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By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Testwork was conducted in order to compare the effectiveness of carbon based catalysts while oxidizing a gold-bearing pyrite concentrate under atmospheric conditions. Without the use of a catalyst the oxidation of pyrite was incomplete after 96 hours, resulting in roughly 60% pyrite oxidation. Furthermore the resulting sulphate yield from unassisted pyrite oxidation ranged between 72 and 84%. It is evident that atmospheric oxidation of pyrite is not viable due to slow oxidation kinetics and high sulphuric acid production when using a ferric sulphate media without a catalyst. The effect of two different carbon based catalysts, one Lewatit® AF 5 a new microporous carbonaceous bead, and the second a granular coconut shell based activated carbon, were tested under the same oxidation conditions as the unassisted pyrite tests. After 96 hours, Lewatit® AF 5 assisted oxidation showed approximately 96% pyrite oxidation with a sulphate yield ranging between 26 and 35%, while the activated carbon assisted oxidation reached approximately 100% pyrite oxidation with a sulphate yield between 36 and 37%. Testwork indicated that not only does the addition of a carbon based catalyst greatly improve the oxidation kinetics and lead to almost complete oxidation, the sulphate yield is also drastically reduced, resulting in very high elemental sulphur yields.INTRODUCTION Pyrite is an important sulphide mineral due to its ability to contain invisible gold concentrations up to 132 g/t (Chryssoulis & Cabri, 1990). As a result, ores composed of only a small amount of pyrite still have the ability to contain high gold grades. This refractory gold cannot be accessed via conventional gold leaching processes, such as cyanidation, and additional oxidative pre-treatment is required to liberate the gold, making it more amenable to extraction (Marsden & House, 2006). Current oxidative pre-treatments do exist consisting of both pyrometallurgical and hydrometallurgical processes including high temperature and high pressure leaching within autoclaves, biological atmospheric leaching and roasting. Autoclaves are a proven process reaching desirable recoveries within approximately a 1–2 hour retention time, due to the increased temperatures and pressures, allowing for an increase in dissolved oxygen (Marsden & House, 2006). The typical reaction for pyrite oxidation within autoclaves is presented in Equations 1, 2 and 3."

Jan 1, 2017

By Guangdong Institute of Resources Comprehensive Utilization, Y. H. Tang, H. X. Hu, T. S. Dong, Z. H. Zhang

"A world class rare metals ore deposit in Africa belongs to a massive granite type poly-metallic pyrochlore-niobium resource. Successful project development in realizing the resource is vital to Africa’s economy and pyrochlore processing technology.The ore properties are quite complex due to the presence of varieties of valuable minerals, fine dissemination and intimate association of minerals and the relative abundance of easy-floatable minerals. The separation of pyrochlore from zircon, calcite and mica is generally considered difficult. Whilst studies have previously been conducted by several independent institutions overseas, no satisfactory process has yet been developed to date for the ore deposit—possibly due to the process designed being too complex; high cost of regents; lower performance.Based on process mineralogy study and extensive testwork, the authors have in recent years developed a new technology—“De-slime—Iron-rejection—Zircon (with calcite) and Calcite reverse flotation—Pyrochlore flotation”. The flow-sheet is characterized by ?1prior removal of slimes and iron minerals; ?2 Zircon (with calcite) and Calcite reverse flotation; and ?3Pyrochlore flotation applying new type of chelating collector GYX3 developed by GZRINM in conjunction with selected regulators and depressants.The process involved in the new technology is simple to implement and facilitates stable operation; the flotation reagent regime is easily adaptable; the cost of main reagent is lower largely because it is easy to manufacture and is environmental friendly. Laboratory test results demonstrated that, for raw ore assaying 0.35% Nb2O5, 0.03% Ta2O5 and 0.45% ZrO2, pyrochlore concentrate grade of >35% Nb2O5 could be obtained with >74% recovery. Meanwhile, the Ta2O5 content in pyrochlore concentrate could be recycled, and ZrO2 recovery >50% could be achieved in zircon concentrate assaying ZrO2>63%—significantly improving the technical-economic indicator. These results were verified in pilot trials of 1.44t/d throughput. The paper presents the new technology in whole, summarizes the key factors affecting its performance and discusses in simple terms the mechanism of separation."

Jan 1, 2016

By T E. Tibbetts

This paper deals with coal sampling in general and with mechanical coal sampling in particular. The necessity of obtaining representative samples is emphasized. Other sections of the paper are devoted to the design and selection of automatic samplers, with a consideration of the three main types, and the testing, operation and maintenance of these samplers. The cost of the installation of an automated sampling system must be related to the value of the material to be sampled, to the volume of coal involved, and to the savings in labour and economy which can be achieved. Introduction T HE Committee?:; on Coal Sampling of the Coal Study Subsection, Thermal Power Section (Eastern Zone), Canadian Electrical Association, was established in November, 1963, to "study the various problem areas of coal sampling." The first undertaking of the Committee was to at-tempt to survey the problem areas of coal sampling through an evaluation of coal sampling difficulties as experienced at both the plant design and operational levels within the electric utilities represented on the Committee. The results of this enquiry indicated that satisfactory answers to almost any conceivable

Jan 1, 1965

By J. Visman

The water cyclone washer has a number of advantages that makes it a desirable machine for the cleaning of fine-grained and friable materials such as 1,4 x 0" slack coals. In this paper results are presented of tests carried out on a shaly coal containing a high percentage of inter-grown materials from the Minto area, New Brunswick. The tests were con-ducted in the pilot plant of the Western Regional Laboratory in Edmonton. The test results show that the cleaning characteristics of this coal can be improved by lightly grinding the recirculating middlings fraction, which constitutes approximately 30 per cent (1.45-2.00 fraction) of the raw feed. • The cleaning of 1;4 x 0" fines by water cyclones compares favourably with other coal cleaning machines and has an added advantage of being extremely simple to operate, low in capital and operating cost, and high in capacity. The application of water cy-clones dates back approximately ten years, following its development at the Dutch State Mines. ( 3) A number of papers published d

Jan 1, 1961

By P. F. Berry

X-ray fluorescence analytical techniques are fairly well established in the mining and metallurgical industries. In recent years, instruments utilizing radioactive isotopes have been developed which, owing to their more compact size, greater reliability and independence of substantial power supplies, are often preferred to X-ray tube installations. Analyses can now readily be carried out in the field, on the factory floor and in otherwise difficult locations. This paper describes many examples of radioisotope X-ray fluorescence for the analysis of metallic minerals, finished metals and alloys and also for the continuous measurement of metallic coatings, such as tin and zinc, on steel. Radiation scatter techniques are also described for certain analyses and for thickness and density measurements.

Jan 1, 1967

By A. Rao, J. A. Davidson, B. L. Jones, K. W. Bowes, D. Craib

Supported by ANSTO, Groundwater Science and Inception Consulting Engineers, Boss has embarked on a series of technical projects aimed at reinforcing the Project’s capability to meet its export permit production capability. This paper will focus on three aspects of this technical program: Reducing the cost of resource expansion through smart use of low cost, surface target generation techniques; Improving the rate of uranium leaching and solution stability (gypsum, jarosite) through lixiviant chemistry modifications; and Development of an ion exchange (IX) process to increase production capacity, and integration of IX and the current solvent extraction circuit with the existing uranium precipitation and product preparation circuits.

Jan 1, 2020

By Jean Scott, G. A. Collins, G. W. Hodgson

WHILE it is well known that trace metals in crude •oils and distillates have been a matter of deep concern to refining engineers because of the damage done .by the metals to cracking catalysts and refractories (8, 5), the trace metals in crude oils may be of great benefit in correlation studies and in origin studies. During the geological processes in which the oil is formed from •animal and vegetable life, the hydrocarbons are subjected to a host of inter-related reactions, both physical and chemical. It has been well demonstrated that the lighter materials, certainly the short-chain paraffin hydrocarbons, are degradation products of the heavier molecules, and it might be concluded that for correlation studies it would be advisable to direct attention as much as possible not to the degradation products of the large molecules but to the large molecules themselves. Be this as it may, the methods at •hand to conduct the study are not particularly precise and, in the past, attention has centred on the simpler small molecules, as evidenced by the great mass of work involving distillation and chromatography with painstaking separation of the simpler 'front-end' hydrocarbons.

Jan 1, 1954

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013

By P. J. Lunder, R. C. Pakalnis

This paper presents the results of research that has been undertaken in order to develop an improved method of determining the strength of hard-rock mine pillars. Pillars are found in various shapes and sizes in all underground mining operations. Prudent engineering design requires that if pillars are to perform as desired, both the pillar strength and the pillar stress must be determined. A detailed pillar stability study has been combined with an extensive database of published pillar case histories (178)resulting in a new “hybrid” pillar strength formula, “The Confinement Formula”, that utilizes classic strength of rock methods combined with empirical methods. “The Confinement Formula” utilizes a “mine pillar friction term” calculated from the average minor/major stress ratio with-in the pillar core. Statistically, the new formula provides better results at predicting pillar strength for the combined database than the best empirically ft pillar methods that currently exist. “The Confinement Formula” allows for the determination of the strength of mine pillars with an increased level of confidence over previously applied methods.

Jan 1, 1997

By Chris M. Healey

"Abstract- The Jasper Gold mine in northern Saskatchewan produced a total mill feed of 140 127 tonnes at an average grade of 19.0 g/t Au. Both diamond drilling and chip samples from under­ ground workings returned extremely high values, up to 12 851 g/t (375 oz/I) Au over 0.10 meter from a chip sample. In the presence of such extremely high grades, the accurate estimation of reserves is a major problem.ln the first part of this study, production data from the mine were used to evaluate the results of a variety of reserve estimation techniques in this environment. In two out of three cases studied, indicator kriging with assays cut to 342.9 g/t (10 oz/I) gave extremely good results. In the third case, however , indicator kriging gave unacceptable results. Instead, lognormal kriging of uncut data gave the best results.Secondly, from the same database, a number of drill-hole spacings were simulated, and reserves estimated from the simulations. As may be expected, the results of this analysis show increasingly better results with tighter drill-hole spacing. However, even with a 5 m by 5 m spacing the variation from actual grade was quite large. This is not a systematic under- or over-estimation of grade, rather a random scatter of results .The results of this study show very clearly the problems of deriving good estimates of reserves when extremely high-grade samples are encountered. There is a high degree of randomness to this database, so reserve estimation in this situation will remain a high-risk operation."

Jan 1, 1993

By W. R. Bacon

"The Canam property is in southern British Columbia, 24 miles southeast of Hope. It is reached by 5 miles of road from Mile 26 on the Hope-Princeton Highway.Between the years 1930, when the property was discovered, and I 938 development work by The Consolidated Mining and Smelting Company of Canada, Limited included some open-cuts and six adits totalling 2,700 feet in length. Canam Copper Company Ltd. explored the property intermittently from 1947 to 1955 by diamond drilling and underground work, including driving No. 10 adit. From surface down to the level of No. 10 adit, about 1,250,000 tons of ore has been outlined with an approximate grade of 1.25 per cent copper, 0.8 ounce silver per ton, and 0.01 ounce gold per ton. The ore in the upper part of the deposit also contains a little molybdenum and a little uranium.In June, 1955 Canam Copper Company Ltd. made arrangements to have the property brought into production under the direction of Mogul Mining Corporation Ltd. of Toronto, and a new low level adit has been started.GENERAL GEOLOGYThe principal rocks on the Canam property are chert, cherty argillite, and argillite. They are considered to be Jurassic or Lower Cretaceous in age. Although massive bands to 150 feet in thickness occur, these rocks are in general thinly bedded. Conformable bands of pyrrhotite, a fraction of an inch in thickness, are not uncommon in the well-bedded rocks, and fine tourmaline can be observed in various places.The sediments strike slightly west of north and dip quite steeply, generally eastward; however, sharp divergences from this general attitude are fairly common.Dark grey dioritic sills, in which slender prismatic crystals are conspicuous, are fairly common in the sediments. In general the sills are less than 25 feet in thickness, but a few are as much as 100 feet thick. Under the microscope the sills are seen to consist largely of amphibole (pargasite) and plagioclase (near An50)."

Jan 1, 1949

By M. Mohammadijoo, J. B. Wiskel, D. G. Ivey, S. Kenny, H. Henein

Cold-wire tandem submerged arc welding (CWTSAW) has recently been developed as a novel welding technique to replace the conventional tandem submerged arc welding (TSAW) process and improve the productivity of pipeline manufacturing. The process involves two electrodes with arcs and one electrically cold electrode. Since heat-input of the welding process is a key factor affecting the properties of the weld metal (WM) and the heat-affected zone (HAZ), and the additional cold-wire affects the heat introduced to the weldment, it is of interest to investigate property and geometry changes in the WM and HAZ when a cold-wire is added to the welding process. In the current research, the CWTSAW process is investigated and optimized by correlating the main welding parameters with the micro-hardness of the WM and HAZ and the geometry of the weld, i.e., the bead width (BW), penetration depth (PD), reinforcement area (RA) and coarse grained heat-affected zone (CGHAZ) area. Three statistical and mathematical methods are employed to optimize the CWTSAW process in terms of the mechanical properties and WM and HAZ geometry of a typical microalloyed steel used for pipeline manufacturing.

Jan 1, 2015

By M. B. McClenaghan, O. P. Lavin, Ian Nichol

"Abstract-Exploration in most areas of Canada has to contend with problems posed by glacial overburden. In many areas exploration for gold has been based on the sampling of tills, frequently by deep overburden drilling, and analyses of heavy mineral concentrates. Notwithstanding the significant role that till geochemistry has played in the discovery of some important gold deposits over the last few years, increased appreciation of the nature of the glacial history and stratigraphy and the character of gold within till has led to the recognition of a number of ways whereby the effectiveness of exploration can be improved upon.In order for till geochemistry to be useful in exploration, a number of conditions must be fulfilled, including:1. mineralization, or alteration halo related to mineralization, subcropping at the bedrock /over­ burden interface; 2.glacial erosion and dispersal of a recognizable signature of mineralization into the glacialsediments; 3, preservation of glacial sediments containing this geochemical component (trace metal or mineral) at positions subsequently selected for sampling (normally drill sites); 4. correct identification of specific till units and associated ice movement history; 5. collection of adequately large and representative samples; 6. appropriate sample preparation and processing; 7, appropriate geochemical analyses; and 8. correct data processing and interpretation.While we have no control over the first two geological conditions, and only limited controlover till availability, we can control the quality and thoroughness of sampling, sample identification, sample preparation, analysis and interpretation. In particular attention needs to be focussed on obtaining a large enough sample to be adequately representative, an unbiased sample must be collected, together with appropriate sample processing, analysis, data processing and interpretation. It is considered that by modifying or extending existing approaches to gold exploration the chances of exploration success can be increased. In particular, analyses of both the heavy mineral and minus 63 ?m fractions of till is recommended because gold in till may occur in different size fractions."

Jan 1, 1992

By J. G. Kelly, C. P. Brown

"In June 1983 a new borehole hoisting system was commissioned at Sherritt Gordon's Fox Mine. Twelve hundred tons-per-day of ore from the 2600 and 2800 levels are being hoisted to the 2000 level through an 8-jt diameter bored winze. This new method replaces the diesel truck haulage system which had been in operation at the mine since 1975.A study was initiated in 1980to determine the most effective method of achieving the required production. The study examined several hoisting alternatives including: expanding the existing trucking system; converting to electrically -powered truck haulage; and deepening the skip compartments of the existing main shaft. The alternative selected as the hoisting method most suited to the requirements was borehole hoisting.Development of the new system commenced in April 1982. Underground excavations included 700 feet of 8-ft diameter borehole, a hoistroom and headframe, storage bins, and a grizzly and rockbreaker station. Equipment installations included: a 5-ft diameter double-drum Nordberg hoist; a counterweighted Kimberley-type skip; two rockbreakers; and the steel sets in the winze. These installations were completed in June 1983. Some problems were encountered after the initial commissioning but these were solved, and since August 1983, the system has proven that the designed capacity is achievable within expected costs."

Jan 1, 1985

By John Stubbles

Data are presented on the global warming issue to reinforce the decision by the U.S to reject the Kyoto protocol. The evidence that CO2 is a problem rather than a benefit is inconclusive and will be discussed in this paper. Nevertheless, for economic reasons alone, the US steel industry will continue to minimize CO2 emissions (and the release of real pollutants) per ton of steel through energy reduction programs. However, relative to inevitable increases in absolute CO2 emissions from the utility industry and the transportation sector, future reductions by the steel industry will be inconsequential in the "big picture."

Jan 1, 2004

By L. H. Van Loon

INTRODUCTION THE property of Madsen Red Lake Gold Mines, Limited lies between Russet and Faulkenham lakes in Baird and Heyson townships, district of Patricia, Ontario. It is about six miles south west of the town of Red Lake, with which it is connected by an all-weather road. All orebodies found to date at the property are silicified lenticular bodies which lie within tuff beds. The ore bas a specific gravity of 2.95. It consists of mica and chlorite schist, silicified and containing a considerable amount of disseminated carbonate, and mineralized with pyrite, pyrrhotite, magnetite, arsenopyrite, and chalcopyrite. Of these, pyrite, in coarse to fine disseminated grains, is by far the most abundant. Pyrrhotite occurs in ?the gangue material as medium to fine disseminated grains. A very small amount of arsenopyrite, in small crystals, is associated with the pyrite, and small grains of chalcopyrite occur in both gangue and pyrite. Although some of the gold present in the ore is quite coarse, a good deal of it is extremely fine.

Jan 1, 1951

By W. A. Lang

COAL of sub-bituminous rank underlies much of the plains area of Alberta. This coal is geo-logically young, and occurs in Belly River and Edmonton strata of Up-per Cretaceous age. Generally, the seams are flat-lying, but in some areas they may dip as much as 5 degrees. The overburden, composed mainly of glacial clays and sand-stones, may vary in depth from a few feet to several thousand feet. Recovery of the coal has 'been by drift, slope, and shaft underground mines, and by open-pit stripping operations. Production has been obtained from a large number of mines, most of which have been relatively small and with preparation equipment limited to a loading tipple with screening facilities, and a picking belt where high-ash materials can be removed from the larger sizes. The coal has been sold for domestic and industrial space-heating, for production of process steam, and for power generation. In re-cent years competition from natural gas, propane, and oil has seriously interfered with the production and marketing of sub-bituminous coal, especially with the disposal of the smaller sizes at a realistic price.

Jan 1, 1958

By B. R. Boardman

Project Environmental Approval is a multi-faceted issue. From a mining perspective, it is a costly item because of avoidable time delay. The government perspective is that the approvals are a necessary part of meeting departmental requirements to ensure that the wellbeing of other uses of the environment is maintained. This paper outlines some of the problems inherent in the environmental approvals process and makes recommendations to both the proponent and government about improving the efficiency of the process.

Jan 1, 1978

By S. Kariyawasam, R. McNealy

Pipelines are subject to multiple threats often requiring quantification of pipeline risk and engineering evaluation of in-line inspection and other data to effect discovery of conditions defined by the regulation. Public concern and pressure from regulatory bodies are accelerating the need for pipeline operators to formalize and intensify their approach to integrity management. Most operators need a phased approach to progressively adopt the most relevant and needed assessments. The organized and relevant assessment steps need to be introduced according to data available and maturity of the integrity management program. Each refinement to the quantification offers distinct advantages to the user. In this paper, the progressive integrity assessment solutions using quantitative methods are presented. Methodologies for engineering evaluation of integrity in-line inspection data for immediate and future integrity are summarized. Corrosion is used as an example, but the approach is applicable to any time-dependent defect based hazard. Strategies for pipeline integrity management are discussed.

Jan 1, 2005

By Ross L. Sherlock, David J. Scott, Gordon MacKay, Wayne Johnson

"Abstract - The demographics of Nunavut indicate a very young and poorly educated population spread over wide areas in small isolated communities. The current economic sectors will be unable to expand and meet the demands of this emerging workforce. Given the realities of Nunavut, the most promising direction in which the economy may expand is through mineral development. The Nunavut Land Claims Agreement (NLCA) has established the legislative framework for sustainable development in Nunavut through mineral development. The NLCA has transferred ownership for much of Nunavut’s potential mineral resources to beneficiaries of the lands claim. Royalties generated from mining operations on subsurface Inuit-owned lands, and to a lesser extent on Crown land, will flow back to beneficiaries of the lands claim through their administrative company, which may then be invested in the communities. Additional benefits of mineral resource development in Nunavut will be realized through impact and benefit agreements.To realize the benefits from mining operations, Nunavut has to be able to attract and support exploration and development companies through the release of high-quality geoscience data. However, due to Nunavut’s isolation and the expense of conducting geoscience fieldwork, the jurisdiction lags far behind the rest of Canada in terms of quality and quantity of government geoscience. About 70% of the territory is inadequately mapped to attract exploration companies or to make informed land-use decisions. The role of government-funded geoscience in Nunavut is to stimulate exploration and discovery through new framework mapping and focused thematic projects. The timely delivery of high-quality geoscience products will attract exploration companies to Nunavut and further their efforts to discover and develop mineral resources in order that the subsequent benefits of this activity may flow to the beneficiaries of the NLCA as well as all other residents of Nunavut."

Jan 1, 2003