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By K M. Watling, F M, G K. Parker

Surface enhanced Raman scattering (SERS) spectroscopy at surfaces under electrochemical control has been applied to elucidate the adsorption of thiol collectors. SERS spectroelectrochemical studies at coinage metal electrodes have been carried out on ethyl xanthate and three iso-xanthates, O-isopropyl-N-ethylthionocarbamate, 2-mercaptobenzothiazole, diisobutyl- dithiophosphinate and butylethoxycarbonylthioura. For each collector, adsorption occurs via charge transfer to form a metal-sulfur bond and, in situations for which the reversible potential of the formation of the bulk phase is known, at underpotentials.

Jan 1, 2005

By Koh P. T L, Varnas S. R

Fluid flow, heat transfer and combustion in a nickel flash smelter have been investigated by numerical modelling and flow visualisation. The three-dimensional numerical model incorporates turbulent two-phase fluid dynamics, radiative heat transfer and combustion. The main features include the use of the k-E turbulence model, the Lagrangian tracking of particles, radiative heat transfer based on the spherical harmonics method, and chemical reactions. The predicted flow fields are in good agreement with data obtained from a series of flow visualisation experiments on a cold water model. The interaction mechanism between the fluid flow and the solid particles is examined for a range of particle sizes both with and without injected oil in a series of simulations. The heat transfer in the shaft is dominated by combustion and radiation, whereas the ignition of particles is influenced by the particle size and the added oil. Flow and temperature fields for both gas and solid particles are presented as well as the fraction of sulphur removed from the particles.

Jan 1, 1992

The Hellyer deposit, hosted in the Cambrian Mt Read Volcanics, displays features typical of volcanogenic massive sulphide orebodies. These include a well developed stringer zone, metal zonation within the orebody, a polymict volcaniclastic sequence flanking the deposit and a hangingwall alteration plume in overlying basaltic pillow laves.Mapping and core logging is very detailed in order to extract as much data as possible from the deposit and its host rocks. A geological log suitable for direct computer input was adopted shortly after the deposit's discovery.

Jan 1, 1990

By P B. Hills, R J. Walton

Narrow vein tabular orebodies are prone to mining induced seismicity. The Tasmania Mine is a complex example of a seismically active tabular orebody, where the contrasting material properties of the host strata and of the orebody itself, serve to exacerbate the seismic response. Analysis of a continuous record of seismicity over a period of seven years has provided significant insight into the fundamental mechanics of the rock mass. Understanding seismicity to permit safe extraction of the orebody has been enhanced by instrumentation of rock mass behaviour in response to mining and mining induced seismicity. It is the purpose of this paper to explore that understanding in respect to the adoption of an alternative down-hole Avoca stoping method for use in particular circumstances.Intensive instrumentation of the Tasmania Mine over a period of four years has provided insight into the behaviour of the rock mass in response to extraction of the narrow vein orebody it encompasses. A range of instruments have been installed in clusters or single installations in order to measure changing stress conditions and the impact of those changes on the rock mass and the reinforcement system.Instruments are often installed in very close proximity to active production stoping. While it has been possible to observe the impact of the mining and mining induced seismicity at very close quarters, instruments installed in these locations are vulnerable to damage and consequently, the level of instrumentation is high. Instruments are continuously logged, typically on a six hourly basis coinciding with the end of regular blasting times. The response of the instrumentation to changed rock mass conditions is considered against the background of development and production blasting and against the seismic record to assess the viability of downhole Avoca stoping.CITATION:Hills, P B and Walton, R J, 2012. Continued observations of rock mass behaviour in response to stoping at the Tasmania mine, Beaconsfield, Tasmania, in Proceedings Narrow Vein Mining 2012 , pp 169-178 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

The Tom, East and West zone, stratiform Zn-Pb-Ag deposits at Macmillan Pass, Yukon, Canada were discovered by Hudson Bay Mining and Smelting Co Ltd prospectors in 1951. Further exploration, including two phases of underground exploration produced an HBM&S calculated reserve of 9.28 Mt of 7.5 per cent Pb, 6.2 per cent Zn and 69.4 g/T Ag for these zones. Cominco Ltd optioned the property in 1988. Deep, surface drilling extended the West and Southeast zones downward 200 - 300 m, indicating an additional potential resource of several million tonnes of good grade. The magnitude of the controlling syndepositional setting suggests that mineralisation continues to greater depth but with increased drilling and possibly mining costs. The 30 x 60 km Macmillan Fold belt trends WNW across the NW Selwyn Basin and Cordilleran trend. Within the fold belt, the Central Block - a complex, rift controlled basin of Devonian siliciclastics, hosts seven zones of Pb-Zn-Ag mineralisation clustered about four hydrothermal centres. The centres, distributed over 24 km, are coincident with small syndepositionally active structural sub-basins. The Tom deposits, in one such sub-basin, are localised by a third order structure consisting of two palaeobathymetric troughs flanking a syndepositional horst. This structure caused drastic facies and thickness changes over 600 metres of strata and focussed the venting of hydrothermal fluids through permeable conglomerates in the horst and its flanking growth faults. Mineral facies are zoned, with Pb-Ag contents rapidly diminishing outward from the vent resulting in restricted areas of high grade Pb-Zn-Ag-Ba ore within more extensive, sub-economic, Ba-Zn mineralisation. Widespread iron carbonate alteration of the footwall and high Si, B and Zn values in the hangingwall 'fingerprint' the deposit and along with the distinct facies variations provide aids to exploring the Tom and like deposits.

Jan 1, 1993

By James S. E

Financial risk of environmental problems is the key to many important business decisions within the mining industry. Massive uncertainty makes it difficult to choose a strategy for managing environmental problems to reduce corporate financial exposure to environmental impairment. A correct and practical method exists to clarify the risks and help make decisions. A case study on an insurance problem illustrates the method.The approach used is to translate existing data on environmental problems into probabilistic expressions of financial risk, and organise the expressions to reveal alternative solution strategies for the insurance problem.

Jan 1, 1993

By Rigby D, Gould K. W, Hart G. H

The variation in chemical and isotopic composition of hydrocarbon gases generated from humic source rocks in the Cooper Basin, the orth West Shelf, the agoorin oil shale deposit. ollinsville and the southern Sydney Basin is reviewed, discussed and interpreted.The primary composition of gases generated in and released from such source rocks appears to be very largely controlled by the degree of dispersion of the organic material. For example in eoaly shales, where the degree of dispersion may be high, products as generated may escape into surrounding inorganic structures where further maturational reactions may proceed. On the other hand, when the organic materials occur in massive form, as in coal seams, the hydrocarbons generated tend to be retained within the coal. Further cracking to the stage of methane generation is usually required before release of hydrocarbon products is significant.Secondary factors of importance in determining seam gas composition in the Bowen (Collinsville) and southern Sydney Basins are the invasion of coal measures by carbon dioxide from external magmatic sources and/or the vertical diffusion and loss from the surface ofgases generated at depth.Isotopic measurements of gas composition have been particularly valuable in determining the origins and histories of the gases examined, in demonstrating when gases are of mixed origins and in the prediction of gas quality in exploration.

Jan 1, 1985

By Soma T

Pyrite and Cu-concentrate were roasted in vertically suspended state in an externally heated tube. Tubes of three different lengths of reaction zone were used for three different reaction times. Roasted ores were submitted to chemical analysis and the extent of roasting reactions was determined. In case of pyrite, extent of roasting reactions was not affected much by reactor length and heating temperature (above 500¦C), but was considerably by ore/air ratio. Micro- scopic and XMA examinations led to the conclus- ion that pyrite particles decomposed to pyrrho- tite and then pyrrhotite was oxidized to give Fe-S-0 melt, magnetite and hematite. The extent of reaction was not uniform in all particles but had a wide distribution from unreacted pyrite to completely oxidized particles. Combustion of Cu-concentrate from Kuroko complex sulfide ore ) was unstable under a uniform wall temperature of 450¦C, but proceed- ed rapidly at temperatures above 500¦C. Sticking of roasted ores to the wall of the reaction tube induced choking of the tube, caused by melting of roasted ores, at tempera- tures above 950¦C. Enrichment of oxygen exterted less influence on reaction rate than heating temperature of the tube. Particle size of ore had a big effect on reaction rate.

Jan 1, 1980

It is a privilege for me to participate in this vitally important discussion of The Role of Governments in the Management of Resources. The distinction of my fellow participants is evidence that this event is a matter of extreme importance and attracts international attention. In the management of natural resources, government and private enterprise share awesome responsibilities for the economic well-being of nations. Mining and its relation to the prosperity of nations is almost as old as recorded history. Copper was being mined and extractive metal- lurgy practised at Timna in Israel's southern desert as far back as 4000 B.C., and the rich mines of Laurium not only saved the Greeks from Persian domination 2500 years ago, but also provided Athens with a monopoly of silver in the Mediterranean world. This bolstered the economic power of Athens and led to the golden age of Greek commerce and culture.

Jan 1, 1978

A nine-month investigation was conducted into the effect on coke quality and blast furnace operation of the addition of bentonite and southern coal to the northern coal fed to the coke ovens at the Newcastle steelworks.Additions of 0·3 per cent bentonite or 25 per cent southern coal to the northern coal increased the coke strength from 15-20 A.S.T.M. stability to 25-30 A.S.T.M. stability. It is likely that improved mixing and blending facilities would, in both cases, give a coke of over 30 A.S.T.M. stability.For the same coke strength, the use of 0 3 per cent imported Wyoming bentonite was considerably cheaper than the use of 25 per cent southern coal, but the use of Australian bentonite promises the same coke strength for still lower costs. Other additives such as coke breeze, charcoal, iron ore fines, and certain other finely divided materials, gave relatively minor improvements in coke quality.There appeared to be sufficient improvement in blast furnace operation and production to justify full scale addition of bentonite to improve coke quality, although other variables, particularly iron ore physical quality, overshadowed on many occasions the effect of coke quality. Further coke trials with southern or bentonite will be carried out when ore quality has been improved by the introduction of ore sintering at Newcastle.INTRODUCTIONDuring the period of operation of the Newcastle coke ovens and blast furnaces from April 1960 (when No. 3 blast furnace was blown in after rebuilding) to December 1960, a bentonite coke trial was carried out based on earlier research findings (Gregory, 1959a, 1959b; Felton and Gregory, 1960; Gregory, 1960) that as little as 0 3 per cent to 05 per cent bentonite clay added to northern N.S.W. high volatile coking coals gave a significant increase in coke strength. The bentonite coke trial was followed by trials...

Jan 1, 1962

A research and testing facility has been developed at Simtars to allow the spontaneous combustion testing of coal on a large scale. In this adiabatic reactor, the coal particle sizing is closer to that which could be found in the goaf and therefore the reaction is more likely to simulate the underground situation. This allows aspects of the spontaneous combustion process and methods for detecting a heating to be investigated which cannot be done in an operational mine. Up to 18 tonnes of run of mine or crushed coal is loaded into the reactor and allowed to self-heat while the temperature and gas profiles within the coal pile are monitored. The gases evolved from the coal are analysed using a fixed gas monitor system and gas chromatography to determine which of the common mine fire indicators and ratios can be used to predict the onset and progress of coal heatings. Benchmarking of the inherent propensity of a coal to spontaneously combust at both the large- and laboratory-scale is also possible by comparing the sample against previously tested samples. It has been found that the coal particle size affects both the time it takes for the coal to react and the location of the developing heating. The heatings generate approximately one metre from the inlet but in the crushed coal case do not progress to an advanced heating stage until the æhot spotÆ migrates towards the coal surface where there is an increased oxygen supply. Physical properties such as the compressive strength of the coal also affect the heating size and the time it takes for a heating to develop. Higher strength coals appear to oxidise more slowly and therefore take longer to self-heat as oxidation of the coal is the heat-generating step in the spontaneous combustion process. The best indicators of the state of the heating were found to be CO make and GrahamÆs ratio which are independent of air flow. Investigation of a potential spontaneous combustion should begin as soon as the CO make or GrahamÆs ratio exceed the background levels. The results from the tests undertaken on a number of Queensland and NSW coals are reported here together with the implications for the mining industry.

Jan 1, 2005

Alcoa of Australia's Western Australian bauxite mining operations in the Darling Ranges, southeast of Perth, present major challenges in the control of air blast. The close proximity of rural communities and the face profile make the traditional methods of air blast control difficult.An extensive blast noise monitoring programme has been established. The development of a computerised blast noise prediction model and the establishment of a radiosonde weather balloon facility have reduced blast induced complaints by a factor of ten.The meteorological factors affecting blast noise transmission are discussed and examples are given of adverse weather conditions for the southwest region of Western Australia.

Jan 1, 1983

In reviewing recent developments in the process mineralogy of gold it is convenient to distinguish between visible (>0.1 pm) and invisible gold (1 - 2 pm in size in polished section; these can scan the surface of a polished section, identifying the gold minerals, recording co-ordinates of the grains for subsequent examination, and making measurements of areas and sizes of the grains. However, problems of sample reliresentivity in polished section mean that such data may not give good quantification of gold mineral proportions and liberation/locking characteristics and other methods are required for this (amalgamation, cyanidation, ultra-fine milling and cyanidation). Characterisation of invisible gold in bulk material (eg a sulphide concentrate) can be done by mineral separation, ultra-fine milling and cyanidation or by quantitative point analyses of a large number of mineral grains. Analytical methods include electron microprobe analysis (detection limit normally -200 ppm but -10 ppm by using special techniques), ion microprobe analysis (secondary ion mass spectrometry - SIMS; detection limit -0.2 ppm) or proton microprobe analysis (PIXE; detection limit

Jan 1, 1992

By Tagawa H

In Japan, geological condition do not only vary in a wide range of strata but are also extremely complex with the existence of faults and aquifers. With respect to rocks, in particular, it is very rare that homogeneous rocks are distributed uniformly. In general, geological conditions are distributed in a wide variety, ranging from earth, sand, soft and medium rocks to hard rocks. Under these geological conditions, when planning of the tunnel construction is to be made out, either blasting method or tunnel boring machines must be selected taking into consideration the geological structures along with the designed tunnel route,' possibility of encountering aquifers, hardness of rocks anticipated and also, the adjacent environ- mental conditions. In the process of select- ing an excavation method,, it is important to make a comparative investigation between the above two methods considering the advantages and disadvantages with regard to the respective operating efficiency, economical efficiency and the conditions and scope of application as well. Furthermore, in addition to these considerations, the recent environmental restriction, which does not allow the blasting in the surroundings of residential areas, must also be taken into account. Because of this, in some cases there is no alternative but to use a static excavation method or a tunneling machine even when these are less efficient than blasting.

Jan 1, 1987

By Clarke RG

Renison Mine was developed as the first all diesel mine in Australia. The foresight of the early planners in committing the Mine to Decline access has paid dividends in the past two decades with Renison Mine establishing itself as one of the most productive underground mines in the world. The excellent productivity has also resulted from the development of mining equipment technology, both on the part of the equipment suppliers and through the coordination of the Mining, Automotive and Technical Design Sections at Renison Mine. Constant improvements in truck and loader design, the design of specific equipment to carry out specialized tasks such as installation of services, scaling and ground support and the conversion to electrically powered equipment have been ongoing at Renison. Currently, larger scale trucks are being investigated for ore and waste haulage due to increased haulage distances and production requirements. It appears as though an articulated low profile truck of around 50 tonnes capacity may provide the short term solution based on the performance data available.

Jan 1, 1982

In the first half of 1987 two four metre diameter raise bore holes were drilled at the Olympic Dam Project for ventilation purposes. The first hole, 476 m x 4.0 m diameter was completed in 96 days, 35 days longer than scheduled. The second hole, 407 m x 4.0 m diameter was completed in 39 days, 2 days ahead of schedule. Both holes were drilled with a Robbins 121R rig using a Wirth head that consisted of 23 face cutters and 5 side cutters, supplied by a contractor. After the sites were located a grouting program was carried out to help seal off an aquifer between 160 and 180 m below the surface. Cavities discovered in the Andamooka Limestone were filled with concrete. Because of the overlying dune sands and clay both sites were pre-sunk to the competent Andamooka Limestone.

Jan 1, 1988

By P J. Howard

Atlas Iron Limited’s McCamey’s North project lies at the eastern end of the Hamersley Basin, approximately 50 km east of Newman, Western Australia, and 3 km northeast of BHP Billiton’s Jimblebar Mine. The presence of significant surface iron mineralisation identified during field reconnaissance, has subsequently been further defined by detailed mapping and RC drilling.The project area is dominated by outcrops of moderate to steeply north and south dipping banded iron formation, cherts and shales of the Boolgeeda Iron Formation overlying rhyolites and rhyodacites of the Woongarra Volcanics. In lower lying areas recent colluvium and alluvium mask the Archaean geology. Drilling and downhole geophysics has allowed a composite stratigraphic section to be compiled through almost the entire Boolgeeda Iron Formation.Surface orientations and subsurface stratigraphic correlations using natural gamma logs indicate large scale open folding about east-west trending fold axes across the project area; while small scale tight to isoclinal folding with similar fold axis orientations are visible at the outcrop scale. These folds are cut by a number of moderate to steeply south-dipping normal faults defining a series of north-dipping fault blocks which repeat the stratigraphy across the project area.Bedded iron mineralisation consists mainly of haematite-martite and goethite ores with best results of 78 m @ 60.5 per cent Fe. Vitreous goethite is observed at the surface of the mineralised horizons. The mineralisation exhibits a strong stratigraphic control and extend down-dip up to 120 m below surface. The strike extent of the mineralisation is still to be determined. An inferred resource of 39 Mt at 58 per cent Fe has been defi ned to date (ASX: AGO 3 February 2011).The fi ndings at McCamey’s North indicate that there is potential for economic iron mineralisation to exist in other areas of Boolgeeda Iron Formation within the Hamersley Basin.

Jul 11, 2011

Alcoa of Australia's Del Park mining op eration is centred 9 km. east of the Pinjarra alumina refinery, and is centrally locatedwith- in the 10, 000 sq. km. lease which the Company holds for bauxite in the Darling Ranges. An- other mining operation is situated near the township of Jarrahdale, and supplies bauxite to the Kwinana refinery. Definition of the bauxite ore, development works and mining to the ore haulage stage, are identical for both mining operations. Exper- ience, and production cost figures, obtained from the Jarrahdale mine, where 100 tonne trucks are used to haul ore to a fixed crushing plant, led to the development of the Del Park mining concept with increased mobility of op- erations. The crushing-conveying-stockpiling arrangement at Del Park consists of a 1200 t. p. h. mobile crusher feeding bauxite to an overland conveyor system which transports the ore approximately 6. 66 km. to the stockpile area in the refinery. In the refinery raw mat- erials area the bauxite is distributed into 200, 000 tonne stockpiles by means of a travel- ling boom stacker.

Jan 1, 1973

The estimate of an ore reserve is a vital statement made about a mineral occurrence by an evaluator. It is important that such a statement communicate reality to all groups involved in a mining project, be they technical, financial, company directors, Stock Exchanges or the public. Ore reserve statements should state both resources and recoverable ore reserves. Resources may be important in very long term considerations, (because mining, metallurgical technology and economics change with time) but recoverable reserves are todays reality. The important factors contributing to recoverable reserves (in a general sense) are geology, mining method (and its impact on dilution and ore loss), metallurgical recovery, costs and commodity prices. These all need to be reflected in the ore reserve statement. In this paper recoverable ore reserve concepts across a wide range of orebodies are considered and discussed with respect to geology, mining method and ore reserve calculation procedures.

Jan 1, 1987

Silica and limestone fluxing levels in copper smelting slags were studied. Copper concentrates with flux additions were smelted to matte (55.5 per cent Cu) and slag in a pilot scale submerged combustion furnace.Results indicated that oxidic and sulphidic copper levels in slags were minimised with a slag Si02 level of 36 per cent and a SiO2/CaO ratio of 5.5. Total copper losses in slags were 0.6 per cent under these conditions.To produce the desired slag chemistry, additions of bulk silica and limestone to copper concentrates of fluctuating grades were predicted numerically. The method employed the solution of two simultaneous equations, each respectively for silica and limestone calculations.The predicted flux additions were applied in a further series of tests and the resultant stages were found to be satisfactory. The method is applicable to smelting 'operations which employ two flux bins, with weigh feeders, so that slag chemistry may be controlled with the flux/concentrate feed mix.

Jan 1, 1985