gold from ore samples of the Rhodes Mining Lahoca deposit, located in northern Hungary. The ore contains just over 2 g Ault and as much as 6% sulfide, mostly as pyrite. Laboratory aerated column tests conducted at Colorado Minerals Research Institute (CMRI) showed that mild to moderate biooxidation of the finely crushed ore occurred rapidly in approximately three months, with cyanide gold recoveries of up to approximately 60%. The results contrast cyanide gold recoveries of less than 30% from non-pretreated ore. Mineralogical examination of biooxidized residues indicated that the mechanism of biooxidation of crushed ore was related to microorganisms following pathways along structural anomalies in the pyrite grains. Such selective biooxidation is an important result to minimize the biooxidation and aeration time and effluent neutralization costs in a commercial operation.IntroductionThis paper describes the development of a heap biooxidation process for the Lahoca gold project The Lahoca deposit is situated in northern Hungary, at the site of a former copper mining area. Lahoca is a large tonnage, relatively shallow, deposit amenable to open-pit mining Lahoca has the potential to produce I 00,000 ounces of gold annually for at least ten years at its minimum reserve base.The laboratory test work conducted initially by Rhodes Mining NL demonstrated that the Lahoca refractory ore is amenable to whole ore and concentrate oxidative pretreatment and cyanidation. Capital and operating costs, however, for such milled ore treatments were considered relatively high. Rhodes Mining subsequently evaluated heap leaching methods, particularly heap biooxidation pretreatment, as a process route that promised superior economics suitable for exploiting lower gold grade refractory ores.This paper focuses on the laboratory column (simulated-heap) biooxidation test work, particularly the proposed mechanism of selective microbial oxidation, wherein only a small amount of the sulfides are oxidized sufficient to allow commercially acceptable gold recoveries by conventional cyanide heap leaching. Selective or minimal biooxidation of sulfides is considered important to minimize biooxidation time and aeration requirements, as well as acid effluent neutralization costs."

Jan 1, 1998

By Fatemeh Pourakbari, Mohammad Reza Yarahmadi, Abbas Sam

Pyrite is the most abundant sulfide gangue mineral in copper porphyry ores. In spite of addition of lime in large quantities to depress pyrite in flotation, considerable amount of this mineral is reported to concentrate, particularly in rougher and scavenger stages. With the Sarcheshmeh pit advancing to a greater depth and reaching to the hypogene zone, the amounts of pyrite and chalcopyrite in the feed are increased. Hence, a reduction in the copper grade and increase in the sulfur content of the concentrate are observed. In this study the effective factors on the pyrite floatability at the circuit flotation was considered at Sarcheshmeh Mine. Mineralization zones in the pit were firstly identified. Then, sampling points were located using GPS system. On the basis of mineralogical composition and morphology, the ore was categorized into five main classes. In this classification the amount of lead and zinc and also pyrite locking with other minerals were analyzed. The study of polished section indicated that inclusion in pyrite was very frequent in all classes, mostly composed of the floatability of pyrite. Flotation tests were performed on the samples of different classes at pH of 11.8 after conditioning time. It was shown that, pyrite floatability was decreased with a decrease in the lead content of the feed samples except for the second class, while for all classes an increase in zinc content contributed to a decrease in pyrite floatability and recovery. It was found that, the lowest pyrite recovery (1.89%) was corresponding to pyrite–molybdenite dominant mineralization with Zn of 0.33% and the highest recovery (86.89%) corresponding to pyrite vein dominant mineralization with Zn equals to 0.9%.

Jan 1, 2016

By Jaeheon Lee

"Biooxidation of gold ores or concentrates could be a very attractive alternative to pressure oxidation (POX) or roasting to liberate the gold grains from various sulfides. Crushed heap bioleaching was successful in US and many operations using tank bioleaching of gold concentrate are currently running around the world. Many parameters need to be considered during the project of sulfidic refractory gold ore process. Capital and operation costs are among the most important ones. Run-of-mine heap biooxidation could be very inexpensive and the smaller the crush size (particle size), the more expensive the capital and operating costs for biooxidation application are expected. The capital cost of biooxidation could be a fraction of the cost for building POX plant or roaster and the operating cost could be 1/3 of POX or roasting depending on the method utilized. A new biooxidation process, Sand Farming, is introduced as an alternative to POX and tank biooxidation process. A relatively coarser particle size (P80 = 650 µm) of the process benefits the low cost of grinding against the conventional grinding size (P80 = 75 µm) for other options. The cost of Sand Farming is less than 40% of that of pressure oxidation with comparable gold recovery from the downstream process. This paper will review the laboratory scale testwork for various biooxidation process of sulfidic refractory gold ores and concentrates and provide the economic evaluation showing the biooxidation could be the most economic method without much sacrificing the overall gold recovery. INTRODUCTIONThe decreased availability and lower grade of raw materials has motivated industries to consider recovering values utilizing low cost process options. The process may treat high grade concentrates or submill grade ores that cannot be processed economically by conventional milling-flotation or leaching. Sulfidic refractory gold ores/concentrates have been economically processed by roasting, pressure oxidation, and biooxidation in stirred tank reactor. The process selection is based on a series of studies including multi-year long ore characterization and metallurgical investigations."

Jan 1, 2016

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By Randy Settgast, Daniel Moos, Hyunil Jo, Ghazal Izadi, Christine Baba

"Analyses of production logs of multiply fractured horizontal wells in unconventional plays show that only a small percent (~30%) of perforation clusters contribute to production. We present in this paper one possible approach to mitigating this problem, based on use of a fully 3-D numerical model of fracture propagation through a heterogeneous medium, by studying the influence both of spacing and of perforation friction on the initiation and propagation of simultaneous hydraulic fractures from a horizontal wellbore. The results indicate that while limited-entry perforating can help to equalize the lengths of fractures simultaneously growing from multiple clusters, it cannot equalize their widths. Both fracture width and fracture length can be equilibrated by combining non-even cluster spacing with limited-entry perforating. This has obvious benefits as it allows equalized placement of proppant across the entire series of perforation clusters, resulting in similar fracture widths and conductivities which enhances the likelihood that all clusters will contribute equally to production.INTRODUCTIONThere is substantial evidence from production logs and other information that during the hydraulic stimulation of horizontal wells, not all perforation clusters within a given stage will produce. One possible cause is the interaction between the hydraulic fractures emanating from each perforation cluster. Typically fractures created at the outer perforation clusters create “stress shadows”, i.e. increases in compressive stress in the minimum principal stress direction, which limit the growth of fractures growing from interior clusters; this is confirmed by modelling [1, 2, 3]. An example of this can be seen in Figure 1 which shows the final configuration of simultaneously propagating fractures from multiple, evenly spaced clusters when there is no perforation friction. The inner fractures are substantially shorter, reproducing the results by Bunger and Peirce [3]. The inner fractures also have substantially smaller widths.One approach to equalize the growth of simultaneously propagating fractures from a horizontal wellbore is by using limited-entry perforating as a method to equilibrate the flow rates into each of the different perforation clusters. Perforation friction is caused by the finite diameter of the entry points into the formation, and leads to a pressure drop across each perforation which is proportional to the flow rate squared. Fractures that take more fluid have a higher fluid velocity through the perforations than fractures receiving less fluid. This causes a larger pressure drop between the wellbore and more rapidly growing fractures, compared to the same pressure drop between the wellbore and the fractures that grow more slowly. Because pressure within the wellbore is approximately the same at each entry point, the larger pressure drop leads to less pressure being delivered to rapidly growing fractures, thereby decreasing their ability to propagate and reducing the amount of fluid they are able to receive. Because the mass rate of injection into the wellbore is constant, this forces more fluid into the fractures that were propagating more slowly, increasing their growth rate. It also increases the pressure required to drive fluid injection. The balance of these effects makes the system largely self-regulating and delivers more balanced fracture growth. While this effect is well known, it is often neglected in current numerical models."

Jan 1, 2015

By D. Royston

Reducing SAG Mill feed size has been a major trend in recent years. ‘Mine to mill’ strategies have reduced blasted-rock size, and in a growing number of operations reducing the primary crusher CSS and/or adding additional crushing upstream of the SAG mill have reduced rock feed size. While reducing feed size will increase SAG mill throughput, issues arise in terms of retaining charge in the mill, exposing the shell lining to impact damage, and maintaining milling performance should the pre-crush system shut down. This paper reviews the past experience on pre-crushing for SAG mills and provides an analysis of liner design (in particular grates and shell liners) for pre-crushed feed.

Jan 1, 2012

By Rodrigo Serna, Nora Schreithofer, Zoltan Javor, Kari Heiskanen

"Mineral floatability is a function of mineral properties such as size, liberation, shape, surface composition, reagent coverage on the surface, level of oxidation on the surface, etc.; pulp chemistry: Eh, pH, temperature, DO, reagent type, etc. and hydrodynamic conditions: turbulence, gas dispersion, D32, etc. The biggest challenge with predicting the floatability of an ore is finding a measurement method that would take into account the effect of all of the variables on the floatability of the minerals. The particle-bubble attachment time measurement is considered as an alternative way to predict the floatability of minerals instead of using expensive and time consuming flotation tests because it takes into considerations both surface chemistry and hydrodynamic parameters present in the froth flotation. The existing particle-bubble attachment time method is suitable for studying some significant flotation variables such as pH, temperature, particle size, reagent type and concentration. Nevertheless, measuring the attachment time as a function of collector coverage or surface oxidation is much more challenging. This paper introduces a new induction timer designed to measure the effect of galvanic interaction on the attachment time of particles. The new setup employs an array of needles to create 6 bubbles with the average size of 2.1 mm. Imaging system is used to set the initial distance between the particle bed and the array of bubbles. The attached particles are collected and sent for further analysis. One of the main benefits of the new experimental setup is that the attached particles can be physically separated from the unattached particles therefore many of the particle properties can be analysed and evaluated.INTRODUCTIONSchumann (1942), and Tomlinson and Fleming (1963) proposed that the flotation rate constant is dependent on four probabilities: particle-bubble collision (PC), particle-bubble attachment (PA), particlebubble aggregate stability in turbulent environment (PE), and particle-bubble aggregate stability in froth phase (PF). Any change in any of these probabilities will affect the overall flotation rate constant. All of the above-introduced probabilities are influenced by stream- variables and mechanical variables but their extent of influence vary. The stream variables are particle properties that have been shown to affect flotation rate constant such as size, shape, liberation, mineralogical composition, reagent surface coverage, surface oxidation, etc. The mechanical variables are the direct and indirect properties of the flotation unit affecting flotation rate constant such as cell and impeller geometry, air rate, impeller speed, air holdup, bubble size, residence time, hydrodynamics, froth depth, etc. For instance, the probability of collision is affected by many mechanical variables (bubble size, hydrodynamics, bubbles holdup etc.) but only one stream variable (particle size) has a major effect on it. On the other hand the probability of attachment is affected by much more stream variables: particle size, shape, liberation, surface composition, particle surface oxidation and collector coverage, Eh, pH, etc."

Jan 1, 2016

By Lastram Rolando, Larry J. Hulbert, Louis J. Cabri, J. H. Gille Laflamme, John L. Campbell, Soey H. Sib, Chris G. Ryan

"The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fine-grained minerals which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700/0 of the major Ni carriers and 78% of the major Cu qurier will be liberated at a grind of 80% -U,.7 ,an (-500 mesh) for typical low-grade gabbro (West zone, sample No.1). For typical ""clinopyroxenite"" (West zone, sample No.2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3) the liberation would be 71% and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total 24.5% for typical low-grade gabbro (West zone, sample No. I), 15% for typical ""clinopyroxenite"" (West zone, sample No.2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fine grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as some would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No.2 and No.3 is closely associated with magnetite. Palladium occurs in diverse ways. It occurs in the form of several Pd minerals (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tellurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chalcopyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerals and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate.However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No.2 and No.3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No.3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No.3, in order to improve Pt and Pd recoveries. Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefined Re-Ir-Qs..Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993