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By W. R. Crane

THE support of roof in mines is dependent largely on the character of the top rock and its occurrence. The formations overlying the orebed in the Birmingham district are sandstone and slate. The sandstone occurs in beds of sufficient thickness to constitute important elements in the system of support; the slate is relatively strong but is thinly stratified. The alternating beds of sandstone and slate furnish an excellent combination in that the former are strong and the latter are impervious; however, their continuity is broken by jointing or slip planes. The thickness, and consequent weight of the overlying formations, is important in so far as the size and arrangement of pillars are concerned but may be relatively unimportant, temporarily at least, as a factor in the support of the roof. The position of the respective beds of sandstone and slate, their relative thickness, and their inherent weakness because of the occurrence of faults and folds, may exert a predominating influence on their support in place, which is affected only in part by the weight of the cover. The only mine in this district that operates under a cover of approximately 2000 ft. (1900 ft.) is the Shannon so-called "twin slope," situated 14,000 ft. southeast of the portal of the No. 7 mine of the Tennessee Coal, Iron, & Railroad Co. The conditions in this mine indicate what may be expected in other mines when the same depth is attained; in fact the effect of pressure is shown in several mines that have not reached two-thirds of that depth. It is evident then that conditions affecting the support of roof will not improve but rather will become more difficult with the extension of the mines into the valley under a constantly increasing weight of cover. Further, the difficulties will probably be augmented by the occurrence of faults and other disturbed ground, the presence and position of which at present are largely unknown.

Jan 9, 1924

By AIME AIME

THE Seventh International Petroleum Exposition and Congress to be held in Tulsa, Okla., Oct. 4 to 11, inclusive, in true western spirit promises to be bigger and better than ever. The Exposition has become an established institution. It gives opportunity to petroleum engineers, technologists, and operators to see each year at one place what the tool makers and machinery manufacturers have to offer which is new or better. It has truly become a place "where men, methods and machinery meet." It is also a convenient focus for technical meetings of various kinds devoted to petroleum and natural gas problems. 'The Petroleum Division of the A. I. M. E. has for several years held its chief fall meeting at Tulsa just preceding the opening of the Es- position. This year our meeting will be on Oct. 2 and 3 and it will be held as usual at Hotel Mayo. The Mid- Continent Oil and Gas Association will, as usual, hold a meeting during the Exposition and this year the Petroleum Division of the A. S. M. E. will hold a three- day session, Oct. 6-8, in the auditorium on the Esposition grounds. In all, six technical sessions are planned by this Society, and aside from reports of committees some 20 technical papers are to be presented. Members of the Institute should attend its own meeting and stay over for as many days as possible for the other meeting at which they will hear and see much of helpful interest.

Jan 1, 1930

By W. F. Dietrich

This paper deals with the methods of mining the high-grade clays of California. The fact that the majority of the clay pits in the state are operated on a scale that is small by comparison with most metal mines causes a diversity of methods and gives rise to problems of selection of the method best suited to given conditions. Two or three operators in California produce approximately 500 tons per day of a single kind of clay from a single pit. About five varieties of clay are mined on a scale of 200 to 400 tons per day; not over 15 varieties are mined on a scale of 50 to 200 tons per day; and more than 50 varieties are mined at the rate of less than 50 tons per day. It is the aim of this paper to delimit, as far as the data at hand permit, the conditions and scale of operations that favor the selection of each dominant method of mining that is actually being applied at California properties. Details of the occurrence and utilization of the clays of California have been given in a recent bulletin1 and will not be considered here. Geographical and Geological Features of California Clay Deposits The greater part of the high-grade clays consumed by clay-working plants in California is mined from one of three producing areas in the state: (1) Lincoln, Placer County, on the eastern edge of the Sacramento valley, 30 miles northeast of Sacramento; (2) Ione, Amador County, in the foothills of the Sierra Nevada, 38 miles northeast of Stockton, and 12 miles west of Jackson, one of the important towns of the famous Mother Lode gold-mining district; and (3) Alberhill, Riverside County, 90 miles southeast of Los Angeles. Other districts of minor importance are near Cardiff and Carlsbad, San Diego County, and El Toro and San Juan Capistrano, Orange County. In addition, there are a number of isolated properties in various parts of the state.

Jan 1, 1928

By R. H. Swallow, George Hess

Aerial photography was once a crude, uncertain tool. Today it is a precision mapping instrument which saves important time and money for strip mining and other industry. Aerial photography began in the boxkite days of aviation. The Army first used it for rough reconnaissance photographs. Then, in the early Twenties, industry began to use aerial photographs of their plants and facilities for advertising or annual reports. The quality of these pictures was not very good by today's standards, but this work began the development of better cameras, better lenses, better photographic techniques.

Jan 1, 1949

By W. R. Atkins

The Negaunee mine is at the east end of the Marquette Range, in the city of Negaunee, on the Upper Peninsula of Michigan. Iron ore was first discovered on this property in 1883 by diamond drilling. A shaft was sunk soon afterward. and the mine has been worked continuously ever since. The total shipments from 1887 to Jan. I, 1945, were 20,417,587 long tons. The mine was taken over by the present operators, The Cleveland-Cliffs Iron Co., in 1903. During the past four years, 1941 to 1944 inclusive, the property has produced an average of nearly a million tons a year, and has employed more than 400 men. Geology The ore body at the Negaunee mine lies in a large syncline dipping about 15° to the west, the ore coming to ledge at the east end of the trough. The ore occurs in the Negaunee formation of the middle Huronian age, which consists of ferruginous cherts and slates through which intrusions of diorite have occurred. Although these intrusions of diorite have an important bearing on the formation of ore on the range, they are not important in this ore body. Some faulting has taken place along the diorite intrusions, or dikes as they are called locally, and also other faults are known to exist across the formation. These faults do not complicate either mining or development of the ore body. The footwall consists of jasper underlain with Siamo slate; the hanging wall is jasper and ferruginous chert. Fig. I shows a typical cross section of the ore body. The ore body is quite regular, about 120 ft. thick in the middle of the syncline and thinning out toward both sides of the fold. Its width ranges from 400 to 800 ft., the average being about 600 ft. The footwall is uniform in dip and strike, but irregular lenses of ore often extend 50 to 75 ft. up into the overlying jasper capping. Method of Mining Ore in the Negaunee mine has been mined by top slicing almost exclusively since 1903 This method of mining has been employed because it is especially adapted to the size and shape of the Negaunee ore body, and to the soft, sticky nature of the ore as well as the generally soft, broken jasper capping. Development The ore body has been developed from six different levels with intervals varying between loo and 125 ft. On the average, the dip causes a horizontal offset of 350 ft. per level, and under these circumstances it has been necessary to carry on considerable development in rock to make available the ore lying along the north and east footwalls. This is not as disadvantageous as might be supposed, because of reduced pressure and the accompanying saving in maintenance costs. The development of the

Jan 1, 1949

By A. F. Henderson, C. F. Cornell, A. F. Dunyon, D. A. Dahlstrom

Ossi E. Palasvirta (Development Engineer, Oliver Iron Mining Diu., U. S. Steel Gorp.)—The authors are to be congratulated for their interesting article, which thoroughly illustrates the variables inherent in filtration of taconite concentrate. The work and the conclusions based thereon largely parallel the test work done by the writer at the Pilotac plant" and the experience gained with a commercial size agitating disk filter in the same plant. At Pilotac, however, a thorough study was also made of the effect of depolarizing (demagnetizing) the filter feed, and it is the purpose of this discussion to comment on the merits of depolarization of the magnetite concentrate prior to filtering. The work at Pilotac was done in three phases: 1) preliminary laboratory testing with a circular filter leaf of 0.047 sq ft, followed by 2) plant testing using a 4-ft diam, single-disk agitating filter that was purchased on the basis of the pilot tests on the 4-ft model. In the laboratory tests depolarization was achieved by slowly withdrawing' batches of thickened concentrate from a coil producing an alternating field of about 300 oersteds. In plant tests the standard Pilotac procedure' was employed, wherein the pulp falls freely through the depolarizing coil. The preliminary tests in the laboratory at first seemed to indicate that although depolarization of the filter feed decreases the cake moisture, it also tends to decrease the thickness of the cake, thus decreasing filtering rate. The tests with the 4-ft disk filter soon showed, however, that the compactness of the cake, attained during the form period because of depolarization, permitted a considerable decrease in drying time without any sacrifice in final moisture content. Thus, the filter could be operated at a much higher speed, and the overall capacity was higher than with magnetized feed. Because of the great compactness of the cake there was little shrinkage during the drying period, which prevented cracking and subsequent loss in vacuum. This in turn permitted operation with as thick a feed pulp as the diaphragm pumps could handle, eliminating the necessity of pulp density control. On the basis of these findings, the 6-ft agitating disk filter has been operated at 2 rpm, using feed pulps varying from 65 to 73 pct solids. Initially Saran 601 was used as medium, but it was later replaced with a relatively open, tight-twist nylon cloth. Filtering rates up to 750 lb per ft- er hr can be attained with feeds averaging about 70 pct- 270 mesh, and there is no trouble because of cracking. The cake moistures vary between 8.5 and 9.5 pct. To recapitulate, the merits of depolarizing the filter feed may be summed up as follows: 1) The well dispersed pulp shows less tendency to settle in the filter tank. 2) The homogeneous filter pool results in more even cake formation. 3) Because of absence of flocs, great compactness of cake is attained during the form period. 4) The cake does not tend to crack during the drying period. 5) A drier cake is produced. 6) A shorter drying period is necessary, permitting higher operating speed, which in turn results in increased capacity. 7) Density of the feed pulp can be kept as high as the equipment can handle. This increases capacity, since it is directly proportional to the percentage of solids in the pool. A few tests were also made to study the effect of chemical flocculants on filtration efficiency. Results showed that the effects of chemical and magnetic floc-culation were quite similar. Thus the use of a floccu-lant would impair rather than improve the filtering of magnetite concentrate. A. F. Henderson, C. F. Cornell, A. F. Dunyon and D. A. Dahlstrom (authors' reply)—We want to thank O. E. Palasvirta for his comments, particularly in view of the encouraging results obtained with demagnetized taconite concentrate. In our studies an attempt was made to evaluate the effects of depolarizing the feed to the plant filters by passing the slurry through a coil, similar to the method described by Palasvirta. Unfortunately, in our experiments there were no startling improvements in performance level, neither cake rate increase nor cake moisture reduction. However, when slow filter cycle speeds were employed, the filter cake tended to crack and the vacuum level dropped, resulting in an increase in cake moisture content. When demagnetized feed was used during slow speeds, no cake cracking was evidenced and the vacuum level remained constant. Thus the depolarizing coil was found necessary only in cases of cracking. It should be noted that most of our test work concerned a feed of 85 to 90 pct —335 mesh and about 60 pct by weight solids concentration. This contrasts with 70 pct —270 mesh and 65 to 73 pct by weight solids as noted by Palasvirta. Reviewing both sets of results, it might be concluded that depolarizing may be successfully employed to alleviate cake cracking tendencies and may markedly improve cake rates and moistures on the coarser taconite concentrates. Further investigations may disclose the exact relationship of grind and pulp density to the depolarizing action.

Jan 1, 1959

By Om P. Garg

During the period between 1970 and 1974 the Iron Ore Company of Canada had embarked on a detailed program to evaluate all aspects of mine design work for its open pit mines around Schefferville, located both in Quebec and Labrador, Newfoundland, Canada. One of the main conclusions was that the majority of the slope angles for the ultimate pit walls could be steeped. During the period 1975 and 1976,five (5) open pit iron ore mines were redesigned using the steeper slope angles up to 55 degrees. Initially these pits were designed at slope angles varying between 37 degrees and 45 degrees due to the generally fractured and leached nature of rocks in the area. During the active mining phase between 1976 and 1979, the stability of the steeper ultimate pit walls was monitored. The mining of ore was successfully completed in 1978 and 1979 in three pits. This of course, resulted in a significant savings due to a reduction in the quantity of waste that had to be removed. The successful pit slope redesign project was a co-operative effort between the Federal Government, Universities and the Iron Ore Company of Canada.

Jan 1, 1983

THE Institute Committee on Industrial Relations, of which Robert Linton is chairman, held a meeting on Feb. 21, listed as one of the technical sessions of the annual meeting, at which reports of the sub-committees were presented. Following are abstracts of these reports. The Institute can furnish mimeo-graphed copies of the complete reports on Safety, Employment, Illness, Mental Factors, and Cripples in Industry. The supply of the other reports has been exhausted. A paper by George F. Kunz, which was presented at the same meeting, is printed here in full.

Jan 6, 1922

By H. W. Hardinge

Disregarding for the present the economic side of a new device, let us turn to that feature of the conical pebble-mill which is of interest from a scientific point of view, and consider the device as a puzzle in which the theories of the cylindrical type of mill have been increased. Many articles have been written on the theory of the tube-mill, and explanations have been made which do not explain ; but these have evolved suggestions of practice which have resulted in changes in the tube as to length, diameter, feed, discharge, speed of rotation, rotation on hollow trunnions, rotation on rings, and changes in the operation as to quantity and size of pebbles, charge of load above or below the axis, crushing by causing the larger pieces of the material of the charge to act as grinders, whether crushing is abrasive or impactive, etc. The practical worker in crushing. is first interested in the endeavor to reach an econonlic means of accomplishing a desired end; but the improvements in crushing-practice have been largely left to the manufacturer of machinery, who, as a rule, has little, if any, knowledge of the specific requirements— such as granulation, sizing for concentration without pulverizing the metals, instead of pulverizing the rock or gangue; the metals being the more friable, while the rock is tough and not so easily disintegrated. A reversal of this practice is the aim of sliming direct for cyanidation or pulverizing for cement, etc. In the ordinary cylindrical mill, having a diameter of 4 or

Jan 1, 1909

By Galen H., Clevenger

THE first and most important thing that affects the majority of lead producers in the Rocky Mountains and the western mining regions is that zinc in an ever-increasing degree is inseparably associated with the lead. The Sullivan mine in British Columbia is not only a great lead mine, but also a great zinc producer. This mine could not reach its full measure of productiveness, nor was its great value established, until a reasonably good physical method was developed for separating the lead from the zinc prior to the recovery of each metal by an appropriate process. The western metallurgists and also metallurgists in other parts of the world have long faced the lead-zinc problem. This for many years stimulated a great deal of experimental work looking toward the development of a physical or chemical method of separating lead and zinc in concentrated form from complex ores. Space will not permit of going into this work in detail, but it is sufficient to say that with but few exceptions the western lead smelter continued smelting charges many times too high in zinc for the most efficient operation of lead furnaces. The zinc was not only lost, as the zinc content of many a western slag dump bears mute testimony, but the cost of lead smelting was increased by reason of the presence of the zinc. The owner of the ore under these circumstances could be paid nothing for the zinc and, indeed, he was penalized for it

Jan 1, 1926

By W. R. Hibbard, J. D. Nisbet

The high temperature properties of Fe-Cr-Co-Ni base alloys and the effects of hardening element additions on these properties are rationalized on the basis of general principles of alloying. DURING the past few years the base elements in high temperature austenitic alloys have gradually been changed from iron-rich materials to nickel-rich, then to cobalt-rich and more recently to various iron, cobalt, and nickel combinations, all with an approximately constant chromium content of 20 pct. Concurrently, the hardening additions of the incongruous* elements, have been shifted from small amounts of a single element to various ratios of molybdenum, tungsten, columbium, carbon, titanium, and aluminum with the percentages of these constituents continually increasing. It has been known that the typical soft high temperature alloy (such as Inconel) consisted of face-centered cubic austenite, but the effect of varying the composition of the base elements, iron, chromium, nickel, and cobalt, has not been broadly analyzed. Therefore, it was reasoned that the first major problem in the understanding of the properties or the further development of high temperature alloys was to study systematically the effect of composition upon the mechanical properties of face-centered cubic Fe-Ni-Co-Cr austenitic solid solutions. The matrix of the strong high temperature alloys (such as Inconel X) is usually also a face-centered cubic solid solution of iron, nickel, chromium, and cobalt but with additional phases which can be generally classified as intermetallic compounds and carbides. It is usually observed that combinations of the hardening elements, tungsten, molybdenum, columbium, tantalum, titanium, aluminum, carbon, and others have been used in these strong high temperature alloys. Thus, it was reasoned that a second major problem in studying these alloys was to understand the effect on mechanical properties of adding

Jan 1, 1954

By E. N. Pugh, J. V. Craig

WhILE it has been established that well-defined microhardness impressions can be produced in germanium by room-temperature indentation,1-3 the role of dislocations in the process is the subject of continuing discussion.4-7 Recently, Carroll and ~anaka'

Jan 1, 1969

By Arthur Flagg

(New York Meeting, February, 1913.) THE Elk City mining district of Idaho occupies a position near the geographical center of Idaho county, a region of mod¬erate elevation in the western foot-hills of the Bitter Root mountains. The district comprises an area of approximately 350 sq. miles, bounded oil the west by the Newsome district and on the south by the Dixie and Oro Grande districts. There are no mining districts to the north or east. Elk City, the principal town and the seat of the mining office for the district, is situated in a hydrographical basin surrounded by low hills. The elevation is 4,200 ft. above sear level. Through this basin flow Elk Creek, Red river, and American river, which unite west of town to form the south fork of the Clearwater. The one township is set out from the Bitter Root Forest Reserve. Though a railroad starting from the Stites terminus of the Clearwater Short Line of the Northern Pacific railroad has been under consideration for some years, the camp is yet with¬out railroad facilities. The projected road would follow the south fork of the Clearwater on easy grades, but would be very expensive to build and maintain. While such a road would greatly benefit those who are now operating in the camp, and in a slight degree stimulate interest in its possibilities, there is hardly business enough to warrant its construction.

Jan 4, 1913

By AIME AIME

THE PAPER, "Surface Effects on Assay Beads Caused by Metals of the. Platinum Group," presented by J. L. Byers, before the Institute of. Metals Division at the February meeting of the Institute, is the subject of interesting discussion, an abstract of which follows. The original paper is available at Institute headquarters as a Preprint. Member-What assurance have you that the percentage of metals, as stated, is really an accumulation?

Jan 1, 1932

By Samuel Frantz

THE purpose of this paper is to relate briefly the development of magnetic separation and its extension from the separation of iron into its present use in the nonmetallic field, to suggest possible future exten-sions of its field of usefulness and its possible cooperation with other separating methods. The engineering design of separating machines, and statistics as to the number of machines in operation, types, their location and production are outside the scope of this paper. Specific data will be given, however, on certain selected applications. A large part of human endeavor consists in separating one thing from another; the good from the bad, the desired from the undesired. In fact, a philosopher might plausibly claim that separating things into categories and choosing between them is the object of thought itself. In dealing with matter, separation is nowhere more inherently necessary to attain our objects than in mining and metallurgy. Both our desire and our ability to make separations are results of the physical differences between things. Gross separations such as removing ore from worthless rock or coal from slate are usually made visually and depend upon form and color, which are physical properties. When the desired and the undesired things are intimately mixed, however, it becomes impractical to select visually even if the individual particles are readily recognizable to the eye, and some automatic way of making the particles separate themselves on the basis of their own inherent differences in physical properties must be resorted to. Some of the physical properties which have been used as a basis of separation are: color, shape, hardness, size, density, elasticity, surface properties (surface tension in contact with liquids, etc.), electrical conductivity, dielectric constant, and magnetic susceptibility. Differences in these properties are used in the following methods of separation: color sorting, sifting, settlement in air and in liquids, floatsink methods, flotation, electrostatic and magnetic separation.

Jan 1, 1932

Jan 1, 1908

Jan 1, 1952

By Amos Bowman

In the last two years I have had an opportunity to study the conditions of gold-mining in the far northwest of the Pacific coast —in Cariboo district, British Columbia. That country joins Alaska

Jan 1, 1887

By C. A. Heiland

FOR the past three years, the senior writer has carried out, with inter-ruptions, a series of investigations into the characteristics of prospecting seismographs of a wide variety of construction. Early in 1932, a com-plete equipment was developed for both refraction and reflection observa-tions; its first function being, however, the application in reflection shooting. The performance of the equipment proved to be highly satis-factory in a series of field tests' which were carried out by the junior writer, whose services were loaned to the Colorado School of Mines by courtesy of the Plains Exploration Co. in Denver. The various problems that were encountered in the construction of the equipment, in its application in the field, and in the interpretation of the results, are fully treated in Publication 47 of the Department of Geophysics of the Colorado School of Mines. Its first part deals with the various problems encountered in the design of the instruments, and presents a discussion of such topics as the free and forced oscillations of damped and undamped mechanical seismographs, the action of oscil-lographic recording instruments and amplifiers, the characteristics of electromagnetic seismographs, and the requirements of damping, natural frequencies and static magnification for the pickups, amplifiers and oscillographs used in refraction and reflection seismographs. Further-more, a detailed discussion of the various methods of static and dynamic tests of seismic receivers, and a description of the reflection equipment developed at the School of Mines is presented. Unfortunately, a delay has occurred in the publication of the first part of this investigation concerning the instrument problems. There-fore, the second part, dealing with the field problems, is herewith pre-sented first.

Jan 1, 1933

By E. T. Turkdogan

The activity of sulfur was determined as a function of composition of ferrous sulfide by equilibrating with hydrogen sulfide-hydrogen gas mixtures at 670° , 800°, and 900". The present results supplement the available data over the composition range from 36.6 to 39.5 pct S. The X-ray lattice spacing measurements made are in accord with the available data and indicate that the limiting composition FeSl.008 may be taken for the iron-iron sulfide equilibrium. The growth rate of ferrous sulfide on iron was measured by reacting iron strips or blocks in hydrogen sulfide-hydrogen gas mixtures. Owing to the slow approach to equilibrium between the gas phase and the surface of the sulfide layer, The sulfidation experiments were carried out for several days. It is shown that the growth rate ullimately proceeds in accordance wilh the parabolic rate law. From the parabolic rate constants and the thermodynamic data on iron sulfide the self-difiusivity and chemical diffusivity of iron in ferrous bisulfide are evalualed. The self-diffusivity of iron thus derived zs found to increase with increasing sulfur content. THE ferrous sulfide known as "pyrrhotite" is a non-stoichiometric phase having a wide composition range from about 50 to about 58 or 60 at. pct, depending on the sulfur activity. RosenQvistl studied the thermodynamics of this phase over wide ranges of temperature and composition. Hauffe and Rahmel' and Meussner and ~irchenall~ studied the parabolic rate of sulfidation of iron in sulfur vapor. By using markers, these investigators showed that the iron cations were the predominant diffusing species in iron sulfide. This is confirmed decisively by the self-diffusivity measurements of condit4 who showed that the self-diffusivity of sulfur in ferrous sulfide is several orders of magnitude lower than the self-diffusivity of iron. Although much has been learned from these studies about the Fe-S system, further research on this subject was considered desirable for better understanding of the physical chemistry of iron sulfide. This work was confined to the study of the kinetics of sulfidation of iron in hydrogen sulfide-hydrogen gas mixtures. The results of this study are given in two consecutive parts. Part I, the present paper, is on the parabolic rate of sulfidation of iron and the diffusivity of iron in ferrous sulfide. The second paper, Part 11, is on the kinetics of the surface reaction between hydrogen sulfide and ferrous sulfide. EXPERIMENTAL Three types of experiments were carried out: i) equilibration of ferrous sulfide with gas of known E. T. TURKDOGAN, member AIME, is Manager,Chemical Metallurgy Division, Edgar C. Bain Laboratory for Fundamental Research, U. S. Steel Corp., Research Center, Monroeville, Pa. Manuscript submitted March 6. 1968. ISD sulfur potential; ii) X-ray studies of ferrous sulfide; and iii) measurements of the parabolic rate of sulfidation of iron. Equilibrium Studies. About 1 g of iron powder or foil. contained in a small recrystallized alumina crucible ind suspended from a calibrated silica spring, was reacted with a hydrogen sulfide-hydrogen mixture of known ratio until no further change in weight was observed. %hen the gas composition was changed and the new state of equilibrium was established after several hours of reaction time. The composition of the sulfide was obtained from the initial weight of the sample and the weight after equilibration. X-Ray Studies. The lattice parameters of some of the equilibrated samples were determined using the General Electric XRD-5 diffractometer with a cobalt tube (no filter) set at 40 kv apd 10 ma; the CoK, radiation was taken as 1.79020A. Observed 220 and 311 diffraction peaks of silicon served as an internal comparison standard to correct for possible misalignment of the goniometer. The lattice parameters of the sulfide phase were calculated from the corrected Bragg angles of the 110 and 102 peaks. Rate Studies. In the initial experiments attempts were made to measure the parabolic rate of sulfidation by measuring the gain in weight of a thin iron strip, -0.05 cm thick, suspended from a silica spring in the reacting atmosphere. The preliminary experiments showed that this technique was not reliable for the measurement of the parabolic growth rate of the iron sulfide layer. In the subsequent experiments the data on growth rate were obtained by measuring, on a microscope stage, change in the thickness of the sample after reaction for a specified time in a hydrogen sulfide-hydrogen mixture of known sulfur activity. For each reaction time a new sample was used. Precision-machined iron blocks, 0.5 by 2 by 5 cu cm, were de-greased and annealed in hydrogen for several hours prior to the sulfidation rate measurements. The experiments were carried out at 670°, 800°, and 900°C in gas mixtures having the ratios, and 1.0 for periods of times from a few hours up to 8 days. Apparatus and Materials. A vertical globar tube furnace with a 3-in.-long uniform temperature zone was used. The glass tube fittings were fused on the zircon reaction tube, 1.5 in. diam. The temperature was measured with a Pt-10 pct Rh/Pt thermocouple placed in the hot zone of the furnace inside the reaction tube (an alumina thermocouple sheath was used). A separate thermocouple was used for the temperature controller which maintained the furnace temperature constant within about 2°C. Anhydrous liquid hydrogen sulfide and oxygen-free dry hydrogen from gas tanks were used in preparing the gas mixtures by the constant head capillary flow-meters. In all cases volume flow rate was 1000 cu cm per min at stp, corresponding to a linear velocity of about 6 cm per sec at 800°C; under these conditions

Jan 1, 1969