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By A Dal-Corobbo

Traditional acid and metalliferous drainage (AMD) wastewater treatment focuses on the iron co-precipitation/adsorption process as this is a very effective method of reducing heavy metals, including copper, lead, zinc, arsenic, etc, to parts per billion (ppb) levels in AMD wastewater streams. One of the drawbacks to this method however is the large volume of sludge produced and subsequent disposal costs for the mine site concerned.A proprietary metals treatment system called high density sludge (denoted HDS) which significantly reduces the quantity of waste generated is described in this paper. This process generates a dewatered sludge that contains in the order of 50 to 55 per cent solids. This sludge is denser than conventionally dewatered sludge, which typically contains only 20 to 30 per cent solids. This advanced process has a wide range of applications and can be easily retrofitted into existing AMD treatment systems. It has been successfully installed at several mine sites to treat AMD wastewaters. This paper discusses the high density sludge process, its benefits and provides data and operating results from pilot test installations.CITATION:Dal-Corobbo, A, 2013. High-density sludge process for treating metal bearing acid and metalliferous drainage wastewaters, in Proceedings Water in Mining 2013 , pp 217-220 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By M I. Pownceby, N A. S Webster, J Manuel, N Ware

The properties of iron ore sinter – commonly defined by measures of tumble strength, reduction degradation and reducibility – have a major impact on blast furnace performance. These properties are largely influenced by raw material properties, in particular the bulk ore composition. Despite this importance, there is a lack of quantitative data on the impact of ore chemical composition on iron ore sintering. This is surprising since the levels of Fe, SiO2, Al2O3, P, MgO and other elements, together with the nature of the minerals in the fine ore, play a major role in determining the abundance and type of high-temperature bonding phases that form during sintering. It is the abundance and nature of the high-temperature bonding phase(s) that directly influences sinter quality. This study combines in situ diffraction experiments in model sinter systems with laboratory-based compact sinter tests using natural ores to examine the links between iron ore composition and sintering temperature and their effects on standard metallurgical sinter quality test methods. Results help to establish the critical compositional and thermal parameters that control the bonding phase chemistry, which in turn influences the physical characteristics of the sinter matrix. This information should enable operators to predict optimum sinter operating conditions based on the initial chemistry and mineralogy of the iron ore fines and recognise the chemical modifications to the original iron ore fines required to produce high-quality iron ore sinter.CITATION:Pownceby, M I, Webster, N A S, Manuel, J and Ware, N, 2015. Iron ore geometallurgy – examining the influence of ore composition on sinter phase mineralogy and sinter strength, in Proceedings Iron Ore 2015, pp 579–586 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By A J. Moore

Blasting operations in open cut mines results in airblast, ground vibration and rock movement with the potential for wild flyrock. In some mines there is a trend towards blasting closer to established infrastructure as extraction boundaries alter with increased resource prices and changed economic circumstances. Mine infrastructure in close proximity to blasting has the potential to be damaged by ground vibration and wild flyrock especially. To provide guidance for the determination of appropriate buffer distances and blast specifications, this paper describes methodologies that may be used to determine the potential for damage to infrastructure by predicting:dynamic blast;near field ground vibration levels;dynamic blast strains induced in infrastructure by consideration of ground vibration,ground strain and response amplification;potential for damage by comparing induced strains with allowable working strainsfrom structure design codes and serviceability requirements; andflyrock throw distances based on models developed from flyrock investigations.This report demonstrates the use of strain prediction methodologies developed during Australian Coal Association Research Programme (ACARP) Project C14057 for infrastructure such as conveyor belts, transmission poles and towers, buildings and bridges.

Nov 8, 2011

This paper covers the key issues such as orebody geometry and grade, geotechnical data and metallurgical response. These must be considered in selecting a mining system for a new orebody. It then focusses on the advantages of open pit mining over underground mining particularly in the areas of costs, speed of development and safety. Environmental issues with waste storage is the only negative which emerges. Consequently, the majority of new large mine developments continue to be open pits. It is also demonstrated that underground mining continues to play an important role, particulary for high-grade deposits at depth. The impact on ore recoveries of recent developments in stabilised fill technology in underground mining is also highlighted. The importance of economics to the decision on mining method is continually emphasised as maximising orebody value should be the prime objective of this Work.

Jan 1, 1997

As this district is so far distant from the other mining centres and its mode of approach so circuitous, I am afraid that many residents of other portions of the Commonwealth never think of paying this" Australia's Silver City" a visit, to learn personally the many and various lessons everywhere available, and to become familiar with the really wonderful and interesting features and deposits (which pature has so lavishly bestowed in the mineralogical world) yet seemed to almost ignore or overlook when disposing of topogr,aphical beauties of landscape and vegetation) unless professional or business duties require their presence here. So it is to those whose life is necessarily spent in other parts of the States where they answer their call of duty, and yet feel an interest, either for business or other reasons, that my paper is specially addressed and prepared, and for that reason I witl endeavour to make my remarks more of an explanatory than a dictatorial nature. I feel sure that there. are many members of our Institute who are much more familiar, and have had many more years' experience in the various methods of timbering, filling, and ore extraction, etc., than myself, but I hope that over I6 years' experience in connection with mines and engineering works, the last six of which have been spent in Broken Hill, where, I have been very closely connected.

Jan 1, 1903

By D Timms

The Kempfield deposit is located in the Hill End Trough, one of several intracratonic basins developed during Silurian–Devonian time, in the eastern province of the Lachlan Orogen, Eastern Australia.The deposit contains an oxide resource of 5.8 Mt @ 58 g/t Ag and a sulfide resource of 14.4 Mt @ 45 g/t Ag, 1.7 per cent Zn and 0.6 per cent Pb, classified and reported in compliance with the JORC Code. The deposit has been previously explored by a number of companies, including INCO, Shell, Jones Mining, Golden Cross Resources and recently Argent Minerals Ltd (Argent). Argent is currently completing a definitive feasibility study with a view to mining the deposit.The deposit is hosted at the boundary between the Molong High to the west, comprising Ordovician sediments and volcanic rocks and the Hill End Trough to the east, interpreted as a back-arc basin containing Silurian sediments and siliceous-feldspathic volcanic rocks. The boundary between these two strato tectonic units is an imbricate thrust fault zone known as the Copperhannia Thrust.The Kempfield deposit is hosted in felsic volcanic rocks known as the Kangaloolah Volcanics. These have been in-faulted and folded into the Middle Ordovician meta-sediments of the Coombing Formation of metasediments along the Copperhannia Thrust. The Kangaloolah Volcanics belong to the Late Silurian Mumbil Group, comprising submarine carbonate-shale facies interspersed with extensive felsic volcanic piles, which grade conformably upwards into turbiditic sandstone and siltstone sequences (interpreted to represent a deeper depositional environment). These turbiditic rocks are known as the Campbells Formation, comprising siltstone, sandstone and andesitic tuff. The rocks at Kempfield are metamorphosed to lower greenschist facies, reflected through the different type of schists.Silver, gold, lead, zinc mineralisation is hosted in barite-rich horizons, near the boundary to quartz-phyric tuffaceous rocks in submarine, immature, reworked felsic ash tuffs. Barite appears to be hosted in greatest concentrations by the coarser grained volcanoclastic sandstones and grits, whilst intercalated siltstones are volumetrically minor and tend to return low barite and silver. Mineralisation is hosted in stratiform and probably stratabound barite-rich horizons. A northeast-trending, steeply dipping, metamorphic cleavage (S1) occurs throughout the project area.

Aug 22, 2011

By M A. Wells

A new approach to more reliably predict the Ni (and Fe, Mg) composition of Ni laterites was tested for RC samples from the (siliceous) oxide–style, Siberia North deposit, Kalgoorlie Nickel Project (KNP), in the north-eastern Yilgarn (WA) using partial least squares regression (PLSR) analysis of diffuse reflectance spectra over the 380 - 2500 nm wavelength range with a multi–element chemistry data set. PLSR cross-validation models were developed to predict FeO, MgO and Ni contents in composite samples with bulk composition limits of >0.08 wt per cent Ni and <6 wt per cent MgO. Calibration and validation models showed a strong, linear trend for predicting FeO and, to a lesser extent, Ni content, whereas PLSR models for predicting Mg content were less reliable. This reflected the prevailing mineralogy and associated element deportment within the oxide laterite profile. For example, Fe and Ni distribution is controlled by relatively few minerals, predominantly goethite and, to a lesser extent, the Fe3+-bearing smectite, nontronite. Magnesium is associated with a range of Mg-bearing minerals, some of which are compositionally complex (eg serpentine, talc, chlorite, smectite and carbonates). Magnesium chemistry alone does not reflect the varied mineralogy of samples with relatively high (5 - 6 wt per cent) MgO contents, which can be spectrally distinct. Hence, samples with similar Mg contents, though comprising Mg-bearing minerals with distinct reflectance spectra, were difficult to model (eg smectite versus Mg-carbonates). The findings of this study demonstrate that characterisation of Ni laterite composition may be achieved as part of routine logging of either drill chips or diamond drill core using PLSR analysis, but that a detailed understanding of the mineral-element association is essential for reliable predictive analysis. This has particular relevance to characterising the geometallurgy of Ni laterites, especially where deposits may be classed as the same type, but have distinct compositional and mineralogical differences.

Sep 5, 2011

By J F. Colinet, G, J A. Zimmer, R J. Timko

It has long been known that ventilation is a cost-effective method to lower respirable dust concentrations in all types of mining applications. The National Institute for Occupational Safety and Health has been working on a number of different research techniques that use ventilation as a critical component to lower respirable dust levels at surface and metal/non-metal operations in the United States. This article presents five such research efforts. The first research area discusses how improving the ventilation flow patterns in an iron ore mill facility lowered respirable dust concentrations by 31 per cent throughout the primary grinding area. The second research area examines how respirable dust levels were lowered at a dimensional stone shop by using air cleaning units suspended from the ceiling. A third area discusses how improvements in ventilation at underground limestone mines lowered respirable dust concentrations. The fourth area examines how improvements in dust filtration and pressurisation systems significantly impacted the air quality in enclosed cabs of surface mining equipment. The last area presents a newly developed clothes cleaning technique. This technique uses an air spray manifold to blow dust from a workerÆs clothing in an enclosed booth, which confines the dust for capture and removal by a baghouse dust collector. These research areas represent an array of different control technologies to lower respirable dust concentrations. Ventilation is an integral part of these control technologies.

Jan 1, 2005

By D Liu, M Edraki, L Berry

The presence of clay minerals slows down the settling rate and mitigates compact consolidation efficiency in tailings dewatering. The increasing use of saline water in many plants, affects the dewatering performance and presents the mining industry with new concerns. Efficient tailings dewatering is a great challenge due to the complexity character of tailings, especially clay mineralogy, clay content, and water chemistry. In this study, existing studies of the effect of different affecting parameters, such as pH, ionic strength and polymer flocculants, on clay aggregation behaviours are reviewed. The settling behaviours of three types of commonly observed clay minerals in tailings, kaolinite, bentonite, and illite, are also investigated in saline water with different water salinity as a case study. The settling rates of clay minerals are found to be affected by water salinity, clay type, clay content and polymer dosage levels. High salinity water hinders the settling of kaolinite but assists the settling of bentonite and illite through formation of different aggregation structures.The current work has indicated that strategies to promote more rapid dewatering could include adjusting flocculant type or level, water salinity and salt balance, and tailings solid content levels. Implementing dewatering strategies may require a more detailed knowledge of the effect of surface chemistry on the nature and strength of the clay inter-particle forces. This study discusses the research gaps on how to better manage clay-rich tailings in saline water and identifies new research directions. The development of a water management model, supported through in-line monitoring data to predict and manipulate of the surface chemistry of the clay component of the tailings could be a new direction to manage the issues associated with clay minerals in the process of dewatering and tailings management. Mine planning (water use requirements, operating costs) could benefit from more detailed studies on dewatering of clay-rich tailings in saline water. CITATION:Liu, D, Edraki, M and Berry, L, 2018. Improving the dewatering efficiency of clay-rich tailings in saline water, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 476–484 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Johnson MT

The microprocessor revolution of the 1970's dramatically improved the price/per- formance of graphics hardware. Together with improved communications and new software concepts and standards this has resulted in the emergence of a new tool with particular application to the mining industry. The Distributed Graphics Processor (DGP) offers more natural means of interaction with com- plex technical models.

Jan 1, 1983

The introduction of new technology into thegold-mining industry has been encouraged in recent years by increases in the price of gold andthe necessity for costs to be contained.At most new gold mines, run-of-mine millingis preferred over crushing and multistage milling, and this change at the head of the circuit leaves no place for the manual sorting of ore and for gravity concentration in the mill circuit.Flotation continues to hold its place in goldrecovery. However, a decline in the demand forsulphuric acid may limit the amount of pyrite thatcan be roasted before cyanidation.

Jan 1, 1984

By E R. Ramanaidou, M A. Wells

Reflectance spectroscopy is now an established technique for mineral exploration and ore characterisation. The efficacy of the technique as a tool to characterise the main iron ore and gangue mineralogy at African Minerals Ltd’s Simbili iron ore deposit in north-central Sierra Leone was tested through reflectance spectroscopic analysis of 13 000 pulped drill reserve samples using CSIRO’s HyLogger-1™ system. Specifically, integration of reflectance spectral data with more traditional methods of analysis, such as geochemical analysis and Satmagan measurements, characterised the mineralogy (ie hematite versus goethite) of the oxidised ore at Simbili, quantified the Al associated with goethite and hematite and evaluated the distribution of the main gangue minerals – kaolinite and gibbsite. Relative changes in the Fe2+/Fe3+-bearing oxide and silicate mineralogy, based on mineral indices derived from reflectance spectroscopic measurements, appeared well-related to changes in the ore profile mineralogy consistent with the main ore types identified at Simbili, as representative of an oxidised banded iron formation sequence. Spectral calibration models, developed from a well-characterised training set of mineral mixtures, representative of the oxidised ore zone mineralogy were used to quantify the distribution of Al associated with kaolinite and gibbsite and the iron oxides, goethite and hematite. Combining these mineral spectral parameters with compositional data enabled the differentiation of Al-substituted goethite and hematite and resulted in the identification of low Al-bearing, or ‘clean’, goethite and hematite from high Al-bearing, or ‘dirty’, goethite and hematite. Spectral quantification of the iron oxide Al composition provides a far more rapid means of quantifying the Al substitution in iron oxides at the deposit scale compared to traditional techniques such as X-ray diffraction analysis. It also enables a level of volumetric characterisation and the potential for large-scale (ie three-dimensional) mapping, which was not previously possible with other techniques. The potential of the technique was also highlighted when mapping the distribution of the main Al-bearing contaminants (gibbsite and kaolinite) identified in the oxidised ore zone at Simbili. Delineation of such zones provides a guide to managing the most appropriate processing options (ie upgrade potential) within a mineralogical framework. Three-dimensional modelling of the gangue phase distribution may also allow the mapping of lithological and/or structural controls that may be prevalent at Simbili. This work highlights the value in the application of HyLogging™ technology for rapid resource characterisation, particularly for volumetric identification and mapping the distribution of both the economic and gangue phases, which otherwise would be difficult to achieve. As such, the technique can provide a fast and inexpensive means to evaluate ore and gangue mineralogy at the deposit scale and provide a first-pass assessment of the mineralogy and compositional attributes, with the potential to better predict ore metallurgical properties.CITATION:Wells, M A and Ramanaidou, E R, 2015. Waste not, want not – delving deeper into the Simbili iron ore deposit using HyLogging™ scanning technology, in Proceedings Iron Ore 2015, pp 337–346 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By L R. Sousa, M He

Rock burst is common in deep underground excavations and is characterised by a violent ejection of block rocks from excavation walls. It is critical to understand the phenomenon of rock burst and particularly the failure mechanism. Laboratory experiments are one of the ways. For that purpose, a rock burst laboratory test system was developed at the State Key Laboratory for Geomechanics and Deep Underground Engineering at the China University of Mining and Technology, Beijing. A true triaxial test system, designated the Deep Underground Rock Burst Analogue Test Machine, was developed, which can transfer a stress state from three-direction-compression on six surfaces to the compression on five surfaces with one set free. The rock burst experimental system comprises an acquisition of acoustic emission signals, a high-speed recording in order to accurately record the kinetic characteristics of rock fragments ejected during a rock burst event and the possibility of infrared thermography showing the surface temperature of the samples. In this paper, analyses of typical results from rock burst tests are presented with a description of the obtained results. The mechanisms of rock burst are illustrated, and a rock burst classification is proposed based on these laboratory tests. For the control of rock burst, the constant resistance, large deformation (CRLD) bolt or anchor is presented for accommodating the large displacement of surrounding rock masses and absorbing the impact of the sudden release of rock burst while outputting a constant resistant force in response to the external load. The CRLD bolt or anchor has had practical applications in underground mines. Finally, in situ tests performed in a tunnel at Qingshui coalmine, China, are analysed in detail.CITATION:He, M and Sousa, L R, 2014. Experiments on rock burst and its control, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 19–32 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By M R. Asef

Although generation of environmentally harmful hydrogen sulfide is considered to be related to sour gas fields, sweet gas reservoirs and waste fluids, travertine springs and geothermal fields may also produce acid gas (H2S and CO2) under certain conditions. The potential parameters influencing such a possibility need to be fully investigated to evaluate the extent of the consequences and predict hydrogen sulfide generation accordingly. Reports on hydrogen sulfide production at different regions and fields were gathered worldwide for the cases when some of them did not have such a problem previously. In order to inspect different aspects of these case studies, some other regions with no hydrogen sulfide content were selected as control. In all cases water samples were taken carefully for chemical analysis in the laboratory. Besides, mineral compositions were characterised in some cases for better evaluation. In order to give a thorough prospect of hydrogen sulfide production, a geochemical model was prepared. In situ engineering geological conditions, especially pressure and temperature, were assigned in the model to investigate the possibility of H2S generation using PHREEQC software. The results of modelling revealed that although many similarities existed between mineral compositions of the cases, certain formations were particularly prone to hydrogen sulfide generation. For better evaluation, important exchangeable cation ratios such as potassium/sodium, calcium/magnesium and ion proportions like sulfate and chloride were calculated as trends of the formations. As expected, the model could successfully monitor a higher ratio of SO42- and Cl- in potential H2S generator formations. Wide variation in percentage of HCO3- was considered as a secondary observatory parameter for better estimation. In addition, it was noticed that higher anion content created an environment ready to absorb any cations and this makes H2S generation easier. Finally, using correlations between predictors and estimators for low depth and deep samples defined the degree of effectiveness for every sample.

Sep 26, 2011

By M Suzuki

Although several models for the surface tension of molten oxide slag have been proposed, suitably accurate predictions of this property are not yet possible. The surface tension, or surface excess free energy, of molten oxides is largely determined by the ionic coordination induced by surface relaxation. However, the associated mechanism of surface structural relaxation for molten oxide mixtures such as slag is complex and not yet fully understood. To allow a better evaluation of surface relaxation characteristics, the present work analysed the ionic coordination associated with the surface-relaxed states of several oxide mixtures. This work especially focused on calcium aluminate slags because these materials exhibit complex relationships between composition and surface tension. The effects of incorporating low concentrations of SiO2 as a surface active component on the surface ionic coordination were also examined. X-ray absorption techniques were used to assess oxygen and cationic elements in glassy samples after surface relaxation treatments, and molecular dynamics simulations based on a polarisable ion model of molten slag with vacuum/melt interfaces were also performed. The X-ray absorption techniques provided data related to electron yields (which are primarily associated with surface features) and fluorescence yields (which evaluate the bulk material). Thus, the ionic coordination characteristics of both regions were investigated. The results of molecular dynamics calculations allowed statistical analysis of the distributions of Al- or Sicentred polymorphs as well as the bond angles between cations and oxygen anions in the vacuumexposed and bulk regions in the equilibrated melt. The results indicated that bridging oxygen ions were preferentially distributed in the relaxed surface region rather than non-bridging oxygens. These bridging oxygen ions represented vertex connections between AlO4 or SiO4 tetrahedra. In the case of the calcium aluminate slags, the addition of one Ca2+ ion as charge compensation for two Al3+ ions was found to be necessary to form two AlO4 tetrahedra. This specific feature of surface ionic coordination could be responsible for the complex trends observed in surface tension data. The incorporation of low concentrations of SiO2 reduced the proportion of tetrahedrally-coordinated Al ions such that higher coordination states become dominant in the bulk of the material, whereas AlO4 tetrahedra were preferentially distributed in the surface region. SiO4 tetrahedra were the preferred Si-centred polymorph and were likely connected to one another to form bridging oxygen ions at the surface. On the basis of these results, a model to predict slag surface tension was proposed, and the energy of the formation of the ionic clusters resulting from surface relaxation was taken into account.

Aug 21, 2024

Minerals processing operations use a significant quantity of fossil carbon to provide energy and as reductant. Greenhouse gas emissions from the use of this fossil carbon contribute to the global increase in anthropogenic CO2 emissions to the atmosphere. In the spirit of fostering thinking about a step change in this situation, this paper explores opportunities for the use of sustainable carbon from biomass sources in a range of mineral processing operations. The exploration shows that many common processes are contenders for fossil carbon replacement and that feasible scientific research by minerals processing technologists would add to deeper understanding of the potential for a sustainable bio-carbon based industry. It is also shown that there are many dilemmas on the social, environmental and economic fronts to be solved before a biomass based industry could become a reality.

Jan 1, 2004

There are a number of factors affecting the discovery and develop- ment of uranium in Australia which makes this mineral almost unique and quite different from other minerals. I. The role of the Australian Government, which initially encouraged the discovery by offering rewards to prospectors who discovered deposits that could become economic. 2. At a later stage, the Commonwealth and South Australian Govern- ments prevented the development and production of "new mines" by refusing to grant mining title and refusing to allow sales of uranium by not issuing export permits. 3. The unique property that uranium and its daughter products possessed, i.e. radioactivity, meant that any person who purchased a geiger coun- ter could go prospecting, even though they had no previous experience in prospecting and they had an equal opportunity of discovering a new deposit as a company or independent geologist. 4. Because the exploration/demand for uranium didn't occur until the 1940s very little background geological information or models were available and so the early discoveries tended to become the locus for exploration rather than moving into areas which might on geological concepts lead to exploration programmes based on geological models. Because of the lack of knowledge there was the exchange of geologists from the U.S. Geological Survey and the South Australia Geologist Survey.

Jan 1, 1988

By G N. Phillips

No new goldfields have been found in the Witwatersrand Basin for over 60 years, and one consequence of this is a long-term decline in gold production. Exploration throughout this period has been based on the placer model that infers alluvial transport of gold grains and then sedimentary sorting in the basin; however, there is no viable source for so much alluvial gold and no single sedimentary setting that hosts the gold.An alternative genetic model can now provide a quantified explanation for the source of the gold, and it does not rely on alluvial gold processes. The hydrothermal model can easily explain the source of the Witwatersrand gold as being derived from the background gold at parts per billion (ppb) level throughout the Kaapvaal craton of South Africa. This gold is involved in metamorphic processes, available for solution in metamorphic fluids, and hence may be transported whilst dissolved in fluid into the Witwatersrand Basin. The hydrothermal model warrants consideration as it can explain the source of gold, the large alteration halo in the goldfields, the mineralogy, and especially the gold-carbon association.Working on the premise that if one model (placer) is not giving the desired results (discovery of new goldfields), then it may be prudent to consider alternatives. Application of a hydrothermal model to guide exploration would place importance on large and small early structures in and around the Witwatersrand Basin; it would also emphasise the geochemical nature of potential host rocks (especially C and Fe) rather than their sedimentary origin.CITATION:Phillips, G N, 2013. Origin of Witwatersrand Gold - a viable source region and source process for gold, in Proceedings World Gold 2013 , pp 175-180 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By R R. Anand

Recent research by CRC LEME from an Australian mineral exploration perspective, has focussed on regolith architecture and mechanisms of geochemical anomaly formation, within transported regolith. Methods have been developed for the rapid production of regolith-landform maps which is the starting point for understanding regolith architecture in the third dimension. Methods for development of 3D regolith models are less well advanced, and require integration of all available geological and geophysical datasets, but still with a heavy reliance on drill-hole information. The base of the transported regolith û the unconformity û remains the most important regolith boundary for geochemical sampling in transported regolith terrains. A new generation portable spectral logger, employing a broader spectrum can interpret important features from drill chips within the regolith. This allows internal architecture, redox fronts and the all-important interface to be objectively identified. Transported lateritic components can provide vectors to mineralisation in depositional regimes. Palaeomagnetic and new radiometric methods which date individual phases of the regolith provide evidence of different episodes, each characterised by different geochemical dispersion patterns in transported regolith. Along with lateritic residuum, calcrete is prime sampling medium. Calcrete is probably enriched in gold through physical and biological processes, rather than straight chemical processes. In South Australia, the lowermost calcrete layer buried within the depositional regime, especially where it lies directly over the silcrete layer at the buried interface, is the desired sampling medium. Certain gum trees, with deep roots in transported regolith have been shown to record anomalous values of gold and basemetals in leaves, twigs and bark. Anomalous metals in acid-sulfate soil seeps can also provide a window through sedimentary cover in respect of mineralisation in the basement. A number of Yilgarn occurrences of gold anomalies in transported cover, strongly infer hydromorphic and biological mobilisation of gold. This inference is supported by micro-analyses of regolith mineral hosts in hardpans and mottled sediments, which show gold and pathfinder elements prefer to reside in goethite and specific types of clay minerals. This creates anomalies in specific mineral phases. However the inference that that these are sites of mobile or labile metal ions remains enigmatic. Similarly there is inconclusive evidence that selective extractions will provide an anomaly not otherwise detected by conventional total dissolution methods. Hydrogeochemistry is a promising exploration tool for basemetal exploration. The importance of microbes in both the dissolution and precipitation of gold in the Australian regolith is demonstrated. We are on the verge of identifying the functional gene sequence of individual active microbes. A consideration of possible mechanisms for creating anomalies in soils above transported regolith, presents difficulties in facilitating upward movement of ions from the watertable to the surface. Perhaps the best avenues of research lies with surrogate soil gases, and biotic transfers.

Jan 1, 2004

By M A. Rhamdhani, K Avarmaa, A Putera, J Chen, G Brooks

Silicon-based photovoltaic cells are currently the most dominant types applied to convert solar energy to electricity. In solar-grade silicon (SG-Si), the control of boron (B) and phosphorus (P) is very critical. Generally, these elements are difficult to remove into acceptable sub-ppm levels from lower grade Si. This study investigates slag treatment as a process for Si refining, focusing on the behaviour of P and B. The experiments were conducted by equilibrating Si-B-P alloys with 43 wt per cent SiO2 – 47 wt per cent CaO – 10 wt per cent Al2O3 slag under inert atmosphere at 1500°C. Different crucible materials were used (Al2O3, SiO2 and MgO), which determined the primary saturation phase for the system and modified the final slag composition accordingly. The samples were equilibrated and analysed with microanalysis techniques (EPMA (electron probe microanalysis) and LA-ICP-MS (laser ablation inductively coupled plasma mass spectrometry)). New standards were prepared and applied in the LA-ICP-MS analyses. Experimental results show that silver is essentially fully dissolved in silicon, as well as most phosphorus with LP ( = wt per cent P in slag/wt per cent P in Si) between 0.1–0.3. The distribution coefficient of boron was measured to be between 1 and 2. The crucible material used had an influence on the phase compositions and slight influence on the distribution coefficients of boron and phosphorus. The experimental results provided new accurate data when considering applicability of slag treatment as a technique for Si refining and Si PV cell recycling.

Jun 19, 2024