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By W. Rostoker

The process of diffusion alloying of mixed powders offers attractive possibilities both commercially and experimentally. It avoids the fabrication difficulties arising from high alloy contents. Indeed, the process is facilitated by larger alloy additions. The direct formation of the part or test piece and the opportunlity to perform machining operations under more favorable conditions are of no small importance. However, it is necessary to make only brief mention of the interesting features. As yet there have been few attempts to study this process in detail and to carry it to completion, if such is possible. It was intended not only to measure the intermediate and optimum magnetic properties of sintered alloys but to use magnetic testing itself as a means of following the progress of alloying under various condi-tions. Having established that alloys could be successfully synthesized by this tech. nique, the opportunity was taken to study the magnetic properties of several alloys of iron and silicon which had hitherto been too difficult to prepare in suitable test piece form. While avoiding some of the difficulties inherent in the fabrication of alloys by orthodox methods, the diffusion alloying process introduces a few of its own. The first of these is the evaluation of the approach to homogenization. In recent years some notable contributions have been made to this question, but considerable uncertainty remains in its definition and evaluation. This work has concerned itself with further study of this problem and it is hoped that more light has been shed on it. The second of these difficulties arises from the presence of porosity. It is inevitable that in the consolidation of a loose bulk of powder, there should remain some voids unless extremely high pressures are repeatedly applied. It was therefore of importance to investigate their effect on magnetic properties. Recently this effect has been studied and certain predictions made of its behavior. It is believed that the experimental results presented here provide a sound substantiation of the theoretical treatment. The attempt has been made to synthesize five alloys of the iron-silicon system and three each of the iron-nickel and iron-cobalt systems. A series of experiments was also conducted on some of these alloys to test their susceptibility to heat treatment. Some unfortunate experiences have provided opportunity to report data on the deleterious effects of nitrogen on magnetic properties when present as a a in protective atmospheres. MateRIALS, PREPARATION OF SAMPLES and Testing The purest materials available were em. ployed for this work. A specially purified,

Jan 1, 1949

By L. G. Austin, P. T. Luckie

The Bond Work Index has been used for many years to estimate the power requirement of a material with known work index. The index is determined by a completely empirical test and no logical base for its use has been formulated. However, consideration of grinding as a unit operation which can be mathematically treated offers the prospect of considerably more accurate design and mill power estimation when sufficient data on large-scale mills becomes available. The interrelation of the Bond type with the unit operation approach is discussed.

Jan 1, 1973

By E. O. Jones, E. Whitehead

During the heating of cold-worked nickel silver, the tendcncy of the material to crack is well known. The present research deals with this question, and may conveniently be divided into the following sections: Changes in these alloys during heating and cooling, determination of the temperature at which cracking occurs, effect of grain size, quenching cracks, methods of overcoming annealing cracking. The work is far from complete, in particular the influence of impurities on this tendency has not been investigated, but the results so far obtained lead to certain definite conclusions, which are of theoretical and practical importance. Changes in Alloys During Heating and Cooling During the annealing of many metals at a temperature just below that at which recrystallization sets in, there is evidence of some change, the effect of which is to harden and embrittle the material. This effect has been most clearly demonstrated in the cases of aluminum, copper, brass, and nickel silver, and appears to be a common property of cold-worked metals and alloys, or, at any rate, the non-ferrous ones. The effect would obviously offer an explanation for certain types of annealing cracking, but the trouble is so much more common in the nickel silvers than in the other alloys that some special cause should be looked for. There is, however, fairly good reason for believing that similar cracking may occur in some of the brasses; D. Bunting1 suggests that the a brasses toward the saturation limit are subject to a transformation closely allied in nature to that known to occur in the nickel silvers at around 320" C. Although the existence of this critical temperature range was known, it did not necessarily follow that this transformation was responsible for the trouble under investigation, so the first portion of this paper deals with the attempts made to determine whether other critical changes might not occur in these alloys. There were already reasons for the belief that such would prove to be the case, as the mechanical properties of the nickel

Jan 1, 1926

By J. M. Hodge, M. A. Orehoski

tions to which it will be subjected, and this premise is probably the most important reason for hardenability control. However, the criterion of hardenability [ ] ture after quenching should consist wholly of martensite; and that transformation of austenite to intermediate-temperature products during quenching will have a deleterious effect upon the physical properties, particularly the toughness, of the tempered material. This implies that, in order to obtain the optimum physical properties from a given steel, its "hardenability" should be high enough to suppress all transformation except that to martensite under the heating and quenching condi- IT is now generally conceded that if a steel is to develop optimum physical properties in the conventionally quenched and tempered condition, the microstruc- [ ] that at present is most widely accepted and used is based on a microstructure of 50 per cent martensite. This criterion, which was suggested by Grossmann,1 does have considerable justification. It may be readily measured by a fracture or etch test and, since it represents the point at which the hardness is changing most rapidly with variations in cooling rate, it may be determined empirically from a hardness-depth curve by determining the point of steepest slope (the inflection point. Furthermore, in plain carbon steels or in steers of low hardenability, the difference in hardenability expressed in

Jan 1, 1945

By G. R. Green, R. C. McDonald

The International Nickel Co., Ontario Div. mines, faced with rising production requirements, short labor supply, and ever increasing labor costs turned to mechanized mining for a solution to its problems. The degree of mechanization of ore removal has increased from 1966 with the purchase of the first diesel-powered load-haul-dump (LHD) machine to the present, with over 53% of all underground production handled by these units. Keeping pace with mechanized ore removal, there has been a parallel development of drilling equipment to complement the mucking units. This paper deals with the applications and economic advantages of mechanized drilling at the underground mines of Inco, Ontario Div. It covers the use of various types of mechanized drills in such mining methods as cut-and-fill, induced block caving, and sublevel caving. The economics of raise boring are also discussed.

Jan 1, 1974

By D. W. Reed, R. L. Reed, Tracht

Laboratory experiments on the reverse combustion of tar sands in a linear adiabatic system have shown that a highly upgraded oil can be produced from an exceedingly viscous, immobile oil. The dependence on the air-injection rate of peak temperature, combustion-zone velocity, oil recovery, air-oil ratio, residual coke and oil, fuel burned and distribution of product gases is shown graphically. Eflects of initial temperature, oxygen concentration, oil saturation and heat loss are discussed. Experiments bearing on the coking properties of heavy oils are mentioned and some results exhibited. Field application of the process hinges on the existence of adequate air permeability and the rate of reaction under reservoir conditions. INTRODUCTION It has been established that oil can be recovered from underground reservoirs by means of at least two fundamentally distinct methods involving in situ combustion of a certain fraction of the oil. Characteristic of both of these known methods is the production of oil from one or more wells by means of hot gases formed when a high-temperature reaction zone is advanced through the reservoir. In both cases, the reaction zone is created by heating certain of the wells to a sufficiently high temperature prior to the introduction of air, and the zone is maintained and advanced through the reservoir by appropriate control of the air-injection rate. In the first of these methods, which is called "forward combustion",' the combustion zone advances in a direction which is generally the same as that of the air flow; whereas in the second method, "reverse combustion",' the combustion zone moves in a direction generally opposite to that of the air flow. Forward combustion, on the one hand, is an ideal combustion process in the sense that a minimum of the most undesirable fraction of the oil is consumed as fuel in the form of coke, a clean sand is left behind and generated heat is used as efficiently as possible. However, the applicability of forward combustion is limited. Since the products of combustion, vaporized oil and connate water must flow into relatively cold regions of the reservoir, there is an upper limit on the viscosity of oil which can be moved by this process in a practical and economical fashion.' On the other hand, it is characteristic of reverse combustion that the vaporized oil and water together with the products of combustion are produced through sand which is already hot and has had its mobile liquid content eliminated. This means there is no upper limit on oil viscosity; indeed, the oil may be an entirely immobile semi-solid. However, fuel for the process is an intermediate fraction of the original oil, and the most undesirable fraction remains on the sand surface as a substantial deposit of coke. Since this coked material is not burned during reverse combustion, it represents energy which is available for the production of oil but is not used for this purpose. It follows that one can expect economics to be somewhat less attractive with reverse combustion than with forward combustion. Nevertheless, it is a process which is designed for reservoirs where forward combustion is impossible and, as such, has become a subject of experimental and theoretical investigation. In this paper, only experiments made with tar sands are discussed. DESCRIPTION OF THE PROCESS We proceed, then, to consider the process of reverse combustion in greater detail. Fig. 1 illustrates a temperature profile defining a combustion zone which moves from right to left when air flows from left to right. In Zone 1, the temperature is the initial reservoir temperature, and the tar sand is as yet unaltered. This statement must be modified to the extent that physical properties of the oil may be changed by low-temperature oxidation at reservoir temperature. As air passes into Zone 2, which has been warmed by conduction, it assists in vaporization of the very light ends (if there are any), and oxidation occurs at a significant rate. In this region, there is almost no production of carbon monoxide or carbon dioxide because predominantly addition-type reactions take place with the formation of oxygenated compounds such as aldehydes and acids together with water. The hydrocarbon-enriched and slightly oxygen-depleted gas stream enters Zone 3 where

By Erwin H. Leeman, Raymond R. Rice, Gerald L. Hassler

In the past few years a great deal of preeise information has been obtained about the relation of natural gas to oil production1. The improvement of our understanding has been of great value, both in prolonging the life of wells and in providing a much needed technical background for the legal problem of proration. But there are two principal aspects of the problem of production. It is necessary to consider not only the energy available, in the form of compressed and dissolved gas and in the pressure of driving water, but also the tenacity with which the sandstone holds the oil. The amount of oil that each sand condition will produce under given conditions of gas content should be determined. Hitherto the effect of the sand has been judged by a study of the flow of each well coupled with a procedure for extrapolating the production curve; hut, as is well known to evaluation engineers, such production curves are subject to changes that are not well understood, and often are affected by outside disturbances. On the whole, the concept of "potential production" is vague principally because the influence of the sand in production is not known beyond the simple ideas of porosity and permeability. The permeability is a quantity that has only inference value where mixtures of gas and oil or of gas, oil and water are present. Excellent studies of the production of oil from reservoirs packed with unconsolidatcd sand are available2, but these studies treat largely of small-scale analogzes to a producing field, and the conclusions to be derived from them arc necessarily of a qualitative character because it is not known in what way these miniature oil fields resemble large ones.

Jan 1, 1936

By Erwin H. Leeman, Raymond R. Rice, Gerald L. Hassler

In the past few years a great deal of preeise information has been obtained about the relation of natural gas to oil production1. The improvement of our understanding has been of great value, both in prolonging the life of wells and in providing a much needed technical background for the legal problem of proration. But there are two principal aspects of the problem of production. It is necessary to consider not only the energy available, in the form of compressed and dissolved gas and in the pressure of driving water, but also the tenacity with which the sandstone holds the oil. The amount of oil that each sand condition will produce under given conditions of gas content should be determined. Hitherto the effect of the sand has been judged by a study of the flow of each well coupled with a procedure for extrapolating the production curve; hut, as is well known to evaluation engineers, such production curves are subject to changes that are not well understood, and often are affected by outside disturbances. On the whole, the concept of "potential production" is vague principally because the influence of the sand in production is not known beyond the simple ideas of porosity and permeability. The permeability is a quantity that has only inference value where mixtures of gas and oil or of gas, oil and water are present. Excellent studies of the production of oil from reservoirs packed with unconsolidatcd sand are available2, but these studies treat largely of small-scale analogzes to a producing field, and the conclusions to be derived from them arc necessarily of a qualitative character because it is not known in what way these miniature oil fields resemble large ones.

Jan 1, 1936

By F. Osmond

When a metal (whether a simple substance, an alloy, or a compound) presents, in each of the smallest parts to which it can be redueed by mechanical division, a constant chemical composition, it is defined as chemically homogeneous. But chemical hombgeneity by no means necessitates mechanical homogeneity. There are no perfectly amorphous metals. Crystalline forces, on the one hand, and tensions or compressions, on the other band, determined by icequalities of temperature in the mass during heating or cooling, give rise in every metal to the formation of geometric elements of structure. These elements may, moreover, assume perfect crystalline forms, with their planes of cleavage; or embryonic crystalline forms, segregated in the midst of. a paste of confused organization; or pseudo-crystalline forms of expansion and contraction, like those produced in the drying of gelatinous precipitates or (most frequently) these different forms associated. 111 either case the adhesions between two adjoining structural elements, respectively homogeneous, may be very different from the interior cohesion of each of these elements. The mechanical properties of this complex aggregate cannot be simple, and, when it is submitted to strains sufficient to produce deformation, the results may be very different according to the type of structure or the manner in which it is affected by the strains. It may be fairly said that a metal does not present a single resistance to tension, or a single resistance to compression, etc., but in fact, at least theoretically, as many resistances to tension, compression, etc., as it may possess coexistent features of structure; only, in any single test, it is the weakest of the resistances involved which makes itself evident. For further explanation, let us imagine a cylinder A B (Fig. I), formed of two similar halves A and B, placed together upon their common base x y. Such a system evidently presents no resistance to axial tension, while it would resist axial compression like a single

Jan 1, 1894

By Richard W. Smith

THERE are three distinct varieties of phosphate rock, in Tennessee, known commercially as: (a) the "brown" rock, which is the residual pro- duct of the weathering and natural concentration of certain phosphatic Ordovician limestones; (b) the "blue " rock, which is an unaltered phosphatic stratum of Mississippian or Devonian age; and (c) the "white" rock, which is the result of chemical replacement and deposition. Before 1894, South Carolina and Florida had supplied most of the phosphate of the United States, South Carolina leading until that date and Florida from then until the present time. In December, 1893, the blue phosphate of Tennessee was discovered almost simultaneously on Swan Creek, in Lewis County, by two independent parties-by one as the result of a careful and systematic search for a workable deposit of the long known kidney phosphate, and by the other through mistaking it for a "bloom" of coal. Leases were taken and, with further prospecting disclosing other deposits in the region, the development progressed as rapidly as 'could be expected without railroad transportation

Jan 1, 1924

By William B. Senseman

FOR reasons well known to mining engineers, wet grinding is quite universal in plants having to do with the extraction of metallic values from crude ores. In the processing of the nonmetallic and industrial minerals, dry grinding is the more common method. The crude materials usually contain less moisture than is required for wet grinding and the products usually are marketed in dry form; most of them as powders. To grind wet, therefore, would entail the addition of water and an expense for drying the product, which is not justified. Furthermore, the material would be a dried cake that would still have to be pulverized or disintegrated before use. For producing fine products, air separators have largely replaced the earlier practice of sizing with screens and bolting reels. Mills in which the air-separating feature is an integral part of the design are now commonplace. Mill designs are many and air systems have developed along various lines, but for the purpose of this discussion, only the fundamental idea need be emphasized the idea of using air for sizing and removing pulverized material from a grinding mill. About 20 years ago, when the use of mills equipped with air separation had become common practice, heated air or gas was introduced to such a system for the removal of moisture. The purpose of this discussion is to outline the developments and trends that have followed this experiment. It is an important development, for mills equipped with air separation are now universally used for pulverizing not only nonmetallic and industrial minerals, but a great variety of other materials. All such mills are essentially the same. Dried material is pulverized, removed by an air stream, trapped in a cyclone collector, and relatively clean air from the cyclone is returned through a fan to the mill. There is no theoretical need for a vent from the system. The practical need is to vent the air that leaks into the system, and, since the cyclone is not 100 per cent efficient as a dust collector, this vented air carries some dust with it. The initial attempt. at drying was made on a system like that described, by the addition of a furnace. The minus pressure within the mill draws hot gas from the furnace. Infiltration air, along with the drying gases and evaporated moisture, is vented as before. The first application was made to a mill used for pulverizing coal. The coal contained very little moisture, so very little drying effect was needed for the success of this experiment. Actually, some calculated efficiencies of over 100 per cent were obtained before due allowance was made for the conversion of mill power into useful heat. When moisture is low,, the heat obtained from the conversion of mill power is an appreciable part of that required. That drying can be effected in the short time interval available in a grinding mill of this type is better understood by visual-

Jan 1, 1945

By M. J. Spendlove, H. W. St. Clair

The problem frequently arises, particularly in refining metals or smelting scrap metals, of separating metals in the metallie state. Many metals may be separated by taking advantage of their difference in vapor pressure. Such separations can be made at atmospheric pressure, but the separations are much more selective and can be carried out at considerably lower temperatures if the distillation is done at pressures of a few millimeters or less in an evacuated enclosure. Until recently, this has not been considered feasible as a metallurgical operation, but the recent improvemcnts that have been made in vacuum technology have broadened the applicability of vacuum processes and have prompted re-examination of low-pressurc distillation of metals as a practicable process. The distillation of zinc from lead is one separation that has already been reduced to practice.l This paper is the first of a series of studies being made on separation of nonferrous metals by distillation at low pressures. Although these experiments were confined to the separation of zinc from aluminum, the significance of the results is by no means confined to these two metals. The purpose has been to investigate a metallurgical technique rather than merely to devise a means of separating specific metals. The experimental work on distillation of zinc from zine-aluminum alloys at reduced pressure grew out of earlier work on distillation at atmospheric pressure.2 The earlier work indicated that it would not be practicable to decrease the zinc in the alloy much below 10 pct owing to the high temperature required. Therefore attention was turned to distillation ah low pressures, at which lower temperatures are required. After preliminary tests were made in a small, evacuated tube furnace, a larger furnace having a capacity of 100 to 150 Ib of metal per charge was constructed. Distillation tests were first made on pure zinc and then on aluminum-zinc alloys of various composition. Particular attention was given to the limit to which zinc could be reduced in the residual metal. Data were also taken on the rate of evaporation, and heat balances were made for both the crucible and the condenser. Distillation Furnace The vacuum-distillation unit is illustrated schematically in Fig 1. The major components are the induction furnace, the condenser, the vacuum system, and the power-conversion unit. Power is supplied to the induction furnace from a 50-kw 3000-cycle motor-driven alternator. The pressure in the furnace is reduced by a vacuum pump having a nominal pumping speed of 10 liters per sec. When in operation, the metal vapors travel upward from the furnace to the water-cooled condenser where they are collected in amounts of 50 to 100 lb. The condenser is removed with aid of an electric hoist. When the system is under vacuum, the condenser is made self-sealing by a rubber gasket between the smooth-faced, water-cooled flanges at the top of the furnace and the bottom of the condenser. The pressure of the atmosphere is more than sufficient to insure sealing. At the conclusion of an experiment, the residual metal can be removed from the furnace by removing the condenser and tilting the furnace with the electric hoist. The metal was cast into the molds carried on a mold truck. A photograph of the furnace and auxiliary equipment is shown in Fig 2. The details of the vacuum furnace are illustrated in Fig 3. The furnace proper is made vacuum-tight with rubber gaskets placed at each end of a fused quartz cylinder. A clamping plate at the bottom and a ring at the top are made to squeeze the rubber between the metal and the end of the quartz tube. A large graphite crucible placed inside the quartz cylinder is thermally insulated and physically supported by refractory insulating bricks. A thermocouple in a quartz protection tube is located at the bottom of the crucible: the leads pass through a rubber seal in the bottom plate. The supporting structure for the furnace is an angle iron frame with transite board sides. The condenser is made in the form of a water jacketed cylinder with an opening to the vacuum line at the top. The bottom has a projecting skirt inside the machined flange to provide additional cooling for the rubber gasket. Condenser sleeves are made in the form of two semicylindrical pieces of sheet metal that fit snugly inside the cooling jacket. The split sleeve facilitates removal of the condensate. Measurement of Temperatare and Pressure The metal temperature was measured by a platinum-platinilm rhodium thermocouple inserted in a well extending up into the bottom of the graphite crucible. During rapid evaporation there is a wide difference in temperature between the surface and the main body of metal in the crucible because of the large amount of heat that must be conducted to the surface to supply the heat of evaporation. The heat of

Jan 1, 1950

By Charles B. Forgan

THE Stan Trg ore body now being exploited by Trepca Mines, Ltd., originated by the metasomatic replacement of limestone and consists mainly of an intimate mixture of sulfides associated with little admixed gangue. The chief sulfides are galena, marmatite, pyrite, and pyrrhotite. Geological structure, embracing both igneous and sedimentary agencies, exerts important control on ore deposition and presents many features of great interest. Geological Formations and Intrusives Stag Trg Series-The dominant formation is the Stan Trg series, which

Jan 1, 1936

By Howard Hughes

IN drilling for water and oil to reasonable depths through the generally soft yielding clay and sand formation of the Coastal Plain of Texas, . Louisiana, and Mississippi, the rotating method of drilling was adopted, principally on account of the easy and quick penetration, and the low cost of the drilling plant. In favorable ground, free of heavy gravel and rock strata, as much as 1,000 ft. has been drilled in less than 36 hr., although such performances were of course rare. Hydraulic rotary drilling, or, as it is now called, rotary drilling, was used in the above States as early as 1880. The plant consisted of an ordinary derrick, a 25-h.p. boiler, a small hoist, a steam pump, and a water swivel with hose attachment, and an ordinary flat diamond-pointed bit. The successful drilling in of a phenomenal oil well by this process on Spindletop, near Beaumont, Texas, on Jan. 10, 1901, and the ascertained impracticability of drilling subsequent wells in the same locality by other methods (owing principally to heavy quicksand under pressure from below), brought rotary drilling into great prominence, practically to the exclusion of any other process throughout the Coastal Plain, and later on elsewhere. The method, as its name implies, involves the rotation of a pipe by means of machinery placed on the derrick floor. A drill bit attached to the lower end cuts a clearance for the drill pipe, with much the same motion and effect as an auger. Water forced through the drill pipe by means of a pump, and escaping through the bit, removes the cuttings and returns to the surface outside the drill pipe. In this manner the hole is kept open, permitting the drill stem to rotate freely. The pressure of the column of muddy water holds up the walls of the hole until it has been cased. Practically all the wells of the Gulf coast region, numbering nearly 10,000, have been drilled with this system. During the last five years its use has been extended to many other States and countries.

Jan 3, 1915

By J. J. Jakosky

The fundamental hydrodynamic principles governing the production of oil from wells have been carefully studied and evaluated by many investigators. These prior studies are quite complete and cover virtually the entire field of oil production and recovery.' One of the most important measurements in production studies is that of the bottom-hole pressure at various rates of production.2 It is the purpose of this paper to outline the technique and economics of fluid-level measurements as applied to pumping wells and to review briefly other methods for obtaining bottom-hole data. The applications of bottom-hole pressure or fluid-level measurements are based on simple hydrodynamic principles. Under equilibrium conditions, pbh = hd + pg + pch [1] when pbk = bottom-hole pressure, Ib. per sq. in. absolute, h = height of fluid in well, ft., d = average fluid density, Ib. per sq. in. per foot, p, = weight of section of gas column 1 in, square from fluid level to casinghead, Pch = casinghead pressure, Ib. per sq. in. absolute. In words, equation 1 states that the bottom-hole pressure is equal to the weight hd of the column of fluid plus the weight of the column of gas between the fluid and the casinghead plus the casinghead pressure. At moderate rates of flow, the rate of production is approximatcly proportional to the difference between the reservoir, or static bottom-hole. pressure and the flowing or producing pressure; i.e.: Q = c(pr - pbh) [2] pr = the reservoir pressure, c = the constant of proportionality. However, at production rates approaching zero and also at high rates the proportionality may break down. By combining equations 1 and 2 the

Jan 1, 1939

By J. J. Jakosky

The fundamental hydrodynamic principles governing the production of oil from wells have been carefully studied and evaluated by many investigators. These prior studies are quite complete and cover virtually the entire field of oil production and recovery.' One of the most important measurements in production studies is that of the bottom-hole pressure at various rates of production.2 It is the purpose of this paper to outline the technique and economics of fluid-level measurements as applied to pumping wells and to review briefly other methods for obtaining bottom-hole data. The applications of bottom-hole pressure or fluid-level measurements are based on simple hydrodynamic principles. Under equilibrium conditions, pbh = hd + pg + pch [1] when pbk = bottom-hole pressure, Ib. per sq. in. absolute, h = height of fluid in well, ft., d = average fluid density, Ib. per sq. in. per foot, p, = weight of section of gas column 1 in, square from fluid level to casinghead, Pch = casinghead pressure, Ib. per sq. in. absolute. In words, equation 1 states that the bottom-hole pressure is equal to the weight hd of the column of fluid plus the weight of the column of gas between the fluid and the casinghead plus the casinghead pressure. At moderate rates of flow, the rate of production is approximatcly proportional to the difference between the reservoir, or static bottom-hole. pressure and the flowing or producing pressure; i.e.: Q = c(pr - pbh) [2] pr = the reservoir pressure, c = the constant of proportionality. However, at production rates approaching zero and also at high rates the proportionality may break down. By combining equations 1 and 2 the

Jan 1, 1939

By Mark J. Klein

The precipitation of nitrogen in quenched and aged CY-35 at. pct Re was followed by internal-friction and electrical-resistivity measurements. It is shown that the precipitation kinetics of nitrogen from solution are many orders of magnitude lower in this alloy than in chromium. The reluctance of nitrogen to precipitate from sol~ction can be attributed to the composilional r-eadjustnzents required in the z.icinity of a chromium nitrade particle for gowth to occur. AS part of an investigation of the mechanism by which rhenium increases the low-temperature ductility of chromium and other Group VI-A metals, it was of interest to compare the concentration of interstitial elements retained in solution in chromium with that of a ductile Cr-Re alloy. The presence of certain interstitial elements in chromium has been shown to decrease its ductility1-5 and, of these interstitials, nitrogen is believed to have the most detrimental effect on mechanical properties. Thus, a comparison of the disposition of nitrogen in chromium with that in a ductile Cr-Re alloy might provide information about the mechanism whereby rhenium enhances the ductility of chromium. In previous internal-friction studies it was shown that the equilibrium solubilities of nitrogen in chromium and Cr-35 at. pct Re did not differ greatly.= However, results indicated that the actual concentration of nitrogen retained in solution at ambient temperatures is likely to be considerably greater in the alloy than in chromium because the precipitation kinetics of nitrogen are greatly retarded by the addition of rhenium. The objective of this investigation was to study the kinetics of nitrogen precipitation in Cr-35 at. pct Re in greater detail and to obtain information concerning the mechanism of nitrogen precipitation in this alloy. The properties studied were internal friction and

Jan 1, 1967

By Douglas M. Smith

Silver-gold ratios were studied at the Tayoltita epithermal vein deposit using channel sample, channel sample line, stope, ore body, and vein sample populations. The ratios are highly variable among individual channel samples (25:1 to greater than 500: 1) with both high and low values randomly distributed within ore bodies and veins. Whole vein ratios for the 14 most important ore producing structures range from 44: 1 to 105:1, and show zonal distribution relative to two small granitic stocks, low values closest to the intrusives. The zoned nature of the deposit suggests that the stocks, apophyses of an underlying batholith of late Eocene age, were the heat engines which powered the hydrothermal system responsible for ore deposition.

Jan 1, 1980

By Robert W. Thomas

During the past 20 years the advantages of reinforced concrete as a substitute for timbering in so-called permanent mine openings have been fully recognized, and its use has become almost general practice in the larger mines. The term "permanent mine openings" is used advisedly and is assumed to embrace such openings as ventilation shafts, material shafts and main hoisting shafts, with their adjacent stations, ore pockets, etc. In the concreting of such openings, the actual cost as compared with that of timbering has been of secondary consideration, the support of large openings, elimination of fire hazards, and prevention of interruptions to production being the primary objectives. The ultimate economy, however, of lining such openings with concrete when they are to remain in use during the entire life of the mine, and especially when they are in bad ground, will seldom be questioned. During this 20-year period there have appeared in engineering publications a number of interesting articles on the use of concrete in mines, nearly always describing some specific project of major proportions, such as the concreting of ore pockets, large stations or main hoisting shafts. Such articles are unquestionably of interest, since the projects require considerable engineering thought, not only in the method of excavating large openings, but in their engineering design as well. Concreting of main hoisting shafts, particularly when this is done with the least possible interruption to production, provides some interesting problems. The concreting of haulage drifts of the dimensions commonly found in mines, on the other hand, soon develops into a routine operation, therefore it is with some hesitancy that the author attempts to prepare an article on this subject. The writer can recall only one article on the concreting of mine haulageways, although several articles have been written concerning the concreting of tunnels considerably larger in dimensions than those required in general mine practice.' From the scarcity of articles on the subject, it would seem that the concreting of haulage drifts is still far from being considered general

Jan 1, 1937

By Louis A. Panek

Caving of previously undisturbed ground was conducted for a period of about 20 months at two locations about 600 m (2000 ft) apart in an Arizona porphyry copper deposit. When mining was suspended the width of the mined zone at both sites was on the order of one-half the depth and the thickness of ore extracted was only a fraction of the rock column. Thus the results have potential application to predicting the subsidence above a cavern-type excavation. Break cables were used to detect the upward progress of caving. Analytical aerotriangulation was used to determine the vertical and horizontal displacements of 400-plus surface targets covering a 1585 m (5200 ft) square area. The measurements are summarized and interpreted with a view to predicting the rate of rise of a caving brow, detecting the initial surface subsidence, and characterizing the extent, the location, and the varying degrees of expected damage to surface facilities.

Jan 1, 1984