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Jan 1, 1894

By T. E. Leontis, F. N. Rhines

THE oxide scale that forms upon magnesium at elevated temperatures is nonprotective in the sense that the rate of oxidation is constant and thus does not decrease with the growth of the scale as it does with other common metals. This generality was first stated by Pilling and Bedworth1 and has been verified by Suzuki2 and by Scheil.3 Pilling and Bedworth argued that the nonprotective characteristic could be predicted from the fact that magnesium oxide occupies less space than does the metal from which it springs, wherefore the scale is not expected to cover the metal so completely as to exclude all direct access to the atmosphere. Linear oxidation is thought by Scheil to be common to all cases where the reaction occurs at the oxide-metal interface. According to Suzuki,2 the product of high-temperature oxidation in the air is MgO contaminated with no more than traces of a nitride. When the metal is allowed to burn freely a fume composed of cubic crystals of Mg04 is given off. Delavault5 observed that excrescences form upon liquid magnesium and alloys in the course of oxidation. Beyond this it is known that the use of atmospheres containing small quantities of sulphur dioxide6 or carbon dioxide serve to retard the oxidation of solid magnesium and that beryllium7and calcium8 minimize the oxidation of molten magnesium exposed to the air. Many studies have been devoted to the nature and rates of "protective" oxidation, as exemplified by the cases of copper and iron, wherein the rate is characteristically parabolic. The theory of parabolic oxidation is well developed.9 Linear oxidation, on the other hand, has received but little attention and the theories proposed by Pilling and Bedworth and by Scheil have yet to withstand careful examination. There exists no comprehensive survey of the high-temperature oxidation of magnesium (or of any other metal that exhibits linear oxidation) over a broad range of temperature, under a variety of atmospheric conditions and covering a large group of alloys. It has been the purpose of the present investigation to provide such a survey, with the object of gaining a fuller understanding of linear oxidation, especially as applied to magnesium. EXPERIMENTAL PROCEDURE AND RESULTS The experimental studies undertaken were of two kinds: (I) measurement of the rate of oxidation as influenced by the

Jan 1, 1946

By Royal Preston Jarvis

The jig, in one form or another, continues to hold a leading place among the machines designed to separate two or more

Jan 1, 1909

By H. Le Chatelier

Jan 1, 1894

By H. C. Fiedler

X HE development of the cube-on edge secondary re-crystallization texture in Si-Fe strip requires that normal grain growth be restrained. It has been shown that the degree of restraint and hence the completeness of secondary recrystallization depends upon the size and number of second-phase particles, which in turn is dependent upon the prior processing history.1y2 The purpose of this note is to show that, for heats in which manganese sulfide particles are providing the restraint to grain growth, the choice of hot rolling temperature depends upon the manganese content. The making and processing of the heats to the final gage of 0.012 in. has been described.3 The compositions are given in Table I. Apparent in Fig. 1 is the decrease in the ability of strips hot-rolled from 1175°C to undergo secondary recrystallization as the manganese content increases. It has been shown that 1175°C is below the solubility temperature of 0.014 pet S in even the 0.038 pct Mn alloy: and the observed behavior is attributed to an increasing fraction of the sulfur forming large manganese sulfide particles at the heating temperature for hot rolling. This fraction of the sulfur is thus unavailable to subsequently form the small, uniformly dispersed particles which are needed to restrain normal grain growth. Since the sulfur is completely in solution at 1325°C,3 strips from all three alloys show strong secondary recrystallization behavior when hot-rolled from that temperature.

Jan 1, 1969

By Bradley Stoughton

THE importance of magnesium alloys as engineering materials has increased rapidly in the past few years. The most important properties of magnesium alloys are their lightness and strength, which result in their. extensive use in aircraft and automobile construction. Recent progress in the metallurgy of magnesium seems to offer hope of the production of the pure metal at a reasonable cost. The use of magnesium would doubtless increase greatly if it could be produced at a cost comparable with that of aluminum. AA preliminary survey of the magnesium-base alloys shows that the most promising from a practical standpoint are magnesium-aluminum and magnesium-zinc as binary alloys, and magnesium-zinc-aluminum as ternary alloys. The research reported in this paper is a preliminary study' of binary magnesium-aluminum and magnesium-zinc alloys, as an introduction to a series of further investigations.

Jan 2, 1926

By E. C. Patton

Jan 1, 1947

By E. C. Patton

Jan 1, 1947

By Robert F. Mehl

THE solid solutions which aluminum forms with copper, and with magnesium and silicon, are not extensive, and accordingly could not be expected to form Widmanstätten figures profusely nor with great ease. A study of the Widmanstätten figures in these systems seemed desirable, however, because of the interest which these alloys bear towards age-hardening theories resulting from the necessary relationship between the age-hardening phenomena and the atomic processes leading to the formation of Widmanstätten figures.1 ALLOYS OF ALUMINUM WITH COPPER The most accurate determination f the solid solubility, of copper in aluminum seems to be that by Dix and Richardson,2 whose results are represented in Fig. 1. According to this work, aluminum dissolves 5.6 weight per cent of copper at 548°, and less than one per cent at room temperature. Judging from the constitutional diagram, this solid solution on cooling tends to precipitate the compound CuAl2, and this conclusion has been confirmed experimentally by Schmid and Wassermann .3

Jan 1, 1932

The Library of the above-named Societies is open from 9 A.M. to 10 P.M. on all week-days, except holidays, from September 1 to June 30, and from 9 A.M. to 6 P.M. during July and August. The Library contains about 55,000 volumes, including sets of technical periodicals and the publications of scientific and technical societies. Members of the Institute, with few exceptions, are forced to spend a portion of their time in "localities isolated from sources of information. To these the Library can render valuable service through correspondence; letters requesting information will receive special attention. The Library is prepared to furnish references and copies of articles on mining and metallurgical subjects; to determine the existence of mining maps, and to furnish general information as to the geology and mineral resources of all countries. All communications should be made as definite as possible so that the information received may be what is desired and not include collateral matter which may not be of interest. The time spent in searching for such collateral matter will be saved, and the information will be sent more promptly and in more usable shape. The members of the Institute can be of service to ,the Library by forwarding copies of mining reports, maps privately issued, and similar material, which will be classified, indexed, and made available to other members. Suggestions for additions to the Library, either by purchase or personal solicitation as gifts, will be welcomed. It is hoped that members while in the city will use the Library freely, and assurance is given that most careful service will be rendered to then.

Jan 7, 1915

By Klaus W. John

The geologic factor of greatest significance in rock mechanics and rock engineering is considered to be the geologic structure represented by joints, faults, and other planes of weakness. This geologic structure differentiates between the rock element and the rock system composed of these elements. Only during the last decade has the difference of the technological properties of element and system been recognized but this appears to be more in theory than in engineering practice. If rock mechanics is to achieve real significance in engineering practice, it has to provide methods of analysis which are realistic compromises between the best representation of the actual conditions and pragmatic engineering. The rock mechanics practitioner has to face the fact that many geological engineering and rock mechanics problems may be too complex to allow rigorous analysis but at the same time are deemed satisfactory for the construction of major structures. Ultimately, the geotechnical engineer or the engineering geologist has to express the effect of geologic factors in quantitative, even if approximate, terms and provide numerical data on strength and deformability of rock systems to be utilized in construction. Qualitative evaluations, quantitative descriptions of geologic features as such, and comparisons of specific test results are always of interest but may not suffice as basis for engineering decisions and designs. The present efforts of the rock mechanics group at the Karlsruhe University, Federal Republic of Germany, are based on a systematic combination of geomechanical models and numerical analyses based on the finite element approach. This group considers that at the present stage

Jan 1, 1970

By Eduardo Martinez Baca

Although Mexico has always been justly considered by the whole world essentially a mining country, this reputation is due principally to the richness of the deposits which have been worked. In reality, the majority of the States have been little

Jan 1, 1902

By A. L. Field

WOOLSEY McA. JOHNSON, Hartford, Conn. (written discussion).¬When ;we regard the number of British thermal units running into the billions that-must be applied to metallurgical slags in the United States, we cannot but conclude that the physical chemistry of-slags is a very important subject when measured in dollars and cents. A further contemplation of the subject shows us that it has been hitherto treated in too purely a practical manner. It is needless to comment at length on the cost of these heat units and on the cost of fluxes to produce these metallurgical slags, for, it amounts to tens of millions of dollars annually. Accordingly, this research is of value to the country. But we must,all balance our results against our efforts. Therefore, while the speaker is unwilling to criticise unduly this meritorious research, lie does criticise it in the interest of the profession for the reason that it seems to him too highly theoretical. The article is much too, scientific to produce results at a minimum cost. Let us explain our meaning. It has been said that there are always two sides to a question. It may be further said that there are always three sides to a question, the two extremes and the middle ground. In any industrial research there are the highly theoretical side, the purely practical side, and the theoretico-practical side. To study a slag and be practical in the studying, there is something needed that represents in the laboratory (or in microcosm) what actually happens macrocosmically in the blast furnace. There is such a thing as the art of metallurgical research occupying the middle ground between theory and practice.

Jan 4, 1917

Curlisle: We're sitting in Don McLaughlin's office overlooking Sun Francisco Bay, and he's going to be good enough to talk about early days in California, maybe about his college years in Berkeley, maybe about his first jobs in mining. Now, Don, would you be good enough to start it off by saying something about George Hearst. I know he died before you were born, but you know a lot about the family, and you no doubt know a lot about him. Certainly, nobody in those days matched his record in getting hold of good mines. McLaughlin: George Hearst died, actually, in the very year that I was born, but as I more or less grew up in the home of Mrs. Phoebe Hearst, who was his widow, I heard a great deal about the mines and the people that made the great fortune she inherited and used so wisely. But I don't think I really had an appreciation of George Hearst until 1 became active in the mining world and realized how many major mines he had picked in the early days and how much he had to do with their development into successful properties. He started in the California gold fields, but it was on the Comstock that he made his first big stake out of his substantial share in the Ophir mine. I believe at that time he was on his own. Then, later, he became associated with Ben Ali Haggin and Lloyd Tevis in San Francisco, and scoured the West for them. They made a little money in Eureka, Nevada, and other places, but the first important property that he obtained for them was the famous Ontario Mine in Park City, which became one of the great silver lead producers of the Continent. Then later he acquired the Homestake.

Jan 6, 1965

By L. L. Wyman

SINCE the presentation, by the writer, of the initial paper on the embrittlement of copper,1 the subject has been investigated further along two separate lines. The first series of investigations involves the "double-deoxidized" copper, while the second series is devoted to single deoxidizers other than those used in the investigations reported upon last year. The object of these experiments is to develop a type of copper that will show the minimum of detrimental effects after having been exposed to alternate oxidation and reduction. The fabrication of this material necessitates the use of alternate oxidizing and reducing atmospheres, at temperatures ranging up to 900° C. Following this treatment it is essential that the soundness and strength of the copper be unimpaired, even in sections of only a few thousandths of an inch in thickness.

Jan 1, 1932

By H. T. Mercer

THE composition of steel and the theory of its heat treatment have been so ably discussed elsewhere that it is unnecessary to go into the subject here. The purpose of this paper is to describe briefly the method of treating drill steel at the Copper Range mines, giving some of the troubles encountered and the manner in which they were overcome or corrected. To study the matter properly, it was necessary to devise a system of records that would show the actual underground performance of the drills. To illustrate this system, the records of the Champion mine are used, as it is at this mine that most of the work along these lines has been done. Reports from each drill machine are made daily by the shop and mine, and tables compiled from these reports show the footage drilled, steel broken, drills received and sent out at the shop, drills sharpened, and bits cut off. These data show what each machine or party is doing and whether the miners' supply of drills is kept up to date. There have been times when the supply of drills has been short and time lost by the miner in looking for drills. The daily records show the number and condition of drills on hand at all times. Under the old method of sharpening, the drills were heated in a coke furnace, the proper degree of heat being judged by color. Then they were sharpened in a word drill-sharpening machine, reheated in a second coke furnace where the proper heat was again determined by color, and quenched in water. While this method was fairly successful in the hands of a careful workman and for the solid steel used in the old piston drill machine, the introduction of the faster water machine, using hollow steel, produced changes both underground and in the shop. Much more was expected of the hollow-steel and' hammer-type machine, with its improved method of rotation, but troubles due to breakage, burnt bits, uneven tempering, etc., at once began to appear.

Jan 8, 1920

From 1917 to 1926 mining at the Climax Molybdenum Co. property was confined to the Leal and White levels at elevations of 12,145 and 11,935 ft respectively and to surface outcrops above the Leal level. At present the production is coming from the Phillipson and Storke levels at elevations of 11,465 and 11,168 ft. Until 1926 when B. S. Butler recognized the relationship existing between the orebody and a central core of fine-grained hydrothermal quartz, the orebody was believed to be tabular in form. The orebody lies within the pre-Cambrian granites and schists and another rock type designated as the Climax porphyry and surrounds a highly silicious core, the mineable portion of which varies in thickness from 250 to 400 ft.

Aug 1, 1955

By Charles S. Barrett, Frederick N. Rhines, Robert F. Mehl

The solid solutions which aluminum forms with copper, and with magnesium and silicon, are not extensive, and accordingly could not be expected to form Widmanstatten figures profusely nor with great ease. A study of the Widmanstatten figures in these systems seemed desirable, however, because of the interest which these alloys bear towards age-hardening theories resulting from the necessary relationship between the age-hardening phenomena and the atomic processes leading to the formation of Widmanstatten figures.' Alloys of Aluminum with Copper The most accurate determination of the solid solubi1it.y of copper in aluminum seems to be that by Dix and Richardsoq2 whose results are represented in Fig. 1. According to this work, aluminum dissolves 5.6 weight per cent of copper at 548", and less than one per cent at room temperature. Judging from the constitutional diagram, this solid solu-lion on cooling tends to precipitate the compound CuA12, and this conclusion has been confirmed experimentally by Schmid and Wassermann.

Jan 1, 1932

By Frederick Clapp

INTRODUCTION - SCOPE OF DISCUSSION There has hitherto been no systematic effort to make public the available information on petroleum in South America and the object of this paper, therefore, is to broadly discuss the subject as it pertains to South America as a whole, endeavoring to collect in readable form what is known regarding individual fields. This article is not intended to exhaustively discuss individual fields, or to solve the many complicated problems regarding petroleum and natural. gas in the various republics, since those necessitate years of study and work by petroleum geologists, engineers, financiers, and drillers. Neither. can the reader expect absolute accuracy in all statements, since this is impossible at the present time. The writer has, of course, attempted to be correct in all cases, but in a review involving so many countries and extending over so many, phases of the subject, it is to be expected that some errors will have crept in.

Jan 10, 1917

By P. Somasundaran, H. S. Hanna

The separation of minerals such as apatite and scheelite by flotation from other salt-type minerals such as calcite is extremely complex owing to the close similarity between their physicochemical properties. In this paper, properties relevant to flotation such as crystal structure, solubility, surface charge and adsorption behavior of important salt-type minerals are examined along with the role of inorganic modifying agents such as silicates and polyphosphates and organic modifying agents such as starch and tannin. Flotation characteristics of these minerals are then reviewed and selected separation problems involving salt-type minerals are discussed.

Jan 1, 1976