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By H. M. Howe

One of the little electric-resistance magnesia crucible-furnaces which I designed for the metallurgical laboratory of the School of Mines of Columbia University is shown, in vertical section, of full natural size, in Fig. 1. The furnace itself consists of two semi-cylinders of magnesia, A A, with a cover of magnesia, B B, and a stopper, C, also of magnesia, which is perforated to admit the leads x, y, of a thermo-electric couple. The furnace is heated by the spiral of platinum wire, D D (entering and departing by the openings I and K), through which a current of any desired strength is passed, bringing it to incandescence, and to ally temperature, not above the melting-point of platinum, which may be desired. The crucible E, actually used in this furnace, is also of magnesia. I have heard of some unsuccessful attempts with furuaces of this general class, and have attributed these failures to the use of siliceous materials for the furnace-walls. Of course such a result is what we should expect, since the silica mould readily be electrolysed by the current, and the resultant silicon would alloy with platinum ; but the little magnesia furnace here clescribed seems to be wholly free from this objection. It has been used in my laboratory for some months, and temperatures, up to 1100° C, hare been developed in it over considerable periods of time—indeed, it has been held near 1400" C. for about two hours—without indication, thus far, of any deterioration of the platinum. In the section shown, F F are a pair of steel disks, bound together, but separated by the inverted thermo-junction, N, of the thermo-electric pyrometer. This arrangement permits the observation and record of retardations in the heating and cooling of F F—in other words, the determinations of the cooling curves of steel—a purpose for which the furnace has been used, thus far, more frequently than in the determination of meltingpoints. For the latter operation, however, it is also suitable.

Jan 1, 1902

By B. B. Zavoico

Considerable progress has been made during the past year throughout the Russian petroleum industry. Perhaps the most remarkable achievement is the execution of the programs set out by the Central Planning Bureau of the Department of Commerce. These programs have been increased twice during the past operating year, necessitating drilling the richest reserves, instead of developing gradually as originally planned. The fulfillment of the set-out programs during the past few years makes therefore the present five-year plan of considerable importance to the international oil statisticians in approximating actual supply conditions up till 1933. The production of all Russian fields increased by 14,200,000 bbl. as compared with the 1927-1928 operating year, while the next year's program anticipates a further increase of 15,700,000 barrels. It appears therefore that production for 1932-33 will total 187,000,000 bbl., or approximately double that of the operating year just closed. It is also evident that the old fields are counted upon to produce only about 67 per cent. of the total, the new fields, not yet discovered, to furnish the balance of 33 per cent. The Soviet oil leaders therefore are hoping to have new fields discovered and developed by 1932-33. However, as in the past wildcatting

Jan 1, 1930

By T. P. Oxford, G. Y. Onoda, E. D. Whitney

Disposal of phosphatic clay waste slurry has been a problem since the advent of hydraulic processing of phosphate rock in Florida. Alternatives to the present practice of storing slimes behind earthen dikes have been earnestly sought for more than a quarter of a century. Seepage dewatering is a promising technique intended to increase waste clay solids content to a level sufficiently high to permit clay disposal in mine cuts, in lieu of above-grade impoundment. An experimental array of vertical seepage columns containing mine tailings sand was constructed. Significant improvement in waste clay dewatering relative to that occurring in a control test was observed when approximately 1800 m3 of waste clay was disposed of in the presence of the seepage aids.

Jan 1, 1983

By Robert L. Gower, John H. Cash

Interconnections for integrated circuits operating at rnicrowaue frequencies rzust be formed as microwave transmission lines. This paper describes the fabrication of one type of microwave transmission line known as microstrip, which can be fabricated on momlithic integvated circuits by deposition of 0.1- to 2.0-mil-thick metal and dielectric films. A microstrip line consists of a narrow conducting strip separated from a gvound plane by a dielectric material. Thick films of good conducting materials are required for low loss at high frequencies. Vacuum-evaporation methods for depositing aluminum and silver films are described. The narrow conducting strip forming the top conductor is defined by photoresist-etching techniques after the thick rnetal film is deposited. Gold plating with a photoresist-masking technique is also used to forrrz thick metal conductors. The microstrip dielectric layer is formed by deposition of suitable dielectric films 0.1 to 2.0 mils thick. Several deposition techniques were investigated. Electron-beam evaporation of quartz is described. Electrical characteristics of deposited microstrip lines at microwave frequencies are included and the microwave power attenuation as a function of conductor and dielectric thickness is given. It is concluded that the deposition of microstrip transmission lines is a practical way to achieve low-loss interconnections in monolithic integrated circuits. CONNECTIONS between devices in low-frequency and digital circuits are usually made by connecting the devices with a length of conductor such as a metal lead oi- a wire. If this method were applied to microwave integrated circuits, the reactance of the connection due to the series inductance and parasitic capacitance would be very high, in fact too high to permit successful circuit operation. In addition, resonance and antenna effects would occur at high frequencies, especially when the connections approach the wavelength.' Connections which are sections of transmis- sion line will overcome these difficulties. The electromagnetic field is confined to the volume of the transmission line, parasitic effects are not present, and circuit design utilizes familiar transmission-line techniques. TRANSMISSION LINES One type of transmission line geometrically adaptable to integrated circuits is known as micrstri. A microstrip line can be generated from a coaxial line as shown in Fig. l(a). The outer conductor of the coaxial line is distorted into an ellipse (b) and finally separated at the extremities of the ellipse to form the strip transmission line shown in (c). One of the ground planes is then removed, leaving a conducting ground plane and a narrow conducting strip separated by a dielectric. Two configurations of the microstrip line were considered in this investigation, Fig. 2. Type (a) is fabricated from a semiconductor slice with the ground plane and top conductor deposited on each side of the slice. The semiconductor slice serves as the die lec-

Jan 1, 1967

By M. R. Tek, K. H. Coats, D. L. Katz

In natural gas storage operations, seasonal pressure fluctuations in the gas reservoir cause the water from the surrounding aquifer to flow into and out of the gas sand. The theory of unsteady-state liquid flow through porous media developed by Van Everdingen and Hurst' has been applied to predict the water movement into and out of the gar bubble for .several .postulated pressure cycles. Those cycles with as many pound-days above the original aquifer pressure as pound-days below, may cause the gas reservoir to slowly grow or shrink rather than hold to a constant volume. Applications to an actual field case study give the predicted gas reservoir monthly pressures and volumes as compared with the observed monthly pressures and volumes. INTRODUCTION A large number of natural gas storage reservoirs are bounded by or adjacent to large water-saturated formations called aquifers. The presence of these aquifers is usually evidenced by the production of water from wells delineating the gas-hearing sands. Some gas storage reservoirs in use today have been purposely developed on aquifers. Cyclic pressure variations in a gas storage reservoir cause water influx and efflux from the surrounding aquifer. This, in turn, results in a varying gas reservoir volume. The prediction of the effect of this aquifer fluid movement on the size and size variation of the gas reservoir can provide information valuable in the study of several reservoir engineering problems. The economics of gas storage operations are directly influenced by the influx of aquifer fluid into the reservoir since a shrinking storage reservoir requires increasing pressures for the storage of the same quantity of gas. Material balance and reserve or recovery calculations also obviously require knowledge of reservoir volume. Various other reservoir engineering calculations such as interpretation of well interference data, evaluation of physical characteristics of porous media, water coning, gas injection and pressure maintenance studies are typical problems where variations of volume due to edge or bottom-water encroachment becomes important. The solution of equations describing influx and efflux of water in the gas sand, application to gas storage reservoir behavior and interpretation of results are the main objectives of this paper. While this work was directed toward gas storage reservoirs, it applies equally well to repressuring of partially depleted oil reservoirs with an active water drive. MATHEMATICAL ANALYSIS As just mentioned, the cyclic pressure variations in an aquifer-surrounded gas storage reservoir cause water movement and varying gas reservoir volume. Prediction of this volume variation from the reservoir pressure cycles or the injection-production schedule requires adoption of a flow model, certain assumptions concerning reservoir and fluid properties, and formulation and solution of the governing differential equation. The flow model used in this study is a gas bubble located on a very large aquifer (Fig. la). Gas bubble radius and aquifer sand thickness are denoted by rr and h, respectively. Fig. lb shows the horizontal, radial two-dimensional porous reservoir attended by the unsteady, compressible motion of the aquifer liquid. Volume variation of the gas bubble is determined from aquifer water flow across the cylindrical boundary, r = r0

By T. Saburi, C. M. Wayman

The massive and martensitic transformations in ß Cu-Ga alloys were studied by optical microscopy and by transmission electron microscopy and diffraction. These types of transformation are distinct and do not merge into one another. An internal fine structure due to stacking faults was found in both the massive phase (m) and the martensite, but the origin of the faults is believed to be different in each case. The faults in the martensite are due to the lattice invariant or "second" shear of the phenom-enological theory, while those in the are probably growth faults and deformation faults arising from the transformation volume change. Evidence is presented for ordering in the ß phase prior to transformation into martensite, and the crystal structures of and ß' and ßi martensites are discussed. THE results from some previous investigations1,2 have led to the suggestion that martensitic and massive transformations have certain common characteristics. It presently seems established that massive transformations like martensitic transformations are essentially diffusionless,1,2 but unlike martensitic transformations, when a new phase forms massively there is no shape change or surface relief.= If the massive-type transformation is crystallographically similar to martensitic transformations, one would expect a fine structure as a result of the lattice invariant shear4 which is a part of the transformation mechanism. The existence of such a fine structure (i.e., slip, twinning, or faulting), if any, can be verified by transmission electron microscopy, and thus the present investigation was undertaken to compare the internal structure of massively and martensitically formed phases in Cu-Ga alloys which were derived from a parent of the same composition. The transformation characteristics of ß Cu-Ga alloys were also studied. The bcc ß phase in the Cu-Ga system, Fig. 1, is stable above 616oc.' Depending upon the cooling rate, ß Cu-Ga alloys can undergo three different types of phase transformations. The ß phase of eutectoid composition (23.7 at. pct Ga) decomposes into the ? phase (hcp) and the phase (complex cubic) by means of a eutectoid reaction. When the cooling rate is increased so that the decomposition of 0 into [ and ? is suppressed, the ß phase transforms into a nonequilibrium hcp phase, herein denoted ?m by a process of very rapid growth called a "massive" transformation. At even faster quenching rates the massive transformation can be suppressed and the ß transforms martensitically. Massive transformations, apparently similar to those in the Cu-Ga system, have also been studied in the Cu-Zn2,6-8 and Ag-Cd systems.9 Definitive characteristics if the Massive Transformations in 0 Cu-Ga Alloys1 1) The most remarkable feature of the massive transformation in Cu-Ga is that there is no bulk composition change on transformation. According to Massalski,1 the resulting [, phase is a supersaturated extension of the equilibrium [ phase. The lattice parameters continue the trend exhibited

Jan 1, 1965

By Clarence Fenner

THE manufacture of optical glass is a process that demands careful regulation and control at all stages in order that satisfactory results may be obtained. The product, to serve its purpose, must meet stringent requirements, which can be assured only by careful procedure in manufacture. During the greater part of the time that a pot of glass is in the furnace, temperatures should be kept within certain rather narrow limits; a departure on either side is likely to be detrimental to the glass and may result in total loss. If the temperature during melting and fining be low, the melt is likely not to fine properly and the glass will contain quantities of bubbles, or "seed," or it may become milky and unfit for use; too high a temperature, on the other hand, is severe on the pot and may cause it to leak or cast stones, or the increased solution of pot material in the melt may acid to the color of the glass and decrease its transmission. Moreover, variations in the working temperature will mean variations in the amount of selective volatilization and, consequently, variations in optical properties from pot to pot. Furthermore, in the closing stages of furnace treatment, the melt is cooled until a certain degree of stiffness is attained, when the pot is withdrawn. The quality of the glass-its freedom from striae and bubbles-will depend in large measure on whether the temperature to which cooling has been carried is suitable. For each type of glass there is a narrowly restricted range of temperature to which each pot of the given type should be cooled before withdrawal. A quick and reliable method of measuring temperatures is, therefore, of the first importance. In the optical-glass work conducted by the staff of the Geophysical Laboratory during the period of the war, much attention was given to the clatter of determining what methods would meet the requirements. This article will deal with these investigations and with the application of the results to actual practice at various plants. At the. time that the work of the Geophysical Laboratory was begun at the Bausch & Lomb plant, each melting furnace was equipped with

Jan 7, 1919

By George W. Becker, Blair R. Benner, Ronald J. Roman

A computer model for the leaching of oxide copper heaps is developed and verified in laboratory tests. The model can be used to scale-up laboratory test data and to simulate the results of various operating philosophies on heap leaching. The model is applicable to leaching processes where the rate of leaching is controlled by a deficiency of reactant or diffusion of a reactant through the leached rock. Several examples are presented showing the sensitivity of the recovery vs. time curve to the variables in leaching.

Jan 1, 1975

By G. Kinder, R. Gilges, W. Stoker, R. Davey

The Bingham Canyon Mine, located 48 km (30 mi) southwest of Salt Lake City, Utah, is operated by Kennecott Copper Corporation's Utah Copper Division. This operation is the world's largest open-pit copper mine and produces 96 000 tons (106,000 st) ore and 327 000 tons (360,000 st) waste each day. This material is loaded by large electric shovels and transported by both truck and rail haulage. To meet the requirements of the Clean Air Act of 1970 (as amended), new facilities for the control of smelter emissions were required and are now nearing the final stages of construction. The facility will be capable of treating all the output from the mine, some 2,530 tons (2,789 st) per day of combined concentrate and precipitate. Costing $280 million and necessitating the replacement of reverberatory furnaces with continuous smelting vessels, the plant, with its massive and complex gas handling and acid-making facility, is required to remain on-stream with the minimum of pollution control equipment outages to conform with Federal Regulation 52.2325. As part of this giant effort, the smelter planning team and supervisory staff considered that new, well organized, highly flexible, readily available maintenance information was essential to assist the maintenance personnel in the performance of their duties.

Jan 1, 1979

By D. M. Lewis, R. C. Emmett, B. C. Wojcik, F. A. Baczek

The ElectroSlurry™ electrowinning concept has been incorporated into a process flowsheet for recovering copper from smelter flue dusts. The process has averaged 96% recovery of the copper as high-grade electrowon cathode, while at the same time removing a majority of the impurities that degrade drawn copper as a result of recycling flue dust and liberator cathodes. The dust is processed through several stages consisting of leaching, copper precipitation, ElectroSlurry electrowinning, and waste liquor treatment. The process may be integrated into a smelter operation and become an effective and feasible means of maintaining good product purity.

Jan 1, 1981

Improvement of drilling operations through the development of new, unconventional drill bits is a prime research target at Sandia Laboratories, Albuquerque, N.M. Sandia is currently focusing efforts on four new bit designs which its engineers believe may eventually improve penetration and reduce operating costs. The Energy Research and Development Administration (ERDA) has budgeted $500,000 in support of this program to date. Two of the drill bits-one that chips rock with high voltage spark discharges, and another which fires small projectiles into the rock ahead of a regular roller bit-are designed to increase both penetration rates and downhole bit life.

Jan 8, 1975

By Michael P. Richardson

INTRODUCTION This paper is intended to be a summation of the state-of-the-art i n draw theory and draw- point spacing. Knowledge of this very important factor in the successful design and operation of a block caving mine is scarce and nonconclusive. It is hoped that the presentation of this paper will stimulate interest and discussion which will lead to a stronger understanding of these a1 1 important factors. Please note that block caving as used here- in refers to block, panel, and mass caving systems in general, not just to the specific system of block caving where discrete blocks of ore are prepared and caved as a unit. DRAW THEORY The knowledge of draw theory as related to the practice of block caving mines is, unfortunately, very limited. In recent years much work in draw theory has been done in respect to sublevel caving systems and an understanding of draw mechanics relating to sublevel caving seems to be emerging. This work is certainly helpful to those of us interested in block caving but the question of "what goes on up above" still hounds us since we are more interested in the region of draw which begins just above the area where sublevel caving interest ends. Herein is presented a brief summary of draw theory with an attempt to look at the factors which can help our understanding of the area of draw influence in block caving mines. Nature of Gravity Flow An understanding of the flow of granular material (rock, sand, grain, or prill as examples) is the first step toward understanding block caving draw. If we take a supported column of granular material and allow gravity flow through an aperture at the bottom of the column, an ellipsoidal shaped zone of disturbance of the in-place material will form and grow with extraction of material through the aperture. The volume of this zone of disturbance or loosening is about 15 times the volume of material extracted at any given time (Kvapil, 1980). Figure 1 shows the development over time of the zone of disturbance. The ellipsoid of disturbance represents a future ellipsoid of extraction which will equate to the volume of materia1 extracted by that future time. Extraction involves the movement of the particles located vertically over the drawhole directly downward while material outside this direct vertical volume moves radially inward and down toward the drawpoint as shown in Figure 2a. Figure 2b shows the result of this motion on originally horizontal strata within the ore column. Increased draw increases the eccentricity of the ellipsoidal volume or, in other words, the ratio of the height over the width of the disturbed area increases as ore is withdrawn from the column (Kvapil , 1980). This becomes important to block caving since eventually a vertical cylinder of draw will be approximated as this ratio increases without bounds. Figure 3 shows this result. The width of this draw cylinder is a critical dimension for the determination of draw point spacing in relationship to block caving mine design. McCormick (1968) for one, felt that within this cylinder of draw, mass flow would take place. This is the

Jan 1, 1981

The following is an incomplete list of members and guests who called at Institute headquarters during the period Oct. 10, 1918 to Nov. 10, 1918. J. Carson Adkerson, Virginia. George H. Parsons, Hayden, Ariz. Andrew B. Armstrong, Connecticut. W. E. Pomeroy, New York. Courtenay DeKalb, San Francisco. Ezra C. Rider, Bisbee, Ariz. Clifford G. Dennis, San Francisco. H. W. Seaman, Chicago, Ill. Rudolph Emmel, Boston, Mass. William Allen Smith, Northampton. Emil Gathmann, Baltimore Md. R. K. Stockwell, Salt Lake City, Utah. Ernest S. Geary, Denver, Colo. W. G. Swart, Duluth, Minn. W. E. Hopper, Washington, D. C. Kirby Thomas, New York. W. Spencer Hutchinson, Boston, Mass. - Warren D. Thompson, Harvard Club. E. W. Kohl, Jr., Philadelphia, Pa. H. Vincent Wallace, Los Angeles, Cal. E. C. Nighman, Butte, Mont. Paul T. Benson, formerly with the Tacoma smelter, has resigned his position there to accept one with the Great Metals Mining and Milling Co. at Nespelem, Wash. Prof. Edward E. Bugbee, of the Mining Department of the Massachusetts Institute of Technology, has been granted a leave of absence to accept the position of Assistant Director of Education for the S.A.T.C. of five southern states with headquarters at Raleigh, N. C.

Jan 12, 1918

By Michael A. Zappia

INTRODUCTION The San Manuel mine of Magmacopper Company is located approximately 72 km northeast of Tucson, Arizona. The mine, concentrator, smelter, electrolytic refinery and continuous rod casting are located on the west side of the San Pedro River valley. Ore Production: 58 1W mtpd Production To Date: Over 340 000 000 mt since 1956. Ore Grade: 0.70% net sulfide cu. As conceived at the present time, the San Manuel ore body is the lower half of what was originally an elliptical (In cross sect ion) cylinder same 2400 m long with major and minor cross sectional axes of 1500 m and 760 m. After emplacement, the cylinder was diagonally sliced along its long dimension by the San Manuel fault, which separated it into halves, moving the upper half same 2500 m down dip and bringing a wedge-shaped blanket of tertiary conglomerate into position over the lower segment of the cylinder. The lower segment is the San Manuel ore body. The upper part, moved down dip, is the Kalamazoo ore body. Originally, these were one ore body. The San Manuel ore body is a structurally weak and highly fractured quartz monzonite, the principal ore minerals being chalcopyrite, with small amounts of molybdenite. The present mining method is full gravity diagonal retreat panel caving by block. This is shown on Figure 2 , (Block Sequence 56, 57, 58, 59 --on the following page.) The ore mined is hoisted to the surface for transportation to the concentrator. BLOCK CAVING MINING SEQUENCE HISTORY The San Manuel mine was planned and developed as a full gravity block caving mine. It continues as a full gravity block caving mine. Since its initial start, the major changes in mining have been in the areas of ground support, rate of draw and undercut sequence. Ground weight resulting from block caving plays a dual role. It can cause extensive damage to ex- traction openings, yet it is necessary to break the ore into easily handled size. The ground- weight problem resolves itself into finding ways to make it manageable. The initial early ground support in the production areas consisted of timber sets and various combinations of steel and timber sets. This sup- port system proved unsatisfactory and a new support system utilizing concrete was developed. Concrete support, 30 cm to 45 cm thick, proved satisfactory. Rates of draw were experimented with. A draw rate of 45 cm to 61 cm (32 to 45 mt) per draw point per day was determined as optimum in con- trolling ground weight. Undercut sequence or mining sequence was recognized as a major contributing factor to ground weight. This is the most difficult factor to change. The lead time from primary development to undercut can be as much as two years. Initial Checkerboard Pattern The initial undercut sequence was in a checker- board pattern (Figure 2). Blocks Sequence 1, 2, 3, 4, 5, 6--next page.

Jan 1, 1981

By J. M. Schopt

COAL petrology is the study of the lithologic composition and texture of coal and includes megascopic as well as microscopic differentiation. Coal petrography is a quantitative study, principally (but not exclusively) microscopical in nature. The distinction between coal petrologic and coal petro-graphic studies usually is not important, but it is important to recognize that these studies differ materially from other types of petrology that deal primarily with minerals. The petrologic entities* of coal are less clearly distinguished than most minerals and the basis of distinction is not always clearly expressed. The relation of coal petrology to geologic, mining, and technologic problems is most evident when results of coal petrologic studies can be stated quantitatively. The chemical and physical composition of coal and the determination of its quality and properties are continuing problems. The source of these problems lies in the heterogeneity of coal and in its almost complete insolubility in ordinary solvents at normal temperatures. The empirical and comparative character of standard chemical coal analytic values is one of the consequences resulting from heterogeneity and insolubility of coal. Nevertheless, these coal analytic methods are highly technical and diversified. Coal petrol.ogy employs a group of similar analytical methods which provide information about coal that the other methods cannot supply. The heterogeneity of coal is most clearly demonstrated by means of petrologic studies. The properties utilized in coal petrologic studies are related to texture (size, form, and association), hardness, light reflectance, and light absorption and transmission (color). Size relations are most evident but are commonly overlooked. Coal is classed chemically as a mixture, and chemical analyses thus show the composition of the sample as a whole. Geologically coal is an organic clastic deposit, derived from diverse plant fragments and particles having a size range comparable to that of a conglomerate or breccia. The mixture of different materials that compose coal, large and small, can be realized only by microscopic study. This is because the fundamental cellular units of plants, from which coal is formed, are microscopic in size. The kinds of altered plant particles and fragments in coal have specific differences in hardness, reflectance, and color that signify differences in composition. These differences must be taken into account in evaluating the aggregate properties of coal. Terminology and Texture Full discussion of terms applied by various petro-logists in analysis of coal is beyond the scope of this article. For convenience the simpler types of petrologic entities that are defined without reference to lithologic occurrence or texture will be called coal components. Fig. 1 lists reactive and relatively inert

Jan 1, 1957

By F. X. Spiegel, D. Bardos, Paul A. Beck

Ti6NileSi7)G is known to be cubic, with 116 atoms in the unit cell. In the present work four new G sili-cides were found with other transition elements and five G germanides. The titanium-group elements are very efficient in forming G phases. The vanadium -group elements are somewhat less efficient, and the chromium-group elements do not form any. Cobalt can replace nickel in most cases, but it is somewhat less efficient. Iron was not found to form any G phases. Germanium is somewhat less efficient than silicon. The (TiNiSi)E phase has been previously identified by Westbrook. However, its crystal structure has not been determined. In the present work the E phase was found to have an orthorhombic unit cell with lattice parameters a. = 7.02, bo = 5.18, co = 11.11A. A large number of other E phases were found at the same stoicheometric ratio in ternary systems of silicon and germanium with transition elements. Lattice parameters similar to those for TiNiSi were measured. The number of atoms per unit cell is estimated at 30 to 36. The vanadium-group elements are somewhat more efficient in forming the E phase than the titanium-group elements. Chromium-group elements were not found to form any E phases. Cobalt is somewhat less efficient than nickel, and iron is less efficient than cobalt. Germanium is not as efficient as silicon. ThE ternary silicide designated as G-phase was first identified by Beattie and versnyder1 and by Beattie and Hagel2 at the approximate composition TiNi2Si. Westbrook et al.' gave the composition as Ti2Ni7Sis. This phase was found to be fcc with a. = 11.201A and 116 atoms per unit cell. Beattie4 and more recently independently Hladishevskii, Kripyakevich, Kuzma, and Teslyuk5 were able to show that this structure is isotypic with MgeSi7CuLe and Th6Mn23. The latter structures had been determined by Florio, Rundle, and snow,' Nagorsen and Witte,7 and Bergman and Waugh.8 According to the crystal structure, Ti8Ni6Si7 may be considered as the ideal composition. The Russian investigators5 identified six additional ternary phases isotypic with Ti6Ni6Si7, in which titanium is replaced by Mn, V, Nb, Ta, Zr, and Hf, and one, namely MneNil6Ge7, in which germanium replaces silicon. They also found that Cr6Ni6Si7, which does not occur as a ternary phase, can be stabilized by replacing 1 at. pct of the Cr by V, Mn, or Ta. Another ternary silicide was found by Westbrook et al.3 at the composition TiNiSi, and it was designated by them as the E phase. The crystal structure of this phase has not been deter-

Jan 1, 1963

Discussion of the paper of WALTER 0. SNELLING, presented at the New York meeting, February, 1915, and printed in Bulletin No. 100, April, 1915, pp. 695 to 704. A. F. LUCAS, Washington, D. C.-Are the results of the experiments in practical operation? WALTER 0. SNELLING.-There have been no large-scale operations up to the present. The necessary conditions of temperature are easily arranged for, but the required condition of pressure, 800 lb., is not so simple a matter. The company has been working on this problem, and at the refinery in Oklahoma work of this kind is now being carried on. The way in which an ordinary still will leak at 50 lb., and more at 100 lb., leaves some doubt in the mind of many as to what can be clone at a continuous working pressure of 800 lb. On the other hand, the fact that they are making ammonia abroad by a method which employs higher pressures and temperatures than anything involved in this method, leads me to believe that the difficulties, which will undoubtedly arise when this is attempted on a commercial scale, can be overcome. WILLIAM N. BEST, New York, N. Y.-Is there any change in the calorific value of these oils?

Jan 5, 1915

By E. C. Kersey, R. J. Gennone

MetALLOGRAPHIC investigations of composites of zinc alloys and aluminum have been made to study the effects of various thermal treatments on the zinc-alloy grain size and diffusion of zinc into the core material. The use of various alloys of zinc has necessitated the development of a universal etchant which will allow microscopic examination of the zinc grain size regardless of the composition.

Jan 1, 1960

By C. M. Marquardt

Tramp iron and steel moving on a conveyor belt cause small currents to be generated in a coil situated in a strong magnetic field, which are converted to an alternating current and are amplified. The output voltage from the amplifier fires a thyratron with a relay in its anode circuit, which actuates a howler and simultaneously drops a spot of marker material on the belt. THE problem of tramp iron removal from moving ore belts is a long standing one. When heavy ore streams are carried on a belt, magnetic pulleys and strong surface magnets fail to remove tramp buried in the ore stream. Tramp iron buried in the ore stream cannot be pulled from the bed by surface magnets and is carried past the magnetic pulley by the falling ore stream. With the increased use of detachable bits the problem of the detection and removal of tramp has become more necessary and difficult. Several types of tramp detectors have been developed. It would serve no practical purpose here to review exhaustively the literature on the subject. Methods of tramp detection used are: (1) The magnetic method, wherein the small current generated by the magnetized tramp passing a Coil is used. (2) The unbalanced oscillator method wherein the tank circuit of a stable radio- or audio-frequency oscillator is unbalanced causing a change of frequency or a change in plate current due to changes in eddy currents, hysteresis, or dielectric because of the presence of tramp. (3) The bridge methods wherein the impedance of one leg of an alternating current inductive bridge is changed due to the presence of conducting tramp. Each of these methods of tramp detection has its field of usefulness. The second and third methods are excellent for oxide iron ores, coal, sand and gravel, grain, etc. However, these latter methods are not suitable for use on ores that contain rich conducting sulphides, since a large piece of pyrite or galena will cause the same detector response as a piece of tramp iron. At the Caselton, Nevada, plant of the Combined Metals Reduction Co., sulphide ores are treated; therefore, it was necessary that a tramp detector operating on only the magnetic properties of the tramp iron be used. Tramp iron detectors of this type operate on the principle that if a piece of tramp iron moves near a coil in a high intensity, steady magnetic field, the presence of the moving tramp iron causes the magnetic flux lines through the coil to change. This induces a mall current in the Coil. In series with the Coil is generally placed a relay sensitive to currents of 1 to 3 microamp. When the tramp iron passes near the coil the flux linkages change, causing this very sensitive relay to actuate. Since the contacts of such a relay are very small it must actuate a second relay capable of breaking a larger current

Jan 1, 1951

By C. M. Marquardt

Tramp iron and steel moving on a conveyor belt cause small currents to be generated in a coil situated in a strong magnetic field, which are converted to an alternating current and are amplified. The output voltage from the amplifier fires a thyratron with a relay in its anode circuit, which actuates a howler and simultaneously drops a spot of marker material on the belt. THE problem of tramp iron removal from moving ore belts is a long standing one. When heavy ore streams are carried on a belt, magnetic pulleys and strong surface magnets fail to remove tramp buried in the ore stream. Tramp iron buried in the ore stream cannot be pulled from the bed by surface magnets and is carried past the magnetic pulley by the falling ore stream. With the increased use of detachable bits the problem of the detection and removal of tramp has become more necessary and difficult. Several types of tramp detectors have been developed. It would serve no practical purpose here to review exhaustively the literature on the subject. Methods of tramp detection used are: (1) The magnetic method, wherein the small current generated by the magnetized tramp passing a Coil is used. (2) The unbalanced oscillator method wherein the tank circuit of a stable radio- or audio-frequency oscillator is unbalanced causing a change of frequency or a change in plate current due to changes in eddy currents, hysteresis, or dielectric because of the presence of tramp. (3) The bridge methods wherein the impedance of one leg of an alternating current inductive bridge is changed due to the presence of conducting tramp. Each of these methods of tramp detection has its field of usefulness. The second and third methods are excellent for oxide iron ores, coal, sand and gravel, grain, etc. However, these latter methods are not suitable for use on ores that contain rich conducting sulphides, since a large piece of pyrite or galena will cause the same detector response as a piece of tramp iron. At the Caselton, Nevada, plant of the Combined Metals Reduction Co., sulphide ores are treated; therefore, it was necessary that a tramp detector operating on only the magnetic properties of the tramp iron be used. Tramp iron detectors of this type operate on the principle that if a piece of tramp iron moves near a coil in a high intensity, steady magnetic field, the presence of the moving tramp iron causes the magnetic flux lines through the coil to change. This induces a mall current in the Coil. In series with the Coil is generally placed a relay sensitive to currents of 1 to 3 microamp. When the tramp iron passes near the coil the flux linkages change, causing this very sensitive relay to actuate. Since the contacts of such a relay are very small it must actuate a second relay capable of breaking a larger current

Jan 1, 1951